The organic geochemistry of ancient sediments, part II
Chemical analysis of sediment and oil hydrocarbon content by gas chromatography and mass spectrometry to establish inception period of bio-organic evolution
MASS SPECTROMETRY↗
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Comet Gas and Dust Dynamics Modeling
This software models the gas and dust dynamics of comet coma (the head region of a comet) in order to support the Microwave Instrument for Rosetta Orbiter (MIRO) project. MIRO will study the evolution of the comet 67P/Churyumov-Gerasimenko's coma system. The instrument will measure surface temperature, gas-production rates and relative abundances, and velocity and excitation temperatures of each species along with their spatial temporal variability. This software will use these measurements to improve the understanding of coma dynamics. The modeling tool solves the equation of motion of a dust particle, the energy balance equation of the dust particle, the continuity equation for the dust and gas flow, and the dust and gas mixture energy equation. By solving these equations numerically, the software calculates the temperature and velocity of gas and dust as a function of time for a given initial gas and dust production rate, and a dust characteristic parameter that measures the ability of a dust particle to adjust its velocity to the local gas velocity. The software is written in a modular manner, thereby allowing the addition of more dynamics equations as needed. All of the numerical algorithms are added in-house and no third-party libraries are used.
Von Allmen, Paul A.↗
Hot gas in evolving galaxy clusters and groups - Implications for the microwave and X-ray backgrounds
A phenomenological model for the luminosity function of galaxy groups and clusters allows its evolution to be described in terms of the two-point galaxy correlation function. The observable properties of hot gas in virialized groups and clusters at high redshift have been computed. These include the spectral distortion by Comptonization of the cosmic blackbody spectrum, fluctuations in the cosmic microwave background arising by this same process, and the diffuse X-ray background and fluctuations therein arising from thermal emission by the intracluster gas.
Schaeffer, Richard↗
Origin and Evolution of the Saturn System
As was the case for Jupiter, Saturn formed either as a result of a gas instability within the solar nebula or the accretion of a solid core that induced an instability within the surrounding solar nebula. In either case, the protoplanet's history can be divided into three major stages: early, quasi-hydrostatic evolution (stage 1); very rapid contraction (stage 2); and late, quasi-hydrostatic contraction (stage 3). During the early history of the Saturn system, giant impact events may have catastrophically disrupted most of the original satellites of Saturn. Such disruption, followed by reaccretion, may be responsible, in part, for the occurrence of Trojans and coorbital moons in the Saturn system, the apparent presence of a stochastic component in the trend of satellite density with radial distance, and the present population of ring particles. Saturn's excess luminosity and viscous dissipation are also discussed in relation to the satellite formation.
Pollack, J. B.↗
Tuning transition metal nanoparticles on a non-traditional support via experimental design
The ability to control metal nanoparticle size and morphology on supported catalysts is crucial for optimizing catalytic performance in targeted applications. Here, this work presents a systematic approach for tuning Ni particle and crystallite size on an unconventional, low-porosity silica fume support through select thermal treatments. The catalyst was synthesized via the deposition of nickelocene onto silica fume, resulting in well-dispersed Ni nanoparticles. A face-centered central composite design was employed to systematically assess the effects of time, temperature, and sintering gas environment on metal particle growth. The results demonstrate that the sintering gas environment is the primary factor governing particle and crystallite evolution, with temperature as the next most significant influence. Nickel nanoparticles sintered at temperatures of 650 °C and above under inert conditions exhibited substantial growth and polycrystalline structures, whereas samples treated in oxidative environments formed NiO, restricting particle mobility. Minimally oxidative (500 ppm O₂) environments facilitated rapid sintering while effectively removing residual ligands from the one-step nickelocene deposition process. Extensive structural characterization via a combination of scanning transmission electron microscopy, X-ray diffraction, hydrogen temperature programmed reduction, and small-angle X-ray scattering revealed that oxidative treatments enhanced metal-support interactions, as evidenced by increased reduction temperatures and narrower particle size distributions. These findings establish quantitative relationships between sintering parameters and Ni nanoparticle characteristics, providing a framework for rational catalyst design through controlled thermal treatments. This methodology is broadly applicable to other catalytic systems and provides a quantitative foundation for catalyst design.
CVD↗
The ATTO-Campina site: A new observatory for tropical convection and gas-aerosol-cloud-precipitation interactions in the Amazon
We present results from ATTO-Campina, a new permanent observational site in central Amazon, about 4 km from the ATTO towers. Operational since 2020, ATTO-Campina characterizes atmospheric, cloud and rainfall properties through remote sensing. The goal is to provide continuous, complementary measurements to the ATTO towers, addressing the rainforest’s complex gas-aerosol-cloud-precipitation dynamics. Using a 3.5-year dataset, we classified convective clouds into three types: shallow cumulus (ShCu), congestus (Con) or (Deep) clouds. The shallow-to-deep transition takes about three hours, starting with ShCu formation at 11:00 local time. The accumulated rainfall peak follows at about 16:00. Only weak downdrafts are present in the upper troposphere where previous studies indicate new particle formation (NPF) occurrence. Strong downdrafts are mostly limited to heights below 5 km. Con and Deep convective days have higher concentrations of ultrafine aerosol and lower concentrations of accumulation-mode particles compared to ShCu. Convective clouds also significantly modify gas mixing ratios. Deep convective clouds are associated with high near-surface O3, consistent with downward transport from the midtroposphere. Our results showcase the added detail achieved by integrating data from the ATTO towers and ATTO-Campina sites. Together, these sites support better understanding of interconnected gas-aerosol-cloud-precipitation processes in the Amazon and their evolution under climate change.
54 ENVIRONMENTAL SCIENCES↗
Recent progress in atomic-scale controlled plasma processing
Atomic-scale control in plasma processing is becoming increasingly critical for fabricating of advanced semiconductor devices, particularly as the industry shifts toward three-dimensional (3D) architectures and high-aspect-ratio (HAR) structures. This review presents a comprehensive overview of recent developments in atomic-scale controlled plasma processes, organized along two key directions: the hierarchical structure of plasma–surface interactions and the generational evolution of atomic layer processing (ALP) technologies. We examined the gas phase, where molecular design enables selective generation of ions and radicals; the boundary layer, where transport phenomena govern species delivery into nanoscale features, and the surface, where temperature-dependent reactions and cyclic processing determine etching selectivity and precision. Building on this foundation, we outline five generations of ALP—from thermal atomic layer deposition to transport-aware, temporally and structurally decoupled processes—highlighting the increasing sophistication of process control. The review further explores the transition from empirical recipe development to science-based, data-driven methodologies. By integrating quantum-chemical modeling, advanced diagnostics, and machine learning, we demonstrated how predictive models can link plasma species composition to process outcomes, enabling autonomous and adaptive control strategies. Finally, this review discusses the broader societal implications of plasma process innovation through the E4 quartet: energy and resource efficiency, environmental sustainability, evolutionary advancement, and educational promotion. These principles guide the development of sustainable and intelligent atomic-scale manufacturing technologies that are not only technically advanced but also socially responsible.
Ishikawa, Kenji [Nagoya Univ. (Japan)] (ORCID:0000↗
The atmosphere of Jupiter
Jupiter atmospheric composition, gas and dust cloud formation as clues to origin and evolution of solar system
Owen, T.↗
Molecule formation in normal clouds
Some aspects of molecule formation in normal interstellar clouds, i.e., clouds having particle densities of less than 100 per cu cm, are discussed in light of recent studies. It is pointed out that, with their relatively large depletion parameter values (DPVs), CH clouds are 'young', whereas OH clouds have small DPVs and are 'old'. The theoretical reason for this is that OH, as a product of grain catalysis, persists over a much longer period of cloud evolution, whereas CH(+), CH, and CN, as products of gas-phase reaction, can be found only in 'young' clouds where depletion has not yet occurred. This may explain why OH has not been seen in radio observations of regions where CH(+), CH, and CN have been seen optically.
Aannestad, P. A.↗
Evolving force-free magnetic fields. III - States of nonequilibrium and the preflare stage
The paper considers whether a neighboring magnetostatic equilibrium exists to allow a magnetic field initially in a force-free configuration to accommodate any imposed weak pressure. The following problem is treated. The foot points of the field are fixed and the plasma is frozen into the field lines under the approximation of infinite electrical conductivity. A weak pressure is introduced. It is determined infinitesimal plasma displacements exist to adjust the field lines to a new equilibrium without changing the field line connectivity. The analysis is carried out for the bipolar force-free fields forming one of two evolutionary sequences modeling the development of the preflare stage. It was found that for the force-free field corresponding to the quasi-static stage of evolution, the neighboring magnetostatic equilibrium always exists and the imposed gas pressure can be accommodated with a slight departure of the field from being exactly force free.
Low, B. C.↗
Molecular clouds in Orion and Monoceros
A 1.2-m millimeter-wave telescope has been used to survey CO in the constellations of Orion and Monoceros. Many new molecular clouds have been found. The distribution of molecular material shows two striking characteristics: (1) Most of the molecular clouds in this region appear to be connected by continuous extensions and filaments. To judge from continuity in radial velocity, most of these connections appear to be real, and are not merely the result of projection along the line of sight; (2) There are at least two slender filamentary features longer than 10 deg in angular extent. These filaments may connect the molecular clouds lying well out of the Galactic plane to clouds lying in the plane. Their shape and orientation suggest that magnetic fields may play a role in their evolution. The observed velocity gradients may be explained by accelerated gas flow along the filament.
Morris, M.↗
Comets and the photochemistry of the paleoatmosphere
Ozone (O3) is a key atmospheric gas in considerations of the photochemistry/chemistry of the paleoatmosphere, chemical evolution, and the origin and evolution of life. The photochemistry/chemistry of atmospheric O3 in the paleoatmosphere is investigated using a one-dimensional photochemical model that includes the chemistry of oxygen, nitrogen, hydrogen, carbon, and chlorine gases. The role of cometary influx of H2O on the photochemistry of the paleoatmosphere is also examined. Recently, it has been suggested that the planet received a significant portion of the volatiles presently in the atmospheric/oceanic/biospheric system from cometary volatile influx. Several consequences of a cometary H2O influx on the photochemistry and structure of the paleoatmosphere are presented.
Levine, J. S.↗
Galactic chemical evolution and nucleocosmochronology - Standard model with terminated infall
Some exactly soluble families of models for the chemical evolution of the Galaxy are presented. The parameters considered include gas mass, the age-metallicity relation, the star mass vs. metallicity, the age distribution, and the mean age of dwarfs. A short BASIC program for calculating these parameters is given. The calculation of metallicity gradients, nuclear cosmochronology, and extinct radioactivities is addressed. An especially simple, mathematically linear model is recommended as a standard model of galaxies with truncated infall due to its internal consistency and compact display of the physical effects of the parameters.
Clayton, D. D.↗
International Halley Watch: Discipline specialists for near-nucleus studies
The purpose of the Near-Nucleus Studies Net is to study the processes taking place in the near-nucleus environment as they relate to the nature of nucleus. This is accomplisghed by measuring the spatial and temporal distribution of dust, gases and ions in the coma on high resolution images taken from many observatories around the world. By modeling the motions of discrete dust features in Comet Halley, it is often possible to determine the locations of the emission sources on the surface and learn about the nucleus structure. In addition to the general goals shared by all IHW nets, the scientific goals of the net has been to determine (1)the gross surface structure of the nucleus, (2)the nucleus spin vector, (3)the distribution and evolution of jet sources and (4)the interrelationships between the gas, dust and ion components of the coma. An additional Comet Giacobini-Zinner watch was carried out by the NNSN in support of the NASA International Cometary Explorer flyby.
Larson, S.↗
Bimodal star formation - Constraints from the solar neighborhood
The chemical evolution resulting from a simple model of bimodal star formulation is investigated, using constraints from the solar neighborhood to set the parameters of the initial mass function and star formation rate. The two modes are an exclusively massive star mode, which forms stars at an exponentially declining rate, and a mode which contains stars of all masses and has a constant star formation rate. Satisfactory agreement with the age-metallicity relation for the thin disk and with the metallicity structure of the thin-disk and spheroid stars is possible only for a small range of parameter values. The preferred model offers a resolution to several of the long-standing problems of galactic chemical evolution, including explanations of the age-metallicity relation, the gas consumption time scale, and the stellar cumulative metallicity distributions.
Wyse, Rosemary F. G.↗
FNAS: The magnetic configuration leading to solar flares
We present a method for solving plasma magnetohydrodynamic (MHD) problems arising from the interaction of plasmas with magnetic fields in stellar atmospheres. Our approach, in contrast to previous methods, is not based on solving equations for the magnetic field and plasma velocity but rather studies the evolution of the electric current and density (and the related gas pressure). We have applied the method to several studies involving linearized departures from static, current-free equilibria. The applications show explicit solutions for cases found in astrophysics and to problems encountered with earlier studies where the gas pressure was neglected. The method is particularly well suited for studying situations which involve a transition between high and low plasma-beta regions. It shows precisely how electric currents, and magnetic free-energy, build up in the plasma as a result of the slow stressing of a potential magnetic field configuration. The method also demonstrates how transverse-current waves, a mix of Alfven and magneto-acoustic modes, propagate in a low-beta plasma for any density stratification and background field geometry.
Fontenla, Juan M.↗
Star-forming galaxy models: Blending star formation into TREESPH
We have incorporated star-formation algorithms into a hybrid N-body/smoothed particle hydrodynamics code (TREESPH) in order to describe the star forming properties of disk galaxies over timescales of a few billion years. The models employ a Schmidt law of index n approximately 1.5 to calculate star-formation rates, and explicitly include the energy and metallicity feedback into the Interstellar Medium (ISM). Modeling the newly formed stellar population is achieved through the use of hybrid SPH/young star particles which gradually convert from gaseous to collisionless particles, avoiding the computational difficulties involved in creating new particles. The models are shown to reproduce well the star-forming properties of disk galaxies, such as the morphology, rate of star formation, and evolution of the global star-formation rate and disk gas content. As an example of the technique, we model an encounter between a disk galaxy and a small companion which gives rise to a ring galaxy reminiscent of the Cartwheel (AM 0035-35). The primary galaxy in this encounter experiences two phases of star forming activity: an initial period during the expansion of the ring, and a delayed phase as shocked material in the ring falls back into the central regions.
Mihos, J. Christopher↗
Relativistic hadrons and the origin of relativistic outflows in active galactic nuclei
We examine the hydrodynamic origin of relativistic outflows in active galactic nuclei (AGN). Specifically, we propose that the presence of a population of relativistic hadrons in the AGN 'central engine' and the associated neutron production suffices to produce outflows which under rather general conditions could be relativistic. The main such condition is that the size of the neutron production region be larger than the neutron flight path tau(sub n) approximately 3 x 10(exp 13) cm. This condition guarantees that the mean energy per particle in the proton fluid, resulting from the decay of the neutrons outside their production region, be greater than the proton rest mass. The expansion of this fluid can then lead naturally to a relativistic outflow by conversion of its internal energy to directed motion. We follow the development of such flows by solving the mass, energy as well as the kinetic equation for the proton gas in steady state, taking into account the source terms due to compute accurately the adiabatic index of the expanding gas, and in conjunction with Bernoulli's equation the detailed evolution of the bulk Lorentz factor. We further examine the role of large-scale magnetic fields in confining these outflows to produce the jets observed at larger scales.
Contopoulos, John↗