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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

HIAD on ULA (HULA) Orbital Reentry Flight Experiment Concept

This paper describes a proposed orbital velocity reentry flight test of a Hypersonic Inflatable Aerodynamic Decelerator (HIAD). The flight test builds upon ground development activities that continue to advance the materials, design, and manufacturing techniques for the inflatable structure and flexible thermal protection system (F-TPS) that comprise the inflatable heat shield. While certain aspects of material and system performance can be assessed using a variety of ground testing capabilities, only orbital velocity energy on a trajectory through the gradient density of the atmosphere can impart the combined aerodynamic and aeroheating design environments in real time. To achieve this at limited cost, the HIAD would be delivered to a spin-stabilized entry trajectory as a secondary payload on the Centaur stage of a United Launch Alliance (ULA) Atlas V launch vehicle. Initial trajectory studies indicate that the combination of launch vehicle capability and achievable reentry vehicle ballistic numbers make this a strategic opportunity for technology development. This 4 to 6 meter diameter scale aeroshell flight, referred to as HIAD on ULA (HULA), would also contribute to ULA asset recovery development. ULA has proposed that a HIAD be utilized as part of the Sensible, Modular, Autonomous Return Technology (SMART) initiative to enable recovery of the Vulcan launch vehicle booster main engines [1], including a Mid-Air Recovery (MAR) to gently return these assets for reuse. Whereas HULA will attain valuable aerothermal and structural response data toward advancing HIAD technology, it may also provide a largest-to-date scaled flight test of the MAR operation, which in turn would allow the examination of a nearly pristine post-entry aeroshell. By utilizing infrared camera imaging, HULA will also attain aft-side thermal response data, enhancing understanding of the aft side aerothermal environment, an area of high uncertainty. The aeroshell inflation will utilize a heritage design compressed gas system to minimize development costs. The data will be captured to both an onboard recorder and a recorder that is jettisoned and recovered separately from the reentry vehicle to mitigate risk. This paper provides an overview, including the architecture and flight concept of operations, for the proposed HULA flight experiment.

Dinonno, J. M.↗
NASA NTRS1993

Advances in Studies of Electrode Kinetics and Mass Transport in AMTEC Cells

Previous work reported from JPL has included characterization of electrode kinetics and alkali atom transport from electrodes including Mo, W, WRh x (Mn), in sodium AMTEC cells and vapor exposure cells; and Mo in potassium vapor exposure cells. These studies were generally performed in cells with small area electrodes (about 1 to 5 cm 2 ), and device geometry had little effect on transport. Alkali metal diffusion coefficients through these electrodes have been characterized, and approximate surface diffusion coefficients were derived in cases of activated transport. A basic model of electrode kinetics and transport at the alkali metal vapor/pourous metal electrode/alkali beta"-alumina solid electrolyte (BASE) three phase boundary has been proposed which accounts for electrochemical reaction rates with a collision frequency near the three phase boundary and tunneling from the porous electrode partially covered with adsorbed alkali metal atoms. The small electrode effect in AMTEC cells has been discussed in several papers, but quantitative investigations have described only the overall effect and the important contribution of electrolyte resistance. The quantitative characterization of transport losses in cells with large area electrodes has been limited to simulations of large area electrode effects, or characterization of transport losses from large area electrodes with significant longitudinal temperature gradients. This paper describes new investigations of electrochemical kinetics and transport, with four 14.4 cm 2 WPt 3.5 electrodes, including the influence of electrode size on the mass transport loss in the AMTEC cell. These electrodes exhibit very slow sintering, as well as excellent sodium transport properties, making them attractive candidates for AMTEC power conversion use. However, the facile sodium transport in WPt 3.5 electrodes makes characterization of the transport process difficult.

electrode↗
DOE OSTI2024

Understanding particle size effect on fast-charging behavior of graphite anode using ultra-thin-layer electrodes

Extreme fast charging (≤ 15 min) of lithium-ion batteries is highly desirable to accelerate mass-market adoption of electric vehicles. However, significant capacity fading, as well as safety issues due to the lithium plating caused by the fast charging rate, limit its implementation. In this study, we investigated the fast-charging capability of graphite materials with various particle sizes. To eliminate the Li + ion concentration gradient effect across the thickness of the electrode, ultra-thin-layer graphite electrodes were developed to investigate the "real" fast-charging capability of graphite at the particle level. Electrochemical assessments as well as microscopic characterizations revealed that smaller particles exhibited superior fast-charging performance, featuring enhanced capacity reversibility, faster charging rate, and less lithium plating under the same fast-charging conditions. It is shown that small-particle graphite (mean radius of 3.3 μm) could withstand a 4C charge (to 80 % state-of-charge) without plating, with minimal plating occurring at 6C. Thicker particles exhibited plating at lower C-rates. Since the experimental data could not directly explain whether intra-particle diffusion limitations or interfacial reaction limitations dominated the plating mechanism, the pseudo-2-dimensional model was used to evaluate the most likely plating mechanism. The model suggested that particle-level diffusion is the dominant mechanism contributing to plating at high rates. Finally, this work provides comprehensive insights into the particle size effects on fast-charging capability, offering a better understanding of fast-charging behavior and valuable guidance for designing optimal electrode architecture for high-rate lithium-ion batteries.

25 ENERGY STORAGE↗
NASA NTRSDate not supplied

Simulation and Modeling of Hypersonic Turbulent Boundary Layers Subject to Adverse Pressure Gradients due to Concave Streamline Curvature

Direct numerical simulations (DNS) of adverse-pressure-gradient turbulent boundary layers over a planar concave wall are presented for a nominal freestream Mach number of 5, with the objective of assessing the limitations of the currently available Reynolds-averaged Navier-Stokes (RANS) models. The wall geometry and flow conditions of the DNS are representative of the experimental data for a Mach 4.9 turbulent boundary layer that was tested on a two-dimensional planar concave wall model in the high-speed blow-down wind tunnel located at the National Aerothermochemistry Laboratory at Texas A&M University (TAMU). The DNS was validated against the experimental results of TAMU for the same flow conditions and wall geometry. An analysis of the DNS datasets was also conducted to provide an assessment of the validity of Morkovin’s hypothesis and the strong Reynolds analog for turbulence subject to mechanical nonequilibrium. In addition to the DNS results, RANS predictions are obtained by using the Baldwin-Lomax (BL), Spalart-Allmaras (SA), and the k - w SST turbulence models. The comparisons between RANS and DNS showed little impact of an adverse pressure gradient on the accuracy of these models, at least up to an incompressible Clauser pressure gradient parameter of beta(sub inc) 1.22. While the Boussinesq assumption provided reasonable predictions for the Reynolds shear stress, it failed to adequately predict the normal components of the Reynolds stress.

turbulent boundary layers↗
DOE OSTI2026

Calcium Gradient-Doped LiNi 0.5 Mn 1.5 O 4 Cathode for Long Cycle Life Lithium-Ion Batteries

High-voltage spinel LiNi 0.5 Mn 1.5 O 4 (LNMO) has attracted considerable attention as a cathode material for next-generation lithium-ion batteries due to its high operating voltage and intrinsically fast lithium-ion diffusion kinetics. However, the practical implementation of LNMO remains limited by its rapid capacity decay, primarily associated with bulk structural instability and parasitic interfacial reactions. To address these issues, we innovatively introduced calcium (Ca) as a dopant to enhance both the oxygen framework and surface stabilities of the LNMO crystal through gradient doping. Observations from the electronic microscopies, X-ray diffraction, and the elemental analysis confirmed that Ca is preferentially enriched at the particle surface, and a disordered crystal phase is preserved in the bulk in the gradient-doped LNMO cathodes. As cathodes in LIBs, the Ca gradient-doped (Ca gr) LNMO materials delivered formation capacities of ∼126−130 mAh/g and exhibited Coulombic efficiencies of 88−95%, which are consistently higher than those of the uniform-doped samples at the same doping level and undoped sample. Especially, the Ca gr 0.05 LNMO cathode demonstrated significantly improved rate capability with ∼113 mAh/g preserved at 10 C, while ∼92 mAh/g and ∼110 mAh/g for undoped and Ca uniform 0.05 LNMO, respectively, and excellent cycling stability, retaining ∼124.1 mAh/g (∼96.3% capacity retention) after 500 cycles. The analysis of cyclic voltammetry, differential capacity, and electrochemical impedance revealed that the excellent electrochemical performance is attributed to the structural and morphological advantages of gradient-doped LNMO cathodes with a disordered bulk structure for fast Li + diffusion and a Ca-enriched surface for minimizing the Mn dissolution.

25 ENERGY STORAGE↗
DOE OSTI2026

Ambient ion focusing from a field-free region to a detector: enhanced signal for explosives and drug detection with mass spectrometry

This study demonstrates ion focusing at ambient pressure and increased ion signal by creating a voltage gradient from a field-free region to a detector, thereby improving the detection of chemicals, such as explosives and drugs. At ambient pressure, ion loss and resulting signal reduction pose challenges that limit detection sensitivity in analytical instruments. Techniques to increase sensitivity, such as atmospheric flow tube-mass spectrometry (AFT-MS), extend ion-molecule reaction times but result in significant overall ion loss due to diffusion. Ion manipulation techniques, though challenging at ambient pressure, can mitigate these losses by concentrating ions toward the detector inlet. Using SIMION, ion trajectories were modeled with a voltage gradient applied between a flow tube and a detector, revealing ion focusing at ambient pressure. Experimental verification with an atmospheric flow tube employed both mass spectrometry and Faraday plate detectors to measure ion beam profiles across varying flow rates, tube diameters, and voltage gradients. Application of a voltage gradient effectively directed ions to the axial center of the flow tube, narrowed ion beam width, and increased signal intensity by 5 to 10 times compared to conditions without a voltage gradient. This ion focusing approach shows promise for improving sensitivity in ambient-pressure instruments. This technique has the potential to enhance detection levels in security and forensic applications, with particular benefits for field-portable devices used at checkpoints to identify explosives and drugs.

ambient pressure↗
NASA NTRS1973

Electromagnetic evidence concerning the lunar interior and its evolution

Reviews of the evidence for magnetization of the moon found from discovery of remanence in lunar samples, direct measurements of fields on the surface of the moon, and direct and indirect determination of fields from lunar orbit. It is shown that the evidence implies that the fields are not only local but that regional properties are found though there is still no direct evidence for a global dipole moment. Limits on the detectibility of a global dipole are given and it is shown that the strength of magnetization for reasonable thermal gradients places possible dipole moments just below the threshold of detectibility of current experiments. The hypothesis of plate magnetics is reviewed. Current ideas regarding the source of the background magnetic field presumed responsible for the magnetization are critically considered. These are the dynamo hypothesis and primordial magnetization. Consequences of both are discussed and finally the constraints placed upon the thermal evolution of the moon are considered.

Sonett, C. P.↗
NASA NTRS1975

Experiments on supersonic boundary-layer separation in three dimensions

A detailed experimental study of three-dimensional separation in supersonic flow is described. Three-dimensional wedges affixed to flat plates were used to generate the flow fields that were used to examine the relationship of cross flow to the extent of separation. Models with strong transverse pressure gradients resulted in a diminished extent of separation about the model plane of symmetry but demonstrated expansive growth of separation to a limit with distance from the plane of symmetry. A secondary flow region was found embedded in the separated flow.

Bachalo, W. D.↗
NASA NTRS1976

Influence of drag coefficient equations on particle motion calculations

An important phase of laser velocimetry investigations in gas flow fields is an analysis of the particle motion in the gas. The present paper examines three important aspects of particle motion calculations. A comparison of various drag coefficient equations with available experimental sphere drag data is made to determine the relative accuracy of the various empirical expressions available. Then, the most accurate drag coefficient equation is used to determine the limitations of Stokes drag equation for calculating relaxation lengths behind normal shocks, and percent velocity lags in one-dimensional constant velocity gradient regions. Finally, a two-dimensional constant velocity gradient gas flow field is examined to determine the importance of the coupling between the governing equations for the components of particle velocity.

Walsh, M. J.↗
NASA NTRS1981

Lean-limit extinction of propane/air mixtures in the stagnation-point flow

The extinction limits of lean propane/air mixtures in the stagnation-point flow of a flat surface were mapped as functions of the surface temperature and the mixture concentration, velocity, and temperature. The maximum flame temperatures and the flame locations were also measured. The results show that the extinction limits are extremely insensitive to the nature of the surface, which can be heated to 1000 C. On the other hand preheating the gas mixture increases the flame temperature by an almost equal amount and therefore significantly extends the extinction limits. It is also found that at extinction the maximum flame temperatures and the flame locations, which when scaled with the velocity gradient, assume almost constant values independent of the other system variables investigated.

Law, C. K.↗
NASA NTRS1984

Particle acceleration parallel and perpendicular to the magnetic field observed by DE-2

Observations by the instrument payload on DE-2 have been used to study the plasma and electrodynamic properties of the ionosphere when field-aligned currents approaching 100 microA/sq m flow at about 900-km altitude. In such a situation, it is found that the thermal ions may account for a substantial fraction of the current carriers and that the bulk of the energetic electron population has undergone a net acceleration of a few hundred electron volts. Large amplitude electrostatic waves that have a maximum near 100 Hz and an energetic ion population that shows evidence for both parallel and perpendicular acceleration to about 30 eV also accompany such events. The horizontal thermal ion drift (electric field) that accompanies these plasma phenomena has extremely large gradients over small spatial scales. Such a signature is consistent with a requirement for a large field-aligned current, and a limit to the available field-aligned potential difference that may be applied to the plasma.

Heelis, R. A.↗
NASA NTRS1989

Documentation of Two- and Three-Dimensional Hypersonic Shock Wave/Turbulent Boundary Layer Interaction Flows

Experimental data for a series of two- and three-dimensional shock wave/turbulent boundary layer interaction flows at Mach 7 are presented. Test bodies, composed of simple geometric shapes, were designed to generate flows with varying degrees of pressure gradient, boundary-layer separation, and turning angle. The data include surface-pressure and heat-transfer distributions as well as limited mean-flow-field surveys in both the undisturbed and the interaction regimes. The data are presented in a convenient form for use in validating existing or future computational models of these generic hypersonic flows.

Kussoy, Marvin I.↗
NASA NTRS1993

Three-dimensional hypersonic shock wave/turbulent boundary-layer interactions

Experimental data for a series of three-dimensional shock wave/turbulent boundary-layer interaction flows at Mach 8.2 are presented. The test bodies, composed of sharp fins fastened to a flat plate test surface, were designed to generate flows with varying degrees of pressure gradient, boundary-layer separation, and turning angle. The data include surface pressure, heat transfer, and skin friction distributions as well as limited mean flowfield surveys in both the undisturbed and interaction regimes. The data were obtained for the purpose of validating computational models of these hypersonic interactions.

Kussoy, M. I.↗
NASA NTRS1993

The structure of mass-loading shocks

A new two-fluid model which describes mass loading in the solar wind (e.g., the interaction of the solar wind with a cometary coma or the local interstellar medium) is presented. The self-consistent back-reaction of the mass-loaded ions is included through their effective scattering in low-frequency MHD turbulence and the invocation of a diffusive approximation. Such an approximation has the advantage of introducing self-consistent dissipation coefficients into the governing equations, thereby facilitating the investigation of the internal structure of shocks in mass-loading environments. To illustrate the utility of the new model, we consider the structure of cometary shocks in the hypersonic one-dimensional limit, finding that the incoming solar wind is slowed by both mass loading and the development of a large cometary ion pressure gradient. The shock is broadened and smoothed by the cometary ions with a thickness of the order of the cometary ion diffusion scale.

Zank, G. P.↗
NASA NTRS1993

Small-scale structure of O2(+) and proton hydrates in a Noctilucent Cloud and polar mesospheric summer echo of August 9/10 1991 above Kiruna

A novel mass spectrometer designed to measure simultaneously positive ion composition in the mesosphere, was successfully launched during the NLC-91 project. Instruments supporting the mass spectrometer were a probed to measure both electrons and positive ions as well as a wave propagation experiment. The location of the Noctilucent Clouds (NLC) was determined by a particle impact sensor to detect secondary electrons and ions from the impact of NLC particle. The density of proton hydrates and of the related total ions is depleted in the NLC region at 83 km. An improved detection limit of 5 x 10(exp 4)/cu m for positive ions and improved height resolution revealed for the first time large gradients in the O2(+), H(+)(H2O)2 and H(+)(H2O)6 densities within a small height range of the order of 50 m. Such gradients at the altitude of NLC and Polar Mesospheric Summer Echoes (PMSE) are associated with strong variability of mesospheric water vapor, temperature and neutral air density.

Balsiger, F.↗
NASA NTRS2016

Evaluation of Current Planetary Boundary Layer Retrieval Capabilities from Space

The PBL over land remains a significant gap in our water and energy cycle understanding from space. This work combines unique NASA satellite and model products to demonstrate the ability of current sensors (advanced IR sounding and lidar) to retrieve PBL properties and in turn their potential to be used globally to evaluate and improve weather and climate prediction models. While incremental progress has been made in recent AIRS retrieval versions, insufficient vertical resolution remains in terms of detecting PBL properties. Lidar shows promise in terms of detecting vertical gradients (and PBLh) in the lower troposphere, but daytime conditions over land remain a challenge due to noise, and their coverage is limited to approximately 2 weeks or longer return times.

AIRS↗
NASA NTRS2003

Analysis of Radial Segregation in Directionally Solidified Hg(0.89)Mn(0.11)Te

Bridgman growth experiments were performed on Hg(0.89)Mn(0.11)Te (MMT) to determine the extent of radial Manganese segregation during directional solidification. MMT crystals were directionally solidified at rates of 0.09 and 0.18 p d s and in axial thermal gradients of 83 and 68"C/cm. Wavelength Dispersive Spectroscopy (WDS) and Fourier Transform Infra-Red (FTIR) analytical techniques were used to determine the radial homogeneity in all boules and the deflection of the solid-liquid interface (SLI) in two boules that were rapidly quenched after 5 to 6 cm of directional solidification. For all growth runs, the measured radial coinpositional variations were on the order of 0.01 molar percent MnTe in the steady state region of growth. Comparison of the measured radial compositional results of the crystals to predicted values in the diffusion-limited regime indicate a strong influence of convection near the solid-liquid interface. This conclusion is supported by the weak influence of the translation rates and axial thermal gradients utilized in this study upon radial compositional homogeneity.

Price, M. W.↗
NASA NTRS2015

Analysis of Advanced Thermoelectric Materials and Their Functional Limits

The world's demand for energy is increasing dramatically, but the best energy conversion systems operate at approximately 30% efficiency. One way to decrease energy loss is in the recovery of waste heat using thermoelectric (TE) generators. A TE generator is device that generates electricity by exploiting heat flow across a thermal gradient. The efficiency of a TE material for power generation and cooling is determined by the dimensionless Figure of Merit (ZT): ZT = S(exp. 2)sigmaT/κ: where S is the Seebeck coefficient, sigma is the electrical conductivity, T is the absolute temperature, and κ is the thermal conductivity. The parameters are not physically independent, but intrinsically coupled since they are a function of the transport properties of electrons. Traditional research on TE materials has focused on synthesizing bulk semiconductor-type materials that have low thermal conductivity and high electrical conductivity affording ZT values of 1. The optimization of the σ/κ ratio is difficult to achieve using current material formats, as these material constants are complementary. Recent areas of research are focusing on using nanostructural artifacts that introduce specific dislocations and boundary conditions that scatter the phonons. This disrupts the physical link between thermal (phonon) and electrical (electron) transport. The result is that κ is decreased without decreasing σ. These material formats give ZT values of up to 2 which represent approximately 18% energy gain from waste heat recovery. The next challenge in developing the next generation of TE materials with superior performance is to tailor the interconnected thermoelectric physical parameters of the material system. In order to approach this problem, the fundamental physics of each parameter S, sigma, and κ need to be physically understood in their context of electron/phonon interaction for the construction of new high ZT thermoelectric devices. Is it possible to overcome the physical limit imposed by of the effect of phonon lattice oscillation and energetic electrons towards thermal conductivity? Is the Seebeck coefficient, based on the difference in voltage over temperature gradient ( deltaV/deltaT), an intrinsic parameter of each material? All these parameters were manipulated using nano-bridge and twin-lattice structural concepts at the NASA Langley Research Center. This talk will review the current trend of TE research to optimize the ZT and discuss about new approaches on increasing ZT within functional limits of each parameter.

Kim, Hyun Jung↗