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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Durability characterization of ceramic materials for gas turbines

The strength retention of ceramic materials during extended high-temperature cyclic exposure is critical to their widespread application in gas turbine engines. During a continuing NASA funded program initated in 1979, reaction bonded silicon nitride (RBSN), sintered silicon carbide (SSC), reaction sintered silicon carbide (RSSC), and sintered silicon nitride (SSN) materials were evaluated following simulated gas turbine engine exposures. Exposures were performed by cycling specimens five times per hour between a high velocity burner discharge and a rapid air quench. The retained flexural strengths were determined following up to 3500 hours of exposure at temperatures up to 1370 C. Post-exposure strengths have been correlated with fractography and surface examination using SEM. Results illustrate excellent strength retention of SSC materials after 3500 hours of exposure to 1370 C. At 1200 C, RBSN and RSSC also demonstrate significant strength retention. Although SSN materials typically suffer significant strength losses during exposures at 1200 C, a new composition, which has improved high-temperature strength, also shows improved durability. In the majority of the materials, strength loss is typically associated with flaw formation in the protective SiO2 layer.

Carruthers, W. D.↗

The design of an air-cooled metallic high temperature radial turbine

Recent trends in small advanced gas turbine engines call for higher turbine inlet temperatures. Advances in radial turbine technology have opened the way for a cooled metallic radial turbine capable of withstanding turbine inlet temperatures of 2500 F while meeting the challenge of high efficiency in this small flow size range. In response to this need, a small air-cooled radial turbine has been designed utilizing internal blade coolant passages. The coolant flow passage design is uniquely tailored to simultaneously meet rotor cooling needs and rotor fabrication constraints. The rotor flow-path design seeks to realize improved aerodynamic blade loading characteristics and high efficiency while satisfying rotor life requirements. An up-scaled version of the final engine rotor is currently under fabrication and, after instrumentation, will be tested in the warm turbine test facility at the NASA Lewis Research Center.

Snyder, Philip H.↗

The dynamics and stability of radiatively driven gas clouds. I - Plane-parallel slabs

A combination of numerical and analytical techniques has been used to investigate the dynamics and stability of optically thin plane-parallel radiatively driven slabs of gas confined by the thermal gas pressure of a high-temperature low-density medium. Scaling laws allow the individual model 'clouds' to be characterized by a single free parameter, chi, a normalized column density which measures the strength of the acceleration due to radiation pressure relative to that due to thermal gas pressure. It is found that these clouds are stable and coherently accelerated only when chi is small. In this regime a simple slab model is constructed which accurately reproduces the more complex gasdynamic results. The low-chi clouds are marginally able to reach the high velocities seen in the atmospheres of quasi-stellar objects, but only if their motion is subsonic with respect to the external confining medium. This implies either that the medium is extremely hot and tenuous or that it is moving outward with the clouds.

Haas, M. R.↗

Plasma-Sprayed Refractory Oxide Coatings on Silicon-Base Ceramics

Silicon-base ceramics are promising candidate materials for high temperature structural applications such as heat exchangers, gas turbines and advanced internal combustion engines. Composites based on these materials are leading candidates for combustor materials for HSCT gas turbine engines. These materials possess a combination of excellent physical and mechanical properties at high temperatures, for example, high strength, high toughness, high thermal shock resistance, high thermal conductivity, light weight and excellent oxidation resistance. However, environmental durability can be significantly reduced in certain conditions such as when molten salts, H2 or water vapor are present. The oxidation resistance of silicon-base materials is provided by SiO2 protective layer. Molten salt reacts with SiO2 and forms a mixture of SiO2 and liquid silicate at temperatures above 800C. Oxygen diffuses more easily through the chemically altered layer, resulting in a catastrophic degradation of the substrate. SiC and Si3N4 are not stable in pure H2 and decompose to silicon and gaseous species such as CH4, SiH, SiH4, N2, and NH3. Water vapor is known to slightly increase the oxidation rate of SiC and Si3N4. Refractory oxides such as alumina, yttria-stabilized zirconia, yttria and mullite (3Al2O3.2SiO2) possess excellent environmental durability in harsh conditions mentioned above. Therefore, refractory oxide coatings on silicon-base ceramics can substantially improve the environmental durability of these materials by acting as a chemical reaction barrier. These oxide coatings can also serve as a thermal barrier. The purpose of this research program has been to develop refractory oxide chemical/thermal barrier coatings on silicon-base ceramics to provide extended temperature range and lifetime to these materials in harsh environments.

Tewari, Surendra↗

Assessment of Using Ideal Gas for Predicting Boattail Flow at Cryogenic Temperatures

The applicability of using ideal gas assumptions to simulate high Reynolds number experimental data that was obtained at cryogenic temperatures is examined. Flow over an axisymmetric nozzle boattail model was calculated using reference temperatures of 117 K and 300 K and at Reynolds numbers from 50 to 200 million per meter. From the testing perspective, pressure, compression factor, and isentropic coefficients calculated using one-dimensional real gas equations are used to examine the departure of cryogenic flow from ideal gas flow across the range of temperatures and potential impacts on measured aerodynamic data. Solutions developed using ideal gas assumptions in a three-dimensional Navier-Stokes code are compared with experimental data obtained at cryogenic temperatures at two unit Reynolds numbers at freestream Mach numbers of 0.6 and 0.9. Results for several one- and two-equation turbulence models are shown. Predicted pressure coefficient distributions along the nozzle boattail differed from experimental data between 8% to less than 0.5% depending on the turbulence model and Mach number. The greatest discrepancy occurred in the level of static pressure recovery in the recompression region where the flow was separated. Solutions using warm and cryogenic freestream temperatures predicted similar boattail pressure distributions at the same unit Reynolds number.

Nozzle↗

Assessment of Using Ideal Gas for Predicting Boattail Flow at Cryogenic Temperatures

The applicability of using ideal gas assumptions to simulate high Reynolds number experimental data that was obtained at cryogenic temperatures is examined. Flow over an axisymmetric nozzle boattail model was calculated using reference temperatures of 117 K and 300 K and at Reynolds numbers from 50 to 200 million per meter. From the testing perspective, pressure, compression factor, and isentropic coefficients calculated using one-dimensional real gas equations are used to examine the departure of cryogenic flow from ideal gas flow across the range of temperatures and potential impacts on measured aerodynamic data. Solutions developed using ideal gas assumptions in a three-dimensional Navier-Stokes code are compared with experimental data obtained at cryogenic temperatures at two unit Reynolds numbers at freestream Mach numbers of 0.6 and 0.9. Results for several one- and two-equation turbulence models are shown. Predicted pressure coefficient distributions along the nozzle boattail differed from experimental data between 8% to less than 0.5% depending on the turbulence model and Mach number. The greatest discrepancy occurred in the level of static pressure recovery in the recompression region where the flow was separated. Solutions using warm and cryogenic freestream temperatures predicted similar boattail pressure distributions at the same unit Reynolds number.

Nozzle↗

Subatmospheric Brayton-cycle Engine Program Review

A solar energy powered electrical generator utilizing a Subatmospheric Brayton cycle engine is examined. The generator consists of a subatmospheric, Brayton-cycle engine and a permanent magnet (PM) alternator. The electrical power is generated by an alternator driven directly by the Brayton-cycle engine rotating group. Features that enhance reliability and performance include air foil bearings on both the Brayton-cycle engine rotating group and the PM alternator, an atmospheric-pressure solar receiver and gas-fired trim heater, and a high temperature recuperator. The subatmospheric Brayton-cycle engine design is based on that of the gas fired heat pump engine.

Johnson, R. L.↗

Advanced Materials and Fabrication Techniques for the Orion Attitude Control Motor

Rhenium, with its high melting temperature, excellent elevated temperature properties, and lack of a ductile-to-brittle transition temperature (DBTT), is ideally suited for the hot gas components of the ACM (Attitude Control Motor), and other high-temperature applications. However, the high cost of rhenium makes fabricating these components using conventional fabrication techniques prohibitive. Therefore, near-net-shape forming techniques were investigated for producing cost-effective rhenium and rhenium alloy components for the ACM and other propulsion applications. During this investigation, electrochemical forming (EL-Form ) techniques were evaluated for producing the hot gas components. The investigation focused on demonstrating that EL-Form processing techniques could be used to produce the ACM flow distributor. Once the EL-Form processing techniques were established, a representative rhenium flow distributor was fabricated, and samples were harvested for material properties testing at both room and elevated temperatures. As a lower cost and lighter weight alternative to an all-rhenium component, rhenium- coated graphite and carbon-carbon were also evaluated. The rhenium-coated components were thermal-cycle tested to verify that they could withstand the expected thermal loads during service. High-temperature electroforming is based on electrochemical deposition of compact layers of metals onto a mandrel of the desired shape. Mandrels used for electro-deposition of near-net shaped parts are generally fabricated from high-density graphite. The graphite mandrel is easily machined and does not react with the molten electrolyte. For near-net shape components, the inner surface of the electroformed part replicates the polished graphite mandrel. During processing, the mandrel itself becomes the cathode, and scrap or refined refractory metal is the anode. Refractory metal atoms from the anode material are ionized in the molten electrolytic solution, and are deposited onto the cathodic mandrel by electrochemical reduction. Rotation of the mandrel ensures uniform distribution of refractory material. The EL-Form process allows for manufacturing in an inert atmosphere with deposition rates from 0.0004 to 0.002 in./h (10.2 to 50.8 m/h). Thicknesses typically range from microns to greater than 0.5 in. (13 mm). The refractory component produced is fabricated, dependably, to within one micron of the desired tolerances with no shrinkage or distortion as in other refractory metal manufacture techniques. The electroforming process has been used to produce solid, nonporous deposits of rhenium, iridium, niobium, tungsten, and their alloys.

Gorti, Sridhar↗

Containerless high temperature property measurements by atomic fluorescence

The use of laser induced fluorescence (LIF) techniques for containerless study of high temperature processes and material properties is studied. Gas jet and electromagnetic levitation and electromagnetic and laser heating techniques are used with LIF in Earth-based containerless high temperature experiments. The work to date includes development of an apparatus and its use in studies of chemical reactions on Al2O3, molybdenum, and tungsten specimens, novel methods for noncontact specimen temperature measurement, and levitation jet properties. Brief summaries of these studies are given. The apparatus is described and detailed results for the current reporting period are presented.

Source record↗

Containerless high temperature property measurements by atomic fluorescence

Laser induced fluorescence (LIF) techniques for containerless study of high temperature processes and material properties was studied. Gas jet and electromagnetic levitation and electromagnetic and laser heating techniques are used with LIF in earth-based containerless high temperature experiments. Included are the development of an apparatus and its use in the studies of (1) chemical reactions on Al2O3, molybdenum, tungsten and LaB6 specimens, (2) methods for noncontact specimen temperature measurement, (3) levitation jet properties and (4) radiative lifetime and collisional energy transfer rates for electronically excited atoms.

Schiffman, R. A.↗

Enabling technologies research and development structures

The technology-development areas of most critical importance to the definition of the NASP vehicle's airframe and integrated propulsion systems are discussed with a view to the progress made to date and the prospects for the expansion of a definitive NASP design data base on materials, structures, etc. It is necessary to achieve a very low structural-mass fraction, to withstand 6000 F radiation equilibrium fuselage nosecap temperatures, to manage an extensive active cooling network for both airframe and propulsion system capable of dissipating 10,000 BTU/sq ft-sec thermal fluxes, to maintain effective hot-gas sealing, and to manufacture high temperature effectiveness-retaining control surfaces. An account is given of successes thus far achieved.

Davis, John G., Jr.↗

Stabilized Alumina/Ethanol Colloidal Dispersion for Seeding High Temperature Air Flows

Seeding air flows with particles to enable measurements of gas velocities via laser anemometry and/or particle image velocimetry techniques can be quite exasperating. The seeding requirements are compounded when high temperature environments are encountered and special care must be used in selecting a refractory seed material. The pH stabilization techniques commonly employed in ceramic processing are used to obtain stable dispersions for generating aerosols of refractory seed material. By adding submicron alumina particles to a preadjusted pH solution of ethanol, a stable dispersion is obtained which when atomized produces a high quality aerosol. Commercial grade alumina powder is used with a moderate size distribution. The technique is not limited to alumina/ethanol and is also demonstrated with an alumina/H2O system. Other ceramic powders in various polar solvents could also be used once the point of zero charge (pH(sub pzc)) of the powder in the solvent has been determined.

Wernet, Judith H.↗

Thermal measurements for jets in disturbed and undisturbed crosswind conditions

A direct comparison is made of the thermal field properties for a low-disturbance and a high-disturbance level condition affecting the low-temperature air jets introduced into gas turbine combustor aft sections in order both to cool the high-temperature gases and quench the combustion reactions. Sixty-four fast-response thermocouples were simultaneously sampled and corrected for their time constant effect at a downstream plane close to the jet exit. Histograms formed from independent samples were sufficiently smooth to approximate a pdf.

Wark, Candace E.↗

Compressible laminar boundary layer with real gas effects for flight conditions to M(e) = 8 and T(o) = 2500 K

One of the problems for the hypersonic flights is the lack of accurate methods for predicting the boundary layer parameters at high Mach numbers and temperatures. At high Mach numbers and temperatures, the real gas effects should be included in calculations of the compressible laminar and turbulent boundary layers. By introducing the Mangler-Levy-Lees transformation, the compressible laminar boundary layer equations were transformed into two ordinary differential equations. To solve these ordinary differential equations for the flow over a flat plate, the Runge-Kutta method of order 5 and 6 was used with a secant method of solving the simultaneous nonlinear equations for the boundary layer conditions. Instead of using the perfect gas assumptions, the properties of air in the temperature range of 100 to 2500 K at M(e) = 8 were used for the calculations. The calculations were carried out for free flight conditions. The real gas effects were significant for the conditions of high freestream Mach numbers, and the boundary layer parameters from the real gas solutions were quite different from the existing formulas and solutions.

Nagamatsu, H. T.↗

Swirling flow of a dissociated gas

Most physical applications of the swirling flow, defined as a vortex superimposed on an axial flow in the nozzle, involve high temperatures and the possibility of real gas effects. The generalized one-dimensional swirling flow in a converging-diverging nozzle is analyzed for equilibrium and frozen dissociation using the ideal dissociating gas model. Numerical results are provided to illustrate the major effects and to compare with results obtained for a perfect gas with constant ratio of specific heats. It is found that, even in the case of real gases, perfect gas calculations can give a good estimate of the reduction in mass flow due to swirl.

Wolfram, W. R., Jr.↗

Observations of the Minor Species Al and Fe in Mercury's Exosphere

We report here on the first observational evidence of Al and Fe in the exosphere of Mercury, based on measurements of resolved emission lines of these metals with Keck-1/HIRES. Al emission was observed on two separate runs, in 2008 and 2013, with tangent column densities of 3.1 +/- 1.0 and 4.0 +/-1.5 x 10(exp 7) Al atoms cm(exp - 2) at altitudes of 1185 and 1870 km (1.5 and 1.75 R(sub M). The Al radiative intensity was seen to increase where the slit crossed the planetary penumbral shadow, and then decrease monotonically with altitude. Fe emission has been observed once, in 2009, indicating an extended source. We also present observed 3- Sigma Ca(+) upper limits near Mercury's equatorial anti-solar limb, from which an abundance limit of 4.0 x 10(exp 6) cm(exp -2) at 1650 km altitude is derived for the Ca ion. A simple model for zenith column abundances of the neutral species yields 1.9 -5.2 x 10(exp 7) Al cm(exp -2) , and 8.2 x 10(exp 8) Fe cm(exp -2) . The observations appear to be consistent with production of these species by impact vaporization, with a large fraction of the Al ejecta in molecular form, and that for Fe in mixed atomic and molecular forms. The scale height of the Al gas is consistent with a kinetic temperature of 6100-8000 K. The apparent high temperature and low density of the Al gas would suggest that it may be produced by dissociation of molecules.

Mercury↗

Growth and micro structural studies on Yittria Stabilized Zirconia (YSZ) and Strontium Titanate (STO) buffer layers

Microstructure of Yittria Stabilized Zirconia (YSZ) and Strontium Titanate (STO) of radio frequency magnetron sputtered buffer layers was studied at various sputtering conditions on Si (100), Sapphire and LaAlO3 (100) substrates. The effect of substrate temperatures up to 800 C and sputtering gas pressures in the range of 50 mTorr. of growth conditions was studied. The buffer layers of YSZ and STO showed a strong tendency for columnar growth was observed above 15 mTorr sputtering gas pressure and at high substrate temperatures. Post annealing of these films in oxygen atmosphere reduced the oxygen deficiency and strain generated during growth of the films. Strong c-axis oriented superconducting YBa2Cu3O7-x (YBCO) thin films were obtained on these buffer layers using pulsed laser ablation technique. YBCO films deposited on multilayers of YSZ and STO were shown to have better superconducting properties.

Srinivas, S.↗