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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Total Temperature Measurements in Icing Cloud Flows Using a Rearward Facing Probe

This paper reports on temperature and humidity measurements from a series of ice-crystal icing tunnel experiments conducted in June 2018 at the Propulsion Systems Laboratory at the NASA Glenn Research Center. The tests were fundamental in nature and were aimed at investigating the icing processes on a two-dimensional NACA0012 airfoil subjected to artificially generated icing clouds. Prior to the tests on the airfoil, a suite of instruments, including total temperature and humidity probes, were used to characterize the thermodynamic flow and icing cloud conditions of the facility. Two different total temperature probes were used in these tests which included a custom designed rearward facing probe and a commercial self-heating total temperature probe. The rearward facing probe, the main total temperature probe, was designed to reduce and mitigate the contaminating effects of icing and ingestion of ice crystals and water droplets at the probe's inlet. The probe also serves as an air-sample inlet for a light absorption based humidity measurement. The paper includes a section which discusses total temperature and humidity measurement considerations, and another section which provides an analysis of the main probe's performance characteristics. A computational fluid dynamic model of the flow around the probe was also conducted to gain insight into the trajectory of the flow entering the probe inlet. The experiments included a series of tests in which the relative humidity of the facility flow was swept through with increasingly larger values. The data showed that the rearward facing probe can reasonably capture the flow's total temperature and humidity under mild to moderate icing conditions but produces anomalous results under more intense icing conditions. The experimental data was also compared to an in-house developed thermodynamic model which takes into account the interaction of the main flow with the icing cloud. Comparison to the thermodynamic model showed that the rearward facing probe measured the predicted trends.

Agui, Juan H.↗
NASA NTRS2022

Responses of Compound Daytime and Nighttime Warm-Dry and Warm-H Events to Individual Anthropogenic Forcings

Daytime heat is often associated with reduced soil moisture and cloud cover, while nighttime heat is connected to high humidity and increased cloud cover. Due to these differing mechanisms, compound daytime and nighttime heat events may respond differently to major anthropogenic forcings (greenhouse gases, anthropogenic aerosols, land-use and land-cover change). Here, we use GISS ModelE2.1-G historical single-forcing runs from 1955 to 2014 to examine how individual anthropogenic forcings affect compound heat events—specifically warm daytime and nighttime temperatures compounded with dry precipitation or high humidity conditions. We show that greenhouse gases alone amplify the natural frequency of warm-dry events by 1.5–5 times and warm-humid events by 2–9 times in tropical and extratropical latitudes. Conversely, aerosols and land-use/land-cover change reduce the frequency of these events, resulting in more modest increases and in some regions, declines, in the historical 'all-forcings' scenario. Individually, aerosol effects are stronger and more widespread compared to land-use, oftentimes reducing the natural frequency of these events by 60%–100%. The responses of these compound events are primarily driven by changes in daytime and nighttime temperatures through large-scale warming via greenhouse gases and cooling from aerosols and land-use/land-cover change. However, changes in warm-dry events are amplified in regions with concurrent precipitation declines (e.g. Central America, Mediterranean regions) and warm-humid events are amplified by global concurrent humidity increases. Additionally, we find differences between daytime and nighttime compound responses in the historical experiment that can be traced back to the individual forcings. In particular, aerosols produce a greater cooling effect on daytime relative to nighttime temperatures, which notably results in a historical reduction of Northern Hemisphere daytime warm-dry events relative to natural conditions. Our analysis provides a more comprehensive understanding of the significant impacts of different anthropogenic climate forcings on daytime and nighttime warm-dry and warm-humid events, informing future risk and impact assessments.

Anthropogenic forcings↗
DOE OSTI2024

Multitarget control models for building thermal comfort and indoor air quality - A critical review

The control techniques in buildings contribute significantly to thermal comfort and indoor air quality (IAQ). However, the gaps are existing for multitarget controls considering both thermal comfort and IAQ. They are: (1) both experimental and modeling control studies were conducted for thermal comfort, focusing on temperature and humidity. (2) All three (physical, grey-box, black-box) modeling approaches were investigated for temperature control. (3) Physical and grey-box modeling approach were adopted for humidity control. (4) physical models were developed for VOCs and CO2 control. (5) grey-box and black-box models were lacking for VOCs and CO2. (6) Multi-target controls were lacking for temperature, humidity and CO2s. (7) Limited studies are available for multi-target controls for temperature, humidity, and VOCs. (8) Multi-target controls are not available yet for temperature, humidity, VOCs, and CO2.

42 ENGINEERING↗
NASA NTRS1997

Temperature lapse rate and methane in Titan's troposphere

We have reanalyzed the Voyager radio occultation data for Titan, examining two alternative approaches to methane condensation. In one approach, methane condensation is facilitated by the presence of nitrogen because nitrogen lowers the condensation level of a methane/nitrogen mixture. The resulting enhancement in methane condensation lowers the upper limit on surface relative humidity of methane obtained from the Voyager occultation data from 0.7 to 0.6. We conclude that in this case the surface relative humidity of methane lies between 0.08 and 0.6, with values close to 0.6 indicated. In the other approach, methane is allowed to become supersaturated and reaches 1.4 times saturation in the troposphere. In this case, surface humidities up to 100% are allowed by the Voyager occultation data, and thus the upper limit must be set by other considerations. We conclude that if supersaturation is included, then the surface relative humidity of methane can be any value greater than 0.08--unless a deep ocean is present, in which case the surface relative humidity is limited to less than 0.85. Again, values close to 0.6 are indicated. Overall, the tropospheric lapse rate on Titan appears to be determined by radiative equilibrium. The lapse rate is everywhere stable against dry convection, but is unstable to moist convection. This finding is consistent with a supersaturated atmosphere in which condensation-and hence moist convection-is inhibited.

Methane/analysis↗
DOE OSTI2025

Surface-Enhanced Raman Detection of the CO 2 Moisture Swing

The development of scalable, energy-efficient carbon dioxide (CO 2 ) capture technologies is critical for achieving net-zero emissions. Moisture swing (MS) sorbents offer a promising alternative to traditional thermal regeneration methods by enabling reversible CO 2 binding through humidity-driven ion hydrolysis. In this study, we investigate the anion speciation dynamics in two classes of MS materials─an anion-exchange resin with a bicarbonate anion and activated carbon impregnated with potassium bicarbonate salt─using both sorption measurements and in situ surface-enhanced Raman spectroscopy (SERS). Ni-coated Ag nanowires were employed as SERS substrates to enhance signal intensity and enable the real-time detection of carbonate (CO 3 2– ), bicarbonate (HCO 3 – ), and hydroxide (OH – ) species under controlled humidity conditions in both air and nitrogen atmospheres. The results reveal humidity-dependent interconversion between anionic species with significant spectral shifts confirming the reversible hydrolysis reactions that drive the MS mechanism. Under humid conditions, we observed the depletion of bicarbonate signals and a concurrent increase in carbonate species, consistent with moisture-induced desorption of CO 2 . With the activated carbon samples, we further observed the formation of hydroxide. These findings not only validate the mechanistic models of humidity-driven anion exchange in MS sorbents but also demonstrate the practical potential of SERS as an operando diagnostic tool for monitoring CO 2 capture media. The ability to resolve and semiquantitatively evaluate the reversible transformation of carbonate, bicarbonate, and hydroxide ions under realistic environmental conditions provides valuable insight for the rational design, performance optimization, and quality control of next-generation sorbent materials for direct air capture applications.

CO2 capture↗
NASA NTRS1976

Acoustic sensor engineering evaluation test report

Two types of one-inch diameter sound pressure level sensors, which are candidates for monitoring ambient noise in the shuttle orbiter crew compartment during rest periods, were exposed to temperature, passive humidity, and vibration. One unexposed sensor of each type served as a reference unit. Except for the humidity exposures, each of the three capacitive microphones was individually tested in sequence with the essential voltage power supply and preamplifier. One unit exibited anomalous characteristics after the humidity exposure but returned to normal after being dried in an oven at 115 deg for two hours. Except for the humidity exposures, each of the three piezoelectric microphones was individually tested with a laboratory type amplifier. Two apparent failures occurred during these tests. The diaphragm on one was found ruptured after the fourth cycle of the humidity test. A second sensor showed an anomaly after the random vibration tests at which time its sensitivity was consistent at about one-half its former value.

Phillips, E. L., Jr.↗
NASA NTRS1984

Forced convection heat transfer to air/water vapor mixtures

Heat transfer coefficients were measured using both dry and humid air in the same forced convection cooling scheme and were compared using appropriate nondimensional parameters (Nusselt, Prandtl and Reynolds numbers). A forced convection scheme with a complex flow field, two dimensional arrays of circular jets with crossflow, was utilized with humidity ratios (mass ratio of water vapor to air) up to 0.23. The dynamic viscosity, thermal conductivity and specific heat of air, steam and air/steam mixtures are examined. Methods for determining gaseous mixture properties from the properties of their pure components are reviewed as well as methods for determining these properties with good confidence. The need for more experimentally determined property data for humid air is discussed. It is concluded that dimensionless forms of forced convection heat transfer data and empirical correlations based on measurements with dry air may be applied to conditions involving humid air with the same confidence as for the dry air case itself, provided that the thermophysical properties of the humid air mixtures are known with the same confidence as their dry air counterparts.

Richards, D. R.↗
NASA NTRS1985

Environmental tests of metallization systems for terrestrial photovoltaic cells

Seven different solar cell metallization systems were subjected to temperature cycling tests and humidity tests. Temperature cycling excursions were -50 deg C to 150 deg C per cycle. Humidity conditions were 70 deg C at 98% relative humidity. The seven metallization systems were: Ti/Ag, Ti/Pd/Ag, Ti/Pd/Cu, Ni/Cu, Pd/Ni/Solder, Cr/Pd/Ag, and thick film Ag. All metallization systems showed a slight to moderate decrease in cell efficiencies after subjection to 1000 temperature cycles. Six of the seven metallization systems also evidenced slight increases in cell efficiencies after moderate numbers of cycles, generally less than 100 cycles. The copper based systems showed the largest decrease in cell efficiencies after temperature cycling. All metallization systems showed moderate to large decreases in cell efficiencies after 123 days of humidity exposure. The copper based systems again showed the largest decrease in cell efficiencies after humidity exposure. Graphs of the environmental exposures versus cell efficiencies are presented for each metallization system, as well as environmental exposures versus fill factors or series resistance.

Alexander, P., Jr.↗
NASA NTRS1994

Physics of greenhouse effect and convection in warm oceans

Sea surface temperature (SST) in roughly 50% of the tropical Pacific Ocean is warm enough (SST greater than 300 K) to permit deep convection. This paper examines the effects of deep convection on the climatological mean vertical distributions of water vapor and its greenhouse effect over such warm oceans. The study, which uses a combination of satellite radiation budget observations, atmospheric soundings deployed from ships, and radiation model calculations, also examines the link between SST, vertical distribution of water vapor, and its greenhouse effect in the tropical oceans. Since the focus of the study is on the radiative effects of water vapor, the radiation model calculations do not include the effects of clouds. The data are grouped into nonconvective and convective categories using SST as an index for convective activity. On average, convective regions are more humid, trap significantly more longwave radiation, and emit more radiation to the sea surface. The greenhouse effect in regions of convection operates as per classical ideas, that is, as the SST increases, the atmosphere traps the excess longwave energy emitted by the surface and reradiates it locally back to the ocean surface. The important departure from the classical picture is that the net (up minus down) fluxes at the surface and at the top of the atmosphere decrease with an increase in SST; that is, the surface and the surface-troposphere column lose the ability to radiate the excess energy to space. The cause of this super greenhouse effect at the surface is the rapid increase in the lower-troposphere humidity with SST; that of the column is due to a combination of increase in humidity in the entire column and increase in the lapse rate within the lower troposphere. The increase in the vertical distribution of humidity far exceeds that which can be attributed to the temperature dependence of saturation vapor pressure; that is, the tropospheric relative humidity is larger in convective regions. The positive coupling between SST and the radiative warming of the surface by the water vapor greenhouse effect is also shown to exist on interannual time scales.

Inamdar, A. K.↗
NASA NTRS1994

Effect of stratification and geometrical spreading on sonic boom rise time

The purpose of our investigation is to determine the effect of unsteadiness (not associated with turbulence) on rise time. The unsteadiness considered here is due to (1) geometrical spreading, (2) stratification, which includes variation in density, temperature, and relative humidity, and (3) N shaped waveform. A very general Burgers equation, which includes all these effects, is the propagation model for our study. The equation is solved by a new computational algorithm in which all the calculations are done in the time domain. The present paper is a progress report in which some of the factors contributing to unsteadiness are studied, namely geometrical spreading and variation in relative humidity. The work of Pierce and Kang, which motivated our study, is first reviewed. We proceed with a discussion of the Burgers equation model and the algorithm for solving the equation. Some comparison tests to establish the validity of the algorithm are presented. The algorithm is then used to determine the distance required for a steady-state shock, on encountering an abrupt change in relative humidity, to reach a new steady state based on the new humidity. It is found that the transition distance for plane shocks of amplitude 70 Pa is about 4 km when the change in relative humidity is 10 percent. Shocks of amplitude 140 Pa require less distance. The effect of spherical and cylindrical spreading is also considered. We demonstrate that a spreading shock wave never reaches steady state and that its rise time will be less than the equivalent steady state shock. Finally we show that an N wave has a slightly shorter rise time than a step shock of the same amplitude.

Cleveland, Robin O.↗
NASA NTRS1994

Friction and Wear Properties of As-deposited and Carbon Ion-implanted Diamond Films

Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 ke V ion energy, resulting in a dose of 1.2310(exp 17) carbon ions/cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, x-ray photoelectron spectroscopy, and x-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40 percent relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and were properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to 10(exp -8)mm(exp 3)/N-m) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4)mm(exp 3/N-m) in ultrahigh vacuum. The carbon ion implanation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, nondiamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine- and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7)mm(exp 3/N-m). Even in ultrahigh vacuum, the presence of the nondiamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6)mm(exp 3)/N-m. Thus, the carbon ion-implanted, fine-grain diamond films can be effectively used as wear-resistant, self-lubricating coatings not only in air and dry nitrogen, but also in ultrahigh vacuum. The wear mechanism of diamond films is that of small fragments chipping off the surface. The size of wear particles is related to the extent of wear rates.

Miyoshi, Kazuhisa↗
NASA NTRS1995

Validation of clear-sky fluxes for tropical oceans from the Earth Radiation Budget Experiment

The existence and magnitude of a systematic bias in the clear-sky longwave fluxes from the Earth Radiation Budget Experiment (ERBE) is investigated. The bias is apparently introduced because the ERBE method for scene identification does not account for large zonal gradients in longwave absorption by water vapor. The ERBE fluxes are compared to fluxes calculated with a radiative transfer model from ship radiosonde measurements. The comparison is based upon an analysis of 5 yr of coincident satellite and radiosonde observations for equatorial ocean regions. The differences between the ERBE and model fluxes are examined as functions of sea surface temperature (SST) and relative humidity. The authors use height-mean relative humidity bar-RH as an index of atmospheric moisture. The average offset between and model ERBE fluxes ranges between +2 and +6 W/sq m for SSTs above 295 K, and the gradients with respect to SST are nearly identical. However, the difference between the model and ERBE depends significantly on the tropospheric relative humidity. ERBE fluxes exceed model fluxes for bar-RH above 70%, and the maximum offset of +9 to +12 W/sq m is consistent with previous estimates. There are also indications that the clear-sky fluxes for bar-RH below 25% may be underestimated by about 10-15 W/sq m. Since extreme values of height-mean humidity are relatively infrequent, the net bias introduced in the ERBE monthly mean clear-sky fluxes is generally less than the systematic error in estimates introduced in the ERBE monthly mean clear-sky fluxes is generally less than the systematic error in estimates of the instantaneous fluxes. These findings support earlier work on the coupling between SST and the atmospheric greenhouse effect, in particular the existence of a super greenhouse effect for oceans warmer than 300 K. Recent reports of much larger systematic differences are not supported by this analysis. The results indicate that comparison of general circulation model (GCM) and ERBE clear-sky longwave fluxes will depend explicitly on atmospheric humidity.

Collins, W. D.↗
NASA NTRS1996

Friction and Wear Properties of As-Deposited and Carbon Ion-Implanted Diamond Films

Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 keV ion energy, resulting in a dose of 1.2 x 10(exp 17) carbon ions per cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40% relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and wear properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to lO(exp -8) mm(exp 3) N(exp -1) m(exp -1)) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4) mm(exp 7) N(exp -1) m(exp -1)) in ultrahigh vacuum. The carbon ion implantation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, non-diamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7) mm(exp 3) N(exp -1) m(exp-1)). Even in ultrahigh vacuum, the presence of the non-diamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6) mm(exp 3) N(exp -1) m(exp -1). Thus, the carbon ion-implanted, fine-grain diamond films can be effectively used as wear-resistant, self-lubricating coatings not only in air and dry nitrogen, but also in ultrahigh vacuum.

Miyoshi, Kazuhisa↗
NASA NTRS1997

How Dry is the Tropical Free Troposphere? Implications for Global Warming Theory

The humidity of the free troposphere is being increasingly scrutinized in climate research due to its central role in global warming theory through positive water vapor feedback. This feedback is the primary source of global warming in general circulation models (GCMs). Because the loss of infrared energy to space increases nonlinearly with decreases in relative humidity, the vast dry zones in the Tropics are of particular interest. These dry zones are nearly devoid of radiosonde stations, and most of those stations have, until recently, ignored the low humidity information from the sondes. This results in substantial uncertainty in GCM tuning and validation based on sonde data. While satellite infrared radiometers are now beginning to reveal some information about the aridity of the tropical free troposphere, the authors show that the latest microwave humidity sounder data suggests even drier conditions than have been previously reported. This underscores the importance of understanding how these low humidity levels are controlled in order to tune and validate GCMs, and to predict the magnitude of water vapor feedback and thus the magnitude of global warming.

Spencer, Roy W.↗
NASA NTRS1999

Sliding Wear and Fretting Wear of DLC-Based, Functionally Graded Nanocomposite Coatings

Improving the tribological functionality of diamondlike carbon (DLC) films--developing, good wear resistance, low friction, and high load-carrying capacity-was the aim of this investigation. Nanocomposite coatings consisting of an amorphous DLC (a-DLC) top layer and a functionally graded titanium-titanium carbon-diamondlike carbon (Ti-Ti(sub x) C(sub y)-DLC) underlayer were produced on AISI 440C stainless steel substrates by the hybrid technique of magnetron sputtering and pulsed-laser deposition. The resultant DLC films were characterized by Raman spectroscopy, scanning electron microscopy, and surface profilometry. Two types of wear experiment were conducted in this investioation: sliding friction experiments and fretting wear experiments. Unidirectional ball-on-disk sliding friction experiments were conducted to examine the wear behavior of an a-DLC/Ti-Ti(sub x) C(sub y)-DLC-coated AISI 440C stainless steel disk in sliding contact with a 6-mm-diameter AISI 440C stainless steel ball in ultrahigh vacuum, dry nitrogen, and humid air. Although the wear rates for both the coating and ball were low in all three environments, the humid air and dry nitrogen caused mild wear with burnishing, in the a-DLC top layer, and the ultrahigh vacuum caused relatively severe wear with brittle fracture in both the a-DLC top layer and the Ti-Ti(sub x) C(sub y)-DLC underlayer. For reference, amorphous hydrogenated carbon (H-DLC) films produced on a-DLC/Ti-Ti(sub x) C(sub y)-DLC nanocomposite coatings by using an ion beam were also examined in the same manner. The H-DLC films markedly reduced friction even in ultrahigh vacuum without sacrificing wear resistance. The H-DLC films behaved much like the a-DLC/Ti-Ti(sub x) C(sub y)-DLC nanocomposite coating in dry nitrogen and humid air, presenting low friction and low wear. Fretting wear experiments were conducted in humid air (approximately 50% relative humidity) at a frequency of 80 Hz and an amplitude of 75 micron on an a-DLC/Ti-Ti(sub x) C(sub y)-DLC-coated AISI 440C disk and on a titanium-6 wt % aluminum-4 wt% vanadium (Ti-6Al-4V) flat, both in contact with a 9.4-mm-diameter, hemispherical Ti-6Al-4V pin. The resistance to fretting wear and damage of the a-DLC/Ti-6Al-4V materials pair was superior to that of the Ti-6Al-4V/Ti-6AI-4V materials pair.

Miyoshi, K.↗
NASA NTRS1999

Electrochemical Measurement of Atmospheric Corrosion

Corrosion of Shuttle thruster components in atmospheres containing high concentrations of nitrogen tetroxide (NTO) and water is an important issue in ground operations of bipropellant systems in humid locations. Measurements of the corrosivities of NTO-containing atmospheres and the responses of different materials to these atmospheres have been accomplished using an electrochemical sensor. The sensor is composed of alternating aluminum/titanium strips separated by thin insulating layers. Under high humidity conditions a thin film of water covers the surface of the sensor. Added NTO vapor reacts with the water film to form a conductive medium and establishes a galvanic cell. The current from this cell can be integrated with respect to time and related to the corrosion activity. The surface layer formed from humid air/NTO reacts in the same way as an aqueous solution of nitric acid. Nitric acid is generally considered an important agent in NTO corrosion situations. The aluminum/titanium sensor is unresponsive to dry air, responds slightly to humid air (> 75% RH), and responds strongly to the combination of humid air and NTO. The sensor response is a power function (n = 2) of the NTO concentration. The sensor does not respond to NTO in dry air. The response of other materials in this type of sensor is related to position of the material in a galvanic series in aqueous nitric acid. The concept and operation of this electrochemical corrosion measurement is being applied to other corrosive atmospheric contaminants such as hydrogen chloride, hydrogen fluoride, sulfur dioxide, and acidic aerosols.

DeArmond, Anna H.↗
NASA NTRS1999

Friction and Wear Properties of Selected Solid Lubricating Films

To evaluate commercially developed solid film lubricants for aerospace bearing applications, we investigated the friction and wear behavior of bonded molybdenum disulfide (MoS2), magnetron-sputtered MoS2 and ion-plated silver films in sliding contact with 6-mm-diameter American Iron and Steel Institute (AISI) 440 C stainless steel balls. Unidirectional sliding friction experiments were conducted with a load of 5.9 N (600 g), a mean Herizian contact pressure of 0.79 GPa maximum 1.19 GPa), and a sliding velocity of 0.2 m/s at room temperature in three environments: ultrahigh vacuum (7x10 (exp -7Pa)), humid air (approx. 20 percent humidity), and dry nitrogen (less than 1 percent humidity). The resultant films were characterized by scanning electron microscopy, energy-dispersive x-ray spectroscopy, and surface profilometry. Marked differences in friction and wear resulted front the environmental conditions and the film materials. The main criteria for judging the performance were coefficient of friction and wear rate, which had to be less than 0.3 and on the order of 10 (exp -6mm exp 3/Nm or less), respectively. The bonded MoS2 and magnetron-sputtered MoS2 films met the criteria in all three environments. Also, the wear rates of the counterpart AISI 440 C stainless steel balls met that criterion in all three environments. The ion-plated silver films met the criteria only in ultrahigh vacuum. In ultrahigh vacuum the bonded MoS2 films were superior. In humid air the bonded MoS2 films had higher coefficient of friction and shorter wear life than did the magnetron-sputtered MoS2 films. The ion-plated silver films had a high coefficient of friction in humid air but relatively low coefficients of friction in the nonoxidative environments. Adhesion and plastic deformation played important roles in all three environments. All sliding involved adhesive transfer of materials.

Miyoshi, Kazuhisa↗
NASA NTRS2000

Reliable, Low-Cost, Low-Weight, Non-Hermetic Coating for MCM Applications

Through an Air Force Research Laboratory sponsored STM program, reliable, low-cost, low-weight, non-hermetic coatings for multi-chip-module(MCK applications were developed. Using the combination of Sandia Laboratory ATC-01 test chips, AvanTeco's moisture sensor chips(MSC's), and silicon slices, we have shown that organic and organic/inorganic overcoatings are reliable and practical non-hermetic moisture and oxidation barriers. The use of the MSC and unpassivated ATC-01 test chips provided rapid test results and comparison of moisture barrier quality of the overcoatings. The organic coatings studied were Parylene and Cyclotene. The inorganic coatings were Al2O3 and SiO2. The choice of coating(s) is dependent on the environment that the device(s) will be exposed to. We have defined four(4) classes of environments: Class I(moderate temperature/moderate humidity). Class H(high temperature/moderate humidity). Class III(moderate temperature/high humidity). Class IV(high temperature/high humidity). By subjecting the components to adhesion, FTIR, temperature-humidity(TH), pressure cooker(PCT), and electrical tests, we have determined that it is possible to reduce failures 50-70% for organic/inorganic coated components compared to organic coated components. All materials and equipment used are readily available commercially or are standard in most semiconductor fabrication lines. It is estimated that production cost for the developed technology would range from $1-10/module, compared to $20-200 for hermetically sealed packages.

Jones, Eric W.↗