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NASA NTRS1972

Photochemistry chemical kinetics in the interstellar medium.

Gas phase processes involving interstellar molecules are considered. The primary process is photodissociation in the ambient radiation field. In obscured regions, a combination of Johnson's (1965) and Stecher's (1969) Perseus extinction curves was used to obtain the radiation field as a function of the extinction at 5,500 A. On the basis of laboratory measurements, it is concluded that the molecules of water, ammonia, methane, and formaldehyde have lifetimes less than one hundred years.

Donn, B.↗

NASA NTRS1979

Spatial distribution and broad-band spectral characteristics of the diffuse X-ray background, 0.1 - 1.0 keV

Preliminary maps covering more than 85 percent of the sky are presented for three energy bands: the B band, the C band, and the M band. The study was undertaken to find evidence that most of the diffuse X-ray background at energies less than 1 keV is local to the galaxy and that it is most probably due to thermal radiation from a low density plasma which fills a substantial fraction of interstellar space. A preliminary analysis of the data is provided including a report that most of the B and C band flux has a common origin, probably in a 10 to the 6th power K region surrounding the Sun, and that most of the M band flux does not originate from the same material.

Mccammon, D.↗

NASA NTRS1986

MID-IR emission of the interstellar medium

IRAS observations of the local interstellar medium and the galactic plane are presented; for all components, the radiation observed at 12 microns represents a large fraction of the far-IR emission. The 12/25 microns color of the diffuse IR emission of the galactic plane increases from the inner to the outer parts while the 60/100 microns ratio decreases, a color-color anticorrelation also observed for giant H II regions. The implications of these observations are discussed.

Boulanger, F.↗

NASA NTRS1991

Infrared emission from isolated dust clouds in the presence of very small dust grains

Models of the effects of small grain-generated temperature fluctuations on the IR spectrum and surface brightness of externally heated interstellar dust clouds are presently constructed on the basis of a continuum radiation transport computer code which encompasses the transient heating of small dust grains. The models assume a constant fractional abundance of large and small grains throughout the given cloud. A comparison of model results with IRAS observations indicates that the observed 12-25 micron band emissions are associated with about 10-A radius grains, while the 60-100 micron emission is primarily due to large grains which are heated under the equilibrium conditions.

Lis, Dariusz C.↗

NASA NTRS1973

Chemistry in interstellar space

The particular characteristics of chemistry in interstellar space are determined by the unique environmental conditions involved. Interstellar matter is present at extremely low densities. Large deviations from thermodynamic equilibrium are, therefore, to be expected. A relatively intense ultraviolet radiation is present in many regions. The temperatures are in the range from 5 to 200 K. Data concerning the inhibiting effect of small activation energies in interstellar clouds are presented in a table. A summary of measured activation energies or barrier heights for exothermic exchange reactions is also provided. Problems of molecule formation are discussed, taking into account gas phase reactions and surface catalyzed processes.

Donn, B.↗

NASA NTRS2002

Laboratory Studies of the Optical Properties and Condensation Processes of Cosmic Dust Particles

A laboratory facility for levitating single isolated dust particles in an electrodynamics balance has been developing at NASA/Marshall Space Flight Center for conducting a variety of experimental, of astrophysical interest. The objective of this research is to employ this innovative experimental technique for studies of the physical and optical properties of the analogs of cosmic grains of 0.2-10 micron size in a chamber with controlled pressure/temperatures simulating astrophysical environments. In particular, we will carry out three classes of experiments to investigate the microphysics of the analogs of interstellar and interplanetary dust grains. (1) Charge characteristics of micron size single dust grains to determine the photoelectric efficiencies, yields, and equilibrium potentials when exposed to UV radiation. These measurements will provide the much-needed photoelectric emission data relating to individual particles as opposed to that for the bulk materials available so far. (2) Infrared optical properties of dust particles obtained by irradiating the particles with radiation from tunable infrared diode lasers and measuring the scattered radiation. Specifically, the complex refractive indices, the extinction coefficients, the scattering phase functions, and the polarization properties of single dust grains of interest in interstellar environments, in the 1-25 micron spectral region will be determined. (3) Condensation experiments to investigate the deposition of volatile gases on colder nucleated particles in dense interstellar clouds and lower planetary atmospheres. The increase in the mass or m/q ratio due to condensation on the particle will be monitored as a function of the dust particle temperature and the partial pressure of the injected volatile gas. The measured data wild permit determination of the sticking efficiencies of volatile gases of astrophysical interest. Preliminary results based on photoelectric emission experiments on 0.2-6.6 micron size silica particles exposed to UV radiation in the 120-200 nm spectral region will be presented.

Abbas, Mian M.↗

NASA NTRS1987

Pulsar activation by the interstellar medium?

Recent work suggests that rotating magnetized neutron stars (i.e., pulsar models) trap plasma instead of emitting it. The trapping arises because nonneutral plasma can be stably trapped within such a magnetosphere provided the overall system charge is nonzero. It has been argued that particles from the interstellar medium would discharge this system, thereby presumably reactivating the system as a pulsar. However, radiation pressure either precludes such discharging (requiring an alternative source of ionization) or pulsar magnetic moments must be almost perfectly aligned with the spin axis (a revolutionary alternative). Indeed, the pulsars for which particles could reach the neutron star are those with periods of at least 3 sec. But those periods are where pulsars become inactive, not active. Conceivably, nulling might represent intermittent accretion of the interstellar medium.

Michel, F. Curtis↗

NASA NTRS2010

Polycyclic Aromatic Hydrocarbons

Carbonaceous materials play an important role in space. Polycyclic Aromatic Hydrocarbons (PAHs) are a ubiquitous component of the carbonaceous materials. PAHs are the best-known candidates to account for the IR emission bands. They are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge is to reproduce in the laboratory the physical conditions that exist in the emission and absorption interstellar zones. The harsh physical conditions of the ISM -low temperature, collisionless, strong UV radiation fields- are simulated in the laboratory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions and radicals are formed from the neutral precursors in an isolated environment at low temperature and probed with high-sensitivity cavity ringdown spectroscopy in the NUV-NIR range. Carbon nanoparticles are also formed during the short residence time of the precursors in the plasma and are characterized with time-offlight mass spectrometry. These experiments provide unique information on the spectra of large carbonaceous molecules and ions in the gas phase that can now be directly compared to interstellar and circumstellar observations (IR emission bands, DIBs, extinction curve). These findings also hold great potential for understanding the formation process of interstellar carbonaceous grains. We will review recent progress in the experimental and theoretical studies of PAHs, compare the laboratory data with astronomical observations and discuss the global implications.

Salama, Farid↗

NASA NTRS1993

Activation of extended red emission photoluminescence in carbon solids by exposure to atomic hydrogen and UV radiation

We report on new laboratory results which relate directly to the observation of strongly enhanced extended red emission (ERE) by interstellar dust in H2 photodissociation zones. The ERE has been attributed to photoluminescence by hydrogenated amorphous carbon (HAC). We are demonstrating that exposure to thermally dissociated atomic hydrogen will restore the photoluminescence efficiency of previously annealed HAC. Also, pure amorphous carbon (AC), not previously photoluminescent, can be induced to photoluminesce by exposure to atomic hydrogen. This conversion of AC into HAC is greatly enhanced by the presence of UV irradiation. The presence of dense, warm atomic hydrogen and a strong UV radiation field are characteristic environmental properties of H2 dissociation zones. Our results lend strong support to the HAC photoluminescence explanation for ERE.

Furton, Douglas G.↗

NASA NTRS1972

Interstellar medium model

A model of the ionized part of the interstellar medium was developed, based on the low frequency observations by the Radio Astronomy Explorer Satellite with a background of nonthermal radiation. This nonthermal background radiation is caused by synchrotron emission from cosmic ray electrons, and at low frequencies this emission is heavily absorbed by free-free absorption from the residual thermal electrons in the interstellar medium. By an appropriate model, parameters relevant to both the thermal and nonthermal components of the interstellar medium are shown. The observations were taken with the 100 deg dipole antenna and separated into galactic and extragalactic components. This model was developed using only the separated galactic component.

Novaco, J. C.↗

NASA NTRS1982

A reinvestigation of the rate of the C/+/ + H2 radiative association reaction

It is noted that new experimental results and statistical theories have prompted a reinvestigation of the rate coefficient of the interstellar reaction in which C(+) + H2 yields CH2(+) + h(nu) in the 10-100 K temperature range. The results presented here indicate a rate coefficient between 10 to the -16 and 10 to the -15 cu cm/s at all temperatures studied. In applying the modified thermal and phase space theories, it is expected that they will be as accurate as for radiative association as for three-body association, provided the ab initio value for the radiative decay rate is correct. It is expected that the calculated values of the rate coefficient will be accurate to within an order of magnitude and will have the correct temperature dependence.

Herbst, E.↗

NASA NTRS2012

High-Resolution and Analytical TEM Investigation of Space Radiation Processing Effects in Primitive Solar System Materials and Airless Planetary Surface Environments

Energetic ions present in the diverse plasma conditions in space play a significant role in the formation and modification of solid phases found in environments ranging from the interstellar medium (ISM) to the surfaces of airless bodies such as asteroids and the Moon. These effects are often referred to as space radiation processing, a term that encompasses changes induced in natural space-exposed materials that may be only structural, such as in radiation-induced amorphization, or may involve ion-induced nanoscale to microscale chemical changes, as occurs in preferential sputtering and ion-beam mixing. Ion sputtering in general may also be responsible for partial or complete erosion of space exposed materials, in some instances possibly bringing about the complete destruction of free-floating solid grains in the ISM or in circumstellar nebular dust clouds. We report here on two examples of the application of high-resolution and analytical transmission electron microscopy (TEM) to problems in space radiation processing. The first problem concerns the role of space radiation processing in controlling the overall fate of Fe sulfides as hosts for sulfur in the ISM. The second problem concerns the known, but as yet poorly quantified, role of space radiation processing in lunar space weathering.

Christoffersen, R.↗

NASA NTRSDate not supplied

Materials and technologies for interstellar flights and intra-galactic spread of life

Small automated spaceships are capable to deliver seeds, frozen ova and gametes to other planetary systems. A spaceship can be equipped with a freezer containing reproductive cells, an artificial uterus, a robotic nursery and school, and a collection of instruments and equipment. The whole spaceship will be frozen during a long interstellar flight. Approaching another star, a spaceship will generate electricity from light, warm up, slow down and land on a suitable planet (if any), give birth to a human, provide care and education. After schooling, the human will vacate the spaceship and either build more space for living (using local materials) or die. A vacant spaceship will supply more people, one at a time. Hopefully, they will collectively create a sustainable colony on a remote planet. Our Milky Way galaxy has hundreds billion stars (i.e., more stars than humans on Earth). Mass production of spacecrafts for intragalactic spread of life will make each spaceship cheaper, will improve employment and purposeful production on Earth, and will spread human life beyond the Solar System. If any spaceship will miss its target stellar system, it will fly to the next one, retaining ability to bring life to another planet. Which materials and technologies are needed for the interstellar life propagation? Materials age during a long interstellar flight, which can last from 10^4 to 10^10 years. We evaluate the computational methods (such as C2NEB, available from https://lib.dr.iastate.edu/ameslab_software/1) that are suitable for addressing materials aging at low temperatures and high radiation levels during the appropriately long-time scales.

Technologies↗

NASA NTRS2002

Laboratory Studies of the Optical Properties and Condensation Processes of Cosmic Dust Grains

A laboratory facility for conducting a variety of experiments on single isolated dust particles of astrophysical interest levitated in an electrodynamics balance has been developed at NASA/Marshall Space Flight Center. The objective of the research is to employ this experimental technique for studies of the physical and optical properties of individual cosmic dust grains of 0.1-100 micron size in controlled pressure/temperatures environments simulating astrophysical conditions. The physical and optical properties of the analogs of interstellar and interplanetary dust grains of known composition and size distribution will be investigated by this facility. In particular, we will carry out three classes of experiments to study the micro-physics of cosmic dust grains. (1) Charge characteristics of micron size single dust grains to determine the photoelectric efficiencies, yields, and equilibrium potentials when exposed to UV radiation. (2) Infrared optical properties of dust particles (extinction coefficients and scattering phase functions) in the 1-30 micron region using infrared diode lasers and measuring the scattered radiation. (3) Condensation experiments to investigate the condensation of volatile gases on colder nucleated particles in dense interstellar clouds and lower planetary atmospheres. The condensation experiments will involve levitated nucleus dust grains of known composition and initial mass (or m/q ratio), cooled to a temperature and pressure (or scaled pressure) simulating the astrophysical conditions, and injection of a volatile gas at a higher temperature from a controlled port. The increase in the mass due to condensation on the particle will be monitored as a function of the dust particle temperature and the partial pressure of the injected volatile gas. The measured data will permit determination of the sticking coefficients of volatile gases and growth rates of dust particles of astrophysical interest. Some preliminary results based on measurements of photoelectric emission and radiation pressure on single isolated 0.2 to 6.6 micron size silica particles exposed to UV radiation at 120-200 nm and green laser light at 532 nm are presented.

Abbas, M. M.↗

NASA NTRS1976

Gamma rays, cosmic rays and galactic structure

Working primarily from the recent SAS-2 observations of galactic gamma rays, the relation of these observations to the large scale distribution of cosmic rays and interstellar gas in the galaxy is reviewed and reexamined. Starting with a discussion of production rates, the case for pion decay being the predominant production mechanism in the galactic disk above 100 MeV is reestablished and it is also pointed out that Compton gamma rays can be a significant source. To facilitate discussion, the concepts of four distinct galactic regions are defined, viz. the nebulodisk, ectodisk, radiodisk and exodisk. Bremsstrahlung and pion decay gamma rays are associated with the first two (primarily the first) regions, and Compton gamma rays and synchrotron radiation are associated with the latter two regions. On a large scale, the cosmic rays, interstellar gas (primarily H2 clouds in the inner galaxy) and gamma ray emissivity all peak in a region between 5 and 6 kpc from the galactic center. This correlation is related to correlation with other population I phenomena and is discussed in terms of the density wave concept of galactic structure. The singular nature of the HI distribution appears to follow the supernova remnant and pulsar distributions in the galaxy.

Stecker, F. W.↗

NASA NTRS1976

Gamma-rays, cosmic rays, and galactic structure

The relation of SAS-2 observations of galactic gamma-rays to the large scale distribution of cosmic rays and interstellar gas in the galaxy is reviewed. Starting with a discussion of production rates, the case for pion decay being the predominant production mechanism in the galactic disk above 100 MeV is reestablished, and it is also pointed out that Compton gamma-rays can be a significant source near l = 0. The concepts of four distinct galactic regions are defined, viz. the nebulodisk, ectodisk, radiodisk and exodisk. Bremsstrahlung and pion decay gamma-rays are associated with the first two (primarily the first) regions, and Compton gamma-rays and synchrotron radiation are associated with the latter two regions. On a large scale, the cosmic rays, interstellar gas (primarily H2 clouds in the inner galaxy) and gamma-ray emissivity all peak between 5 and 6 kpc from the galactic center. This correlation is related to correlation with other population I phenomena and is discussed in terms of the density wave concept of galactic structure.

Stecker, F. W.↗

NASA NTRS1985

Interstellar clouds - From a dynamical perspective on their chemistry

The possibility is examined that in the course of its dynamical evolution, a single mass of interstellar gas would exhibit properties of diffuse clouds, dense clouds and finally also of clouds perturbed by shocks or intense UV or X-ray radiation generated by a star of its own creation. This concept provides a common thread through the bewildering diversity of physical and chemical compositional properties shown by interstellar clouds. From this perspective, instead of being static objects, interstellar clouds are possibly incessantly evolving from initially diffuse to later dense state and then to star formation which ultimately restructures or disperses the remaining cloud material to begin the whole evolutionary process once again. Based on a simplified study of interstellar chemistry from a dynamical perspective, the ideas are presented as an heuristic: to encourage thought on the future direction of molecular astrophysics and the need to consider the chemical behavior of interstellar clouds in conjunction with, rather than in isolation from, their dynamical behavior. A physical basis must be sought for the semiempirical temperature formula which has been given a critical role in the collapse of diffuse clouds. Self-shielding effects in the chemistry of CO were neglected and this drawback should be removed; the ability of the model to explain the fractional abundances of more complex molecules, such as cyanopolyynes, should be examined.

Prasad, S. S.↗

NASA NTRS1975

The spectral energy distribution of NGC 1275

An analysis of absolute spectral energy distributions of interstellar gas for a galaxy (NGC 1275) is presented. Infrared spectra data shows heavy reddening. It is proposed that the interstellar gas may be ionized by shock waves or by nonthermal or stellar radiation. It is suggested, that high velocity, emission-line knots are H2 regions in a Perseus cluster galaxy or intergalactic gas cloud seen in projection against NGC 1275.

Shields, G. A.↗