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At least 433 records · Page 24

A statistical study of F region ion temperatures at high latitudes based on Atmosphere Explorer C data

The ion-energy balance in the high-latitude F region was studied using 40,000 simultaneous ion-temperature and drift measurements on Atmosphere Explorer C. The large number of measurements revealed how the mean ion temperature, and the average deviation from that mean, change as a function of ion drift speed during solar-minimum conditions. It was found that, in spite of an apparent large scatter in the data, the measurements could always be reasonably explained in terms of fluctuations in the neutral dynamical properties, to which the ion energy is coupled. The results also provide evidence for increased neutral drifts as the ion E x B drift increases. Evidence for systematic ion-drag effects can also be found, on the average, for dc electric fields stronger than 60 mV/m.

St.-Maurice, J.-P.↗

Radio metric errors due to mismatch and offset between a DSN antenna beam and the beam of a troposphere calibration instrument

Two components of the error of a troposphere calibration measurement were quantified by theoretical calculations. The first component is a beam mismatch error, which occurs when the calibration instrument senses a conical volume different from the cylindrical volume sampled by a Deep Space Network (DSN) antenna. The second component is a beam offset error, which occurs if the calibration instrument is not mounted on the axis of the DSN antenna. These two error sources were calculated for both delay (e.g., VLBI) and delay rate (e.g., Doppler) measurements. The beam mismatch error for both delay and delay rate drops rapidly as the beamwidth of the troposphere calibration instrument (e.g., a water vapor radiometer or an infrared Fourier transform spectrometer) is reduced. At a 10-deg elevation angle, the instantaneous beam mismatch error is 1.0 mm for a 6-deg beamwidth and 0.09 mm for a 0.5-deg beam (these are the full angular widths of a circular beam with uniform gain out to a sharp cutoff). Time averaging for 60-100 sec will reduce these errors by factors of 1.2-2.2. At a 20-deg elevation angle, the lower limit for current Doppler observations, the beam-mismatch delay rate error is an Allan standard deviation over 100 sec of 1.1 x 10(exp -14) with a 4-deg beam and 1.3 x 10(exp -l5) for a 0.5-deg beam. A 50-m beam offset would result in a fairly modest (compared to other expected error sources) delay error (less than or equal to 0.3 mm for 60-sec integrations at any elevation angle is greater than or equal to 6 deg). However, the same offset would cause a large error in delay rate measurements (e.g., an Allan standard deviation of 1.2 x 10(exp -14) over 100 sec at a 20-deg elevation angle), which would dominate over other known error sources if the beamwidth is 2 deg or smaller. An on-axis location is essential for accurate troposphere calibration of delay rate measurements. A half-power beamwidth (for a beam with a tapered gain profile) of 1.2 deg or smaller is desired for calibration of all types of radio metrics. A water-vapor radiometer calibration beam of this size with very low sidelobes would require a clear aperture antenna with a diameter of at least 1.5 m if the primary water vapor sensing channel were in the 20-22 GHz range.

R P Linfield↗

SU-F-J-29: Dosimetric Effect of Image Registration ROI Size and Focus in Automated CBCT Registration for Spine SBRT

Purpose: Spinal stereotactic body radiotherapy (SBRT) involves highly conformal dose distributions and steep dose gradients due to the proximity of the spinal cord to the treatment volume. To achieve the planning goals while limiting the spinal cord dose, patients are setup using kV cone-beam CT (kV-CBCT) with 6 degree corrections. The kV-CBCT registration with the reference CT is dependent on a user selected region of interest (ROI). The objective of this work is to determine the dosimetric impact of ROI selection. Methods: Twenty patients were selected for this study. For each patient, the kV-CBCT was registered to the reference CT using three ROIs including: 1) the external body, 2) a large anatomic region, and 3) a small region focused in the target volume. Following each registration, the aligned CBCTs and contours were input to the treatment planning system for dose evaluation. The minimum dose, dose to 99% and 90% of the tumor volume (D99%, D90%), dose to 0.03cc and the dose to 10% of the spinal cord subvolume (V10Gy) were compared to the planned values. Results: The average deviations in the tumor minimum dose were 2.68%±1.7%, 4.6%±4.0%, 14.82%±9.9% for small, large and the external ROIs, respectively. The average deviations in tumor D99% were 1.15%±0.7%, 3.18%±1.7%, 10.0%±6.6%, respectively. The average deviations in tumor D90% were 1.00%±0.96%, 1.14%±1.05%, 3.19%±4.77% respectively. The average deviations in the maximum dose to the spinal cord were 2.80%±2.56%, 7.58%±8.28%, 13.35%±13.14%, respectively. The average deviation in V10Gy to the spinal cord were 1.69%±0.88%, 1.98%±2.79%, 2.71%±5.63%. Conclusion: When using automated registration algorithms for CBCT-Reference alignment, a small target-focused ROI results in the least dosimetric deviation from the plan. It is recommended to focus narrowly on the target volume to keep the spinal cord dose below tolerance.

60 APPLIED LIFE SCIENCES↗

The Evolving Polarized Jet of Black Hole Candidate Swift J1745-26

Swift J1745−26 is an X-ray binary towards the Galactic Centre that was detected when it went into outburst in September 2012. This source is thought to be one of a growing number of sources that display "failed outbursts", in which the self-absorbed radio jets of the transient source are never fully quenched and the thermal emission from the geometrically-thin inner accretion disk never fully dominates the X-ray flux. We present multifrequency data from the Very Large Array, Australia Telescope Compact Array and Karoo Array Telescope (KAT- 7) radio arrays, spanning the entire period of the outburst. Our rich data set exposes radio emission that displays a high level of large scale variability compared to the X-ray emission and deviations from the standard radio-X-ray correlation that are indicative of an unstable jet and confirm the outburst's transition from the canonical hard state to an intermediate state. We also observe steepening of the spectral index and an increase of the linear polarization to a large fraction (is approx. equal to 50%) of the total flux, as well as a rotation of the electric vector position angle. These are consistent with a transformation from a self-absorbed compact jet to optically-thin ejecta - the first time such a discrete ejection has been observed in a failed outburst - and may imply a complex magnetic field geometry.

black↗

Extension of structure-reactivity correlations for the hydrogen abstraction reaction by bromine atom and comparison to chlorine atom and hydroxyl radical

Recently we presented structure-reactivity correlations for the gas-phase ambient-temperature rate constants for hydrogen abstraction from sp 3 -hybridized carbon by chlorine atom and hydroxyl radical (Cl•/HO• + HCR 3 → HCl/HOH + •CR 3 ); the reaction enthalpy effect was represented by the independent variable Δ r H and the polar effect by the independent variables F and R, the Hammett constants for field/inductive and resonance effects. Both these reactions are predominantly exothermic and have early transition states. Here we present a parallel treatment for Br• whose reaction is significantly endothermic with a correspondingly late transition state. In spite of lower expectations because the available data base is less extensive and much more scattered and because long temperature extrapolations are often required, the resulting least-squares fit (log k 298,Br = –0.147 Δ r H –4.32 ΣF –4.28 ΣR –12.38 with r 2 = 0.92) was modestly successful and useful for initial predictions. The coefficient of Δ r H was ~4-fold greater, indicative of the change from an early to a late transition state; meanwhile the sizable coefficients of ΣF and ΣR indicate the persistence of the polar effect. Although the mean unsigned deviation of 0.79 log k 298 units is rather large, it must be considered in the context of a total span of over 15 log units in the data set. Lastly, the major outliers are briefly discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Unveiling the structure and electronic characteristics of amorphous GeS for high performance threshold switching

Ovonic threshold switching selectors are widely studied owing to the essential application in high density phase-change memory. Amorphous GeS is proposed as a potential candidate for the excellent performance. However, the knowledge of amorphous GeS is still insufficient up to date. Here, we have studied the structure and electronic characteristics of GeS in the amorphization process, by using ab initio molecular dynamics simulations. The results indicate that the amorphous GeS is mainly made up of Ge–S bonds. The Ge- and S-centered clusters are dominantly in the form of octahedral structures in liquid GeS. Furthermore, during the amorphization process, most of Ge-centered clusters become highly coordinated octahedrons while a small number of Ge-centered clusters change to tetrahedrons, and the S-centered clusters deviate from the octahedral structure gradually. In addition, the large bandgap and the relatively small mid-gap states in amorphous GeS lead to a high switching voltage.

42 ENGINEERING↗

Spinodal backreaction during inflation and initial conditions

We investigate how long wavelength inflationary fluctuations can cause the background field to deviate from classical dynamics. For generic potentials, we show that, in the Hartree approximation, the long wavelength dynamics can be encapsulated by a two-field model operating in an effective potential. The latter is given by a simple Gaussian integral transformation of the original inflationary potential. We use this new expression to study backreaction effects in quadratic, hilltop, flattened, and axion monodromy potentials. We find that the net result of the altered dynamics is to slightly modify the spectral tilt, drastically decrease the tensor-to-scalar ratio, and to effectively smooth over any features of the potential, with the size of these deviations set by the initial value of power in large scale modes and the shape of the potential during the entire evolution.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The Atacama Cosmology Telescope: Large-scale velocity reconstruction with the kinematic Sunyaev-Zel'dovich effect and DESI LRGs

The kinematic Sunyaev-Zel'dovich (kSZ) effect induces a non-zero density-density-temperature bispectrum, which we can use to reconstruct the large-scale velocity field from a combination of cosmic microwave background (CMB) and galaxy density measurements, in a procedure known as “kSZ velocity reconstruction”. This method has been forecast to constrain large-scale modes with future galaxy and CMB surveys, improving their measurement beyond what is possible with the galaxy surveys alone. Such measurements will enable tighter constraints on large-scale signals such as primordial non-Gaussianity, deviations from homogeneity, and modified gravity. In this work, we demonstrate a statistically significant measurement of kSZ velocity reconstruction for the first time, by applying quadratic estimators to the combination of the ACT DR6 CMB+kSZ map and the DESI LRG galaxies (with photometric redshifts) in order to reconstruct the velocity field. We do so using a formalism appropriate for the 2-dimensional projected galaxy fields that we use, which naturally incorporates the curved-sky effects important on the largest scales. We find evidence for the signal by cross-correlating with an external estimate of the velocity field from the spectroscopic BOSS survey and rejecting the null (no-kSZ) hypothesis at 3.8σ. Our work presents a first step towards the use of this observable for cosmological analyses.

Sunyaev-Zeldovich effect↗

The primordial matter power spectrum on sub-galactic scales

The primordial matter power spectrum quantifies fluctuations in the distribution of dark matter immediately following inflation. Over cosmic time, overdense regions of the primordial density field grow and collapse into dark matter haloes, whose abundance and density profiles retain memory of the initial conditions. By analysing the image magnifications in 11 strongly lensed and quadruply imaged quasars, we infer the abundance and concentrations of low-mass haloes, and cast the measurement in terms of the amplitude of the primordial matter power spectrum. We anchor the power spectrum on large scales, isolating the effect of small-scale deviations from the Lambda cold dark matter (ΛCDM) prediction. Assuming an analytic model for the power spectrum and accounting for several sources of potential systematic uncertainty, including three different models for the halo mass function, we obtain correlated inferences of $\log _{10}\left(P / P_{\Lambda \rm {CDM}}\right)$, the power spectrum amplitude relative to the predictions of the concordance cosmological model, of $0.0_{-0.4}^{+0.5}$, $0.1_{-0.6}^{+0.7}$, and $0.2_{-0.9}^{+1.0}$ at k = 10, 25, and 50 $\rm {Mpc^{-1}}$ at $68 {{\ \rm per\ cent}}$ confidence, consistent with CDM and single-field slow-roll inflation.

79 ASTRONOMY AND ASTROPHYSICS↗

Frequency Control Support of a Doubly-Fed Induction Generator Based on the Torque Limit

This paper proposes a torque limit-based inertial control scheme of a doubly-fed induction generator (DFIG) that supports the frequency control of a power system. If a frequency deviation occurs, the proposed scheme aims to release a large amount of kinetic energy (KE) stored in the rotating masses of a DFIG to raise the frequency nadir (FN). Upon detecting the event, the scheme instantly increases its output to the torque limit and then reduces the output with the rotor speed so that it converges to the stable operating range. To restore the rotor speed while causing a small second frequency dip (SFD), after the rotor speed converges the power reference is reduced by a small amount and maintained until it meets the reference for maximum power point tracking control. The test results demonstrate that the scheme can improve the FN and maximum rate of change of frequency while causing a small SFD in any wind conditions and in a power system that has a high penetration of wind power, and thus the scheme helps maintain the required level of system reliability. The scheme releases the KE from 2.9 times to 3.7 times the Hydro-Quebec requirement depending on the power reference.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Technical Note: Dosimetric effects of couch position variability on treatment plan quality with an MRI-guided Co-60 radiation therapy machine

Purpose: Magnetic resonance imaging (MRI) guidance in radiation therapy brings real-time imaging and adaptive planning into the treatment vault where it can account for interfraction and intrafraction movement of soft tissue. The only commercially available MRI-guided radiation therapy device is a three-head {sup 60}Co and MRI system with an integrated treatment planning system (TPS). Couch attenuation of the beam of up to 20% is well modeled in the TPS. Variations in the patient’s day-to-day position introduce discrepancies in the actual couch attenuation as modeled in the treatment plan. For this reason, the authors’ institution avoids plans with beams that pass through or near the couch edges. This study investigates the effects of differential beam attenuation by the couch due to couch shifts in order to determine whether couch edge avoidance restrictions can be lifted. Couch shifts were simulated using a Monte Carlo treatment planning system and ion chamber measurements performed for validation. Methods: A total of 27 plans from 23 patients were investigated. Couch shifts of 1 and 2 cm were introduced in combinations of lateral and vertical directions to simulate patient position variations giving 16 shifted plans per reference plan. The 1 and 2 cm shifts were based on shifts recorded in 320 treatment fractions. Results: Following TG176 recommendations for measurement methods, couch attenuation measurements agreed with TPS modeled attenuation to within 2.1%. Planning target volume D95 changed less than 1% for 1 and 2 cm couch shifts in only the x-direction and less than 3% for all directions. Conclusions: Dosimetry of all plans tested was robust to couch shifts up to ±2 cm. In general, couch shifts resulted in clinically insignificant dosimetric deviations. It is conceivable that in certain cases with large systematic couch shifts and plans that are particularly sensitive to shifts, dosimetric changes might rise to a clinically significant level.

60 APPLIED LIFE SCIENCES↗

Search for pair production of scalar leptoquarks decaying into first- or second-generation leptons and top quarks in proton–proton collisions at $\sqrt{s}$ = 13 TeV with the ATLAS detector

A search for pair production of scalar leptoquarks, each decaying into either an electron or a muon and a top quark, is presented. This is the first leptoquark search using ATLAS data to investigate top-philic cross-generational couplings that could provide explanations for recently observed anomalies in B meson decays. This analysis targets high leptoquark masses which cause the decay products of each resultant top quark to be contained within a single high-p T large-radius jet. The full Run 2 dataset is exploited, consisting of 139 fb -1 of data collected from proton–proton collisions at √s=13 TeV from 2015 to 2018 with the ATLAS detector at the CERN Large Hadron Collider. In the absence of any significant deviation from the background expectation, lower limits on the leptoquark masses are set at 1480 GeV and 1470 GeV for the electron and muon channel, respectively.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Skylab altimeter observations over terrain

The author has identified the following significant results. Data obtained by Skylab radar altimeter (S193) over the continental U.S.A. for pass 1 of SL-3 were analyzed to relate radar return signal parameters such as range, power, and waveform to ground track terrain features. The altimeter, which was originally designed for ocean observations, performed predictably well over terrain with moderate to low relief. The maximum return from more complex areas corresponded usually to the lower flatter regions within the seven kilometer diameter footprint. Altimeter measured heights correlated with map topography with an rms deviation of + or - 30 m for terrain topography with large height dispersion (passes 1 and 28) and + or - 5 m for slowly varying terrain (passes 16, 17, and 18). Analysis of the waveform and statistical characteristics of the individual signals indicated that larger signal power was usually related to dominantly specular reflections from patches 100 m or larger. Results established the capability of a spacecraft altimeter system to observe characteristic radar signatures for different types of terrain within the bandwidth restrictions of the AGC and range tracker loops.

Shapiro, A.↗

Gradients of meteorological parameters in convective and nonconvective areas

Horizontal gradients of geopotential height, temperature, and wind speed were computed at the 850-, 700-, 500-, and 200-mb levels. Mixing ratio gradients also were computed, but only for the 850-, 700-, and 500-mb levels. Rawinsonde data was provided at 3- to 6-h intervals. Cumulative frequency distributions and statistical parameters showed that the variability and magnitude of the gradients decreased as the gradients were computed over progressively longer distances. Most frequency distributions were positively skewed, and the standard deviations of the gradient distributions were roughly half as large as the means. An examination of the differences of gradients observed in convective and nonconvective areas was made after convective areas were determined objectively using Manually Digitized Radar data. The gradients of height, wind speed, and mixing ratio at 850 mb were larger in convective than nonconvective areas. No general relationship held for the meteorological variables at other levels. Intensive examination of the gradients observed near squall lines revealed typical gradient patterns and trends in the magnitudes of the gradients associated with convective systems.

Mccown, M. S.↗

Monodisperse Latex Reactor (MLR): A materials processing space shuttle mid-deck payload

The monodisperse latex reactor experiment has flown five times on the space shuttle, with three more flights currently planned. The objectives of this project is to manufacture, in the microgravity environment of space, large particle-size monodisperse polystyrene latexes in particle sizes larger and more uniform than can be manufactured on Earth. Historically it has been extremely difficult, if not impossible to manufacture in quantity very high quality monodisperse latexes on Earth in particle sizes much above several micrometers in diameter due to buoyancy and sedimentation problems during the polymerization reaction. However the MLR project has succeeded in manufacturing in microgravity monodisperse latex particles as large as 30 micrometers in diameter with a standard deviation of 1.4 percent. It is expected that 100 micrometer particles will have been produced by the completion of the the three remaining flights. These tiny, highly uniform latex microspheres have become the first material to be commercially marketed that was manufactured in space.

Kornfeld, D. M.↗

Use of a Stanton Tube for Skin-Friction Measurements

A small total-pressure tube resting against a flat-plate surface was used as a Stanton tube and calibrated as a skin-friction meter at various subsonic and supersonic speeds. Laminar flow was maintained for the supersonic runs at a Mach number M(sub infinity) of 2. At speeds between M(sub infinity) = 1.33 and M(sub infinity) = 1.87, the calibrations were carried-out in a turbulent boundary layer. The subsonic flows were found to be in transition. The skin-friction readings of a floating-element type of balance served as the reference values against which the Stanton tube was calibrated. A theoretical model was developed which, for moderate values of the shear parameter tau, accurately predicts the performance of the Stanton tube in subsonic and supersonic flows. A "shear correction factor" was found to explain the deviations from the basic model when T became too large. Compressibility effects were important only in the case of turbulent supersonic flows, and they did not alter the form of the calibration curve. The test Reynolds numbers, based on the distance from the leading edge and free-stream conditions, ranged from 70,000 to 875,000. The turbulent-boundary-layer Reynolds numbers, based on momentum thickness, varied between 650 and 2,300. Both laminar and turbulent velocity profiles were taken and the effect of pressure gradient on the calibration was investigated.

Abarbanel, S. S.↗

Approaching the basis set limit for DFT calculations using an environment-adapted minimal basis with perturbation theory: Formulation, proof of concept, and a pilot implementation

Recently developed density functionals have good accuracy for both thermochemistry (TC) and non-covalent interactions (NC) if very large atomic orbital basis sets are used. To approach the basis set limit with potentially lower computational cost, a new self-consistent field (SCF) scheme is presented that employs minimal adaptive basis (MAB) functions. The MAB functions are optimized on each atomic site by minimizing a surrogate function. High accuracy is obtained by applying a perturbative correction (PC) to the MAB calculation, similar to dual basis approaches. Compared to exact SCF results, using this MAB-SCF (PC) approach with the same large target basis set produces <0.15 kcal/mol root-mean-square deviations for most of the tested TC datasets, and <0.1 kcal/mol for most of the NC datasets. The performance of density functionals near the basis set limit can be even better reproduced. With further improvement to its implementation, MAB-SCF (PC) is a promising lower-cost substitute for conventional large-basis calculations as a method to approach the basis set limit of modern density functionals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Large Hyperfine Coupling Arising from Pseudo- 2 S Ground States in a Series of Lutetium(II) Metallocene Complexes

The synthesis of molecules with strong coupling between electronic and nuclear spins represents an important challenge in molecular quantum information science. Here, we report the synthesis and characterization of the divalent lutetium metallocene complexes Lu(Cp Me 5 )(Cp iPr 5 ) (Cp Me 5 = pentamethylcyclopentadienyl; Cp iPr 5 = pentaisopropylcyclopentadienyl), Lu(Cp iPr 4 Et ) 2 (Cp iPr 4 Et = ethyltetraisopropylcyclopentadienyl), and Lu(Cp iPr 4 ) 2 (Cp iPr 4 = tetraisopropylcyclopentadienyl). The molecular structures of these complexes, as determined through singlecrystal X-ray diffraction, feature a common bent sandwich geometry, with average Cp–Lu–Cp angles ranging from 159.9° to 152.6°. Analysis of continuous-wave electron paramagnetic resonance (EPR) spectra for the complexes reveals nearly isotropic g tensors with only a slight deviation from that of a free electron. Moreover, an extremely large splitting of the eight-line spectra indicates the presence of strong hyperfine coupling, and simulations provide isotropic hyperfine coupling constants of A iso = 4.38, 4.30, and 4.17 GHz across the series, where the value of A iso is found to decrease as the Cp–Lu–Cp angle becomes more acute. Notably, these values are the largest yet observed for any lanthanide complex. Moreover, EPR and computational analysis show that the large values of A iso stem from large s-orbital character up to 41.2% in the corresponding singly occupied molecular orbitals. To our knowledge, this degree of s-character in a molecular orbital is the largest yet reported for an open-shell isolable complex. These results outline a general strategy toward the isolation of paramagnetic molecules with strong hyperfine coupling and highly isotropic doublet electronic ground states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗