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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1995

Reflectance spectroscopy of ferric sulfate-bearing montmorillonites as Mars soil analog materials

Spectroscopic analyses have shown that smectites enhanced in the laboratory with additional ferric species exhibit important similarities to those of the soils on Mars. Ferrihydrite in these chemically treated smectites has features in the visible to near-infrared region that resemble the energies and band strengths of features in reflectance spectra observed for several bright regions on Mars. New samples have been prepared with sulfate as well, because S was found by Viking to be a major component in the surface material on Mars. A suite of ferrihydrite-bearing and ferric sulfate-bearing montmorillonites, prepared with variable Fe3+ and S concentrations and variable pH conditions, has been analyzed using reflectance spectroscopy in the visible and infrared regions, Mossbauer spectroscopy at room temperature and 4 K, differential thermal analysis, and X-ray diffraction. These analyses support the formation of ferrihydrite of variable crystallinity in the ferrihydrite-bearing montmorillonites and a combination of schwertmannite and ferrihydrite in the ferric sulfate-bearing montmorillonites. Small quantities of poorly crystalline or nanophase forms of other ferric materials may also be present in these samples. The chemical formation conditions of the ferrihydrite-bearing and ferric sulfate-bearing montmorillonites influence the character of the low temperature Mossbauer sextets and the visible reflectance spectra. An absorption minimum is observed at 0.88-0.89 micrometers in spectra of the ferric sulfate-bearing samples, and at 0.89-0.92 micrometers in spectra of the ferrihydrate-bearing montmorillonites. Mossbauer spectra of the ferric sulfate-bearing montmorillonites indicate variable concentrations of ferrihydrite and schwertmannite in the interlaminar spaces and along grain surfaces. Dehydration under reduced atmospheric pressure conditions induces a greater effect on the adsorbed and interlayer water in ferrihydrite-bearing montmorillonite than on the water in ferric sulfate-bearing montmorillonite. Reflectance spectra of ferric sulfate-bearing montmorillonite include a strong 3-micrometers band that is more resistant to dry atmospheric conditions than the 3-micrometers band in spectra of similarly prepared ferrihydrite-bearing montmorillonites.

NASA Discipline Exobiology↗
NASA NTRS2005

Evaluation of Aerosol Properties over Ocean from Moderate Resolution Imaging Spectroradiometer (MODIS) during ACE-Asia

The Aerosol Characterization Experiment-Asia (ACE-Asia) was conducted in March-May 2001 in the western North Pacific in order to characterize the complex mix of dust, smoke, urban/industrial pollution, and background marine aerosol that is observed in that region in springtime. The Moderate Resolution Imaging Spectroradiometer (MODIS) provides a large-scale regional view of the aerosol during the ACE-Asia time period. Focusing only on aerosol retrievals over ocean, MODIS data show latitudinal and longitudinal variation in the aerosol characteristics. Typically, aerosol optical depth (tau(sub a)) values at 0.55 micrometers are highest in the 30 deg. - 50 deg. latitude band associated with dust outbreaks. Monthly mean tau(sub a) in this band ranges approx. 0.40-70, although large differences between monthly mean and median values indicate the periodic nature of these dust outbreaks. The size parameters, fine mode fraction (eta), and effective radius (r(sub eff)) vary between monthly mean values of eta = 0.47 and r(sub eff)= 0.75 micrometers in the cleanest regions far offshore to approximately eta = 0.85 and r(sub eff) =.30 micrometers in near-shore regions dominated by biomass burning smoke. The collocated MODIS retrievals with airborne, ship-based, and ground-based radiometers measurements suggest that MODIS retrievals of spectral optical depth fall well within expected error (DELTA tau(sub a) = plus or minus 0.03 plus or minus 0.05 tau(sub a)) except in situations dominated by dust, in which cases MODIS overestimate both the aerosol loading and the aerosol spectral dependence. Such behavior is consistent with issues related to particle nonsphericity. Comparisons of MODIS-derived r(sub eff) with AERONET retrievals at the few occurrences of collocations show MODIS systematically underestimates particle size by 0.2 micrometers. Multiple-year analysis of MODIS aerosol size parameters suggests systematic differences between the year 2001 and the years 2000 and 2002, which are traced to instrumental electronic cross talk. Sensitivity studies show that such calibration errors are negligible in tau(sub a) retrievals but are more pronounced in size parameter retrievals, especially for dust and sea salt.

Chu, D. A.↗
NASA NTRS2005

The Angstrom Exponent and Bimodal Aerosol Size Distributions

Powerlaws have long been used to describe the spectral dependence of aerosol extinction, and the wavelength exponent of the aerosol extinction powerlaw is commonly referred to as the Angstrom exponent. The Angstrom exponent is often used as a qualitative indicator of aerosol particle size, with values greater than two indicating small particles associated with combustion byproducts, and values less than one indicating large particles like sea salt and dust. In this study, we investigate the relationship between the Angstrom exponent and the mode parameters of bimodal aerosol size distributions using Mie theory calculations and Aerosol Robotic Network (AERONET) retrievals. We find that Angstrom exponents based upon seven wavelengths (0.34, 0.38, 0.44, 0.5, 0.67, 0.87, and 1.02 micrometers) are sensitive to the volume fraction of aerosols with radii less then 0.6 micrometers, but not to the fine mode effective radius. The Angstrom exponent is also known to vary with wavelength, which is commonly referred to as curvature; we show how the spectral curvature can provide additional information about aerosol size distributions for intermediate values of the Angstrom exponent. Curvature also has a significant effect on the conclusions that can be drawn about two-wavelength Angstrom exponents; long wavelengths (0.67, 0.87 micrometers) are sensitive to fine mode volume fraction of aerosols but not fine mode effective radius, while short wavelengths (0.38, 0.44 micrometers) are sensitive to the fine mode effective radius but not the fine mode volume fraction.

Schuster, Gregory L.↗
NASA NTRS2007

Characterization of MODIS Solar Diffuser On-orbit Degradation

MODIS reflective solar bands (RSB) are calibrated on-orbit by a solar diffuser (SD) and a solar diffuser stability monitor (SDSM). The SD bi-directional reflectance factor (BRF) was characterized pre-launch by the instrument vendor using reference samples traceable to NIST reflectance standards. Its on-orbit degradation is regularly monitored by the SDSM. It consists of a solar integration sphere (SIS) with 9 filtered detectors with wavelengths ranging from 0.41 to 0.94 micrometer, a rotating mirror assembly, and an electronics module. During each SD/SDSM calibration, the SDSM views the sunlight directly and the sunlight diffusely reflected from the SD panel. The time series of SDSM measurements (ratio of the SD view response to the Sun view response) is used to compute the SD BRF degradation at each SDSM detector wavelength. Since launch Terra MODIS has operated for more than seven years and Aqua for nearly five years. The SD panel on each MODIS instrument has experienced noticeable degradation with the largest changes observed in the VIS spectral region. Following a brief description of the MODIS RSB calibration methodology and SD/SDSM operational activities, this paper illustrates the SD on-orbit degradation results for both Terra and Aqua MODIS. It discusses the impacts on the SD RF degradation due to sensor operational conditions and SD solar exposure time. For Aqua MODIS, operated under the same conditions, the SD annual degradation rate is approximately 2.9% at 0.41 micrometers, 1.6% at 0.47 micrometers, and less than 1.1% at wavelengths above 0.53 micrometers. For Terra MODIS, however, an SD door (SDD) related anomaly in May 2003 had led to a decision to keep the SDD permanently at its open position. Since then its SD has experienced a much faster SD degradation rate.

Xiong, X.↗
NASA NTRS2010

Evidence for Interlayer Collapse of Nontronite on Mars from Laboratory Visible and Near-IR Reflective Spectra

Dioctahedral smectites (e.g., nontronite and montmorillionite) are interpreted to occupy the optical surface of Mars at a number of locations on the basis of spectral features derived from interlayer H2O and MOH (M=Fe(3+)2, Fe(3+)Al, Al2, etc.) as observed by orbiting MRO-CRISM and MEx-OMEGA hyperspectral imaging spectrometers. At wavelengths shorter than approximately 2.7 micrometers, the strongest bands from interlayer H2O occur at approximately 1.4 and 1.9 micrometers from 2v1 and v1+v2, respectively, where v1 and v2 are the fundamental stretching and bending vibrations of the H2O molecule. Smectite MOH vibrations occur near 1.4 micrometers (stretching overtone) and in the region between 2.1 and 2.7 micrometers (stretching + bending combination). Because interlayer H2O can exchange with the martian environment, a number of studies have examined the strength of the interlayer H2O spectral features under Mars-like environmental conditions. The relationship between spectral properties and the underlying crystal structure of the smectites was not determined, and the extent of interlayer H2O removal was not established. We report combined visible and near-IR (VNIR), Mossbauer (MB), and powder X-ray diffraction (XRD) data for samples of the Fe-bearing smectite nontronite where the interlayer was collapsed by complete removal of interlayer H2O.

Morris, Richard V.↗
NASA NTRS2011

Interpreting Methanol v(sub 2)-Band Emission in Comets Using Empirical Fluorescence g-Factors

For many years we have been developing the ability, through high-resolution spectroscopy targeting ro-vibrational emission in the approximately 3 - 5 micrometer region, to quantify a suite of (approximately 10) parent volatiles in comets using quantum mechanical fluorescence models. Our efforts are ongoing and our latest includes methanol (CH3OH). This is unique among traditionally targeted species in having lacked sufficiently robust models for its symmetric (v(sub 3) band) and asymmetric (v(sub 2) and v(sub 9) bands) C-H3 stretching modes, required to provide accurate predicted intensities for individual spectral lines and hence rotational temperatures and production rates. This has provided the driver for undertaking a detailed empirical study of line intensities, and has led to substantial progress regarding our ability to interpret CH3OH in comets. The present study concentrates on the spectral region from approximately 2970 - 3010 per centimeter (3.367 - 3.322 micrometer), which is dominated by emission in the (v(sub 7) band of C2H6 and the v(sub 2) band of CH3OH, with minor contributions from CH3OH (v(sub 9) band), CH4 (v(sub 3)), and OH prompt emissions (v(sub 1) and v(sub 2)- v(sub 1)). Based on laboratory jet-cooled spectra (at a rotational temperature near 20 K)[1], we incorporated approximately 100 lines of the CH3OH v(sub 2) band, having known frequencies and lower state rotational energies, into our model. Line intensities were determined through comparison with several comets we observed with NIRSPEC at Keck 2, after removal of continuum and additional molecular emissions and correcting for atmospheric extinction. In addition to the above spectral region, NIRSPEC allows simultaneous sampling of the CH3OH v(sub 3) band (centered at 2844 per centimeter, or 3.516 micrometers and several hot bands of H2O in the approximately 2.85 - 2.9 micrometer region, at a nominal spectral resolving power of approximately 25,000 [2]. Empirical g-factors for v(sub 2) lines were based on the production rate as determined from the v(sub 3) Q-branch intensity; application to comets spanning a range of rotational temperatures (approximately 50 - 90 K) will be reported. This work represents an extension of that presented for comet 21P/Giacobini-Zinner at the 2010 Division for Planetary Sciences meeting [3]. Our empirical study also allows for quantifying CH3OH in comets using IR spectrometers for which the v(sub 3) and v(sub 2) bands are not sampled simultaneously, for example CSHELL/NASA IRTF or CRIRES/VLT.

DiSanti, Michael↗
NASA NTRS2011

Ground and Airborne Methane Measurements Using Optical Parametric Amplifiers

We report on ground and airborne methane measurements with an active sensing instrument using widely tunable, seeded optical parametric generation (OPG). The technique has been used to measure methane, CO2, water vapor, and other trace gases in the near and mid-infrared spectral regions. Methane is a strong greenhouse gas on Earth and it is also a potential biogenic marker on Mars and other planetary bodies. Methane in the Earth's atmosphere survives for a shorter time than CO2 but its impact on climate change can be larger than CO2. Carbon and methane emissions from land are expected to increase as permafrost melts exposing millennial-age carbon stocks to respiration (aerobic-CO2 and anaerobic-CH4) and fires. Methane emissions from c1athrates in the Arctic Ocean and on land are also likely to respond to climate warming. However, there is considerable uncertainty in present Arctic flux levels, as well as how fluxes will change with the changing environment. For Mars, methane measurements are of great interest because of its potential as a strong biogenic marker. A remote sensing instrument that can measure day and night over all seasons and latitudes can localize sources of biogenic gas plumes produced by subsurface chemistry or biology, and aid in the search for extra-terrestrial life. In this paper we report on remote sensing measurements of methane using a high peak power, widely tunable optical parametric generator (OPG) operating at 3.3 micrometers and 1.65 micrometers. We have demonstrated detection of methane at 3.3 micrometers and 1650 nanometers in an open path and compared them to accepted standards. We also report on preliminary airborne demonstration of methane measurements at 1.65 micrometers.

Numata, Kenji↗
NASA NTRS2012

Design of High Resolution Soft X-Ray Microcalorimeters Using Magnetic Penetration Thermometers

We have designed high-resolution soft x-ray microcalorimeters using magnetic penetration thermometers (MPTs) in an array of pixels covering a total of 2 square centimeters to have a resolving power of 300 at energies around 300 eV. This performance is desirable for studying the soft x-ray background from the warm hot intergalactic medium. MPT devices have small sensor heat capacity and high responsivities, which makes them excellent detector technology for attempting to attain sub-eV resolution. We are investigating the feasibility of pixels with absorbers that are 625 x 625 square micrometers, up to 1 x 1 square millimeters in area and 0.35 micrometer thick and thinner. Our tests have shown that suspended gold absorbers 0.35 micrometers thick (RRR = 6.7) are feasible to fabricate. We modeled the thermal diffusion from such thin gold over the size of a 625 x 625 square micrometer absorber, and conclude that the effect of the thermalization on the resolution of a 300 eV photon is an additional approximately 0.2 eV FWHM of broadening. We discuss the thermal effects of small absorber attachment sterns on solid substrate, as well as considerations for multiplexed readout. We will present the progress we have made towards building and testing this soft x-ray detector.

Busch. Sarah↗
NASA NTRS2012

Adaptation of a Filter Assembly to Assess Microbial Bioburden of Pressurant Within a Propulsion System

A report describes an adaptation of a filter assembly to enable it to be used to filter out microorganisms from a propulsion system. The filter assembly has previously been used for particulates greater than 2 micrometers. Projects that utilize large volumes of nonmetallic materials of planetary protection concern pose a challenge to their bioburden budget, as a conservative specification value of 30 spores per cubic centimeter is typically used. Helium was collected utilizing an adapted filtration approach employing an existing Millipore filter assembly apparatus used by the propulsion team for particulate analysis. The filter holder on the assembly has a 47-mm diameter, and typically a 1.2-5 micrometer pore-size filter is used for particulate analysis making it compatible with commercially available sterilization filters (0.22 micrometers) that are necessary for biological sampling. This adaptation to an existing technology provides a proof-of-concept and a demonstration of successful use in a ground equipment system. This adaptation has demonstrated that the Millipore filter assembly can be utilized to filter out microorganisms from a propulsion system, whereas in previous uses the filter assembly was utilized for particulates greater than 2 micrometers.

Benardini, James N.↗
NASA NTRS2012

Metrology of Large Parts

As discussed in the first chapter of this book, there are many different methods to measure a part using optical technology. Chapter 2 discussed the use of machine vision to measure macroscopic features such as length and position, which was extended to the use of interferometry as a linear measurement tool in chapter 3, and laser or other trackers to find the relation of key points on large parts in chapter 4. This chapter looks at measuring large parts to optical tolerances in the sub-micron range using interferometry, ranging, and optical tools discussed in the previous chapters. The purpose of this chapter is not to discuss specific metrology tools (such as interferometers or gauges), but to describe a systems engineering approach to testing large parts. Issues such as material warpage and temperature drifts that may be insignificant when measuring a part to micron levels under a microscope, as will be discussed in later chapters, can prove to be very important when making the same measurement over a larger part. In this chapter, we will define a set of guiding principles for successfully overcoming these challenges and illustrate the application of these principles with real world examples. While these examples are drawn from specific large optical testing applications, they inform the problems associated with testing any large part to optical tolerances. Manufacturing today relies on micrometer level part performance. Fields such as energy and transportation are demanding higher tolerances to provide increased efficiencies and fuel savings. By looking at how the optics industry approaches sub-micrometer metrology, one can gain a better understanding of the metrology challenges for any larger part specified to micrometer tolerances. Testing large parts, whether optical components or precision structures, to optical tolerances is just like testing small parts, only harder. Identical with what one does for small parts, a metrologist tests large parts and optics in particular to quantify their mechanical properties (such as dimensions, mass, etc); their optical prescription or design (i.e. radius of curvature, conic constant, vertex location, size); and their full part shape. And, just as with small parts, a metrologist accomplishes these tests using distance measuring instruments such as tape measures, inside micrometers, coordinate measuring machines, distance measuring interferometers; angle measuring instruments such as theodolites, autocollimators; and surface measuring instruments including interferometers, stylus profilers, interference microscopes, photogrammetric cameras, or other tools. However, while the methodology may be similar, it is more difficult to test a large object for the simple reason that most metrologists do not have the necessary intuition. The skills used to test small parts or optics in a laboratory do not extrapolate to testing large parts in an industrial setting any more than a backyard gardener might successfully operate a farm. But first, what is a large part? A simple definition might be the part's size or diameter. For optics and diffuse surface parts alike, the driving constraint is ability to illuminate the part's surface. For reflective convex mirrors, large is typically anything greater than 1 meter. But, for refractive optics, flats or convex mirrors, large is typically greater than 0.5 meter. While a size definition is simple, it may be less than universal. A more nuanced definition might be that a large part is any component which cannot be easily tested in a standard laboratory environment, on a standard vibration isolated table using standard laboratory infrastructure. A micro-switch or a precision lens might be easily measured to nanometer levels under a microscope in a lab, but a power turbine spline or a larger telescope mirror will not fit under that microscope and may not even fit on the table.

Stahl, H. Philip↗
NASA NTRS2013

Submillimeter Follow-up of Wise-Selected Hyperluminous Galaxies

We have used the Caltech Submillimeter Observatory (CSO) to follow-up a sample of Wide-field Infrared Survey Explorer (WISE) selected, hyperluminous galaxies, the so-called W1W2-dropout galaxies. This is a rare (approximately 1000 all-sky) population of galaxies at high redshift (peaks at zeta = 2-3), which are faint or undetected by WISE at 3.4 and 4.6 micrometers, yet are clearly detected at 12 and 22 micrometers. The optical spectra of most of these galaxies show significant active galactic nucleus activity. We observed 14 high-redshift (zeta greater than 1.7) W1W2-dropout galaxies with SHARC-II at 350-850 micrometers, with nine detections, and observed 18 with Bolocam at 1.1 mm, with five detections. Warm Spitzer follow-up of 25 targets at 3.6 and 4.5 micrometers, as well as optical spectra of 12 targets, are also presented in the paper. Combining WISE data with observations from warm Spitzer and CSO, we constructed their mid-IR to millimeter spectral energy distributions (SEDs). These SEDs have a consistent shape, showing significantly higher mid-IR to submillimeter ratios than other galaxy templates, suggesting a hotter dust temperature.We estimate their dust temperatures to be 60-120 K using a single-temperature model. Their infrared luminosities are well over 10(exp 13) solar luminosity. These SEDs are not well fitted with existing galaxy templates, suggesting they are a new population with very high luminosity and hot dust. They are likely among the most luminous galaxies in the universe.We argue that they are extreme cases of luminous, hot dust-obscured galaxies (DOGs), possibly representing a short evolutionary phase during galaxy merging and evolution. A better understanding of their long-wavelength properties needs ALMA as well as Herschel data.

Wu, Jingwen↗
NASA NTRS2013

Wise Detections of Known QSOS at Redshifts Greater Than Six

We present WISE All-Sky mid-infrared (IR) survey detections of 55 % (17/31) of the known QSOs at z greater than 6 from a range of surveys: the SDSS, the CFHT-LS, FIRST, Spitzer and UK1DSS. The WISE catalog thus provides a substantial increase in tiie quantity of IR data available for these sources: 17 are detected in the WISE Wl (3.4 micrometer) band, 16 in W2 (4.6 micrometers), 3 in W3 (12 micrometers) and 0 in W4 (22micrometers). This is particularly important with Spitzer in its warm-mission phase and no faint follow-up capability at wavelengths longwards of 5 micrometers until the launch of JWST. WISE thus provides a useful tool for understanding QSOs found in forthcoming large-area optical/IR sky surveys, using PanSTARRS, SkyMapper, VISTA, DES and LSST. The rest-UV properties of the WISE-detected and the WISE-non-detected samples differ: the detections have brighter i/z-band magnitudes and redder rest-UV colors. This suggests thai a more aggressive hunt for very-high-redshift QSOs, by combining WISE Wl and W2 data with red observed optical colors could be effective at least, for a subset of dusty candidate QSOs. Stacking the WISE images of the WISE-non-detected QSOs indicates that they are on average significantly fainter than the WISE-detccted examples, and are thus not narrowly missing detection in the WISE catalog. The WISE-catalog detection of three of our sample in the W3 band indicates that their mid-ID flux can be detected individually, although there is no stacked W3 detection of sources detected in Wl but not. W3. Stacking analyses of WISE data for large AGN samples will be a useful tool, and high-redshifl. QSOs of all types will be easy targets for JWST.

Galaxies: Evolution↗
NASA NTRS2014

Comparison of Marine Boundary Layer Cloud Properties from CERES-MODIS Edition 4 and DOE ARM AMF Measurements at the Azores

Marine boundary layer (MBL) cloud properties derived from the NASA Clouds and the Earth's Radiant Energy System (CERES) project using Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) data are compared with observations taken at the Department of Energy Atmospheric Radiation Measurement (ARM) Mobile Facility at the Azores (AMF-Azores) site from June 2009 through December 2010. Cloud properties derived from ARM ground-based observations were averaged over a 1 h interval centered at the satellite overpass time, while the CERES-MODIS (CM) results were averaged within a 30 km×30 km grid box centered over the Azores site. A total of 63 daytime and 92 nighttime single-layered overcast MBL cloud cases were selected from 19 months of ARM radar-lidar and satellite observations. The CM cloud top/base heights (Htop/Hbase) were determined from cloud top/base temperatures (Ttop/Tbase) using a regional boundary layer lapse rate method. For daytime comparisons, the CM-derived Htop (Hbase), on average, is 0.063 km (0.068 km) higher (lower) than its ARM radar-lidar-observed counterpart, and the CM-derived Ttop and Tbase are 0.9 K less and 2.5 K greater than the surface values with high correlations (R(sup 2) = 0.82 and 0.84, respectively). In general, the cloud top comparisons agree better than the cloud base comparisons, because the CM cloud base temperatures and heights are secondary products determined from cloud top temperatures and heights. No significant day-night difference was found in the analyses. The comparisons of MBL cloud microphysical properties reveal that when averaged over a 30 km× 30 km area, the CM-retrieved cloud droplet effective radius (re) at 3.7 micrometers is 1.3 micrometers larger than that from the ARM retrievals (12.8 micrometers), while the CM-retrieved cloud liquid water path (LWP) is 13.5 gm( exp -2) less than its ARM counterpart (114.2 gm( exp-2) due to its small optical depth (9.6 versus 13.7). The differences are reduced by 50% when the CM averages are computed only using the MODIS pixel nearest the AMF site. Using the effective radius retrieved using 2.1 micrometers channel to calculate LWP can reduce the difference between the CM and ARM microwave radiometer retrievals from 13.7 to 2.1 gm2. The 10% differences between the ARM and CERES-MODIS LWP and r(sub e) retrievals are within the uncertainties of the ARM LWP (approximately 20gm( exp -2)) and r(sub e) (approximately 10%) retrievals; however, the 30% difference in optical depth is significant. Possible reasons contributing to this discrepancy are increased sensitivities in optical depth from both surface retrievals when τ is approximately 10 and topography. The τ differences vary with wind direction and are consistent with the island orography.Much better agreement in τ is obtained when using only those data taken when the wind is from the northeast, where topographical effects on the sampled clouds are minimal.

Xi, Baike↗
NASA NTRS2014

Aerosol Remote Sensing in Polar Regions

Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness tau(lambda) at visible and near-infrared wavelengths, from which best-fit values of Ångström's exponent alpha were calculated. Analyzing these data, the monthly mean values of tau(0.50 micrometers) and alpha and the relative frequency histograms of the daily mean values of both parameters were determined for winter-spring and summer-autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of alpha versus tau(0.50 micrometers) showed: (i) a considerable increase in tau(0.50 micrometers) for the Arctic aerosol from summer to winter-spring, without marked changes in alpha; and (ii) a marked increase in tau(0.50 micrometer) passing from the Antarctic Plateau to coastal sites, whereas alpha decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of tau(lambda) and alpha at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterize vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of tau(lambda) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface-atmosphere system over polar regions.

Sun-photometer measurements↗
NASA NTRS2016

Cooling History and Redox State of NWA 8694 Chassignite: Comparison with Chassigny and NWA 2737

NWA 8694 is a new chassignite whose constituent minerals are more Fe-rich than those in the other known chassignites (Chassigny and NWA 2737), and may suggest a petrogenetic relationship to nakhlites. In this abstract we report mineralogy of NWA 8694 to infer its cooling rate and redox state, and discuss its thermal and shock history in comparison with other chassignites. NWA 8694 is a cumulate dunite of approximately 2 mm olivine with interstitial pyroxene and feldspar. Olivine is homogeneous (Fo(sub 55-56)), but Ca decreases at the approximately 50-100 micrometer rim (0.25-0.1 wt% CaO). Because the Ca-depleted rim is narrower than those in other chassignites (approximately 50 micrometer), NWA 8694 may have cooled slightly faster than the others (approximately 30 C/yr), but would be in the same order. Pyroxenes are low- and high-Ca pyroxenes, both exhibiting sub-micron exsolution textures (0.2-0.3 micrometer wide lamellae with the spacing of 0.8-1.8 micrometers). Although the low-Ca pyroxene host has an orthopyroxene composition (Wo approximately 2), the EBSD analysis suggests a pigeonite structure (P2(sub 1)/c), which is also reported from the Chassigny pyroxene. The size of exsolution texture is a bit smaller, but broadly similar to those in other chassignites, implying a similar fast cooling rate (35-43 C/yr). Feldspars are isotropic (plagioclase: clustered around An25Or10, K-feldspar: approximately An19Or78), suggestive of extensive shock metamorphism, consistent with undulatory extinction of olivine. Feldspar compositions are around the equilibrium isotherm of approximately 800 C. The olivine and chromite compositions give an equilibration temperature of 760-810 C and logfO2 of QFM+/-0.3. The inferred fast cooling rate and high fO2 of NWA 8694 are both similar to those of Chassigny and NWA 2737, and suggest a common formation condition (e.g., thick lava flow or shallow intrusion) under oxidizing condition. The Fe-rich mineral compositions of NWA 8694 may be due to crystallization from more fractionated melt than the other chassignites. The shock degree of NWA 8694 would be similar to Chassigny, but distinct from NWA 2737 with darkened olivine showing more extensive shock.

Mikouchi, T.↗
NASA NTRS1973

Simultaneous Red - Blue Lidar and Airborne Impactor Measurements

Simultaneous two-color (0.6943 micrometers and 0.3472 micrometers) LIDAR measurements were made in the troposphere and lower stratosphere over Boulder, Colorado during March 1973. In addition, on the evening of March 26, airborne single-stage impactor measurements were made at four altitudes-- 10,500, 25,000, 33,000 and 43,000 feet MSL. These data were integrated at constant altitude for 15,45, 45, and 60 minutes respectively. The LIDAR data were taken with Langley's 48" LIDAR using a dichroic beamsplitter to separate the return at 0.6943 micrometers and 0.3472 micrometers. The analog waveforms for both colors were digitized simultaneously; one on an NCAR data acquisition system and the other on the 48" Langley data acquisition system. A discussion of the preliminary results from these measurements will be presented.

McCormick, M. P.↗
NASA NTRS2017

Ground-Based Observing Campaign of Briz-M Debris

In 2015, NASA's Orbital Debris Program Office (ODPO) completed the installation of the Meter Class Autonomous Telescope (MCAT) on Ascension Island. MCAT is a 1.3m optical telescope designed with a fast tracking capability for observing orbital debris at all orbital regimes (Low-Erath orbits to Geosyncronous (GEO) orbits) from a low latitude site. This new asset is dedicated year-round for debris observations, and its location fills a geographical gap in the Ground-based Electro Optical Space Surveillance (GEODSS) network. A commercial off the shelf (COTS) research grade 0.4m telescope (named the Benbrook telescope) will also be installed on Ascension at the end of 2016. This smaller version is controlled by the same master software, designed by Euclid Research, and can be tasked to work independently or in concert with MCAT. Like MCAT, it has a the same suite of filters, a similar field of view, and a fast-tracking Astelco mount, and is also capable of tracking debris at all orbital regimes. These assets are well suited for targeted campagins or surveys of debris. Since 2013, NASA's ODPO has also had extensive access to the 3.8m infrared UKIRT telescope, located on Mauna Kea. At nearly 14,000-ft, this site affords excellent conditions for collecting both photometery and spectroscopy at near-IR (0.9 - 2.5 micrometers SWIR) and thermal-IR (8 - 25 micrometers; LWIR) regimes, ideal for investigating material properties as well as thermal characteristics and sizes of debris. For the purposes of understanding orbital debris, taking data in both survey mode as well as targeting individual objects for more in-depth characterizations are desired. With the recent break-ups of Briz-M rocket bodies, we have collected a suite of data in the optical, near-infrared, and mid-infrared of in-tact objects as well as those classified as debris. A break-up at GEO of a Briz-M rocket occurred in January, 2016, well timed for the first remote observing survey-campaign with MCAT. Access to the 3.8m UKIRT telescope has also allowed for investigating this break-up in the near-infrared at wavelengths where debris is often much more reflective, allowing for the potential detection of a smaller population of these debris. In addition, a suite of near-IR reflectance spectroscopy (0.8-2.5 micrometers) and thermal-IR (8-15 micrometers) of individual in-tact and debris Briz-M objects has been collected. Analysis of the survey data will be discussed.

Lederer, S. M.↗
NASA NTRS2017

Infrared Continuum and Line Evolution of the Equatorial Ring Around SN 1987A

Spitzer observations of SN 1987A have now spanned more than a decade. Since day approximately 4000, mid-infrared (mid-IR) emission has been dominated by that from shock-heated dust in the equatorial ring (ER). From 6000 to 8000 days after the explosion, Spitzer observations included broadband photometry at 3.6-24 micrometer, and low and moderate resolution spectroscopy at 5-35 micrometer. Here we present later Spitzer observations, through day 10,377, which include only the broadband measurements at 3.6 and 4.5 micrometer. These data show that the 3.6 and 4.5 micrometer brightness has clearly begun to fade after day approximately 8500, and no longer tracks the X-ray emission as well as it did at earlier epochs. This can be explained by the destruction of the dust in the ER on timescales shorter than the cooling time for the shocked gas. We find that the evolution of the late time IR emission is also similar to the now fading optical emission. We provide the complete record of the IR emission lines, as seen by Spitzer prior to day 8000. The past evolution of the gas as seen by the IR emission lines seems largely consistent with the optical emission, although the IR [Fe(II)]and [Si(II)]lines show different, peculiar velocity structures.

Arendt, Richard G.↗