Search NASA⌕ Search

SEARCH · Search NASA

Results for “NH3”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Infrared scans of Jupiter

Spatial scans at eight wavelengths between 7.8 and 24 microns along Jupiter's meridian and along the Equatorial Zone, the North Equatorial Belt, and the South Tropical Zone are considered. Some features of these scans are differences in brightness temperatures between the Great Red Spot and the surrounding South Tropical Zone, a higher temperature at high northern latitudes than high southern latitudes, equal or possibly higher temperatures of zones than belts at 7.8 microns in contrast to higher temperatures of belts at other observed wavelengths, very strong limb darkening at 8.9 microns possibly due to a large scale height or a nonuniform distribution of solid NH3 particles, and inhomogeneities within belts and zones.

Sinton, W. M.↗
NASA NTRS1980

Longitudinal variability of methane and ammonia bands on Jupiter

Results of a quantitative study of the longitudinal variations of methane and ammonia absorption on Jupiter are presented. A total of 78 high signal-to-noise ratio photoelectric spectra in the range 6000 to 6600 A were obtained on two consecutive nights, with complete longitudinal equatorial coverage each night through 9-min exposures covering a total of over 9 h. Analysis of the equivalent widths of the CH4 6190 A and NH3 6450 A absorption bands by means of a blind, automated, self-consistent method of continuum determination reveals large equivalent widths in both bands near longitudes of 35 and 340 deg and small equivalent widths near 150 deg, with a high degree of correlation between the equivalent widths of the bands. Continuum molecular absorption is found to be slightly negatively correlated with band equivalent widths. Radiative transfer calculations based on the model of Sato and Hansen (1979) using a doubling and adding technique indicate that the observed longitudinal variables of equivalent widths and continuum reflectivity are the results of longitudinal variations in ammonia cloud altitude.

Cochran, W. D.↗
NASA NTRS1980

Interferometry of Saturn and its rings at 1.30-cm wavelength

Interferometric observations of Saturn and its rings at a wavelength of 1.30 cm are presented in an attempt to place constraints upon the amount of thermal radiation emitted by the ring particles. Model-fitting and aperture synthesis techniques were used to analyze the data obtained on nine baselines at a frequency of 23 GHz. Ring optical depth is found to be close to that observed at visible wavelengths, while ring brightness temperature is only 7 + or - 1 K, requiring the ring particles to be nearly conservative scatterers at this wavelength and implying an upper limit of 2.4 m to the radius of a typical ring particle with a lower limit of 0.95 to its single scattering albedo. An observed difference between planetary radii observed at 1.30 and 3.71 cm is interpreted in terms of limb darkening and found to be marginally different from the predictions of atmospheric models in which NH3 is the principal source of microwave opacity.

Schloerb, F. P.↗
NASA NTRS1979

Overview of the NASA tropospheric environmental quality remote sensing program

This paper will summarize the current NASA Tropospheric Environmental Quality Remote Sensing Program for studying the global and regional troposphere from space, airborne and ground-based platforms. As part of the program to develop remote sensors for utilization from space, NASA has developed a series of passive and active remote sensors which have undergone field test measurements from airborne and ground platforms. Recent measurements with active lidar and passive gas filter correlation and infrared heterodyne techniques will be summarized for measurements of atmospheric aerosols, CO, SO2, O3, and NH3. These measurements provide the data base required to assess the sensitivity of remote sensors for applications to urban and regional field measurement programs. Studies of Earth Observation Satellite Systems are currently being performed by the scientific community to assess the capability of satellite imagery to detect regions of elevated pollution in the troposphere. The status of NASA sponsored research efforts in interpreting satellite imagery for determining aerosol loadings over land and inland bodies of water will be presented, and comments on the potential of these measurements to supplement in situ and airborne remote sensors in detecting regional haze will be made.

Allario, F.↗
NASA NTRS1980

Kinetic inhibition of CO and N2 reduction in the solar nebula

It is shown that the conversion of CO to methane and of N2 to ammonia in the primitive solar nebula was probably so slow relative to radial mixing rates or nebula evolutionary rates that only small amounts of NH3 and CH4 could have been present. Thus most of the nitrogen was present as N2 and most of the carbon as CO and CO2 throughout the nebula. The consequences of this kinetic effect upon the composition of cometary ices and of the Jovian planets, the melting and outgassing behavior of ice rich planetary satellites, and the abundance of carbon in the terrestrial planets are briefly discussed.

Lewis, J. S.↗
NASA NTRS1980

A model of comet comae. II - Effects of solar photodissociative ionization

Improvements to a computer model of coma photochemistry are described. These include an expansion of the chemical reactions network and new rate constants that have been measured only recently. Photolytic reactions of additional molecules are incorporated, and photolytic branching ratios are treated in far greater detail than previously. A total of 25 photodissociative ionization (PDI) reactions are now considered (as compared to only 3 PDI reactions previously). Solar PDI of the mother molecule CO2 is shown to compete effectively with photoionization of CO in the production of observed CO(+). The CO(+) density peak predicted by the improved model, for CO2 or CO mother molecules, is deep in the inner coma, in better agreement with observation than the old CO2 model. However, neither CO2 nor CO mother molecule calculations reproduce the CO(+)/H2O(+) ratio observed in comet Kohoutek. PDI products of CO2, CO, CH4, and NH3 mother molecules fuel a complex chemistry scheme, producing inner coma abundances of CN, C2, and C3 much greater than previously calculated.

Huebner, W. F.↗
NASA NTRS1980

A model for gas phase chemistry in interstellar clouds. II - Nonequilibrium effects and effects of temperature and activation energies

The chemical evolution of diffuse and dense interstellar clouds is examined via the time-dependent model outlined by Prasad and Huntress (1980). This paper presents specific results for CH, CO, CH4, O2, CH2O, CN, C2, C2H, HC3N, and NH3. Comparison with observations and predictions of other contemporary models show that cloud temperature plays a very important role through the inverse temperature dependence of radiative association reactions and through activation energies in neutral reactions and selected ion-molecule reactions. The observed fractional abundance of CN with respect to H2 and more accurate recent laboratory data on CN + O and CN + O2 reactions suggest that there is an unidentified, yet efficient, mechanism for conversion of O and O2 into polyatomic species. C2H and HC3N are synthesized early in the history of dense clouds. The value of the fractional abundance of C2H remains high, because as the cloud cools down the activation energy in the C2H + O reaction closes down this most important loss channel. A rapidly decreasing fractional abundance of O with time can also accomplish the same result. The value of the fractional abundance of HC3N remains high because it is an unreactive molecule and probably does not condense readily onto grains.

Prasad, S. S.↗
NASA NTRS1981

Design, development, and field testing of Infrared Heterodyne Radiometer (IHR) for remote profiling of tropospheric and stratospheric species

The performance of a dual-channel infrared heterodyne radiometer, designed to remotely monitor the concentration and vertical distribution of selected atmospheric species, is described. Ground based solar viewing measurement using the IHR were performed at selected laser transitions for ammonia (NH3 and ozone O3). Flight tests were conducted aboard the Galileo II, NASA Ames CV-990, on the Latitude Survey Mission. Ozone was the selected atmospheric species for the airborne flight measurements because of the scientific interest in this atmospheric species, the availability of in situ monitors, the coordinated ozone measurements, and the availability of ground truth data. The IHS was operated in the solar viewing mode to determine ozone distributions in the stratosphere and in the nadir viewing mode to determine the ozone distribution in the troposphere. Airborne atmospheric propagation measurements also were carried out at selected CO2 laser transitions.

Lange, R.↗
NASA NTRS1980

Infrared observations of circumstellar ammonia in OH/IR supergiants

Ammonia has been detected in the circumstellar envelopes of VY Canis Majoris, VX Sagittarii, and IRC +10420 by means of several absorption lines in the nu-2 vibration-rotation band near 950 kaysers. The line profiles are well resolved (0.2 km/sec resolution) and show the gas being accelerated to terminal expansion velocities near 30 km/sec. The observations reveal a method for determining the position of the central star on VLBI maps of OH maser emission to an accuracy of approximately 0.2 arcsec. A firm lower limit of 2 x 10 to the 15th/sq cm is obtained for the NH3 column density in VY Canis Majoris.

Mclaren, R. A.↗
NASA NTRS1981

Atmospheric ammonia - Measurements and modeling

Ammonia possesses a unique position in the terrestrial atmosphere in that it is the only gaseous basic constituent. Ammonia readily forms aerosols, and by virtue of its high solubility controls the pH of cloud droplets and precipitation. Over the past year a ground-based solar viewing Infrared Heterodyne Radiometer has been used at Langley Research Center to infer the vertical distribution of ammonia. Ground level in situ measurements of ammonia have also been obtained to supplement the profile data. The ammonia profiles have been analyzed and interpreted with a one-dimensional photochemical model of the troposphere to assess the sources and sinks of NH3.

Hoell, J. M., Jr.↗
NASA NTRS1980

Laboratory studies of some of the major ion-molecule reactions occurring in cometary comae

Laboratory results have been obtained for some of the key ion-molecule reactions which should occur in the inner coma of comets. A complete listing is given of laboratory data presently available for ion-molecule reactions occurring in a mixture of H2O, CO2, CO, CH4, N2, and NH3 cometary volatiles. From these data, the most important reactions occurring in the coma of a water-dominated comet are extracted for use in models of the physics and chemistry of cometary comae.

Huntress, W. T., Jr.↗
NASA NTRS1981

Infrared observations of the Saturnian system from Voyager 1

Atmospheric chemistry analyses of Saturn based on Voyager 1 infrared spectral and radiometric data are presented, including characteristics of the planet's rings and of Titan and other satellites. Infrared spectra of Saturn indicate the presence of H2, CH4, NH3, PH3, C2H2, and C2H6, with the possibility of C3H4 and C3H8. The atmospheric thermal structure of the planet shows hemispheric asymmetries that are consistent with seasonally varying insolation response, with an extensive small-scale latitudinal structure. Atmospheric chemistries of Titan, and optical and thermal characteristics for the rings of Saturn, are also given.

Hanel, R.↗
NASA NTRS1981

AFGL trace gas compilation - 1980 version

A new edition of the AFGL trace gas compilation is now available. Absorption line parameters of positions, intensities, and half-widths are given for the major bands of thirteen gases covering the spectral region from 0 to 10,000/cm. In addition to updating the original gases (NO, SO2, NO2, and NH3), the molecules HNO3, OH, HF, HCl, HBr, HI, ClO, OCS, and H2CO have been added to the compilation. The sources for the additions and modifications are described.

Rothman, L. S.↗
NASA NTRS1980

Theoretical predictions of deuterium abundances in the Jovian planets

Current concepts for the origin of the Jovian planets and current constraints on their interior structure are used to support the argument that the presence of large amounts of 'ice' (H2O, CH4, and NH3) in Uranus and Neptune indicates temperature low enough to condense these species at the time Uranus and Neptune formed. Such low temperatures, however, imply orders-of-magnitude fractionation effects for deuterium into the 'ice' component if isotopic equilibration can occur. The present models thus imply that Uranus and Neptune should have D/H ratio at least four times primordial, contrary to observation for Uranus. It is found that the Jovian and Saturnian D/H should be close to primordial regardless of formation scenario.

Hubbard, W. B.↗
NASA NTRS1981

LOX/Hydrocarbon auxiliary propulsion for the Space Shuttle Orbiter

The initial efforts are reported of a study evaluating liquid oxygen/hydrocarbon (LOX/HC) auxiliary propulsion system (APS) concepts for a second generation Space Shuttle Orbiter. The APS consists of: (1) an orbital maneuvering subsystem (OMS), (2) an aft reaction control subsystem (ARCS), and (3) a forward reaction control subsystem (FRCS). The overall study approach compares candidate LOX/HC concepts and evaluates major system/component design options, regarding the overall system, pressurization assembly, propellant tankage and feedline, accumulator, and engine conditioner and thrust chamber assemblies. Among the HC fuels considered are C3H8, CH4, NH3, and C2H5OH.

Orton, G. F.↗
NASA NTRS1981

An ICR investigation of ion-molecule reactions of HCN

Laboratory reaction rates and product distributions measured by the ion cyclotron resonance technique are reported for a series of reactions of HCN(+) ions with the neutral molecules HCN, CH4, NH3, H2O, CO, CO2, N2 and O2. Rate coefficients are also reported for reactions of positive ions derived from these molecules with HCN. A comparison of the results with a survey of literature values for rate coefficients of HCN(+) reactions shows some exothermic proton transfers from HCN(+) to be inefficient.

Mcewan, M. J.↗
NASA NTRS1981

Study of the ammonia ice cloud layer in the Equatorial Region of Jupiter from the infrared interferometric experiment on Voyager

Spectra from the Voyager 1 infrared interferometer spectrometer (IRIS) obtained near the time of closest approach to Jupiter were analyzed for the purpose of inferring ammonia cloud properties associated with the Equatorial Region. Comparisons of observed spectra with synthetic spectra computed from a radiative transfer formulation, that includes multiple scattering, yielded the following conclusions: (1) very few NH3 ice particles with radii less than 3 microns contribute to the cloud opacity; (2) the major source of cloud opacity arises from particles with radii in excess of 30 microns; (3) column particle densities are between 1 and 2 orders of magnitude smaller than those derived from thermochemical considerations alone, implying the presence of important atmospheric motion; and (4) another cloud system is confirmed to exist deeper in the Jovian troposphere.

Marten, A.↗
NASA NTRS1981

Radio astronomy

A K-band reflected-wave ruby maser was used on the 64-meter (DSS-43) antenna at the Tidbinbilla Tracking Station, near Canberra, Australia. Spectral line observations were carried out near 22 GHz for water vapor sources and near 24 GHz for ammonia sources. The water vapor observations were made in the direction of known southern OH and H2O maser sources. All of the previously detected water line sources examined were detected. In addition, two new water vapor maser sources were discovered, G301.1+1.1and G308.9+0.1. The spectrum of G301.0+1.1 is presented six ammonia sources were found: G291.3-0.7, G305.4+0.2, G322.2+0.6, G327.3-0.5, G333.6-0.2, and G268.4-0.8. Spectra of two of these sources, G291.3-0.7 (RCW 57) and G305.4+0.2, are presented. Both show clearly the presence of the quadrupole splitting satellite lines that will allow the determination of NH3 optical depths in these clouds.

Shaffer, R. D.↗