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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Trends in aerosol abundances and distributions

The properties of aerosols that reside in the upper atmosphere are described. Special emphasis is given to the influence these aerosols have on ozone observation systems, mainly through radiative effects, and on ambient ozone concentrations, mainly through chemical effects. It has long been appreciated that stratospheric particles can interfere with the remote sensing of ozone distribution. The mechanism and magnitude of this interference are evaluated. Separate sections deal with the optical properties of upper atmospheric aerosols, long-term trends in stratospheric aerosols, perturbations of the stratospheric aerosol layer by volcanic eruptions, and estimates of the impacts that such particles have on remotely measured ozone concentrations. Another section is devoted to a discussion of the polar stratospheric clouds (PSC's). These unique clouds, recently discovered by satellite observation, are now thought to be intimately connected with the Antarctic ozone hole. Accordingly, interest in PSC's has grown considerably in recent years. This chapter describes what we know about the morphology, physical chemistry, and microphysics of PSC's.

Turco, R. P.↗
NASA NTRS1992

A survey of ultraviolet variability in blazars

This is the first comprehensive, consistent survey of the ultraviolet variability properties of a large sample of blazars. All of the 14 blazars with five or more observations in a single IUE camera showed significant variability. The strength of the ultraviolet variability is positively correlated with both the apparent ultraviolet luminosity and the degree of optical polarization of the source. This is the first clear indication that the ultraviolet continua of blazars are beamed. A search for rapid variability yielded nine 'events' with doubling time scales of 0.5-7 days. These rapid flux variations and correlations argue for the standard synchrotron self-Compton model, and against the accretion disk model, which would predict slower variations and the opposite sense of correlation.

Edelson, Rick↗
NASA NTRS2008

Mid-Infrared OPO for High Resolution Measurements of Trace Gases in the Mars Atmosphere

The Martian atmosphere is composed primarily (>95%) of CO2 and N2 gas, with CO, O2, CH4, and inert gases such as argon comprising most of the remainder. It is surprisingly dynamic with various processes driving changes in the distribution of CO2, dust, haze, clouds and water vapor on global scales in the meteorology of Mars atmosphere [I]. The trace gases and isotopic ratios in the atmosphere offer important but subtle clues as to the origins of the planet's atmosphere, hydrology, geology, and potential for biology. In the search for life on Mars, an important process is the ability of bacteria to metabolize inorganic substrates (H2, CO2 and rock) to derive energy and produce methane as a by-product of anaerobic metabolism. Trace gases have been measured in the Mars atmosphere from Earth, Mars orbit, and from the Mars surface. The concentration of water vapor and various carbon-based trace gases are observed in variable concentrations. Within the past decade multiple groups have reported detection of CH4, with concentrations in the 10's of ppb, using spectroscopic observations from Earth [2]. Passive spectrometers in the mid-infrared (MIR) are restricted to the sunlit side of the planet, generally in the mid latitudes, and have limited spectral and spatial resolution. To accurately map the global distribution and to locate areas of possibly higher concentrations of these gases such as plumes or vents requires an instrument with high sensitivity and fine spatial resolution that also has global coverage and can measure during both day and night. Our development goal is a new MIR lidar capable of measuring, on global scales, with sensitivity, resolution and precision needed to characterize the trace gases and isotopic ratios of the Martian atmosphere. An optical parametric oscillator operating in the MIR is well suited for this instrument. The sufficient wavelength tuning range of the OPO can extend the measurements to other organic molecules, CO2, atmospheric water vapor, clouds, temperature, dust, and aerosols, as well as possibly polar-cap properties. Our OPO-approach may allow a new capability for active remote sensing of the outer planets and moons, where the weaker sunlight further limit passive instruments. Here we report on the OPO development effort for this lidar instrument.

Yu, Anthony W.↗
NASA NTRSDate not supplied

Study of Martian Polar Caps with GISS ROCKE-3D GCM

Martian polar caps consist of both H 2 O and CO 2 ice. While H 2 O ice is mainly passive on modern Mars, it may have not been the case in recent Martian history, when its obliquity was higher, or when it was changing rapidly. The distribution of ice species in the snowpack affects its physical and thermodynamic properties. In the upper layers, it determines its albedo and thermal emissivity. Thus understanding the mutual effect between these ices and their interaction with the atmosphere is crucial for understanding the evolution of Martian polar regions. In this study, we employ a newly-developed Exotic Ices snow model coupled to the NASA Goddard Institute for Space Studies (GISS) ROCKE-3D planetary General Circulation Model (GCM) [1] to study the behavior of Martian polar caps. ROCKE-3D is a planetary GCM developed at NASA GISS as an extension of its Earth climate model, modelE [2]. It has been extensively used to simulate climate of various planets, including Mars (e.g. [3,4]). The Exotic Ices snow model was specially developed for planetary applications which involve more than one condensable in the atmosphere, in which case snow can contain multiple species of ice (CO2 and H 2 O in the Mars case). For each species of ice, the model uses their proper physical properties and phase diagram, but otherwise it treats all species of ice on an equal footing. The combined effects on albedo, thermal inertia and mutual insulation are treated accordingly. The snowpack interacts with the atmospheric dust cycle, and can accumulate a prognostic amount of dust, though the effect of dust on snow properties is not currently treated explicitly, and is prescribed. In this study, we first validate our model against the modern Martial climate, for which we use mission results from Mars Climate Sounder (atmospheric temperature and dust optical depth), SPICAM on Mars Express (atmospheric water), and Viking 2 (surface pressure). We investigate the effect of snow radiative properties on CO 2 and water cycles and the ability of our model to accurately reproduce those with minimal model tuning. We then perform simulations for several obliquities from a recent Martian past, and investigate the behavior of the Martian polar caps in such conditions.

Mars↗
NASA NTRS2010

Statistics of Cloud Optical Properties from Airborne Lidar Measurements

Cloud optical properties, such as extinction-to-backscatter ratio and depolarization ratio, have a significant impact on the accuracy of cloud extinction retrievals from lidar systems because parameterizations of these variables are often used in non-ideal conditions to determine cloud type and optical depth. Statistics and trends of these optical parameters were analyzed for four years, 2003-2007, of Cloud Physics Lidar data during five projects of varying geographic locations. Extinction-to-backscatter ratio (at 532 nm) was derived by calculating the transmission loss through the cloud layer, while depolarization ratio was computed using the parallel and perpendicular polarized 1064 nm channels. The majority of the cloud layers yielded an S-ratio between 10 and 40 sr with the S-ratio frequency distribution centered at 25 sr for ice clouds, 21 sr for mixed phase clouds, and 11 sr for water clouds. On average for ice clouds, S ratio slightly decreased with decreasing temperature, while depolarization ratio increased significantly as temperatures decreased. Trends for water and mixed phase clouds were also observed. Ultimately, these observed trends in optical properties as a function of temperature and geographic location will improve current parameterizations of extinction-to-backscatter ratio, which consequently increases accuracy in cloud optical depth and radiative forcing estimates.

Yorks, John E.↗
DOE OSTI2022

Strong Induced Circular Dichroism in a Hybrid Lead‐Halide Semiconductor Using Chiral Amino Acids for Crystallite Surface Functionalization

Abstract Chirality is a desired property in functional semiconductors for optoelectronic, catalytic, and spintronic applications. Here, introducing enantiomerically‐pure 3‐aminobutyric acid (3‐ABA) into thin films of the 1D semiconductor dimethylammonium lead iodide (DMAPbI 3 ) is found to result in strong circular dichroism (CD) in the optical absorption. X‐ray diffraction and grazing incidence small angle X‐ray scattering (GISAXS) are applied to gain molecular‐scale insights into the chirality transfer mechanism, which is attributed to a chiral surface modification of DMAPbI 3 crystallites. This study demonstrates that the CD signal strength can be controlled by the amino‐acid content relative to the crystallite surface area. The CD intensity is tuned by the composition of the precursor solution and the spin‐coating time, thereby achieving anisotropy factors ( g abs ) as high as 1.75 × 10 –2 . Grazing incidence wide angle scattering reveals strong preferential ordering that can be suppressed via tailored synthesis conditions. Different contributions to the chiroptical properties are resolved by a detailed analysis of the CD signal utilizing an approach based on the Mueller matrix model. This report of a novel class of chiral hybrid semiconductors with precise control over their optical activity presents a promising approach for the design of circularly polarized light detectors and emitters.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Optical and chemical analysis of iron in Luna 20 plagioclase.

Review of analytical data on the iron content of Luna 20 anorthitic plagioclase, obtained by a highly sensitive technique for measuring polarized absorption related to crystal-field splittings and by automated electron microprobe analysis of oriented single crystals. The iron content is found to range from a few hundredths to a few tenths of a weight per cent from crystal to crystal. The optical and chemical properties of the iron appear to be caused by postcrystallization migration and exsolution. Postcrystallization effects may obscure evidence of the original oxidation state and iron concentration of these crystals.

Bell, P. M.↗
NASA NTRS1994

Passive microwave observations of the Wedell Sea during austral winter and early spring

The results of multispectral passive microwave observations (6.7 to 90-GHz) are presented from the cruises of the FS Polarstern in the Weddell Sea from July to December 1986. This paper includes primarily the analysis of radiometric observations taken at ice station sites. Averaged emissivity spectra for first-year (FY) ice were relatively constant throughout the experiment and were not statistically different from FY ice signatures in the Arctic. Detailed ice characterization was carried out at each site to compare the microwave signatures of the ice with the physical properties. Absorption optical depths of FY ice were found to be sufficiently high that only the structure in the upper portions of the ice contributed significantly to interstation emissivity variations. The emissivities at 90-GHz, e(90), had the greatest variance. Both e(90) at vertical polarization and GR(sub e)(90, 18.7)(defined as (e(sub V)(90)-e(sub V)(18.7))/e(sub V)(90 + e(sub V)(18.7)) depended on the scattering optical depth which is a function of the snow grain diameter and layer thickness. The variance showed a latitude dependence and is probably due to an increase in the strength of snow metamorphism nearer the northern edge of the ice pack. The contribution of variations of near-surface brine volume to the emissivity was not significant over the range of values encountered at the station sites. Emissivity spectra are presented for a range of thin ice types. Unsupervised principal component analysis produced three significant eigenvectors and showed a separation among four different surface types: open water, thin ice, FY ice, and FY ice with a thick snow cover. A comparison with SMMR satellite data showed that average ice concentrations derived from the ship's ice watch log were consistent with the satellite concentrations. The surface based emissivities for FY ice were also compared with emissivities calculated from scanning multichannel microwave radiometer (SMMR) satellite radiances. Best agreement was found at 6.7 and 10-GHz, while at 18 and 37-GHz, SMMR emissivities were slightly lower than surface based results. For the three lower frequencies agreement was found within a confidence limit of 95% and for 37-GHz within about 90%.

Grenfell, T. C.↗
NASA NTRS1999

Global Observations of Aerosols and Clouds from Combined Lidar and Passive Instruments to Improve Radiation Budget and Climate Studies

Current uncertainties in the effects of clouds and aerosols on the Earth radiation budget limit our understanding of the climate system and the potential for global climate change. Pathfinder Instruments for Cloud and Aerosol Spaceborne Observations - Climatologie Etendue des Nuages et des Aerosols (PICASSO-CENA) is a recently approved satellite mission within NASA's Earth System Science Pathfinder (ESSP) program which will address these uncertainties with a unique suite of active and passive instruments. The Lidar In-space Technology Experiment (LITE) demonstrated the potential benefits of space lidar for studies of clouds and aerosols. PICASSO-CENA builds on this experience with a payload consisting of a two-wavelength polarization-sensitive lidar, an oxygen A-band spectrometer (ABS), an imaging infrared radiometer (IIR), and a wide field camera (WFC). Data from these instruments will be used to measure the vertical distributions of aerosols and clouds in the atmosphere, as well as optical and physical properties of aerosols and clouds which influence the Earth radiation budget. PICASSO-CENA will be flown in formation with the PM satellite of the NASA Earth Observing System (EOS) to provide a comprehensive suite of coincident measurements of atmospheric state, aerosol and cloud optical properties, and radiative fluxes. The mission will address critical uncertainties iin the direct radiative forcing of aerosols and clouds as well as aerosol influences on cloud radiative properties and cloud-climate radiation feedbacks. PICASSO-CENA is planned for a three year mission, with a launch in early 2003. PICASSO-CENA is being developed within the framework of a collaboration between NASA and CNES.

Winker, David M.↗
NASA NTRS2006

Use of Photoelastic Modulators for High-accuracy Spectropolarimetric Imaging of Aerosols

Passive multiangular, multispectral, and polarimetric sensing approaches each have unique strengths for the measurement of tropospheric aerosol column abundances and microphysical properties. Current spaceborne multispectral and multiangular aerosols sensors operate at approximately 1 km resolution. Under NASA's Instrument Incubator Program, we are developing an electro-optic imaging approach that will enable adding high-accuracy polarimetry to such observations. To achieve a degree of linear polarization (DOLP) uncertainty of 0.5%, our approach temporally modulates the linear-polarization component of incoming light at a rapid rate, enabling each detector within a focal-plane array, combined with polarization analyzers, to measure the relative proportions of the linear Stokes components Q or U to the total intensity. Our system uses tandem photoelastic modulators (PEMs) within a high-reflectance, low diattenuation camera design. The two PEMs vibrate at slightly different resonant frequencies, leading to modulation of the polarized light at a heterodyne frequency of ~25 Hz. High-speed (1 kHz) readout of the detector arrays samples the output waveforms from which Q/I and U/I are derived. We report on experimental and theoretical analyses of PEM and optical system performance, along with plans for developing ruggedized PEMs capable of withstanding launch and on-orbit stresses.

photoelastics↗
DOE OSTI2025

Interpretable ensemble learning unveils main aerosol optical properties in predicting cloud condensation nuclei number concentration

Variations in cloud condensation nuclei number concentration (N CCN ) significantly influence cloud microphysics, yet direct N CCN measurements remain challenging. Here, we present an N CCN ensemble learning (NEL) model utilizing ensemble learning and interpretability analysis on aerosol optical parameters. Validated at two land sites, two ocean sites and one polar site within the Atmospheric Radiation Measurement program, the mean absolute percentage error range of the NEL model across different environments is from 12% to 36%, demonstrating high accuracy. Key findings reveal that aerosol optical parameters can serve as predictors for N CCN . Aerosol scattering and backscattering coefficients, absorption coefficient, backscatter fraction (BSF), and Ångström exponent (AE) are positively correlated with N CCN , while single scattering albedo shows negative correlations. N CCN prediction at land sites is highly sensitive to BSF, largely driven by the backscattering coefficient, as fine particles dominate in these sites. At ocean sites, N CCN prediction is more sensitive to AE, primarily influenced by the scattering coefficient, due to the higher proportion of larger particles. At the polar site, N CCN prediction shows sensitivity to both BSF and AE, mainly driven by the scattering coefficient, as polar sites are cleaner and contain larger particles. These differences reflect the variation in particle size and number concentration across different environments.

Atmospheric science↗
NASA NTRS1993

Inference of cirrus cloud properties using satellite-observed visible and infrared radiances. II - Verification of theoretical cirrus radiative properties

The study presents a methodology developed to apply a parameterization of radiative transfer calculations to satellite analyses of cirrus clouds. Cloud heights and optical depths are derived from visible and IR window measurements taken during FIRE when cirrus clouds were present. Geostationary satellite retrievals are compared to lidar-derived cloud heights and retrievals from a polar-orbiting satellite taken at different angles to determine which theoretical models of scattering phase function and single-scattering albedo best represent actual cirrus clouds. Models using small scattering phase function and single-scattering albedo best represent actual cirrus clouds. It is concluded that interpretation of cirrus reflectance with water-droplet models leads to biased results. The cloud-height and optical depth biases can be minimized with the aid of the C20 or cirrostratus models.

Minnis, Patrick↗
DOE OSTI2026

A Visual Understanding of Circular Dichroism Spectroscopy

Mapping chemical and structural properties to electronic and magnetic responses is critical to many applications such as quantum information science, where the precise storage and transmission of unique information is paramount. Specifically, constructing molecules and materials that provide strong polarized responses at tunable frequencies and with large anisotropies is key to optical processing of quantum information. Chiral molecules provide chiroptical response to circularly polarized light, making them attractive for quantum information science and other applications related to sensing, polarized photodetectors, and spintronics. Predicting a molecular design, a priori, with large anisotropies to circularly polarized light is challenging due to the complex interplay between electric and magnetic components of the optical response. In this work, we explore a visual representation of the electronic chiroptical response by decomposing the rotary strength into its constituent components. Here, we make use of the intuitive electronic oscillator framework to develop classical intuition regarding the rotary strength and its constituents. We explore three model chemical systems that exhibit local and global chirality. Our analysis reveals that local chirality necessarily exhibits competition between the local chiral center and chirality induced in other fragments of the molecule, resulting in both unexpected nonmonotonic trends and sign flips in chemically adjacent geometries. Furthermore, we can visually distinguish between local and global chirality via examination of the transition chiral tensor. Interestingly, we make strong connections to ferromagnetic and antiferromagnetic spin systems in that chiroptically inactive transitions exhibit antiferromagnetic-like alternating orbital patterns while active transitions show domain formation in an ferromagnetic-like alignment that produces a net chiroptical response.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Infrared properties of Titan's clouds and aerosols

Using Voyager 1 Infrared Interferometer Spectrometer (IRIS) data, the infrared properties of Titan's north polar hood continuum were deduced. Stratospheric opacities were found to increase monotonically with wavenumber between 250 and 600/cm. The increase becomes more extreme with decreasing altitude; this behavior is consistent with a photochemical aerosol overlying layers of condensated organics lower down. Stratospheric optical thicknesses of order 0.1 were found at 600/cm, which became smaller as the wavelength decreased. An aerosol mass mixing ratio approximately 6 x 10 exp -8 and a mass flux approximately 10 exp -14 g/sq cm/s was inferred at 160 km. The column abundance for condensed C4N2 was found to exceed that for the vapor by a factor of 30 or more. An upper limit of 4 x 10 exp -10 was inferred for the mole fraction of gaseous C4N2.

Samuelson, Robert E.↗
NASA NTRS2004

Status of Solar Sail Material Characterization at NASA's Marshall Space Flight Center

Near term solar sail propelled science missions are targeting the Lagrange point 1 (Ll) as well as locations sunward of L1 as destinations. These near term missions include the Solar Polar Imager' and the L1 Diamond '. The Environmental Effects Group at NASA's Marshall Space Flight Center (MSFC) continues to actively characterize solar sail material in preparation for these near term solar sail missions. Previous investigations indicated that space environmental effects on sail material thermo-optical properties were minimal and would not significantly affect the propulsion efficiency of the sail. These investigations also indicated that the sail material mechanical stability degrades with increasing radiation exposure. This paper will further quantify the effect of space environmental exposure on the mechanical properties of candidate sail materials. Candidate sail materials for these missions include Aluminum coated Mylar(TradeMark), Teonex(TraeMark), and CP1 (Colorless Polyimide). Experimental data will be presented on sail material response to charged particle radiation and subsequent Hypervelocity Impact (HVI). Data will also be presented indicating mechanical property variations in sail material resulting from electron exposure, proton exposure, and a combined electron and proton exposure. Tabular data consisting of areal density, thickness, thermo-optical, mechanical, and electrical properties, vacuum stability and outgassing will be presented.

Edwards, David L.↗
NASA NTRS2004

Space Environmental Effects on Candidate Solar Sail Materials

The National Aeronautics and Space Administration's (NASA) Marshall Space Flight Center (MSFC) continues research into the utilization of photonic materials for spacecraft propulsion. Spacecraft propulsion, using photonic materials, will be achieved using a solar sail. A solar sail operates on the principle that photons, originating from the sun, impart pressure to the sail and therefore provide a source for spacecraft propulsion. The pressure imparted ot a solar sail can be increased, up to a factor of two, if the sun-facing surface is perfectly reflective. Therefore, these solar sails are generally composed of a highly reflective metallic sun-facing layer, a thin polymeric substrate and occasionally a highly emissive back surface. Near term solar sail propelled science missions are targeting the Lagrange point 1 (L1) as well as locations sunward of L1 as destinations. These near term missions include the Solar Polar Imager and the L1 Diamond. The Environmental Effects Group at NASA's Marshall Space Flight Center (MSFC) continues to actively characterize solar sail material in preparation for these near term solar sail missions. Previous investigations indicated that space environmental effects on sail material thermo-optical properties were minimal and would not significantly affect the propulsion efficiency of the sail. These investigations also indicated that the sail material mechanical stability degrades with increasing radiation exposure. This paper will further quantify the effect of space environmental exposure on the mechanical properties of candidate sail materials. Candidate sail materials for these missions include Aluminum coated Mylar, Teonex, and CP1 (Colorless Polyimide). These materials were subjected to uniform radiation doses of electrons and protons in individual exposures sequences. Dose values ranged from 100 Mrads to over 5 Grads. The engineering performance property responses of thermo-optical and mechanical properties were characterized. The contribution of Near Ultraviolet (NUV) radiation combined with electron and proton radiation was also investigated.

Edwards, David L.↗
DOE OSTI2021

Optically Induced Static Magnetization in Metal Halide Perovskite for Spin‐Related Optoelectronics

Abstract Understanding the feasibility to couple semiconducting and magnetic properties in metal halide perovskites through interface design opens new opportunities for creating the next generation spin‐related optoelectronics. In this work, a fundamentally new phenomenon of optically induced magnetization achieved by coupling photoexcited orbital magnetic dipoles with magnetic spins at perovskite/ferromagnetic interface is discovered. The depth‐sensitive polarized neutron reflectometry combined with in situ photoexcitation setup, constitutes key evidence of this novel effect. It is demonstrated that a circularly polarized photoexcitation induces a stable magnetization signal within the depth up to 7.5 nm into the surface of high‐quality perovskite (MAPbBr 3 ) film underneath a ferromagnetic cobalt layer at room temperature. In contrast, a linearly polarized light does not induce any detectable magnetization in the MAPbBr 3 . The observation reveals that photoexcited orbital magnetic dipoles at the surface of perovskite are coupled with the spins of the ferromagnetic atoms at the interface, leading to an optically induced magnetization within the perovskite’s surface. The finding demonstrates that perovskite semiconductor can be bridged with magnetism through optically controllable method at room temperature in this heterojunction design. This provides the new concept of utilizing spin and orbital degrees of freedom in new‐generation spin‐related optoelectronic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Photocurrent Spectroscopy of Dark Magnetic Excitons in 2D Multiferroic NiI 2

Abstract Two‐dimensional (2D) antiferromagnetic (AFM) semiconductors are promising components of opto‐spintronic devices due to terahertz operation frequencies and minimal interactions with stray fields. However, the lack of net magnetization significantly limits the number of experimental techniques available to study the relationship between magnetic order and semiconducting properties. Here, they demonstrate conditions under which photocurrent spectroscopy can be employed to study many‐body magnetic excitons in the 2D AFM semiconductor NiI 2 . The use of photocurrent spectroscopy enables the detection of optically dark magnetic excitons down to bilayer thickness, revealing a high degree of linear polarization that is coupled to the underlying helical AFM order of NiI 2 . In addition to probing the coupling between magnetic order and dark excitons, this work provides strong evidence for the multiferroicity of NiI 2 down to bilayer thickness, thus demonstrating the utility of photocurrent spectroscopy for revealing subtle opto‐spintronic phenomena in the atomically thin limit.

Lebedev, Dmitry↗