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At least 433 records · Page 24

A survey of bimolecular ion-molecule reactions for use in modeling the chemistry of planetary atmospheres, cometary comae, and interstellar clouds

All bimolecular positive ion-molecule reactions reported from 1965 to 1985 for temperatures below 1000 K are included in the present survey of those ion-molecule reactions pertinent to the chemistries of planetary atmospheres, cometary comae, and interstellar clouds. This survey is intended as an update of the first, by Huntress (1977). The tabular presentation is organized according to reactant ion, with cross-references for both the ionic and the neutral reactants as well as the ionic and neutral products.

Anicich, V. G.↗

New laboratory measurements on ammonia's inversion spectrum, with implications for planetary atmospheres

Microwave spectral measurements have been performed on pure room-temperature gaseous ammonia at frequencies from 1.75 to 18 GHz (1.7-17 cm), at 50-, 100-, and 300-torr pressures. These measurements are part of a laboratory program to measure the microwave absorption spectrum of ammonia, under conditions applicable to giant planet atmospheres, now in progress at the Jet Propulsion Laboratory. The pure ammonia data reported here agree well with previous data by Bleaney and Loubser (1950) at 100 and 300 torrs, and with predictions of the absorptivity formalism published by Berge and Gulkis. Success with pure ammonia but failure with mixtures of ammonia in hydrogen and helium (Spilker, 1990) indicates that the Berge and Gulkis formalism does not correctly handle foreign-gas effects on ammonia inversion lines. This may require modifying conclusions of radio astronomical and radio occultation studies that used this formalism. Notably, a suggested depletion of ammonia and superabundance of hydrogen sulfide may have been exaggerated as a result of inaccuracies in the Berge and Gulkis formalism.

Spilker, Thomas R.↗

Short-term cyclic variations and diurnal variations of the Venus upper atmosphere

The vertical structure of the nighttime thermosphere and exosphere of Venus was discussed. A comparison of the day and nighttime profiles indicates, contrary to the model of Dickinson and Riley (1977), that densities (principally atomic oxygen) dropped sharply from day to night. It was suggested either that the lower estimates were related to cooler exospheric temperatures at night or that the atomic bulge was flatter than expected at lower altitudes. Large periodic oscillations, in both density and inferred exospheric temperatures, were detected with periods of 5 to 6 days. The possibility that cyclic variations in the thermosphere and stratosphere were caused by planetary-scale waves, propagated upward from the lower atmosphere, was investigated using simultaneous temperature measurements obtained by the Venus radiometric temperature experiment (VORTEX). Inferred exospheric temperatures in the morning were found to be lower than in the evening as if the atmosphere rotated in the direction of the planet's rotation, similar to that of earth. Superrotation of the thermosphere and exosphere was discussed as a possible extension of the 4-day cyclic atmospheric rotation near the cloud tops.

Keating, G. M.↗

The Formation of Solid Particles from their Gas-Phase Molecular Precursors in Cosmic Environments with NASA Ames' COSmIC Facility

We present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid gains from their gas-phase molecular precursors in environments as varied as stellar/circumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

COSmIC↗

Synthesis and Spectroscopy of Large Carbon Molecules with Ames' COSmIC Facility in Support of NASA's Space Missions

We present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid gains from their gas-phase molecular precursors in environments as varied as stellar/circumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed.

Spectroscopy↗

Laboratory Studies of Cosmic Dust with NASA Ames' COSmIC Facility – Applications to Interstellar and Planetary Issues

I will present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in deciphering the diffuse interstellar bands (DIBs) and in monitoring in the laboratory the formation of solid dust grains from their gas-phase molecular precursors in environments as varied as stellarcircumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

COSmIC↗

Microsystems, Space Qualified Electronics and Mobile Sensor Platforms for Harsh Environment Applications and Planetary Exploration

NASA Glenn Research Center is presently developing and applying a range of sensor and electronic technologies that can enable future planetary missions. These include space qualified instruments and electronics, high temperature sensors for Venus missions, mobile sensor platforms, and Microsystems for detection of a range of chemical species and particulates. A discussion of each technology area and its level of maturity is given. It is concluded that there is a strong need for low power devices which can be mobile and provide substantial characterization of the planetary environment where and when needed. While a given mission will require tailoring of the technology for the application, basic tools which can enable new planetary missions are being developed.

Hunter, Gary W.↗

Development of Electronics for Low-Temperature Space Missions

Electronic systems that are capable of operating at cryogenic temperatures will be needed for many future NASA space missions, including deep space probes and spacecraft for planetary surface exploration. In addition to being able to survive the harsh deep space environment, low-temperature electronics would help improve circuit performance, increase system efficiency, and reduce payload development and launch costs. Terrestrial applications where components and systems must operate in low-temperature environments include cryogenic instrumentation, superconducting magnetic energy storage, magnetic levitation transportation systems, and arctic exploration. An ongoing research and development project for the design, fabrication, and characterization of low-temperature electronics and supporting technologies at NASA Glenn Research Center focuses on efficient power systems capable of surviving in and exploiting the advantages of low-temperature environments. Supporting technologies include dielectric and insulating materials, semiconductor devices, passive power components, optoelectronic devices, and packaging and integration of the developed components into prototype flight hardware. An overview of the project is presented, including a description of the test facilities, a discussion of selected data from component testing, and a presentation of ongoing research activities being performed in collaboration with various organizations.

Patterson, Richard L.↗

Trace of planetary nebula evolution by distance-independent parameters

Using existing infrared and radio data on a sample of 432 planetary nebulae, we derived a number of distance-independent parameters for comparison with evolutionary models of planetary nebulae. We find that many of the observed properties of planetary nebulae can be explained by current central star evolutionary models, even if the time scales are subject to significant change by a factor of up to an order of magnitude. Specifically, we find that the evolutionary tracks are well separated in the radio surface brightness-central star temperature plane, therefore allowing us to determine the core mass of individual planetary nebulae. We also obtain the luminosity and gravity of the central stars of individual nebulae, from their temperature and core mass, without relying on the distance assumptions. We find that our results of the core mass are in good agreement with those of Mendez et al. (1992) and Tylenda et al. (1991). A systematic, large discrepancy is found between the luminosity found in this work and that found by Gathier and Pottasch (1986).

Zhang, C. Y.↗

Miniaturized Single-Shot Valve and its Application to the ExoMars Pasteur Payload

Hermetically sealing a gas tank and opening it into tubing under telecommand control is a function required in various space instruments. There are a number of space valves that are power saving, withstand vibration, and do not contaminate the gas. But none of them combines these features with low mass and the ability to withstand temperatures of 130 C during the sterilization process mandatory for planetary missions. In this paper, a novel miniature valve is presented, which is particularly adapted to space applications. It is electrically actuated, utilizing a bimetallic snap-disc that pierces a metallic membrane by a needle pin, thereby opening the valve. The design of this single-shot valve is such that it allows it to withstand a temperature of 130 C and a pressure of 50 bars. The valve is also lightweight (6.62 g) and it requires only 9 W to operate.

Muller, Pierre↗

Development of Electronics for Low Temperature Space Missions

The operation of electronic systems at cryogenic temperatures is anticipated for many future NASA space missions such as deep space probes and planetary surface exploration. For example, an unheated interplanetary probe launched to explore the rings of Saturn would reach an average temperature near Saturn of about -183 C. In addition to surviving the deep space harsh environment, electronics capable of low temperature operation would contribute to improving circuit performance, increasing system efficiency, and reducing payload development and launch costs. Terrestrial applications where components and systems must operate in low temperature environments include cryogenic instrumentation, superconducting magnetic energy storage, magnetic levitation transportation system, and arctic exploration. An on-going research and development program on low temperature electronics at the NASA Glenn Research Center focuses on the development of efficient power systems capable of surviving and exploiting the advantages of low temperature environments. Inhouse efforts include the design, fabrication, and characterization of low temperature power systems and the development of supporting technologies for low temperature operations, such as dielectric and insulating materials, semiconductor devices, passive power components, opto-electronic devices, as well as packaging and integration of the developed components into prototype flight hardware.

Patterson, Richard L.↗

Electronic Components and Systems for Cryogenic Space Applications

Electronic components and systems capable of operation at cryogenic temperatures are anticipated in many future NASA space missions such as deep space probes and planetary surface exploration. For example, an unheated interplanetary probe launched to explore the rings of Saturn would reach an average temperature near Saturn of about - 183 C. In addition to surviving the deep space harsh environment, electronics capable of low temperature operation would contribute to improving circuit performance, increasing system efficiency, and reducing payload development and launch costs. Terrestrial applications where components and systems must operate in low temperature environments include cryogenic instrumentation, superconducting magnetic energy storage, magnetic levitation transportation system, and arctic exploration. An on-going research and development program at the NASA Glenn Research Center focuses on the development of reliable electronic devices and efficient power systems capable of surviving in low temperature environments. An overview of the program will be presented in this paper. A description of the low temperature test facilities along with selected data obtained from in-house component testing will also be discussed. Ongoing research activities that are being performed in collaboration with various organizations will also be presented.

Patterson, R. L.↗

Examining Metasomatism in Low fO2 Environments: Exploring Sulfidation Reactions in Various Planetary Bodies

Hydrothermal systems are common on Earth in a variety of tectonic environments and at different temperature and pressure conditions. These systems are commonly dominated by H2O, and they are responsible for element transport and the production of ore deposits. Unlike the Earth (fO2~FMQ), many other planetary bodies (e.g., Moon and asteroids) have fO2 environments that are more reduced (IW+/-2), and H2O is not the important solvent responsible for element transport. One example of a texture that could result from element transport and metasomatism, which appears to occur on numerous planetary bodies, is sulfide-silicate intergrowths. These subsolidus assemblages are interpreted to form as a result of sulfidation reactions from a S-rich fluid phase. The composition of fluids may vary within and among parent bodies and could be sourced from magmatic (e.g. Moon) or impact processes (e.g. HED meteorites and Moon). For example, it has been previously demonstrated on the Moon that the interaction of olivine with a hydrogen- and sulfur-bearing vapor phase altered primary mineral assemblages, producing sulfides (e.g. troilite) and orthopyroxene. Formation of these types of "sulfidation" assemblages can be illustrated with the following reaction: Fe2SiO4(ol) + 1/2 S(2 system) = FeS(troi)+ FeSiO3(opx) + 1/2 O2 system. The products of this reaction, as seen in lunar rocks, is a vermicular or "worm-like" texture of intergrown orthopyroxene and troilite. Regardless of the provenance of the S-bearing fluid, the minerals in these various planetary environments reacted in the same manner to produce orthopyroxene and troilite. Although similar textures have been identified in a variety of parent bodies, a comparative study on the compositions and the origins of these sulfide-silicate assemblages has yet to be undertaken. The intent of this study is to examine and compare sulfide-silicate intergrowths from various planetary bodies to explore their petrogenesis and examine the nature of low fO2 (IW+/-2) element migration and sulfidation reactions.

Srinivasan, P.↗

Global oscillation amplitudes excited by the Jupiter-comet collision

The energy released during the collision of fragments of comet Shoemaker-Levy 9 with Jupiter in 1994 July may excite a spectrum of global oscillation modes. We estimate the maximum amplitudes to which the p-modes, discontinuity modes, inertial modes, and r-modes can be excited by assuming that the full kinetic energy of the fragment, which we take to be 10(exp 30) ergs, is converted into the energy of each individual mode. We have used two realistics Jovian models as the basis for our estimates: one with and one without the predicted 'plasma phase transition' (PPT) of hydrogen. A density discontinuity in the planet's hydrogen-helium envelope is associated with the PPT. We find that high-frequency p-modes, with periods approximately less than 15 minutes, may be excited to sufficiently large amplitudes to be observable as Doppler shifts (velocity amplitudes approximately greater than serveral m/s) or temperature variations (delta(T) approximately greater than 0.01 K) at the planetary surface. Inertial modes may also be observable. If the PPT exists in Jupiter, inertial modes with periods approximately 8 hr or approximately 2.2 days trapped in the surface region of the planet, above the PPT, may be detectable as temperature fluctuations of order delta(T) approximately 0.01 K. Inertial modes with periods of order 8-8.5 hr appear to be particularly strongly excited if the PPT exists. If the PPT does not exist in Jupiter, intertial modes with periods approximately 8-8.5 hr have much lower amplitudes. In this case, inertial modes with periods longer than approximately 18 hr may produce temperature fluctuations of order delta(T) approximately 0.01 K. Discontinuity modes associated with the PPT and r-modes unfortunately may not reach observable amplitudes.

Lee, U.↗

The Response of the Quasi-Biennial Oscillation to Increased CO and its Modulation by Composition Feedbacks

The Quasi-Biennial Oscillation (QBO) impacts the large-scale circulation by altering lower stratospheric meridional temperature gradients which alter the propagation of upward propagating planetary waves. Proposed teleconnections of the QBO include impacts on the stratospheric polar vortices, extratropical surface winter climate, and the Madden-Julian Oscillation. However, long-term projections of the QBO remain highly uncertain. While recent multi-model investigations (Richter et al. 2019, Butchart et al. 2020) show that the amplitude of the QBO weakens robustly among models, changes in QBO period and stability remain highly uncertain. Here we examine the QBO response to increased greenhouse gases using the NASA Goddard Institute for Space Studies Middle Atmosphere Model E2.2 (Rind et al., 2020; Orbe et al. 2020). Compared to lower vertical resolution versions of ModelE, E2.2 also has a higher model top (0.002 hPa) and employs additional interactive non-orographic gravity wave drag sources from convection and shear, which produce a sufficiently realistic QBO, thus rendering it suitable for use in climate change studies. Overall, we find that both the QBO period and amplitude decrease in response to increased CO , the former related to increased lower stratospheric momentum fluxes (associated with convection) and the latter associated partly with a stronger residual mean circulation. Experiments integrated using fully interactive chemistry also reveal that ozone feedbacks significantly impact the magnitude of the QBO amplitude response. Finally, integrations using fixed (pre-industrial) sea surface temperatures (SST) show that the QBO amplitude responds differently to rapid adjustments versus SST feedbacks, as compared to the QBO period.

Quasi-Biennial Oscillation↗

A Brief Overview of Silicon Carbide Based Smart Sensor System Technologies for Planetary and Aeronautics Applications

A range of aerospace application related to planetary exploration and aeronautic engine operations require Smart Sensor System technologies operational in harsh environments. A Smart Sensor System as described here implies the use of sensors combined with electronics and other supporting technologies. For example, missions to the surface of planets like Venus or Mercury are challenged by extreme temperatures and environments, e.g., extended Venus operation 465°C [1]. In response, NASA has been developing capabilities for a small lander that is designed to operate for months in the extreme temperatures. These capabilities span electronics, sensors, communications, and power. Such a lander would enable new revolutionary science. Similar game changing capabilities are enabled by the introduction of high temperature smart systems into aeronautic engine applications to enable distributed intelligence within the engine system [2]. Core to meeting these applications is operational harsh environment electronics, corresponding sensor systems, and their integration. This presentation concentrates on the status of Smart System technologies emphasizing the role of Silicon Carbide (SiC) electronics and sensors. For example, SiC integrated circuit (IC) electronics have matured to a state where a simple long-life scientific probe is feasible for extended Venus surface operations [1, 3]. Maturation of these high temperature electronics and other technologies has been part of NASA projects to provide an operational system for in situ exploration of the Venus surface for up to 60 days [1,3-4]. This is in parallel to work expanding the capabilities of the sensor technology to provide science measurements on the Venus surface. This technology development, as well as that for other planetary applications and intelligent high temperature engine operations, will be discussed.

engine monitoring↗

Effects of dispersed particulates on the rheology of water ice at planetary conditions

Effects of the initial grain size and the hard particulate impurities on the transient and the steady state flows of water ice I were investigated under laboratory conditions selected as appropriate for simulating those of the surfaces and interiors of large moons. The samples were molded with particulate volume fraction, phi, of 0.001 to 0.56 and particle sizes of 1 to 150 microns; deformation experiments were conducted at constant shortening rates of 4.4 x 10 exp -7 to 4.9 x 10 exp -4 per sec at pressures of 50 and 100 MPa and temperatures 77 to 223 K. The results obtained suggest that viscous drag occurs in the ice as it flows around hard particulates. Mixed-phase ice was found to be tougher than pure ice, extending the range of bulk plastic deformation vs. faulting to lower temperatures and higher strain rates. It is suggested that bulk planetary compositions of ice + rock (phi = 0.4-0.5) are roughly 2 orders of magnitude more viscous than pure ice, leading to thermal instability inside giant icy moons and possibly explaining the retention of crater topography on icy planetary surfaces.

Durham, William B.↗

Planetary Protection Concerns During Pre-Launch Radioisotope Power System Final Integration Activities

The Advanced Stirling Radioisotope Generator (ASRG) is a next-generation radioisotope-based power system that is currently being developed as an alternative to the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG). Power sources such as these may be needed for proposed missions to solar system planets and bodies that have challenging Planetary Protection (PP) requirements (e.g. Mars, Europa, Enceladus) that may support NASA s search for life, remnants of past life, and the precursors of life. One concern is that the heat from the ASRG could potentially create a region in which liquid water may occur. As advised by the NASA Planetary Protection Officer, when deploying an ASRG to Mars, the current COSPAR/NASA PP policy should be followed for Category IVc mission. Thus, sterilization processing of the ASRG to achieve bioburden reduction would be essential to meet the Planetary Protection requirements. Due to thermal constraints and associated low temperature limits of elements of the ASRG, vapor hydrogen peroxide (VHP) was suggested as a candidate alternative sterilization process to complement dry heat microbial reduction (DHMR) for the assembled ASRG. The following proposed sterilization plan for the ASRG anticipates a mission Category IVc level of cleanliness. This plan provides a scenario in which VHP is used as the final sterilization process. Keywords: Advanced Stirling Radioisotope Generator (ASRG), Planetary Protection (PP), Vapor hydrogen peroxide (VHP) sterilization.

Chen, Fei↗