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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Dry-processed electrodes enabled by polytetrafluoroethylene fibrillation for high-performance lithium-ion batteries

The dry processing technique of polytetrafluoroethylene (PTFE) fibrillation offers significant advancements in cost reduction, environmental impact, and electrochemical performance. Dry processing alone allows for ∼ 20–60% cost reduction and increases of up to 40 mg cm⁻2 of areal loading – it typically comes at a reduction of rate capability. By leveraging the network structure of fibers, this method enhances rate capability and cycling performance, providing a compelling alternative to the conventional and currently predominant wet processing. The review delves into PTFE fibrillation mechanisms and examines critical influencing factors including material properties and processing parameters. It also discusses challenges associated with the electrodes fabricated by PTFE fibrillation, including structural instability due to insufficient PTFE fibrillization, compromised electrical conductivity from an insufficient conductive network, inhomogeneous dispersion resulting from the absence of solvents, restricted ionic transport due to increased electrode thickness, inadequate adhesion to current collector because of low surface energy of PTFE, electrochemical degradation due to low lowest unoccupied molecular orbital (LUMO) level of PTFE, particle damage during processing and environmental concerns related PTFE being a perfluoroalkyl and polyfluoroalkyl substances (PFAS). Recent research innovations aimed at mitigating these issues, their application in beyond-lithium batteries, and future research directions are thoroughly discussed.

Park, Hyunji↗
DOE OSTI2014

Control of both particle and pore size in nanoporous palladium alloy powders

Energy storage materials often involve chemical reactions with bulk solids. Porosity within the solids can enhance reaction rates. The porosity can be either within or between individual particles of the material. Greater control of the size and uniformity of both types of pore should lead to enhancements of charging and discharging rates in energy storage systems. Furthermore, to control both particle and pore size in nanoporous palladium (Pd)-based hydrogen storage materials, first we created uniformly sized copper particles of about 1 μm diameter by the reduction of copper sulfate with ascorbic acid. In turn, these were used as reducing agents for tetrachloropalladate in the presence of a block copolymer surfactant. The copper reductant particles are geometrically self-limiting, so the resulting Pd particles are of similar size. The surfactant induces formation of 10 nm-scale pores within the particles. Some residual copper is alloyed with the Pd, reducing hydrogen storage capacity; use of a more reactive Pd salt can mitigate this. The reaction is conveniently performed in gram-scale batches.

25 ENERGY STORAGE↗
DOE OSTI2022

Mineral-hydrogel composites for mitigating harmful algal bloom and supplying phosphorous for photo-biorefineries

Harmful algal blooms (HAB) are a major environmental concern in eutrophic aquatic systems. To mitigate HABs and recover the phosphorus that drives algal growth, this study developed hydrogel composites seeded with calcium phosphate and wollastonite particles, which first adsorb phosphate (P) and then precipitate it as calcium phosphate. Using a fast-growing cyanobacterium, Synechococcus elongatus 2973, as a model microalga, we found that the mineral-hydrogel composites reduced dissolved P in BG11 media from 5.1 mg/L to 0.31 mg/L, initially reducing the biomass growth rate by up to 73 % and ultimately reducing the total biomass concentration by 75 %. When applied to municipal wastewater and agricultural run-off, the composites removed 96 % and 91 % of the dissolved P, respectively. Moreover, when the recovered P-enriched composites were reused as a slow-release bio-compatible fertilizer in a photobioreactor, they effectively supported algal growth without blocking light and interfering with photosynthesis. The P-enriched composites could tune the P concentration in the culture medium and significantly promote algal lipid accumulation. Finally, this study demonstrates the mineral-hydrogel composites' potential to treat point sources of P pollution and subsequently facilitate photoautotrophic biofuel production as a nutrient, effectively recycling the captured P.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2019

Automated Quantitative Analysis of Extended Irradiation Defects - Dislocations, Voids and Precipitates in Neutron Irradiated HT-9 Steel

Structural alloys that make up the core components of nuclear reactors are exposed to radiation that can substantially alter the microstructure and mechanical properties of the material. Irradiation can cause the formation of extended defects including dislocation line and loops, voids and various types of precipitates. To understand the irradiation effects, it is critical to characterize these defects individually and collectively to quantify how they evolve throughout irradiation stages. Transmission electron microscopy (TEM) is a standard tool for providing extensive size, number density and spatial distribution of extended irradiation defects, however, manual measurement of defect size and number density requires time-intensive effort to analyze enough defects that provide a statistically meaningful result and are prone to errors of subjectivity. In this work, we developed a set of MATLAB algorithms offering robust and automated identification and quantification of extended irradiation defects like dislocation lines, voids and precipitates commonly observed in neutron irradiated cladding alloys [1]. Using a neutron-irradiated HT-9 martensitic alloy irradiated at 412°C to 111.8 dpa, we demonstrate the capability of these algorithms for quantitative defect analysis. Figure 1 presents defect images of the HT-9 using an advanced diffraction contrast imaging scanning transmission electron microscopy (DCI STEM) that suppresses bend contours and provides better defect contrast compared to conventional TEM [2]. The first step of defect analysis is defect identification, a process that can be digitally achieved by contrast thresholding (for simple defect contrast) and by machine learning computer vision for defect semantic segmentation [3]. Here, labeled binary defect images (Figures 2a and 2c) were used. For dislocation density quantification, we employed an optimized circular-grid intersection method first introduced by Dr. John Steeds [4]. This method is shown in Figures 2a and 2b, where the number of intersections of dislocation lines with circular traces was measured. This produces an unbiased sampling of dislocation lines, regardless of their orientation. This process was optimized with automated digital intersection number and grid length registration. Interestingly, it was found that a relatively large number of circles in a set circular gird is was needed to produce an invariant result (Figure 2b), with a low systematic measurement error. This demonstrates the main advantage of computer-based defect analysis, in performing repetitive operations quickly with a reduced systematic error. For the quantitative analysis of voids and precipitates a challenge encountered with automated defect analysis is feature overlap, particularly when the density of voids/precipitates is high. To mitigate this problem, as shown in Figure 2d, we modified the popular circular Hough transformation and treated ‘circular shape’ as the particle descriptor for voids/precipitates, efficiently resolving the overlapping particles. In summary, this automated digital quantification together with machine learning enabled defect identification [3] opens new opportunities for standardizing the characterization workflow for quantitative analysis of extended irradiation defects.

Sainju, Rajat↗
DOE OSTI2018

Optimization of Secondary Air Injection in a Wood-Burning Cookstove: An Experimental Study

Nearly 40% of the world's population regularly cooks on inefficient biomass stoves that emit harmful airborne pollutants, such as particulate matter (PM). Secondary air injection can significantly reduce PM mass emissions to mitigate the health and climate impacts associated with biomass cookstoves. However, secondary air injection can also increase the number of ultrafine particles emitted, which may be more harmful to health. This research investigates the effect of secondary air injection on the mass and size distribution of PM emitted during solid biomass combustion. An experimental wood-burning cookstove platform and parametric testing approach are presented to identify and optimize secondary air injection parameters that reduce PM and other harmful pollutants. Size-resolved measurements of PM emissions were collected and analyzed as a function of parametric stove design settings. The results show that PM emissions are highly sensitive to secondary air injection flow rate and velocity. Although increasing turbulent mixing (through increased velocity) can promote more complete combustion, increasing the total flow rate of secondary air may cause localized flame quenching that increases particle emissions. As a result, biomass cookstoves that implement secondary air injection should be carefully optimized and validated to ensure that PM emission reductions are achieved throughout the particle size range.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Two distinct components of the delayed single electron noise in liquid xenon emission detectors

Single electron noise which persists for many milliseconds is known to follow ionizing events in liquid/gas xenon emission detectors. Due to the long timescale, this noise can be mistaken for a genuine signal. Therefore, it is a limiting background to the low-energy threshold of dark matter searches, and could prevent discovery-class searches for MeV scale hidden sector dark matter. A systematic study reveals distinct fast and slow components to the noise. The fast component is compatible with the hypothesis of electrons which were trapped below the liquid surface, and can be reduced by increasing the electric field across the liquid/gas interface. However, the slow component increases linearly with electric field. Hypotheses for the origin of this effect are discussed, and techniques for mitigation are suggested.

47 OTHER INSTRUMENTATION↗
DOE OSTI2025

Design and implementation of the cosmic ray tagger system for the ICARUS detector at FNAL

The ICARUS-T600 Liquid Argon Time Projection Chamber is operating at Fermilab at shallow depth and thus exposed to a high flux of cosmic rays that can fake neutrino interactions. A cosmic ray tagging (CRT) system (∼ 1100 m 2 ), surrounding the cryostat with two layers of fiber embedded plastic scintillators, was developed to mitigate the cosmic ray induced background. Using nanosecond-level timing information, the CRT can distinguish incoming cosmic rays from outgoing particles from neutrino interactions in the TPC. In this paper an overview of the CRT system, its installation and commissioning at Fermilab, and its performance are discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Utilizing HYSPLIT for Emergency Response Modeling at SRS

The threat of a disaster happening at the Savannah River Site (SRS) is low, but not zero. When an emergency arises, emergency responders utilize a variety of tools to detect, track, and mitigate the disaster. HYSPLIT is a community atmospheric dispersion model that is highly configurable and has been used operationally to simulate particle, chemical, and radionuclide releases. We have developed a preliminary user interface (UI) that configures HYSPLIT to run for a variety of Emergency Action Level (EAL) scenarios at SRS. Using a hypothetical EAL scenario of an accidental release of Pu-238 in H-area and K-area onsite, an analysis was done to show how a preliminary UI framework allows HYSPLIT to be run on a terminal without the need form an active network connection. The study was successful in multiple aspects. For the preliminary UI, users were able to input certain characteristics of the hypothetical EAL such as hours of emission (how long was Pu-238 being released), curies of release, release start time (when does the model run start), and type of radionuclide directly into the terminal. For HYSPLIT, the model was successful in being able to take the UI input, calculate the results from the inputs and output multiple figures of both total volumetric airborne concentrations and surface deposition. We used the Pu-238 Derived Intervention Level (DIL) deposition thresholds for produce, dairy, and beef for visualization of the surface deposition, showing how a release would impact ingestion pathways.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
NASA NTRS2008

Modification of Roberts' Theory for Rocket Exhaust Plumes Eroding Lunar Soil

Roberts' model of lunar soil erosion beneath a landing rocket has been updated in several ways to predict the effects of future lunar landings. The model predicts, among other things, the number of divots that would result on surrounding hardware due to the impact of high velocity particulates, the amount and depth of surface material removed, the volume of ejected soil, its velocity, and the distance the particles travel on the Moon. The results are compared against measured results from the Apollo program and predictions are made for mitigating the spray around a future lunar outpost.

Metzger, Philip T.↗
NASA NTRSDate not supplied

Self-Aligned Focusing Schlieren at the 0.3-M Transonic Cryogenic Tunnel and the National Transonic Facility

The implementation of a self-aligned focusing schlieren (SAFS) system at two cryogenic wind tunnels at NASA Langley Research Center is discussed. Risk-reduction testing of the SAFS system was first performed at the 0.3-M Transonic Cryogenic Tunnel to evaluate the system’s operation in a small-scale characteristic cryogenic facility. Testing was conducted with three models: a three-quarter span 25.4-mm-diameter cylinder, a semi-span 65A006 tapered unswept airfoil, and a full-span SC(3)-0712 airfoil. Testing with the cylinder and semi-span airfoil revealed a highly dynamic shock environment, whereas the shock on the full-span airfoil was stationary, solidifying the usage of this model for a pre-/post-shock particle tracking velocimetry measurement. Temperature-induced polarization-altering window stresses were encountered during low-temperature testing, and were mitigated using a “non-ideal” quartz/quartz Rochon prism that had largely been neglected since the SAFS system’s first introduction in favor of the more favorable “ideal” glass/quartz Rochon prism. The size of the SAFS system was then decreased in order to fit inside an environmentally-controlled camera can enclosure at the National Transonic Facility (NTF) for testing of a sting-mounted aircraft model. The SAFS system was demonstrated to be effective at filtering out the large density gradient flow in the 0.3-M plenum, and the thick, high density turbulent boundary layers on the wind tunnel walls at the NTF. Results of the testing campaigns and improvements to future systems are discussed.

Joshua M. Weisberger↗
NASA NTRSDate not supplied

Self-Aligned Focusing Schlieren at the 0.3-M Transonic Cryogenic Tunnel and the National Transonic Facility

The implementation of a self-aligned focusing schlieren (SAFS) system at two cryogenic wind tunnels at NASA Langley Research Center is discussed. Risk-reduction testing of the SAFS system was first performed at the 0.3-M Transonic Cryogenic Tunnel to evaluate the system’s operation in a small-scale characteristic cryogenic facility. Testing was conducted with three models: a three-quarter span 25.4-mm-diameter cylinder, a semi-span 65A006 tapered unswept airfoil, and a full-span SC(3)-0712 airfoil. Testing with the cylinder and semi-span airfoil revealed a highly dynamic shock environment, whereas the shock on the full-span airfoil was stationary, solidifying the usage of this model for a pre-/post-shock particle tracking velocimetry measurement. Temperature-induced polarization-altering window stresses were encountered during low-temperature testing and were mitigated using a “non-ideal” quartz/quartz Rochon prism that had largely been neglected since the SAFS system’s first introduction in favor of the more favorable “ideal” glass/quartz Rochon prism. The size of the SAFS system was then decreased in order to fit inside an environmentally controlled camera can enclosure at the National Transonic Facility (NTF) for testing of a sting-mounted aircraft model. The SAFS system was demonstrated to be effective at filtering out the large density gradient flow in the0.3-M plenum, and the thick, high density turbulent boundary layers on the wind tunnel walls at the NTF. Results of the testing campaigns and improvements to future systems are discussed.

Joshua M Weisberger↗
DOE OSTI2024

Mitigation and characterization of crosstalk between laser-driven radiography sources

Radiography with multiple probe species offers the potential to extract additional information about a given object as compared to radiography with a single probe species. Notably, the flexibility for high-power, short-pulse lasers to accelerate a variety of particle species makes laser-driven sources an attractive option to achieve multi-probe radiography. However, crosstalk produced by each of laser-driven source may be responsible for substantial backgrounds on detectors, becoming a significant barrier to achieving simultaneous radiography. In this work, we describe measurements of and mitigation strategies against crosstalk between laser-driven radiography sources in experiments at the OMEGA EP laser.

47 OTHER INSTRUMENTATION↗
DOE OSTI2015

A novel approach in organic waste utilization through biochar addition in wood/polypropylene composites

Highlights: • Biochar made from waste wood was added with wood polypropylene composites. • 24% biochar gave the best mechanical properties. • 6% biochar had no effect on physico-mechanical properties of composites. • Coupling agent remained unreacted in composites having higher amount of biochar. - Abstract: In an attempt to concurrently address the issues related to landfill gas emission and utilization of organic wastes, a relatively novel idea is introduced to develop biocomposites where biochar made from pyrolysis of waste wood (Pinus radiata) is added with the same wood, plastic/polymer (polypropylene) and maleated anhydride polypropylene (MAPP). Experiments were conducted by manufacturing wood and polypropylene composites (WPCs) mixed with 6 wt%, 12 wt%, 18 wt%, 24 wt%, and 30 wt% biochar. Though 6 wt% addition had similar properties to that of the control (composite without biochar), increasing biochar content to 24 wt% improved the composite’s tensile/flexural strengths and moduli. The biochar, having high surface area due to fine particles and being highly carbonised, acted as reinforcing filler in the biocomposite. Composites having 12 wt% and 18 wt% of biochar were found to be the most ductile and thermally stable, respectively. This study demonstrates that, WPCs added with biochar has good potential to mitigate wastes while simultaneously producing biocomposites having properties that might be suited for various end applications.

09 BIOMASS FUELS↗
DOE OSTI2021

Tokamak ITG-KBM transition benchmarking with the mixed variables/pullback transformation electromagnetic gyrokinetic scheme

Electromagnetic gyrokinetic simulation of high temperature plasma is required to predict confinement in magnetic fusion devices and has posed challenges for existing codes. In this paper, we demonstrate successful global gyrokinetic simulation of the ion temperature gradient-driven mode-kinetic ballooning mode transition in a toroidal fusion plasma test case using the mixed variables/pullback transformation (MV/PT) scheme with the particle-in-cell codes XGC and ORB5, and compare to results from a conventional continuum code from the literature. Furthermore, the MV/PT scheme combines explicit time integration with mitigation of the well-known electromagnetic gyrokinetic “cancelation problem.” We calculate eigenmodes in the electrostatic and parallel vector potentials, and find good agreement in growth rate, real frequency, and the normalized plasma pressure of mode transition.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Evolution of the marker distribution in gyrokinetic $δf$ particle-in-cell simulations

The evolution of the particle weight in a δf particle-in-cell simulation depends on the marker distribution that can evolve in a turbulent field due to turbulent diffusion. When Monte Carlo methods are used to implement the test particle collision operator, or when the particle motion is not strictly Hamiltonian in a collisionless simulation, the marker distribution will evolve along the particle trajectory and, in general, cannot be known exactly. A two-dimensional numerical marker distribution is proposed as an approximation. It is shown to be advantageous over other common methods for evaluating the marker distribution in long-time turbulence simulations. A generalized two-weight δf-method is proposed to mitigate the marker evolution problem.

, Monte Carlo methods↗
DOE OSTI2018

The importance of calorimetry for highly-boosted jet substructure

Jet substructure techniques are playing an essential role in exploring the TeV scale at the Large Hadron Collider (LHC), since they facilitate the efficient reconstruction and identification of highly-boosted objects. Both for the LHC and for future colliders, there is a growing interest in using jet substructure methods based only on charged-particle information. The reason is that silicon-based tracking detectors offer excellent granularity and precise vertexing, which can improve the angular resolution on highly-collimated jets and mitigate the impact of pileup. In this paper, we assess how much jet substructure performance degrades by using track-only information, and we demonstrate physics contexts in which calorimetry is most beneficial. Specifically, we consider five different hadronic final states—W bosons, Z bosons, top quarks, light quarks, gluons—and test the pairwise discrimination power with a multi-variate combination of substructure observables. In the idealized case of perfect reconstruction, we quantify the loss in discrimination performance when using just charged particles compared to using all detected particles. We also consider the intermediate case of using charged particles plus photons, which provides valuable information about neutral pions. In the more realistic case of a segmented calorimeter, we assess the potential performance gains from improving calorimeter granularity and resolution, comparing a CMS-like detector to more ambitious future detector concepts. Broadly speaking, we find large performance gains from neutral-particle information and from improved calorimetry in cases where jet mass resolution drives the discrimination power, whereas the gains are more modest if an absolute mass scale calibration is not required.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Fast and Simple Ag/Cu Ion Exchange on Cu Foil for Anode-Free Lithium-Metal Batteries

Lithium-metal batteries with zero excess lithium on the anode side paired with a fully lithiated cathode are regarded as a form of the highest energy-density configuration. Unfortunately, the continuous lithium loss over cycling from a limited amount of lithium reservoir significantly degrades the overall cell performance in the anode-free system. To mitigate the deterioration, modifying the current collector for enhanced lithium cycling is an indispensable route. Here, we apply a Ag/Cu ion exchange to precipitate micro-sized Ag particles on the Cu current collector to enhance the lithium reversibility via (de)alloying process. Further, we show a smoother morphology of lithium upon alloying, which leads to a lowered nucleation potential as well as increased average Coulombic efficiency in Li||Cu cells regardless of electrolyte formulation. The preferred lithium adsorption on Ag and AgLi over Cu is demonstrated with density functional theory calculations, which supports that Li is forming a gamma-phase alloy in the last stage rather than being deposited beneath the alloy. Lastly, this simple Cu foil modification enhances lithium reversibility and reduces its nucleation barrier, thus mitigating the capacity fade of a Cu||LiFePO 4 with reduced polarization.

25 ENERGY STORAGE↗
DOE OSTI2026

Robust direct laser acceleration of electrons with flying-focus laser pulses

Direct laser acceleration (DLA) offers a compact source of high-charge, energetic electrons for generating secondary radiation or neutrons. While DLA in high-density plasma optimizes the energy transfer from a laser pulse to electrons, it exacerbates nonlinear propagation effects, such as filamentation, that can disrupt the acceleration process. Here, we show that superluminal flying-focus pulses (FFPs) mitigate nonlinear propagation, thereby enhancing the number of high-energy electrons and resulting x-ray yield. Three-dimensional particle-in-cell simulations show that, compared to a Gaussian pulse of equal energy (1 J) and intensity (2 × 10 20 W/cm 2 ), an FFP produces 80 × more electrons above 100 MeV, increases the electron cutoff energy by 20%, triples the high-energy x-ray yield, and improves x-ray collimation. These results illustrate the ability of spatiotemporally structured laser pulses to provide additional control in the highly nonlinear, relativistic regime of laser-plasma interactions.

Laser-produced plasmas↗