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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Analysis of Solids Obtained from 201O, 201P, 202A, and 202B Contactors in the Salt Waste Processing Facility

In December 2022, Savannah River Mission Completion personnel recovered solids samples from four contractors (EXT-001, EXT-007, EXT-031, and EXT-040) employed at the Salt Waste Processing Facility (SWPF). These solids were submitted to Savannah River National Laboratory for analysis and characterization. This Technical Report outlines the analytical findings and observations associated with these samples and explores the potential source of solid generation within the SWPF. The following conclusions are offered as a result of this work: the light color solids recovered from EXT-007 are consistent with crystallized, soluble salt components (such as sodium nitrate, sodium hydroxide, and sodium carbonate), all of which can be easily re-dissolved in process water and do not represent a threat to SWPF CSSX processing. While the light solids from the top of EXT-040 were not analyzed, it is believed that they share similar characteristics to those recovered from EXT-007; The dark color solids recovered from EXT-001, EXT-031, and the inside of EXT-040 appear to be complex, consisting of several different types of solids: High concentrations of mercury (Hg, 40-75% by mass) partially present as elemental Hg are consistent with the precipitation of Hg 0 /Hg 2+ from disproportionation of Hg + species in pH swing conditions; Moderate concentrations of titanium (Ti) (2-7%, by mass) are also present, often co-located with Hg. This is consistent with co-precipitation, entrainment, and/or amalgamation of Ti and Hg; Moderate concentrations of iron (Fe) (1-3%, by mass) are observed in SWPF solids and are likely attributable to erosion of stainless-steel components within the CSSX process; Small concentrations of tungsten (W) and cobalt (Co) (<1%, by mass) are observed in SWPF solids. The presence of these solids is consistent with the erosion of components coated with W and Co (e.g., Stellite); Small concentrations of aluminum (Al) (<1%, by mass) are observed in the form of gibbsite and potentially sodium aluminosilicate. The presence of these compounds is likely attributable to the pH swing observed between the scrub and extraction cycles within the CSSX process. The following recommendations are made as a result of this work: Testing should be performed to determine the chemical drivers, process, and mechanism of Hg precipitation in CSSX processing. Special care should be taken to include titanium in tests to evaluate the potential for co-precipitation, entrainment, and amalgamation; Hg-mitigation options that would minimize or eliminate risks of Hg precipitation and solids accumulation (e.g., Hg-absorption techniques, ion exchange/adsorbents, flowsheet changes, etc.) should be assessed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1989

Numerical experiments on stability and transition in plane channel flow

Various secondary and tertiary instabilities in plane channael flow are explored via time-dependent numerical simulations using the incompressible Navier-Stokes equations. Comparisons are made between transitional flows at Reynolds numbers 1500, 5000, and 8000. The lambda vortex, detached shear layer, and inverted vortex regions are identified, and the origin of the latter is explained. The laminar breakdown of the Re = 1500 flow is computed with high resolution, and the nature of its ensuing hairpin eddies is clarified by numerical particle paths. The potential of center-mode, rather than wall-mode transitions is proposed, and the resulting flow structure is described.

Zang, Thomas A.↗
NASA NTRS2008

Using the Space Glove to Teach Spatial Thinking

The challenge of extending students' skills in spatial thinking to astronomical scales was the central focus of our K-8 curriculum development. When the project's lead teacher requested a curriculum that cumulatively built on each prior year's learning in a spiral fashion, I knew exactly what the school was asking for. Second and third graders began by noticing the cyclical patters that the sun, moon, and stars make in the sky. Fourth graders explored the phases of the moon by taking turns modeling and sketching them in their classroom and then comparing them to the real sky. Sixth !graders used real telescopes to observe a moving model of our solar system and walked a scale model of the planets' orbits. The curriculum is designed to expand students' capacity to visualize space in a hierarchical fashion that asks them to imagine themselves from a broader number of spatial perspectives through hands-on activities. The "situational awareness" Peter's story describes is a hallmark of high-performance engineering and innovation. Keeping in mind the potential outcomes of multiple paths of pursuit from multiple perspectives while keeping track of their relative merits and performance requirements is a demanding spatial task. What made it possible for Peter to transform the failure of his first glove into triumph was the mental space in which that failure provided exactly the information needed for a new breakthrough. In at least two cases, Peter could immediately "see" the full implications of what his hands were telling him. He tells the story of how putting his hands in a Phase VI astronaut glove instantly transformed his understanding of the glove challenge. Six months into his development, the failure of circumferentially wrapped cords to produce a sufficiently flexible glove again forced him to abandon his assumptions. His situational awareness was so clear and compelling it became a gut-level response. Peter's finely developed spatial skills enabled him to almost instinctively focus his full energy on a carefully constructed set of experiments. The finger's ability to sense pressure, force, and work gave him the immediate feedback required to solve this one central problem. Once properly understood, his failure quickly led to the magical "Aha!" moment of discovery; the rest is history. Just as children need opportunities to develop hands-on understanding, engineers need to explore new possibilities through incremental hands-on failure. High-performance innovation is all about learning to make maximum use of thinking spatially to direct this process. Peter Homer's glove also reminds us that efficient engineering decisions need to be made as close to the hardware as possible. Whether we're doing hands-on education or hands-on engineering, it is when we trust in our ability to "feel our way" through failure that we reach our highest potential.

Lord, Peter↗
NASA NTRS2013

First Results from NASA's Lunar Atmosphere and Dust Environment Explorer (LADEE)

As of early August, 2013, the Lunar Atmosphere and Dust Environment Explorer (LADEE) mission is scheduled for launch on a Minotaur V rocket from Wallops Flight Facility during a five-day launch period that opens on Sept. 6, 2013 (early Sept. 7 UTC). LADEE will address 40 year-old mysteries of the lunar atmosphere and the question of levitated lunar dust. It will also pioneer the next generation of optical space communications. LADEE will assess the composition of the lunar atmosphere and investigate the processes that control its distribution and variability, including sources, sinks, and surface interactions. LADEE will also determine whether dust is present in the lunar exosphere, and reveal its sources and variability. These investigations are relevant to our understanding of surface boundary exospheres and dust processes occurring at many objects throughout the solar system, address questions regarding the origin and evolution of lunar volatiles, and have potential implications for future exploration activities. Following a successful launch, LADEE will enter a series of phasing orbits, which allows the spacecraft to arrive at the Moon at the proper time and phase. This approach accommodates any dispersion in the Minotaur V launch injection. LADEE's arrival at the moon in early October. The spacecraft will approach the moon from its leading edge, travel behind the Moon out of sight of the Earth, and then re-emerge and execute a three-minute Lunar Orbit Insertion maneuver. This will place LADEE in an elliptical retrograde equatorial orbit with an orbital period of approximately 24 hours. A series of maneuvers is then performed to reduce the orbit to become nearly circular with a 156-mile (250- kilometer) altitude. Spacecraft checkout and science instrument commissioning will commence in early-October and will nominally span 30 days but can be extended for an additional 30 days in the event of contingencies. Following commissioning, the 100-day Science Phase is performed at an orbit with periapsis between 20-60 km. This orbit must be constantly managed due to the Moon's highly inhomogeneous gravity field. During the Science Phase, the moon will rotate more than three times underneath the LADEE orbit. LADEE employs a high heritage instrument payload: a Neutral Mass Spectrometer (NMS) from Goddard Space Flight Center, an Ultraviolet/Visible Spectrometer (UVS) from Ames Research Center, and a dust detection experiment (LDEX) from the University of Colorado/LASP. It will also carry the Lunar Laser Communications Demonstration (LLCD) as a technology demonstration. The LLCD is funded by the Human Exploration Operations Mission Directorate (HEOMD), managed by GSFC, and built by the MIT Lincoln Lab. Contingent upon LADEE's successful lunar orbit insertion and checkout, we will report the early results from the science investigations.

Moon↗
NASA NTRS2005

In-Space Repair of Reinforced Carbon-Carbon (RCC) Thermal Protection System Structures

Advanced repair and refurbishment technologies are critically needed for the RCC-based thermal protection system of current space transportation system as well as for future Crew Exploration Vehicles (CEV). The damage to these components could be caused by impact during ground handling or due to falling of ice or other objects during launch. In addition, in-orbit damage includes micrometeoroid and orbital debris impact as well as different factors (weather, launch acoustics, shearing, etc.) during launch and re-entry. The GRC developed GRABER (Glenn Refractory Adhesive for Bonding and Exterior Repair) material has shown multiuse capability for repair of small cracks and damage in reinforced carbon-carbon (RCC) material. The concept consists of preparing an adhesive paste of desired ceramic with appropriate adhesives and then applying the paste to the damaged/cracked area of the RCC composites with adhesive delivery system. The adhesive paste cures at 100-120 C and transforms into a high temperature ceramic during simulated entry conditions. A number of plasma torch and ArcJet tests were carried out to evaluate the crack repair capability of GRABER materials for Reinforced Carbon-Carbon (RCC) composites. For the large area repair applications, PLASTER (Patch Laminates and Sealant Technology for Exterior Repair) based systems have been developed. In this presentation, critical in-space repair needs and technical challenges as well as various issues and complexities will be discussed along with the plasma performance and post test characterization of repaired RCC materials.

Singh, Mrityunjay↗
NASA NTRS2006

In-Space Repair of Reinforced Carbon-Carbon Thermal Protection System Structures

Advanced repair and refurbishment technologies are critically needed for the thermal protection system of current space transportation system as well as for future Crew Exploration Vehicles (CEV). The damage to these components could be caused by impact during ground handling or due to falling of ice or other objects during launch. In addition, in-orbit damage includes micrometeoroid and orbital debris impact as well as different factors (weather, launch acoustics, shearing, etc.) during launch and re-entry. The GRC developed GRABER (Glenn Refractory Adhesive for Bonding and Exterior Repair) material has shown multiuse capability for repair of small cracks and damage in reinforced carbon-carbon (RCC) material. The concept consists of preparing an adhesive paste of desired ceramic with appropriate additives and then applying the paste to the damaged/cracked area of the RCC composites with adhesive delivery system. The adhesive paste cures at 100-120 C and transforms into a high temperature ceramic during simulated entry conditions. A number of plasma torch and ArcJet tests were carried out to evaluate the crack repair capability of GRABER materials for Reinforced Carbon-Carbon (RCC) composites. For the large area repair applications, integrated system for tile and leading edge repair (InSTALER) have been developed. In this presentation, critical in-space repair needs and technical challenges as well as various issues and complexities will be discussed along with the plasma performance and post test characterization of repaired RCC materials.

Singh, Mrityunjay↗
DOE OSTI2023

Integrated End-to-end Performance Prediction and Diagnosis for Extreme Scientific Workflows

This report details recent progress for the ASCR funded project “Integrated End-to-end Performance Prediction and Diagnosis for Extreme Scientific Workflows”. We refer to the project as IPPD/2, reflecting the 2017 renewal under expanded scope and partners In IPPD/2, we increased our research scope to include data motion. We are focusing on three major aspects: a) observe how data is generated, distributed, and used; b) analyze how data is (repeatedly) consumed with a focus both on repeated patterns and anomalies; and c) explore how to optimize data motion. This new work on data motion will augment and complement IPPD/2’s research that focused on the computational aspects of tasks. We leverage and extend our existing tools and demonstrate our work on the Belle II workflow suite as well as on workflows from NSLS-II. The highlights of our work are as follows: Provenance for Workflows: Provenance is used to provide information enabling quality control, re-run computational workflows, and reproduce results. IPPD/2 has been building a scalable provenance management system that enables the capture of provenance from the high-level workflow through all relevant system levels in one integrated environment. Leveraging this work, our recent efforts have included using provenance as an enabling technique. Workload characterization: Leveraging provenance and analysis, we characterize data movement within network, storage, and memory over a variety of workloads. This characterization enables an understanding by performance analysts and application developers of the range of behaviors that could be expected. Performance Prediction for Workflows: The goal of modeling distributed workflows is to understand performance bottlenecks and enable more intelligent task scheduling to optimize selected metrics of interest (e.g., task throughput or output data rate). IPPD/2 has utilized both analytical and AI/ML modeling methodologies for performance modeling. Advanced Scheduling and Fault Modeling for Workflows: Scheduling of large-scale scientific workflows on geographically distributed resources is a challenging problem. To improve workflow throughput, we combined novel scheduling algorithms with task predictions from performance modeling and fault modeling. Dynamically Alleviating Bottlenecks in Workflows: Exploiting our provenance, analysis, and modeling efforts, we have explored and developed several techniques for dynamically detecting and alleviating bottlenecks in data movement. In particular, we have spent considerable effort demonstrating our techniques on production-like workflow configurations.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS2008

Extreme Temperature Operation of a 10 MHz Silicon Oscillator Type STCL1100

The performance of STMicroelectronics 10 MHz silicon oscillator was evaluated under exposure to extreme temperatures. The oscillator was characterized in terms of its output frequency stability, output signal rise and fall times, duty cycle, and supply current. The effects of thermal cycling and re-start capability at extreme low and high temperatures were also investigated. The silicon oscillator chip operated well with good stability in its output frequency over the temperature region of -50 C to +130 C, a range that by far exceeded its recommended specified boundaries of -20 C to +85 C. In addition, this chip, which is a low-cost oscillator designed for use in applications where great accuracy is not required, continued to function at cryogenic temperatures as low as - 195 C but at the expense of drop in its output frequency. The STCL1100 silicon oscillator was also able to re-start at both -195 C and +130 C, and it exhibited no change in performance due to the thermal cycling. In addition, no physical damage was observed in the packaging material due to extreme temperature exposure and thermal cycling. Therefore, it can be concluded that this device could potentially be used in space exploration missions under extreme temperature conditions in microprocessor and other applications where tight clock accuracy is not critical. In addition to the aforementioned screening evaluation, additional testing, however, is required to fully establish the reliability of these devices and to determine their suitability for long-term use.

Patterson, Richard L.↗
NASA NTRS2011

Influence of Sensory Dependence on Postural Control

The current project is part of an NSBRI funded project, "Development of Countermeasures to Aid Functional Egress from the Crew Exploration Vehicle Following Long-Duration Spaceflight." The development of this countermeasure is based on the use of imperceptible levels of electrical stimulation to the balance organs of the inner ear to assist and enhance the response of a person s sensorimotor function. These countermeasures could be used to increase an astronaut s re-adaptation rate to Earth s gravity following long-duration space flight. The focus of my project is to evaluate and examine the correlation of sensory preferences for vision and vestibular systems. Disruption of the sensorimotor functions following space flight affects posture, locomotion and spatial orientation tasks in astronauts. The Group Embedded Figures Test (GEFT), the Rod and Frame Test (RFT) and the Computerized Dynamic Posturography Test (CDP) are measurements used to examine subjects visual and vestibular sensory preferences. The analysis of data from these tasks will assist in relating the visual dependence measures recognized in the GEFT and RFT with vestibular dependence measures recognized in the stability measures obtained during CDP. Studying the impact of sensory dependence on the performance in varied tasks will help in the development of targeted countermeasures to help astronauts readapt to gravitational changes after long duration space flight.

Santana, Patricia A.↗
NASA NTRS2018

How NASA is Building a Petabyte Scale Geospatial Archive in the Cloud

NASA's Earth Observing System Data and Information System (EOSDIS) is working towards a vision of a cloud-based, highly-flexible, ingest, archive, management, and distribution system for its ever-growing and evolving data holdings. This free and open source system, Cumulus, is emerging from its prototyping stages and is poised to make a huge impact on how NASA manages and disseminates its Earth science data. This talk outlines the motivation for this work, present the achievements and hurdles of the past 18 months and charts a course for the future expansion of Cumulus. We explore not just the technical, but also the socio-technical challenges that we face in evolving a system of this magnitude into the cloud. The NASA EOSDIS archive is currently at nearly 30 PBs and will grow to over 300PBs in the coming years. We've presented progress on this effort at AWS re:Invent and the American Geophysical Union (AGU) Fall Meeting in 2017 and hope to have the opportunity to share with FOSS4G attendees information on the availability of the open sourced software and how NASA intends on making its Earth Observing Geospatial data available for free to the public in the cloud.

NASA Archive↗
NASA NTRSDate not supplied

OSIRIS-REx Earth Return Orbit Determination Analysis and Performance

Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) was a NASA New Frontiers–class asteroid sample return mission to (101955) Bennu. OSIRIS-REx performed a series of Trajectory Cor-rection Maneuver (TCM)s to target an Entry Interface (EI) point for Earth Return and entry, descent, and landing (EDL). On September 24, 2023, the Sample Re-turn Capsule (SRC) separated from the spacecraft, entered the atmosphere, and ultimately landed at the Utah Test and Training Range for recovery. This paper gives an overview of the updated orbit determination (OD) covariance analysis that went into the Earth return and reentry analysis after asteroid departure. Tracking data assumptions and multiple filter cases are analyzed to show performance. Operational OD results from TCM-9 and subsequent targeting maneuvers up to entry interface are provided. We show parameter error analysis contributions from the OD setup and their breakdown in the B-Plane error ellipses. Finally, we discuss the terminal OD solutions into EI and reconstruction results using onboard image data.

Jason M. Leonard↗
NASA NTRS2020

The Flux of Impact Ejecta on the Lunar Surface from Scaling Considerations: Implications for Operational Hazards and Geomorphic Forcing

The impact cratering process has been critical to the evolution of the Moon’s surface over its geologic history and remains an important ongoing process today. Impact events have a major local effect, but also excavate ejecta particles that re-impact the lunar surface over a wide area. Quantifying the flux of ejecta to a given point on the Moon is the subject of this work. We also estimate how this flux is partitioned into different particle sizes and different ejecta velocities. Motivation: There are two main factors motivating this work. First, and most critically, is the assessment of the hazard posed by impact ejecta for future surface exploration (i.e., to infrastructure, spacesuits, etc.). LROC observations of new craters have led to the reemphasized need to consider this hazard. In fact, a hazard assessment of this type was made prior to Apollo, although some of the underlying assumptions of that work are now clearly obsolete (see [4]). We also now know much more about the impactor flux, scaling of impact events, and scaling of ejecta than was known in the 1960's, so revisiting this hazard assessment is appropriate.We note that also have recently revisited the earlier hazard estimates and independently revised them downward using an entirely different analytical approach. The second motivation is that several recent papers have argued that the flux of distal ejecta is the controlling factor in how fast the lunar surface evolves. For this reason, improving understanding of the ejecta mass flux and how the flux translates into geomorphic work is of interest. To be clear, it is obvious that the ejecta mass flux is much larger than the primary impactor mass flux – indeed, this is self-evident because the craters excavated by hypervelocity impacts are much larger than their impactors. On the other hand, the energy delivered by a given primary to the surface is larger than the sum of the energy delivered by all its associated ejecta, as required by conservation, aggravated by the fact that not all of an impactor’s kinetic energy is partitioned into ejecta excavation. If distal ejecta and secondaries control lunar geomorphic evolution, this suggests that re-impacting ejecta must more efficiently translate their energy into geomorphic work than primaries. It is also easy to imagine the relative efficiency of primary and secondary impacts to do geomorphic work varying with the size of the primary. Considering the details of this process is thus of significant interest for lunar geomorphology.

Fassett, C. I.↗
NASA NTRS2010

Igniter Testing and Development for Liquid Oxygen/Liquid Methane (LOX/LCH4) and Liquid Oxygen/Gaseous Hydrogen (LOX/GH2) Injectors

In support of NASA's efforts to advance methane technology for future exploration missions, two different igniter concepts were developed and tested at NASA's Marshall Space Flight Center for ignition of oxygen/methane propellants. The first type of igniter, an impinging injection, spark-initiated torch igniter (impinging igniter), used traditional spark plug technology to produce a small, but very intense, pulsed plasma as the ignition source. The second type of igniter, a microwave-generated plasma igniter (microwave igniter), used a microwave magnetron to produce a continuous, larger-volume plasma as the ignition source. Two new designs for both types of igniters were leveraged off past oxygen/methane igniter designs that were tested at MSFC and documented in a 2008 JANNAF paper. In this most recent work, the two new igniters were to be tested at the component level as well as inside a liquid oxygen/liquid methane (LOX/LCH4) 40-element swirl coaxial injector. Although the microwave igniter achieved ignition in every test, it encountered technical difficulties that prevented it from being tested with the injector. The impinging igniter required several design iterations as well as testing at different mixture ratios and mass flow rates before reliable operation with minimal ignition delay was achieved. The final design of the impinging igniter was successfully tested in the LOX/LCH4 injector. The same igniter was later re-configured and component-tested to demonstrate reliable ignition of oxygen/hydrogen propellants. Future tests of the impinging igniter will include ignition of a LOX/hydrogen two-stage swirl injector, which is one of several injector concepts being tested in the Lunar Lander Descent Engine Test Bed at MSFC. All igniter and injector tests have been funded by the Propulsion & Cryogenics Advanced Development project managed by Glenn Research Center and sponsored by NASA s Exploration Technology Development Program.

Osborne, Robin J.↗
NASA NTRS1994

Development and application of computational aerothermodynamics flowfield computer codes

Research was performed in the area of computational modeling and application of hypersonic, high-enthalpy, thermo-chemical nonequilibrium flow (Aerothermodynamics) problems. A number of computational fluid dynamic (CFD) codes were developed and applied to simulate high altitude rocket-plume, the Aeroassist Flight Experiment (AFE), hypersonic base flow for planetary probes, the single expansion ramp model (SERN) connected with the National Aerospace Plane, hypersonic drag devices, hypersonic ramp flows, ballistic range models, shock tunnel facility nozzles, transient and steady flows in the shock tunnel facility, arc-jet flows, thermochemical nonequilibrium flows around simple and complex bodies, axisymmetric ionized flows of interest to re-entry, unsteady shock induced combustion phenomena, high enthalpy pulsed facility simulations, and unsteady shock boundary layer interactions in shock tunnels. Computational modeling involved developing appropriate numerical schemes for the flows on interest and developing, applying, and validating appropriate thermochemical processes. As part of improving the accuracy of the numerical predictions, adaptive grid algorithms were explored, and a user-friendly, self-adaptive code (SAGE) was developed. Aerothermodynamic flows of interest included energy transfer due to strong radiation, and a significant level of effort was spent in developing computational codes for calculating radiation and radiation modeling. In addition, computational tools were developed and applied to predict the radiative heat flux and spectra that reach the model surface.

Venkatapathy, Ethiraj↗
NASA NTRSDate not supplied

Mission Design & Operations Approach for the HelioSwarm Mission

HelioSwarm: The Nature of Turbulence in Space Plasmas is a transformational mission to explore the dynamic three-dimensional mechanisms controlling the physics of plasma turbulence, a ubiquitous process occurring in the heliosphere and plasmas throughout the universe. Turbulence is the process by which energy contained in fluctuating magnetic fields and plasma motion cascades from large to smaller spatial scales. HelioSwarm achieves its science goals by making simultaneous measurements across a wide range of measurement baselines, spanning magnetohydrodynamic scales (1000’s of km) to sub-ion heating scales (10’s of km), using a novel nine-spacecraft swarm. The swarm operates in a high-altitude lunar resonant Earth orbit (two-week period, ~63 RE apogee, ~13 RE perigee), giving it access to both the pristine solar wind and regions of strongly driven turbulence (specifically the magnetosphere and foreshock), and utilizes customized relative orbital motion of the swarm members to produce the range of measurement baselines and configurations. The swarm comprises eight “node” spacecraft, manufactured by Blue Canyon Technologies, and a “hub” spacecraft produced by Northrop Grumman Corp. The hub serves as a communications relay, with all communications between the ground and the nodes flowing through it. Mission operations are conducted within the Multi-Mission Operations Center at the NASA Ames Research Center and science operations at the University of New Hampshire, Durham. HelioSwarm was selected in 2022 as one of NASA’s newest Heliophysics Explorer missions to proceed from mission concept into mission implementation, with a target launch in 2029. This paper provides an overview of the mission’s science goals and objectives, the mission design, and the concept of operations, with an emphasis on how the swarm aspects of the mission both enable the science measurements and present unique operational challenges. The paper then describes the proposed development approach for the mission operations system and ground data system which relies on a selective combination of scaling strategies to meet the challenges.

HelioSwarm↗
NASA NTRS2020

POEMMA’s Target-of-Opportunity Sensitivity to Cosmic Neutrino Transient Sources

We investigate the capability of the Probe Of Extreme Multi-Messenger Astrophysics (POEMMA)in performing Target-of-Opportunity (ToO) neutrino observations. POEMMA is a proposed space-based probe-class mission for ultra high-energy cosmic ray and very-high-energy neutrino detection using two spacecraft, each equipped with a large Schmidt telescope to detect optical and near-ultraviolet signals generated by extensive air showers (EASs). POEMMA will be sensitive to Cherenkov radiation from upward-moving EASs initiated by tau neutrinos interacting in the Earth. POEMMA will be able to quickly re-point (90◦in 500 s) each of the two spacecraft to the direction of an astrophysical source, which in combination with its orbital speed will provide it with unparalleled capability to follow up transient alerts. We calculate POEMMA’s transient sensitivity for two observational configurations for the satellites (ToO-stereo and ToO-dual for smaller and larger satellite separations, respectively) and investigate the impact of variations arising due to POEMMA’s orbital characteristics on its sensitivity to tau neutrinos in various regions of the sky. We explore separate scenarios for long (∼105−6s) and short (∼103s) duration events, accounting for intrusion from the Sun and the Moon in the long-duration scenario. We compare the sensitivity and sky coverage of POEMMA for ToO observations with those for existing experiments (e.g., IceCube, ANTARES, and the Pierre Auger Observatory) and other proposed future experiments (e.g., GRAND200k).For long bursts, we find that POEMMA will provide a factor of&7 improvement in average neutrino sensitivity above 300 PeV with respect to existing experiments, reaching the level of model predictions for neutrino fluences at these energies and above from several types of long-duration astrophysical transients (e.g., binary neutron star mergers and tidal disruption events). For short bursts, POEMMA will improve the sensitivity over existing experiments by at least an order of magnitude forEν∼>100 PeV in the “best-case” scenario. POEMMA’s orbital characteristics and rapid re-pointing capability will provide it access to the full celestial sky, including regions that will not be accessible to ground-based neutrino experiments. Finally, we discuss the prospects for POEMMA to detect neutrinos from candidate astrophysical neutrino sources in the nearby universe. Our results demonstrate that with its improved neutrino sensitivity at ultra-high energies and unique full-sky coverage, POEMMA will be an essential, complementary component in a rapidly expanding multi-messenger network.

Tonia M Venters↗
DOE OSTI2024

Self‐Standing Chiral Covalent Organic Framework Thin Films with Full‐Color Tunable Guest‐Induced Circularly Polarized Luminescence

Abstract Exploring self‐standing chiral covalent organic framework (COF) thin films with controllable circularly polarized luminescence (CPL) is of paramount significance but remains a challenging task. Herein, we demonstrate the first example of self‐standing chiral COF films employing a polymerization‐dispersion‐filtration strategy. Pristine, low‐quality chiral COF films were produced by interfacial polymerization and then re‐dispersed into COF colloidal solutions. Via vacuum assisted assembly, these COF colloids were densely stacked and assembled into self‐standing, pure chiral COF films ( L‐ / D‐ CCOF‐F) that were transparent, smooth, crack‐free and highly crystalline. These films were tunable in thicknesses, areas, and roughness, along with strong diffuse reflectance circular dichroism (DRCD) and cyan CPL signals, showing an intrinsic luminescence asymmetric factor ( g lum ) of ~4.3×10 −3 . Furthermore, these COF films served as host adsorbents to load various achiral organic dye guests through adsorption. The effective chiral transfer and energy transfer between CCOF‐F and achiral fluorescent dyes endowed the dyes with strong chirality and tunable DRCD, resulting in intense, full‐color‐tunable solid‐state CPL. Notably, the ordered arrangement of dye guest molecules within the preferentially oriented chiral pores of CCOF‐F contributed to an amplified | g lum | factor of up to 7.2×10 −2 , which is state‐of‐the‐art for COF‐based CPL materials. This work provides new insights into the design and fabrication of self‐standing chiral COF films, demonstrating their great potential for chiroptical applications.

Tang, Xihao↗
DOE OSTI2025

In Situ Atomic Tracking on the Interfacial Etching and Reconfiguration of Cu-ReSe 2 Contact during Thermal Annealing

The Schottky barrier height can be greatly affected by the metal diffusion, reaction, and covalent bonding formation at the contact. Exploring novel methods and revealing the fundamental mechanisms for contact engineering are of vital importance for microelectronic devices. Here, in this study, the annealing induced interfacial reactions at Cu-ReSe 2 contact are dynamically revealed from the atomic scale. Accompanied by the diffusion of Se to Cu, ReSe 2 is gradually decomposed to a thin Re interlayer through a “chain-by-chain” manner. Theoretical calculations show that the Cu atoms can facilitate the chemical bond breaking of ReSe 2 , significantly lowering the Se diffusion energy barrier toward Cu. The formed Re/ReSe 2 heterostructure presents a metal-like band structure, which underscores the critical role of Cu in altering the interfacial chemistry and promoting carrier transport across the interface. Our results can provide vital insights into the contact properties of ReSe 2 and provide a possible method for fabricating high-performance ReSe 2 -based devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗