Stimulated Raman emission in liquids.
Angular emission properties of stimulated Raman radiation from liquids, noting two classes of radiation
RAMAN SCATTERING↗
SEARCH · Search NASA
Results for “Raman Scattering”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Analysis of the stimulated Raman effects in an anisotropic crystal KDP.
Stimulated Raman effects in anisotropic crystal potassium dihydrogen phosphate with Stokes generations
ANISOTROPIC MATERIAL↗
Optical measurement methods in thermogasdynamics
A review is presented of a number of optical methods of flow measurements. Consideration is given to such spectroscopic methods as emission and absorption techniques, electron beam-stimulated fluorescence, and light scattering - Rayleigh, Raman and Mie - methods. The following visualization methods are also discussed: shadow photography, schlieren photography, interferometry, holographic interferometry, laser anemometry, particle holography, and electron-excitation imaging. A large bibliography is presented and the work is copiously illustrated with figures and photographs.
Stursberg, K.↗
Rayleigh rejection filters for 193-nm ArF laser Raman spectroscopy
Selected organic absorbers and their solvents are evaluated as spectral filters for the rejection of 193-nm Rayleigh light associated with the use of an ArF excimer laser for Raman spectroscopy. A simply constructed filter cell filled with 0.5 percent acetone in water and an optical path of 7 mm is shown effectively to eliminate stray Rayleigh light underlying the Raman spectrum from air while transmitting 60 percent of the Raman light scattered by O2.
Mckenzie, Robert L.↗
Dual wavelength Raman lidar observations of tropical cirrus clouds during the ALBATROSS campaign 1996
Explore the source record for details and available documents.
Polarstern Raman lidar Raman scattering Raylerigh ↗
Multiplex coherent raman spectroscopy detector and method
A multiplex coherent Raman spectrometer (10) and spectroscopy method rapidly detects and identifies individual components of a chemical mixture separated by a separation technique, such as gas chromatography. The spectrometer (10) and method accurately identify a variety of compounds because they produce the entire gas phase vibrational Raman spectrum of the unknown gas. This is accomplished by tilting a Raman cell (20) to produce a high-intensity, backward-stimulated, coherent Raman beam of 683 nm, which drives a degenerate optical parametric oscillator (28) to produce a broadband beam of 1100-1700 nm covering a range of more than 3000 wavenumber. This broadband beam is combined with a narrowband beam of 532 nm having a bandwidth of 0.003 wavenumbers and focused into a heated windowless cell (38) that receives gases separated by a gas chromatograph (40). The Raman radiation scattered from these gases is filtered and sent to a monochromator (50) with multichannel detection.
Chen, Peter↗
Prediction of Turbulent Temperature Fluctuations in Hot Jets
Large-eddy simulations (LES) were used to investigate turbulent temperature fluctuations and turbulent heat flux in hot jets. A high-resolution finite-difference Navier-Stokes solver was used to compute the flow from a 2-inch round nozzle. Three different flow conditions of varying jet Mach numbers and temperature ratios were examined. The LES results showed that the temperature field behaves similar to the velocity field, but with a more rapidly spreading mixing layer. Predictions of mean, mu-bar(sub i), and fluctuating, mu'(sub i), velocities were compared to particle image velocimetry data. Predictions of mean, T-bar, and fluctuating, T', temperature were compared to data obtained using Rayleigh scattering and Raman spectroscopy. Very good agreement with experimental data was demonstrated for the mean and fluctuating velocities. The LES correctly predicts the behavior of the turbulent temperature field, but over-predicts the levels of the fluctuations. The turbulent heat flux was examined and compared to Reynolds-averaged Navier-Stokes (RANS) results. The LES and RANS simulations produced very similar results for the radial heat flux. However, the axial heat flux obtained from the LES differed significantly from the RANS result in both structure and magnitude, indicating that the gradient diffusion type model in RANS is inadequate. Finally, the LES data was used to compute the turbulent Prandtl number and verify that a constant value of 0.7 used in the RANS models is a reasonable assumption.
hot jets↗
Comparison of Numerical Models for Computing Underwater Light Fields
Seven models for computing underwater radiances and irradianes by numberical solution of the radiative transfer equation are compared. The models are applied to the solution of several problems drawn from optical oceanography.
computing↗
Microgravity Effects on Nonequilibrium Melt Processing of Neodymium Titanate: Thermophysical Properties, Atomic Structure, Glass Formation and Crystallization
The relationships between materials processing and structure can vary between terrestrial and reduced gravity environments. As one case study, we compare the nonequilibrium melt processing of a rare-earth titanate, nominally 83TiO 2 -17Nd 2 O 3 , and the structure of its glassy and crystalline products. Density and thermal expansion for the liquid, supercooled liquid, and glass are measured over 300–1850 °C using the Electrostatic Levitation Furnace (ELF) in microgravity, and two replicate density measurements were reproducible to within 0.4%. Cooling rates in ELF are 40–110 °C s −1 lower than those in a terrestrial aerodynamic levitator due to the absence of forced convection. X-ray/neutron total scattering and Raman spectroscopy indicate that glasses processed on Earth and in microgravity exhibit similar atomic structures, with only subtle differences that are consistent with compositional variations of ~2 mol. % Nd 2 O 3 . The glass atomic network contains a mixture of corner- and edge-sharing Ti-O polyhedra, and the fraction of edge-sharing arrangements decreases with increasing Nd 2 O 3 content. X-ray tomography and electron microscopy of crystalline products reveal substantial differences in microstructure, grain size, and crystalline phases, which arise from differences in the melt processes.
thermophysical properties↗
Laser Rayleigh and Raman Diagnostics for Small Hydrogen/oxygen Rockets
Localized velocity, temperature, and species concentration measurements in rocket flow fields are needed to evaluate predictive computational fluid dynamics (CFD) codes and identify causes of poor rocket performance. Velocity, temperature, and total number density information have been successfully extracted from spectrally resolved Rayleigh scattering in the plume of small hydrogen/oxygen rockets. Light from a narrow band laser is scattered from the moving molecules with a Doppler shifted frequency. Two components of the velocity can be extracted by observing the scattered light from two directions. Thermal broadening of the scattered light provides a measure of the temperature, while the integrated scattering intensity is proportional to the number density. Spontaneous Raman scattering has been used to measure temperature and species concentration in similar plumes. Light from a dye laser is scattered by molecules in the rocket plume. Raman spectra scattered from major species are resolved by observing the inelastically scattered light with linear array mounted to a spectrometer. Temperature and oxygen concentrations have been extracted by fitting a model function to the measured Raman spectrum. Results of measurements on small rockets mounted inside a high altitude chamber using both diagnostic techniques are reported.
Degroot, Wilhelmus A.↗
Raman spectrum of alpha-N sub 2.
Raman spectrum of solid alpha-nitrogen at low temperatures, calculating scattering intensities and Raman active librational lattice vibrations
Brith, M.↗
The use of lidar for stratospheric measurements
Stratospheric measurements possible with ground-based, airborne, and satellite-borne lidar systems are reviewed. The instruments, basic equations, and formats normally used for various scattering and absorption phenomena measurements are presented including a discussion of elastic, resonance, Raman, and fluorescence scattering techniques.
Mccormick, M. P.↗
The use of lidar for stratospheric measurements
This paper reviews stratospheric measurements possible with ground-based, airborne, and satellite-borne lidar systems. The instruments, basic equations, and formats normally used for various scattering and absorption phenomena measurements are presented including a discussion of elastic, resonance, Raman, and fluorescence scattering techniques.
Mccormick, M. P.↗
Molecular rotations and kinetics by light scattering
Molecular rotations and kinetics from spectral features of molecular Raman spectra, using light scattering spectroscopy
Callender, R.↗
Lidar applications to pollution studies.
This paper discusses the application of lidar (laser radar) to the measurement of air pollution. Lidar techniques and instrumentation utilizing elastic, Raman, and fluorescence scattering are discussed. Data showing measurements of the mixing of particulate pollutants in the atmosphere are presented. These data include: simultaneous two-wavelength results, isopleths showing the temporal dynamics of particulate mixing, measurements of the top of the earth's mixing layer, and measurements in a valley with restricted circulation and mixing. All measurements are compared with simultaneous radiosonde and/or aircraft-mounted temperature probe support. In addition, a second generation lidar system presently under development is described.
Mccormick, M. P.↗
Laser applications to atmospheric sciences: A bibliography
A bibliography is given of 1460 references of the applications of lasers to atmospheric sciences. The subjects covered include: aerosols; clouds; the distribution and motion of atmospheric natural and man-made constituents; winds; temperature; turbulence; scintillation; elastic, Raman and resonance scattering; fluorescence; absorption and transmission; the application of the Doppler effect and visibility. Instrumentation, in particular lidar, is included, also data handling, and interpretation of the data for meteorological processes. Communications, geodesy and rangefinding are not included as distinct areas. The application to the atmosphere is covered, but not the ocean or its surface.
Harris, F. S., Jr.↗
Laser measure of sea salinity, temperature and turbidity in depth
A method is described in which a pulsed laser is used to probe the sea. Backscattered light is analyzed in time, intensity and wavelength. Tyndall, Raman and Brillouin scattering are used to obtain the backscatter turbidity, sound velocity, salinity, and the temperature as a function of depth.
Hirschberg, J. G.↗
Pulsed resonance spectroscopy applied to turbulent combustion flows
The application of pulsed resonance spectroscopy to the measurement of species concentrations in chemically reacting turbulent flows is discussed. The theory of such measurements is developed. An uncertainty analysis is performed, and the results are applied to typical combustion conditions. Experimental aspects are discussed. The method shows a significant theoretical improvement in accuracy over Raman and Reyleigh scattering techniques, and no significant barriers appear to block its development.
Daily, J. W.↗