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NASA NTRS2010

The AuScope Project and Trans-Tasman VLBI

Three 12-meter radio telescopes are being built in Australia (the AuScope project) and one in New Zealand. These facilities will be fully-equipped for undertaking S and X-band geodetic VLBI observations and correlation will take place on a software correlator (part of the AuScope project). All sites are equipped with permanent GPS receivers to provide co-location of several space geodetic techniques. The following scientific tasks of geodesy and astrometry are considered. 1. Improvement and densification of the International Celestial Reference Frame in the southern hemisphere; 2. Improvement of the International Terrestrial Reference Frame in the region; 3. Measurement of intraplate deformation of the Australian tectonic plate.

Lovell, Jim↗

NASA NTRS2012

Bound-free Spectra for Diatomic Molecules

It is now recognized that prediction of radiative heating of entering space craft requires explicit treatment of the radiation field from the infrared (IR) to the vacuum ultra violet (VUV). While at low temperatures and longer wavelengths, molecular radiation is well described by bound-bound transitions, in the short wavelength, high temperature regime, bound-free transitions can play an important role. In this work we describe first principles calculations we have carried out for bound-bound and bound-free transitions in N2, O2, C2, CO, CN, NO, and N2+. Compared to bound ]bound transitions, bound-free transitions have several particularities that make them different to deal with. These include more complicated line shapes and a dependence of emission intensity on both bound state diatomic and atomic concentrations. These will be discussed in detail below. The general procedure we used was the same for all species. The first step is to generate potential energy curves, transition moments, and coupling matrix elements by carrying out ab initio electronic structure calculations. These calculations are expensive, and thus approximations need to be made in order to make the calculations tractable. The only practical method we have to carry out these calculations is the internally contracted multi-reference configuration interaction (icMRCI) method as implemented in the program suite Molpro. This is a widely used method for these kinds of calculations, and is capable of generating very accurate results. With this method, we must first of choose which electrons to correlate, the one-electron basis to use, and then how to generate the molecular orbitals.

Schwenke, David W.↗

NASA NTRS1988

Full configuration-interaction study of the ionic-neutral curve crossing in LiF

Full configuration-interaction (FCI) calculations are used to assess the relative ability of methods for truncating the n-particle expansion in describing the ionic-neutral curve crossing between the two lowest Sigma(+) states of LiF. While the FCI calculations yield a smooth dipole moment function, MRCI calculations based on CASSCF orbitals optimized for the lowest state at all r values yield a discontinuous dipole moment function. However, when the orbitals are optimized using a state-averaged CASSCF procedure, with equal weights for the ionic and neutral solutions, both the CASSCF and MRCI dipole moment functions are smooth and in reasonable agreement with the FCI. No single-reference-based method is found to work satisfactorily. Potential curves for the lowest two Sigma(+) states are determined in both the adiabatic and diabatic representations using a large atomic natural orbit Gaussian basis set and a state-averaged CASSCF/MRCI treatment of electron correlation.

Bauschlicher, Charles W., Jr.↗

NASA NTRS2000

Validation of real-time three-dimensional echocardiography for quantifying left ventricular volumes in the presence of a left ventricular aneurysm: in vitro and in vivo studies

OBJECTIVES: To validate the accuracy of real-time three-dimensional echocardiography (RT3DE) for quantifying aneurysmal left ventricular (LV) volumes. BACKGROUND: Conventional two-dimensional echocardiography (2DE) has limitations when applied for quantification of LV volumes in patients with LV aneurysms. METHODS: Seven aneurysmal balloons, 15 sheep (5 with chronic LV aneurysms and 10 without LV aneurysms) during 60 different hemodynamic conditions and 29 patients (13 with chronic LV aneurysms and 16 with normal LV) underwent RT3DE and 2DE. Electromagnetic flow meters and magnetic resonance imaging (MRI) served as reference standards in the animals and in the patients, respectively. Rotated apical six-plane method with multiplanar Simpson's rule and apical biplane Simpson's rule were used to determine LV volumes by RT3DE and 2DE, respectively. RESULTS: Both RT3DE and 2DE correlated well with actual volumes for aneurysmal balloons. However, a significantly smaller mean difference (MD) was found between RT3DE and actual volumes (-7 ml for RT3DE vs. 22 ml for 2DE, p = 0.0002). Excellent correlation and agreement between RT3DE and electromagnetic flow meters for LV stroke volumes for animals with aneurysms were observed, while 2DE showed lesser correlation and agreement (r = 0.97, MD = -1.0 ml vs. r = 0.76, MD = 4.4 ml). In patients with LV aneurysms, better correlation and agreement between RT3DE and MRI for LV volumes were obtained (r = 0.99, MD = -28 ml) than between 2DE and MRI (r = 0.91, MD = -49 ml). CONCLUSIONS: For geometrically asymmetric LVs associated with ventricular aneurysms, RT3DE can accurately quantify LV volumes.

NASA Discipline Cardiopulmonary↗

NASA NTRS2004

Identification of Interplanetary Coronal Mass Ejections at 1 AU Using Multiple Solar Wind Plasma Composition Anomalies

We investigate the use of multiple simultaneous solar wind plasma compositional anomalies, relative to the composition of the ambient solar wind, for identifying interplanetary coronal mass ejection (ICME) plasma. We first summarize the characteristics of several solar wind plasma composition signatures (O(+7)/O(+6), Mg/O, Ne/O, Fe charge states, He/p) observed by the ACE and WIND spacecraft within the ICMEs during 1996 - 2002 identsed by Cane and Richardson. We then develop a set of simple criteria that may be used to identify such compositional anomalies, and hence potential ICMEs. To distinguish these anomalies from the normal variations seen in ambient solar wind composition, which depend on the wind speed, we compare observed compositional signatures with those 'expected' in ambient solar wind with the same solar wind speed. This method identifies anomalies more effectively than the use of fixed thresholds. The occurrence rates of individual composition anomalies within ICMEs range from approx. 70% for enhanced iron and oxygen charge states to approx. 30% for enhanced He/p (> 0.06) and Ne/O, and are generally higher in magnetic clouds than other ICMEs. Intervals of multiple anomalies are usually associated with ICMEs, and provide a basis for the identification of the majority of ICMEs. We estimate that Cane and Richardson, who did not refer to composition data, probably identitied approx. 90% of the ICMEs present. However, around 10% of their ICMEs have weak compositional anomalies, suggesting that the presence of such signatures does not provide a necessary requirement for an ICME. We note a remarkably similar correlation between the Mg/O and O(7)/O(6) ratios in hourly-averaged data both within ICMEs and the ambient solar wind. This 'universal' relationship suggests that a similar process (such as minor ion heating by waves inside coronal magnetic field loops) produces the first-ionization potential bias and ion freezing-in temperatures in the source regions of both ICMEs and the ambient solar wind.

Richardson, I. G.↗

NASA NTRS2011

Photocatalytic Active Radiation Measurements and Use

Photocatalytic materials are being used to purify air, to kill microbes, and to keep surfaces clean. A wide variety of materials are being developed, many of which have different abilities to absorb various wavelengths of light. Material variability, combined with both spectral illumination intensity and spectral distribution variability, will produce a wide range of performance results. The proposed technology estimates photocatalytic active radiation (PcAR), a unit of radiation that normalizes the amount of light based on its spectral distribution and on the ability of the material to absorb that radiation. Photocatalytic reactions depend upon the number of electron-hole pairs generated at the photocatalytic surface. The number of electron-hole pairs produced depends on the number of photons per unit area per second striking the surface that can be absorbed and whose energy exceeds the bandgap of the photocatalytic material. A convenient parameter to describe the number of useful photons is the number of moles of photons striking the surface per unit area per second. The unit of micro-einsteins (or micromoles) of photons per m2 per sec is commonly used for photochemical and photoelectric-like phenomena. This type of parameter is used in photochemistry, such as in the conversion of light energy for photosynthesis. Photosynthetic response correlates with the number of photons rather than by energy because, in this photochemical process, each molecule is activated by the absorption of one photon. In photosynthesis, the number of photons absorbed in the 400 700 nm spectral range is estimated and is referred to as photosynthetic active radiation (PAR). PAR is defined in terms of the photosynthetic photon flux density measured in micro-einsteins of photons per m2 per sec. PcAR is an equivalent, similarly modeled parameter that has been defined for the photocatalytic processes. Two methods to measure the PcAR level are being proposed. In the first method, a calibrated spectrometer with a cosine receptor is used to measure the spectral irradiance. This measurement, in conjunction with the photocatalytic response as a function of wavelength, is used to estimate the PcAR. The photocatalytic response function is determined by measuring photocatalytic reactivity as a function of wavelength. In the second method, simple shaped photocatalytic response functions can be simulated with a broad-band detector with a cosine receptor appropriately filtered to represent the spectral response of the photocatalytic material. This second method can be less expensive than using a calibrated spectrometer.

Davis, Bruce A.↗

NASA NTRS1972

Effect of operating conditions on the exhaust emissions from a gas turbine combustor

Exhaust concentrations of total unburned hydrocarbons, carbon monoxide, and nitric oxide were measured from a single J-57 combustor liner installed in a 30 diameter test section. Tests were conducted over a range of inlet total pressures from 1 to 20 atmospheres, inlet total temperatures from 310 to 590 K, reference velocities from 8 to m/sec, and fuel-air ratios from 0.004 to 0.015. Most of the data were obtained using ASTM A-1 fuel; however, a limited number of tests was performed with natural gas fuel. Combustion efficiency and emission levels are correlated with operating conditions. Sampling error at operating conditions for which combustion efficiency was below about 90 percent resulted in abnormally low readings for hydrocarbon emissions.

Briehl, D.↗

NASA NTRS1969

Noise elimination by piecewise cross correlation of photometer outputs

A piecewise cross correlation technique has been developed to analyze the outputs of remote detection devices. The purpose of this technique is to eliminate the noise from optical background fluctuations, from transmission fluctuations and from detectors by calculating the instantaneous product of the detector output and a reference signal. Each noise component causes positive and negative oscillations of the instantaneous product and may thus be cancelled by an integration of the instantaneous product. The resultant product mean values will then contain the desired information on the spatial and temporal variation of emission, absorption and scattering processes in the atmosphere.

Krause, F. R.↗

NASA NTRS1976

A vector autopilot system

Current technology has evolved low cost, highly reliable solid state vector magnetometers with excellent angular resolution. This paper discusses the role of a three-axis magnetometer as a new instrument for aircraft attitude determination. Using flight data acquired by an instrumented aircraft, attitude is calculated using the earth's magnetic field vector and compared to measured attitudes. The magnetic field alone is not adequate to resolve all attitude variations and the need for a second reference angle or vector is discussed. A system combining the functions of heading determination and attitude measurement is presented to show that both functions can be implemented with essentially the same component count required to measure heading alone. It is concluded that with the correlation achieved in calculated and measured attitude there is a potential application of vector magnetometry in attitude measurement systems.

Pietila, R.↗

NASA NTRS1980

Sm-Nd isotopic evolution of chondrites

The Nd-143/Nd-144 and Sm-147/Nd-144 ratios measured in 5 chondrites and the Juvinas achondrite correlated with the variation of 4.2% in Sm-147/Nd-144. Most of the spread in the range of these ratios results from small heterogeneities in the chondrites and does not reflect the large-scale volumetric averages. A new set of self-consistent reference values were selected for the 'chrondritic uniform reservoir' (CHUR); the new Sm-147/Nd-144 value is 1.6% higher than the previous value assigned to CHUR using the Juvinas data of Lugmair (1975). The new CHUR curve indicates significant changes in model ages for lunar rocks and in the interpretation of early lunar chronology.

Jacobsen, S. B.↗

NASA NTRS1983

Effect of flameholder pressure drop on emissions and performance of premixed-prevaporized combustors

Parametric tests were conducted to determine the effects of flameholder pressure drop on the emissions and performance of lean premixed-prevaporized combustors. A conical flameholder mounted in a diverging duct was tested with two values of flameholder blockage. Emissions of nitrogen oxides, carbon monoxide, carbon dioxide, and unburned hydrocarbons were measured for combustor entrance conditions of 600 to 800 K air temperature, 0.3 MPa to 0.5 MPa pressure, and 20 m/sec to 35 m/sec reference velocity. Jet A fuel was injected at flow rates corresponding to an equivalence ratio range from 0.8 down to the lean stability limit. Emission results for the high-blockage flameholder were a substantial improvement over the low-blockage emission results. A correlation of combustion efficiency with flameholder pressure drop was developed for pressure drops less than 9 percent.

Duerr, R. A.↗

NASA NTRS2014

Assessment of a Technique for Estimating Total Column Water Vapor Using Measurements of the Infrared Sky Temperature

A method for estimating the integrated precipitable water (IPW) content of the atmosphere using measurements of indicated infrared zenith sky temperature was validated over east-central Florida. The method uses inexpensive, commercial off the shelf, hand-held infrared thermometers (IRT). Two such IRTs were obtained from a commercial vendor, calibrated against several laboratory reference sources at KSC, and used to make IR zenith sky temperature measurements in the vicinity of KSC and Cape Canaveral Air Force Station (CCAFS). The calibration and comparison data showed that these inexpensive IRTs provided reliable, stable IR temperature measurements that were well correlated with the NOAA IPW observations.

integrated precipitable water (IPW)↗

NASA NTRS2012

Synthesizing SMOS zero-baselines with Aquarius brightness temperature simulator

The antenna pattern and observation geometry of the SMOS zero-baseline radiometer, which is used as a reference for the SMOS brightness temperature calibration, was applied to Aquarius simulator, which is used as a reference for the Aquarius brightness temperature calibration. In the preliminary analysis, simulations carried out over a three month period show remarkable agreement between the measurements and simulations. This fundamental agreement would indicate that the brightness temperature products of the two missions should be well correlated. Some discrepancies were also found, cause of which seems to be consistent with findings of other studies and can be corrected for.

Kainulainen, J.↗

NASA NTRSDate not supplied

Modeling and Simulation Credibility Assessment of Finite Element Models for Fall From Heights Injury Scenarios

Finite element (FE) computational models of the whole human body are being used to investigate the injury modalities and mechanisms arising from suited astronauts’ ExtraVehicular Activities (EVAs). These FE whole body models – simplified Elemance and THUMS pedestrian versions – have undergone a series of verification and validation (V&V) assessments for applications in automotive, domestic, and contact sports arenas. However, the FE models’ Modeling and Simulation (M&S) credibility assessments for simulating suited astronaut injuries due to fall from heights in altered gravity environments are limited. The current study evaluates the M&S credibility of simplified Elemance and THUMS pedestrian FE models based on eight credibility factors – data pedigree, input pedigree, code verification, solution verification, conceptual validation, referent validation, results uncertainty, and results robustness – as per NASA-STD-7009A [1]. These credibility factors were assigned ordinal scores ranging between 0 to 4, with a score of 0 in the case of insufficient evidence and 4 when all data for the model is known, used appropriately, and traceable to the Real-World System (RWS) with acceptable accuracy, precision, and uncertainty. The credibility factor sufficiency thresholds were assigned upon guidance from NASA EVA subject matter experts. The factor scores were ascertained through the evaluation of M&S credibility assessment procedures described in the published literature and FE model reports. The M&S credibility scores for the Elemance and THUMS FE models vary between 1 and 3 for data pedigree, input pedigree, and referent validation credibility factors, and between 0 and 1 for code verification, solution verification, conceptual validation, results uncertainty and results robustness. The results show that these FE models are credible for simulating fall from heights injury scenarios in specific kinematic and kinetic ranges that correlate with highway and contact sports-related external conditions. Multiple credibility elevation strategies are prescribed to improve the Elemance and THUMS models’ credibility for use in the EVA fall from height injury scenarios.

R A Perkins↗

NASA NTRS2007

Earth Global Reference Atmospheric Model (GRAM99): Short Course

Earth-GRAM is a FORTRAN software package that can run on a variety of platforms including PC's. For any time and location in the Earth's atmosphere, Earth-GRAM provides values of atmospheric quantities such as temperature, pressure, density, winds, constituents, etc.. Dispersions (perturbations) of these parameters are also provided and have realistic correlations, means, and variances - useful for Monte Carlo analysis. Earth-GRAM is driven by observations including a tropospheric database available from the National Climatic Data Center. Although Earth-GRAM can be run in a "stand-alone" mode, many users incorporate it into their trajectory codes. The source code is distributed free-of-charge to eligible recipients.

Leslie, Fred W.↗

NASA NTRS1979

Average plasma environment at geosynchronous orbit

The average plasma environment at geosynchronous orbit (GSO) is derived from a whole year's worth of plasma data obtained by the UCSD electrostatic electrometer on board ATS 5. The result is primarily intended for use as a general reference for engineers designing a large spacecraft to be flown at GSO. A simple mathematical formula using a 3rd order polynomial is found to be adequate for representing the yearly averaged particle energy spectrum from 70 to 41,000 eV under different geomagnetic conditions. Furthermore, correlation analyses with the geomagnetic planetary index Kp and with the auroral electrojet index AE were carried out in the hope that the ground observations of the geomagnetic field variations can be used to predict the plasma variations in space. Unfortunately, the results indicate that such forecasting is not feasible by use of these two popular geomagnetic parameters alone.

Su, S. Y.↗

NASA NTRS1989

Experimental tests of methods for the measurement of rainfall rate using an airborne dual-wavelength radar

Several attenuation-based methods for estimating the rainfall rate were applied to measurements made by an airborne dual-wavelength radar operating at 0.87 cm, the K(a)-band, and at 3 cm, the X-band. These methods included the traditional Z-R methods, designated Z(X)-R and Z(K)-R for the X- and K(a) band wavelengths, respectively; single- and dual-wavelength surface reference techniques (SRT and DSRT, respectively); and standard dual-wavelength methods with and without range-averaging. As the primary sources of error for these methods are nearly independent, agreement among the rain rates obtained with these methods would lend confidence in the results. Correlation coefficients obtained between the rainfall rates with the Z(X)-R and DSRT methods were generally between 0.7 and 0.9. Good agreement among the methods occurred most often in stratiform rain for rain rates betwen a few mm/hr to about 15 mm/hr, i.e., where attenuation at the shorter wavelength is significant but not so severe as to result in a loss of signal.

Meneghini, R.↗

NASA NTRS1992

A comparison of the coupled cluster and internally contracted averaged coupled-pair functional levels of theory for the calculation of the MCH2(+) binding energies for M = Sc to Cu

The correlation contribution to the M-C binding energy for the MCH2(+) systems can exceed 100 kcal/mol. At the self-consistent field (SCF) level, these systems can be more than 50 kcal/mol above the fragment energies. In spite of the poor zeroth-order reference, the coupled cluster single and double excitation method with a perturbational estimate of triple excitations, CCSD(T), method is shown to provide an accurate description of these systems. The maximum difference between the CCSD(T) and internally contracted averaged coupled-pair functional binding energies is 1.5 kcal/mol for CrCH2(+), with the remaining systems agreeing to within 1.0 kcal/mol.

Bauschlicher, Charles W., Jr.↗