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At least 433 records · Page 24

Fire- and heat-resistant laminating resins based on maleimido-substituted aromatic cyclotriphosphazenes

A novel class of flame- and heat-resistant polymers has been synthesized by the thermal polymerization of maleimido-substituted aromatic cyclotriphosphazenes. The polymer obtained from tris-(aminophenoxy)tris(maleimidophenoxy)cyclotriphosphazene has good thermal stability and is noteworthy for its high char yield, viz., 82 percent at 800 C in nitrogen and 81 percent at 700 C in air. Graphite-fabric laminates prepared with this polymer did not burn in pure oxygen, even at 300 C, and were tested for mechanical properties. Hexakis(4-maleimidophenoxy)cyclotriphosphazene and some fluorine-containing monomers have also been synthesized. The structures of these cyclic phosphazene precursors and polymers were characterized by FT IR spectrophotometry, H-1 NMR, F-19 NMR, and P-31 solid-state magic angle spinning NMR spectroscopy, and mass spectrometry. The curing behavior of the polymer precursors and the thermal stabilities of the polymers were evaluated by differential scanning calorimetry (DSC) and thermogravimetric analyses (TGA).

Kumar, D.↗

The reflection spectrum of liquid sulfur - Implications for Io

The spectral reflectance from 0.38 to 0.75 micron of a column of liquid sulfur has been measured at several temperatures between the melting point (approximately 118 C) and 173 C. Below 160 C the spectral reflectance was observed to vary reversibly as a function of temperature, indepenent of the previous thermal history of the column. Once the temperature exceeded 160 C, the spectrum would not change given a subsequent decrease in temperature. The spectral reflectance of the liquid-sulfur column at all temperatures was very low (10-19 percent). Combining this information with Voyager spectrophotometry of Jupiter's satellite Io, it is concluded that liquid sulfur at any temperature on Io's surface would be classified as a 'black area' according to the standards used by the Voyager imaging team in their spectrophotometric analysis (Soderblom, Johnson, Morrison, Danielson, Smith, Veverka, Cook,Sagan, Kupferman, Pieri, Mosher, Avis, Gradie, and Clancy /1980/.

Nelson, R. M.↗

Optical identification of 2S 1417-62

The 17 s X-ray pulsar 2S 1417-62 has been identified with a V of approximately 16.9 mag OB star on the basis of an X-ray position obtained with the Einstein X-Ray Observatory and spectrophotometry with the 4-m telescope at Cerro Tololo Inter-American Observatory. Strong H-alpha emission is observed as well as significant changes in X-ray luminosity. The optical counterpart may be either a Be or a B I star, but the H-alpha emission strength and galactic position suggest that a Be star is more likely. A Be star identification also further supports the limit of approximately 15 days or more on the system binary period obtained by Kelley et al. (1981) from pulse timing studies.

Grindlay, J. E.↗

Broad band X-ray astronomical spectroscopy

The Broad Band X-Ray Telescope (BBXRT) experiment has been designed for high sensitivity, moderate resolution spectrophotometry of cosmic sources in the range 0.5 to 12 keV. Principal elements are two co-aligned imaging telescopes with cooled Si(Li) detectors at each focus. The mirror design uses an approximate geometry of tightly nested, conical, foil reflectors that allow a large filling factor (high throughput) at small grazing angles (high energy response). Each detector consists of a cluster of five elements defined with grooves on a single crystal. This arrangement affords some spatial resolution as well as a means of substantial background reduction. Shuttle borne measurements will typically be of 2000 s duration for sources with a flux of 10 to the -12 erg/sq cm-s.

Serlemitsos, P. J.↗

The 3000 A bump in quasars

New observations of the 3000 A bump in quasars are presented and some simple considerations regarding its physical origin are addressed. Absolute spectrophotometry of 30 quasars with redshifts between 0.53 and 0.70 was obtained with the multichannel spectrometer on the 5 m Hale telescope with a rest wavelength coverage of 2000-5000 A. The continuum observations are well represented by a single power law plus a smooth, broad bump and superposed Fe II multiplets. The strength of the bump correlates fairly well with that of H-beta but poorly with those of the Mg II and Fe II lines. Models consisting of a power law and optically thick hydrogen continua with temperatures of about 12,000 K, and Balmer-edge optical depths equal to three fit the observed energy distributions well. The physical conditions and continuum emission of a dense slab of hydrogen heated by gamma rays are analyzed.

Oke, J. B.↗

GD 323 - A white dwarf with a stratified H/He atmosphere?

New optical and ultraviolet (IUE) spectrophotometry of the hot white dwarf GD 323 are presented. The optical spectra exhibit broad, shallow Balmer lines, together with weaker He I lambda-4471, lambda-4921 lines. However, the effective temperature and helium abundance derived from the optical spectrum appear incompatible with parameters derived from the optical colors and the overall energy distribution - thus suggesting that GD 323 does not have a homogeneous, mixed composition atmosphere. The alternative interpretations of substantial reddening, a rapidly rotating subdwarf, an accreting short-period binary, and a detached DA + DB binary system are ruled out. It is suggested instead that GD 323 may have a stratified atmosphere, with an optically thin hydrogen layer overlying a helium envelope at T(e) about 30,000 K; however, this conclusion must be properly tested.

Liebert, J.↗

IUE observations of Centaurus X-4 during the 1979 May outburst

Ultraviolet spectrophotometry of the X-ray transient/burst source Centaurus X-4 at several intervals during the peak and decay of the May 1979 X-ray transient event was obtained. The spectrum was characterized by a blue continuum with alpha = 0.0 + or - 0.3 (F/nu/ varies as nu to the alpha power) and strong emission lines of N V lambda 1240, C IV lambda 1550, and Si IV lambda 1398. The relative intensities of the emission lines and the ratio of line to continuum strengths remained nearly constant during the decline. The emission lines may have arisen from a 'disk chromosphere', from X-ray heating of the K4 V companion star, or both. The ultraviolet data are combined with previously published optical and X-ray data to determine some of the physical characteristics of the system and to show that X-ray reprocessing plays an important role in producing the optical and ultraviolet continua.

Blair, W. P.↗

Comet Bowell 1980b

Optical filter photometry, and optical and ultraviolet spectrophotometry data collected between November 1980 and June 1982 of Comet Bowell are presented. It was determined that Comet Bowell began producing significant amounts of OH, though not other species, before perihelion at a heliocentric distance near 4.6 AU. As the comet approached perihelion at 3.4 AU, OH production decreased and CN and C2 species were detected at normal concentrations. An outburst in April 1982 was dominated by OH. The grains in 1982 near perihelion showed increases in albedo between 3150 and 4500 A and 1.2 and 1.6 microns. The presence of two grains populations was suggested, together with the conclusion that Comet Bowell was physically a typical new comet entering the inner solar system from the Oort cloud for the first time.

Feldman, P. D.↗

Notes on the system TV Geminorum

Low-resolution SWP spectra and high-resolution LWR spectra of the SRc variable star TV Gem have been studied. The available ultraviolet spectrophotometry and UBV photometry of the system can be interpreted in terms of the blended light from a B3.5 IV star and an M1 Iab star. The separation of the two stars is less than about 3 arc sec. Since the magnitude difference is a minimum in the B filter, being about 1.6 mag there, direct observation of TV Gem in a passband at 4400 A under conditions of good seeing might reveal the blue companion. No evidence was found for absorption lines of Mg II formed in the part of the wind of the M star which is projected against the disk of the B star.

Underhill, A. B.↗

The mysterious 10 micron emission feature in the spectrum of Nova Aquilae 1982

Broad-band 1.2-23 micron photometry and 1 percent resolution 7-14 micron spectrophotometry of Nova Aql 1982 are presented. This nova developed similarly to other dusty novae in that the appearance of thermal infrared emission from a circumstellar dust shell was coincident with a downward transition at visual wavelengths. A strong 10 micron emission feature appeared in the spectrum of Nova Aql 1982 during the dust shell development phase. This feature was not entirely similar to emission features previously observed in other stars with circumstellar shells. The contrast of the nova's 10 micron feature was larger than those observed in the SiC-rich shells of carbon stars. On the other hand, although the nova emission feature was reminiscent of the 10 micron silicate emission feature observed in oxygen-rich supergiants, it peaked at a slightly longer wavelength and there was no corresponding 20 micron emission feature. The contrast of the feature increased with time. It is concluded that an anomalous dust grain component, tentatively identified as SiC, nucleated and grew in the circumstellar shell of Nova Aql 1982.

Ney, E. P.↗

Surface of Miranda - Identification of water ice

Near-infrared spectrophotometry at 5-percent resolution shows Miranda to have a water-ice surface. Estimates of Miranda's albedo made from the depth of its 2.0-micron absorption band suggest that its visual geometric albedo is likely to be between 10 and 70 percent which when combined with the satellite's visual magnitude, yields a diameter of 500 + or 225 km. There is some evidence that suggests the visual geometric albedo of Miranda may be greater than or equal to 0.3, which implies that its diameter may lie near the lower end of the estimated range. With these results all the Uranian satellites are now known to have water-ice surfaces.

Brown, R. H.↗

The nature of the filaments northeast of the supernova remnant IC 443

New optical spectrophotometry of the faint filaments northeast of the bright supernova remnant IC 443 show emission-line ratios very similar to those seen in the bright filaments of IC 443 and other supernova remnants. This suggests that these northeastern filaments also represent shock-heated interstellar gas and are not simply the southern boundary of the neighboring H II region S249 as previously suspected. If these filaments are associated with IC 443, they then reveal a much more extended remnant structure than previously assumed and permit a relatively accurate determination of IC 443's distance via its interaction with S249.

Fesen, R. A.↗

Detalied X-ray observations of the Cygnus Loop

High quality X-ray spectra and imaging observations of the Cygnus Loop have been obtained with three different instruments. The High Resolution Imager (HRI) on the Einstein Observatory was used to obtain arcsecond resolution images of select bright regions in the Cygnus Loop which permit detailed comparisons between the X-ray, optical, and radio structure of the Loop. The Imaging Proportional Counter (IPC) on the Einstein Observatory was used to obtain an arcminute resolution map of essentially the full Loop structure. Finally, an Imaging Gas Scintillation Proportional Counter (IGSPC), carried aloft by a sounding rocket last fall, obtained modest resolution, spatially resolved spectrophotometry of the Cygnus Loop. An X-ray map of the Loop in the energy of the O VIII line was obtained. These data combine to yield a very powerful probe of the abundance, temperature, and density distribution of material in the supernova remnant, and in the interstellar medium.

Ku, W. H.-M.↗

An optical investigation of the peculiar supernova remnant CTB 80

Interference-filter photographs and optical spectrophotometry are used to investigate the optical emission associated with the peculiar supernova remnant CTB 80. Optically, the remnant consists of outlying diffuse and filamentary emission surrounding a small, central ring of filaments which are coincident with the central radio emission peak. Spectra of two filaments in the southwestern part of the remnant show strong forbidden S II emission relative to H-alpha; in conjunction with the nonthermal radio emission in this region, this suggests that the filaments are shock heated. Filaments outside the radio structure in the northeast show a similar optical spectrum and may also be a part of CTB 80. The central filaments form a well-defined shell structure in the light of forbidden O III emission 5007 A but are irregular in H-alpha showing both knots and diffuse emission.

Blair, W. P.↗

Ultraviolet and visible flare observations of EQ Pegasi B

EQ Peg AB (dM43+dM5.5e) was monitored in the visible at the Whipple Observatory and ultraviolet with IUE on September 2, 1981. In the visible spectrophotometry of EQ Peg B the H-beta emission strengthened by a factor of 2 relative to the nearby stellar continuum within a few minutes and decayed over an hour. This flare in EQ Peg B was coincident with the enhancement of ultraviolet emission lines of C IV 1550 A, He II 1640 A, and C II 1335 A in the combined light of EQ Peg AB. The ultraviolet fluxes during the flare can be interpreted as similar to those either in the thermal phases of large two-ribbon solor flares where radiative cooling balances thermal conduction or in gas cooling quickly from X-ray emitting temperatures. The appearance of the ultraviolet continuum at 1700-1900 A and ratio of H-alpha to H-beta fluxes during the flare are consistent with models producing these emissions in the chromosphere.

Baliunas, S. L.↗

Planned observations of P/Halley with the Hopkins Ultraviolet Telescope on Space Shuttle

The Hopkins Ultraviolet Telescope (HUT) is an f/2 90-cm prime-focus telescope with an f/2 Rowland-circle spectrograph designed for far-ultraviolet spectrophotometry of faint astronomical sources. The wavelength range is 850-1850 A with an ultimate spectral resolution of 2 A, but for observations of solar-system objects the spectrograph is responsive, in second order, to wavelengths as short as 500 A. The HUT is one of three instruments to be carried on Space Shuttle in 1986 as part of an ultraviolet astronomy payload, and it is intended to use these instruments for observations of Halley during the encounters in March, 1986. In addition to its unique capability to observe at wavelengths shorter than 1150 A, the spectral region that includes the resonance transitions of the noble gases, the HUT is significantly more sensitive for observations of extended sources than either IUE or Space Telescope.

Feldman, P. D.↗

Spectral Characteristics of Dust in Planetary Nebulae

Some carbon-rich planetary nebulae exhibit a strong broad emission feature beginning at Lambda which is approximately 24 microns and extending to Lambda greater than 30 microns. Thirty to 55 micron spectrophotometry of Ic 418 and NGC 6572, both of which have the strong broad emission feature, allow the wavelength dependence of the emissivity of the dust responsible for the feature to be defined. Comparison with laboratory spectra of candidate materials which are likely to condense in a carbon-rich environment suggests that the feature arises from MgS. The implications of such a strong feature arising from a relatively minor dust constituent are discussed. The environment in which MgS may be found is considered. It is speculated that MgS will be seen in objects with C/O ratios only slightly greater than one, but not in extremely carbon rich objects. In objects with much higher carbon abundances, the formation of CS consumes S so that insufficient MgS can form to exhibit the strong feature. These observations imply that the emergent far infrared spectrum of carbon-rich objects are very different depending on the abundance of the low temperature condensate MgS.

Moseley, H.↗

Ultraviolet spectroscopy of selected astronomical sources

The birth rates of various kinds of white dwarf progenitors are estimated and the spectra of two very hot O-type white dwarfs are analyzed. The effective temperature of LSE 21 was found to be in excess of 100,000 K. The abundance of iron in the atmospheres of two central stars and numerous very hot O-type subdwarfs was found to be strongly variable. Results obtained by high resolution optical spectroscopy, UBV photometry, and low resolution IUE spectrophotometry for LSS 2018, the central star of the planetary nebulae DS1, are summarized. A planetary nebula surrounding the very hot subdwarf LSS 1362 was discovered. Analysis of results obtained by high resolution optical spectra shows agreement with an effective temperature of 110,000 K derived using low resolution IUE observations.

Drilling, J. S.↗