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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Thermoelectric Properties of Self Assembled TiO2/SnO2 Nanocomposites

Recent advances in improving efficiency of thermoelectric materials are linked to nanotechnology. Thermodynamically driven spinodal decomposition was utilized to synthesize bulk nanocomposites. TiO2/SnO2 system exhibits a large spinodal region, ranging from 15 to 85 mole % TiO2. The phase separated microstructures are stable up to 1400 C. Semiconducting TiO2/SnO2 powders were synthesized by solid state reaction between TiO2 and SnO2. High density samples were fabricated by pressureless sintering. Self assemble nanocomposites were achieved by annealing at 1000 to 1350 C. X-ray diffraction reveal phase separation of (Ti(x)Sn(1-x))O2 type phases. The TiO2/SnO2 nanocomposites exhibit n-type behavior; a power factor of 70 W/mK2 at 1000 C has been achieved with penta-valent doping. Seebeck, thermal conductivity, electrical resistivity and microstructure will be discussed in relation to composition and doping.

Dynys, Fred↗
NASA NTRS2008

MEMS/ECD Method for Making Bi(2-x)Sb(x)Te3 Thermoelectric Devices

A method of fabricating Bi(2-x)Sb(x)Te3-based thermoelectric microdevices involves a combination of (1) techniques used previously in the fabrication of integrated circuits and of microelectromechanical systems (MEMS) and (2) a relatively inexpensive MEMS-oriented electrochemical-deposition (ECD) technique. The present method overcomes the limitations of prior MEMS fabrication techniques and makes it possible to satisfy requirements.

Lim, James↗
NASA NTRS2009

Thermoelectric properties by high temperature annealing

The present invention generally provides methods of improving thermoelectric properties of alloys by subjecting them to one or more high temperature annealing steps, performed at temperatures at which the alloys exhibit a mixed solid/liquid phase, followed by cooling steps. For example, in one aspect, such a method of the invention can include subjecting an alloy sample to a temperature that is sufficiently elevated to cause partial melting of at least some of the grains. The sample can then be cooled so as to solidify the melted grain portions such that each solidified grain portion exhibits an average chemical composition, characterized by a relative concentration of elements forming the alloy, that is different than that of the remainder of the grain.

Ren, Zhifeng↗
NASA NTRS2007

Mechanical Alloying for Making Thermoelectric Compounds

An economical room-temperature mechanical alloying process has been shown to be an effective means of making a homogeneous powder that can be hot-pressed to synthesize a thermoelectric material having reproducible chemical composition. The synthesis of a given material consists of the room temperature thermomechanical-alloying process followed b y a hot-pressing process. Relative to synthesis of nominally the same material by a traditional process that includes hot melting, this s ynthesis is simpler and yields a material having superior thermoelect ric properties.

Huang, Chen-Kuo↗
NASA NTRS2010

Efficient thermoelectric device

A high efficiency thermo electric device comprising a multi nanolayer structure of alternating insulator and insulator/metal material that is irradiated across the plane of the layer structure with ionizing radiation. The ionizing radiation produces nanocrystals in the layered structure that increase the electrical conductivity and decrease the thermal conductivity thereby increasing the thermoelectric figure of merit. Figures of merit as high as 2.5 have been achieved using layers of co-deposited gold and silicon dioxide interspersed with layers of silicon dioxide. The gold to silicon dioxide ratio was 0.04. 5 MeV silicon ions were used to irradiate the structure. Other metals and insulators may be substituted. Other ionizing radiation sources may be used. The structure tolerates a wide range of metal to insulator ratio.

Ila, Daryush↗
NASA NTRS2010

Thermoelectric Converter for Loop Heat Pipe Temperature Control: Experience and Lessons Learned

This paper describes the theoretical background and implementation methodology of using a thermoelectric converter (TEC) for operating temperature control of a loop heat pipe (LHP). In particular, experimental results from ambient and thermal vacuum tests of an LHP are presented for illustrations. The most commonly used state-of-the-art method to control the LHP operating temperature is to cold bias its compensation chamber (CC) and use an electrical heater to maintain the CC at the desired set point temperature. Although effective, this approach has its shortcomings in that the electrical heater can only provide heating to the CC, and the required power can be large under certain conditions. An alternative method is to use a TEC, which is capable of providing both heating and cooling to the CC. In this method, one side of the TEC is attached to the CC, and the other side is connected to the evaporator via a thermal strap. Using a bipolar power supply and a control algorithm, a TEC can function as a heater or a cooler, depending on the direction of the current flow. Extensive ground tests of several LHPs have demonstrated that a TEC can provide very tight temperature control for the CC. It also offers several additional advantages: (1) The LHP can operate at temperatures below its natural operating temperature at low heat loads; (2) The required heater power for a TEC is much less than that for an electrical heater; and (3) It enhances the LHP start-up success. Although the concept of using a TEC for LHP temperature control is simple, there are many factors to be considered in its implementation for space applications because the TEC is susceptible to the shear stress and yet has to sustain the dynamic load under the spacecraft launch environment. The added features that help the TEC to withstand the dynamic load will inevitably affect the TEC thermal performance. Some experiences and lessons learned are addressed in this paper.

Ku, Jentung↗
NASA NTRS2011

Thermoelectric Energy Conversion Technology for High-Altitude Airships

The High Altitude Airship (HAA) has various application potential and mission scenarios that require onboard energy harvesting and power distribution systems. The power technology for HAA maneuverability and mission-oriented applications must come from its surroundings, e.g. solar power. The energy harvesting system considered for HAA is based on the advanced thermoelectric (ATE) materials being developed at NASA Langley Research Center. The materials selected for ATE are silicon germanium (SiGe) and bismuth telluride (Bi2Te3), in multiple layers. The layered structure of the advanced TE materials is specifically engineered to provide maximum efficiency for the corresponding range of operational temperatures. For three layers of the advanced TE materials that operate at high, medium, and low temperatures, correspondingly in a tandem mode, the cascaded efficiency is estimated to be greater than 60 percent.

Choi, Sang H.↗
NASA NTRS2006

Thermoelectric Inhomogeneities in (Ag(sub 1-y)SbTe2)(sub x)(PbTe)(sub 1-x)

A document presents a study of why materials of composition (Ag1 ySbTe2)0.05 (PbTe)0.95 [0< or = y < or = 1] were previously reported to have values of the thermoelectric figure of merit [ZT (where Z = alpha(sup 2)/rk, alpha is the Seebeck coefficient, r is electrical resistivity, k is thermal conductivity, and T is absolute temperature)] ranging from <1 to >2. In the study, samples of (AgSbTe2)0.05(PbTe)0.95, (Ag0.67SbTe2)0.05 (PbTe)0.95, and (Ag0.55SbTe2)0.05(PbTe)0.95 were prepared by melting followed, variously, by slow or rapid cooling. Analyses of these samples by x-ray diffraction, electron microscopy, and scanning-microprobe measurements of the Seebeck coefficient led to the conclusion that these materials have a multiphase character on a scale of the order of millimeters, even though they appear homogeneous in x-ray diffraction and electron microscopy. The Seebeck measurements showed significant variations, including both n-type and p-type behavior in the same sample. These variations were found to be consistent with observed variations of ZT. The rapidly quenched samples were found to be less inhomogeneous than were the furnace-cooled ones; hence, rapid quenching was suggested as a basis of research on synthesizing more nearly uniform high-ZT samples.

Snyder, G. Jeffrey↗
NASA NTRS2011

Loop Heat Pipe Transient Behavior Using Heat Source Temperature for Set Point Control with Thermoelectric Converter on Reservoir

The LHP operating temperature is governed by the saturation temperature of its reservoir. Controlling the reservoir saturation temperature is commonly done by cold biasing the reservoir and using electrical heaters to provide the required control power. With this method, the loop operating temperature can be controlled within 0.5K or better. However, because the thermal resistance that exists between the heat source and the LHP evaporator, the heat source temperature will vary with its heat output even if the LHP operating temperature is kept constant. Since maintaining a constant heat source temperature is of most interest, a question often raised is whether the heat source temperature can be used for LHP set point temperature control. A test program with a miniature LHP was carried out to investigate the effects on the LHP operation when the control temperature sensor was placed on the heat source instead of the reservoir. In these tests, the LHP reservoir was cold-biased and was heated by a control heater. Test results show that it was feasible to use the heat source temperature for feedback control of the LHP operation. In particular, when a thermoelectric converter was used as the reservoir control heater, the heat source temperature could be maintained within a tight range using a proportional-integral-derivative or on/off control algorithm. Moreover, because the TEC could provide both heating and cooling to the reservoir, temperature oscillations during fast transients such as loop startup could be eliminated or substantially reduced when compared to using an electrical heater as the control heater.

Ku, Jentung↗
NASA NTRS2012

Multi-Mission Radioisotope Thermoelectric Generator Heat Exchangers for the Mars Science Laboratory Rover

The addition of the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) to the Mars Science Laboratory (MSL) Rover requires an advanced thermal control system that is able to both recover and reject the waste heat from the MMRTG as needed in order to maintain the onboard electronics at benign temperatures despite the extreme and widely varying environmental conditions experienced both on the way to Mars and on the Martian surface. Based on the previously successful Mars landed mission thermal control schemes, a mechanically pumped fluid loop (MPFL) architecture was selected as the most robust and efficient means for meeting the MSL thermal requirements. The MSL heat recovery and rejection system (HRS) is comprised of two Freon (CFC-11) MPFLs that interact closely with one another to provide comprehensive thermal management throughout all mission phases. The first loop, called the Rover HRS (RHRS), consists of a set of pumps, thermal control valves, and heat exchangers (HXs) that enables the transport of heat from the MMRTG to the rover electronics during cold conditions or from the electronics straight to the environment for immediate heat rejection during warm conditions. The second loop, called the Cruise HRS (CHRS), is thermally coupled to the RHRS during the cruise to Mars, and provides a means for dissipating the waste heat more directly from the MMRTG as well as from both the cruise stage and rover avionics by promoting circulation to the cruise stage radiators. A multifunctional structure was developed that is capable of both collecting waste heat from the MMRTG and rejecting the waste heat to the surrounding environment. It consists of a pair of honeycomb core sandwich panels with HRS tubes bonded to both sides. Two similar HX assemblies were designed to surround the MMRTG on the aft end of the rover. Heat acquisition is accomplished on the interior (MMRTG facing) surface of each HX while heat rejection is accomplished on the exterior surface of each HX. Since these two surfaces need to be at very different temperatures in order for the fluid loops to perform efficiently, they need to be thermally isolated from one another. The HXs were therefore designed for high in-plane thermal conductivity and extremely low through-thickness thermal conductivity by using aluminum facesheets and aerogel as insulation inside a composite honeycomb core. Complex assemblies of hand-welded and uniquely bent aluminum tubes are bonded onto each side of the HX panels, and are specifically designed to be easily mated and demated to the rest of the RHRS in order to ease the integration effort.

Mastropietro, A. J.↗
NASA NTRS2013

Vapor Compression and Thermoelectric Heat Pump Heat Exchangers for a Condensate Distillation System: Design and Experiment

Maximizing the reuse of wastewater while minimizing the use of consumables is critical in long duration space exploration. One of the more promising methods of reclaiming urine is the distillation/condensation process used in the cascade distillation system (CDS). This system accepts a mixture of urine and toxic stabilizing agents, heats it to vaporize the water and condenses and cools the resulting water vapor. The CDS wastewater flow requires heating and its condensate flow requires cooling. Performing the heating and cooling processes separately requires two separate units, each of which would require large amounts of electrical power. By heating the wastewater and cooling the condensate in a single heat pump unit, mass, volume, and power efficiencies can be obtained. The present work describes and compares two competing heat pump methodologies that meet the needs of the CDS: 1) a series of mini compressor vapor compression cycles and 2) a thermoelectric heat exchanger. In the paper, the system level requirements are outlined, the designs of the two heat pumps are described in detail, and the results of heat pump performance tests are provided. A summary is provided of the heat pump mass, volume and power trades and a selection recommendation is made.

Erickson, Lisa R.↗
NASA NTRS2012

Vapor Compression and Thermoelectric Heat Pumps for a Cascade Distillation Subsystem: Design and Experiment

Humans on a spacecraft require significant amounts of water for drinking, food, hydration, and hygiene. Maximizing the reuse of wastewater while minimizing the use of consumables is critical for long duration space exploration. One of the more promising consumable-free methods of reclaiming wastewater is the distillation/condensation process used in the Cascade Distillation Subsystem (CDS). The CDS heats wastewater to the point of vaporization then condenses and cools the resulting water vapor. The CDS wastewater flow requires heating for evaporation and the product water flow requires cooling for condensation. Performing the heating and cooling processes separately would require two separate units, each of which would demand large amounts of electrical power. Mass, volume, and power efficiencies can be obtained by heating the wastewater and cooling the condensate in a single heat pump unit. The present work describes and compares two competing heat pump methodologies that meet the needs of the CDS: 1) a series of mini compressor vapor compression cycles and 2) a thermoelectric heat exchanger. In the paper, the CDS system level requirements are outlined, the designs of the two heat pumps are described in detail, and the results of heat pump analysis and performance tests are provided. The mass, volume, and power requirement for each heat pump option is compared and the advantages and disadvantages of each system are listed.

Erickson, Lisa R.↗
NASA NTRS2013

High Temperature Stable Nanocrystalline SiGe Thermoelectric Material

A method of forming a nanocomposite thermoelectric material having microstructural stability at temperatures greater than 1000 C. The method includes creating nanocrystalline powder by cryomilling. The method is particularly useful in forming SiGe alloy powder.

Yang, Sherwin↗
NASA NTRS2016

Usage of Multi-Mission Radioisotope Thermoelectric Generators (MMRTGs) for Future Potential Missions

The goal of NASAs Radioisotope Power Systems (RPS) Program is to make RPS ready and available to support the exploration of the solar system in environments where the use of conventional solar or chemical power generation is impractical or impossible to meet the needs of the missions. To meet this goal, the RPS Program, working closely with the Department of Energy, performs mission and system studies (such as the recently released Nuclear Power Assessment Study), evaluates the readiness of promising technologies to infuse in future generators, assesses the sustainment of key RPS capabilities and knowledge, forecasts and tracks the Programs budgetary needs, and disseminates current information about RPS to the community of potential users. This presentation focuses on the needs of the mission community and provides users a better understanding of how to integrate the MMRTG (Multi-Mission Radioisotope Thermoelectric Generator).

Radioisotope↗
NASA NTRS2016

Multi-Mission Radioisotope Thermoelectric Generator Experience on Mars

The Mars Science Laboratory (MSL) Curiosity rover has been operating on Mars using the F1 Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) for over one and one-half Mars years (over three Earth years). During this extended period, Curiosity has provided a wealth of information about operating with a MMRTG in the Mars surface environment. This paper discusses MMRTG performance over the life of the mission as affected not only by expected radioisotope degradation, but also by the thermal environment, including seasonal, wind, and time-of-sol effects. Additionally, issues related to MMRTG internal shorts will be discussed including detection, impacts on operations, and clearing the shorts.

RTG↗
NASA NTRS2018

A Simple Thermoelectric Droplet Generator

A new design for a droplet generator capable of producing single droplets is presented. The design relies on thermoelectric heating to vaporize water at the interface between a droplet and a blunt syringe tip. While other designs require careful tuning to produce drops of varying size, this technique enables the simple creation of droplets of any size within a range. The design is of simple construction and can be completed with off-the-shelf components, and relies on resistive heating to vaporize water at or near the droplet-nozzle interface and release the droplets. We demonstrated that the design can be used to produce droplets as small as 110 µm or as large as 2 mm. Drop size is limited by the geometry of the nozzle since water must wet the tip of the nozzle and hang under gravity. Our experiments showed that released droplets have relatively small disturbances introduced by the release mechanism when compared to competing techniques. These disturbances were intermittently observed as the voltage, pulse width, and drop size were changed, and optimal settings were determined for the smallest drop sizes produced.

Andrew Work↗