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Pluminate: Quantifying aerosol injection behavior from simulation, experimentation and observations

Marine aerosol injections are a key component in further understanding of both the potentials of deliberate injection for marine cloud brightening (MCB), a potential climate intervention (CI) strategy, and key aerosol-cloud interaction behaviors that currently form the largest uncertainty in global climate model (GCM) predictions of our climate. Since the rate of spread of aerosols in a marine environment directly translates to the effectiveness and ability of aerosol injections in impacting cloud radiative forcing, it is crucial to understand the spatial and temporal extent of injected-aerosol effects following direct injection into marine environments. The ubiquity of ship-injected aerosol tracks from satellite imagery renders observational validation of new parameterizations possible in 2D, however, 3D compatible data is more scarce, and necessary for the development of subgrid scale parameterizations of aerosol-cloud interactions in GCMs. This report introduces two novel parameterizations of atmospheric aerosol injection behavior suitable for both 3D (GCM-compatible) and 2D (observation-related) modeling. Their applicability is highlighted using a wealth of different observational data: small and larger scale salt-aerosol injection experiments conducted at SNL, 3D large eddy simulations of ship-injected aerosol tracks and 2D satellite images of ship tracks. The power of experimental data in enhancing knowledge of aerosol-cloud interactions is in particular emphasized by studying key aerosol microphysical and optical properties as observed through their mixing in cloud-like environments.

54 ENVIRONMENTAL SCIENCES↗

Exploring and Visualizing A-Train Instrument Data

The succession of US and international satellites that follow each other in close succession, known as the A-Train, affords an opportunity to atmospheric researchers that no single platform could provide: Increasing the number of observations at any given geographic location.. . a more complete "virtual science platform". However, vertically and horizontally, co-registering and regridding datasets from independently developed missions, Aqua, Calipso, Cloudsat, Parasol, and Aura, so that they can be inter-compared can be daunting to some, and may be repeated by many. Scientists will individually spend much of their time and resources acquiring A-Train datasets of interest residing at various locations, developing algorithms to match up and graph datasets along the A-Train track, and search through large amounts of data for areas and/or phenomena of interest. The aggregate amount of effort that can be expended on repeating pre-science tasks could climb into the tens of millions of dollars. The goal of the A-Train Data Depot (ATDD) is to enable free movement of remotely located A-Train data so that they are combined to create a consolidated vertical view of the Earth's Atmosphere along the A-Train tracks. The innovative approach of analyzing and visualizing atmospheric profiles along the platforms track (i.e., time) is accomplished by through the ATDDs Giovanni data analysis and visualization tool. Giovanni brings together data from Aqua (MODIS, AIRS, AMSR-E), Cloudsat (cloud profiling radar) and Calipso (CALIOP, IIR), as well as the Aura (OMI, MLS, HIRDLS, TES) to create a consolidated vertical view of the Earth's Atmosphere along the A-Train tracks. This easy to learn and use exploration tool will allow users to create vertical profiles of any desired A-Train dataset, for any given time of choice. This presentation shows the power of Giovanni by describing and illustrating how this tool facilitates and aids A-Train science and research. A web based display system Giovanni provides users with the capability of creating co-located profile images of temperature and humidity data from the MODIS, MLS and AIRS instruments for a user specified time and spatial area. In addition, Cloud and Aerosol profiles may also be displayed for the Cloudsat and Caliop instruments. The ability to modify horizontal and vertical axis range, data range and dynamic color range is also provided. Two dimensional strip plots of MODIS, AIRS, OM1 and POLDER parameters, co-located along the Cloudsat reference track, can also be plotted along with the Cloudsat cloud profiling data. Center swath pixels for the same parameters can also be shown as line plots overlaying the Cloudsat or Calipso profile images. Images and subsetted data produced in each analysis run may be downloaded. Users truly can explore and discover data specific to their needs prior to ever transferring data to their analysis tools.

Kempler, S.↗

Large-Scale Air Mass Characteristics Observed Over the Remote Tropical Pacific Ocean During March-April 1999: Results from PEM-Tropics B Field Experiment

Eighteen long-range flights over the Pacific Ocean between 38 S to 20 N and 166 E to 90 W were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (O3), water vapor (H2O), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in O3, carbon monoxide, hydrocarbons, and aerosols and an increase in H2O. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced O3 and aerosols and an associated decrease in H2O. Average latitudinal and longitudinal distributions of O3 and H2O were constructed from the remote and in situ O3 and H2O data, and these distributions are compared with results from PEM-Tropics A conducted in August-October 1996. During PEM-Tropics B, low O3 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced O3 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their O3, aerosols, clouds, and potential vorticity characteristics. The data from each flight were binned by altitude according to air mass type, and these results showed the relative observational frequency of the different air masses as a function of altitude in seven regions over the Pacific. The average chemical composition of the major air mass types was determined from in situ measurements in the NH and SH, and these results provided insight into the origin, lifetime, and chemistry of the air in these regions.

Browell, Edward V.↗

The Effect of Aerosols and Clouds on the Retrieval of Infrared Sea Surface Temperatures

Comparisons are performed between spatially averaged sea surface temperatures (ASST2) as derived from the second Along-Track Scanning Radiometer (ATSR-2) on board the second European Remote Sensing Satellite (ERS-2) and the NOAA-NASA Advanced Very High Resolution Radiometer (AVHRR) Oceans Pathfinder dataset (MPFSST). Difference maps, MPFSST 2 ASST2, along with the application of a simple statistical regression model to aerosol and cloud data from the Total Ozone Mapping Spectrometer ( TOMS), are used to examine the impact of possible aerosol and cloud contamination. Differences varied regionally, but the largest biases were seen off western Africa. Nighttime and daytime differences off western Africa were reduced from -0.5degrees to -0.2degreesC and from -0.1degrees to 0degreesC, respectively. Significant cloud flagging, based on the model, occurred in the Indian Ocean, the equatorial Pacific, and in the vicinity of the Gulf Stream. Comparisons of the MPFSST and the ASST2 with in situ data from the 2002 version of the World Oceanic Database (WOD02) off western Africa show larger mean differences for the MPFSST. The smallest mean differences occurred for nighttime ASST2 - WOD02 with a value of 0.0degrees +/- 0.4degreesC.

clouds↗

Rain, Snow, Hurricanes, and Blizzards: Remote Sensing of Cloud Particles

Hurricanes, blizzards and other weather events are important to understand not only for disaster preparation, but also to track the global energy balance and to improve weather and climate forecasts. For several decades, passive radiometers and active radars on aircraft and satellites have been employed to remotely sense rain rates and the properties of liquid particles. In the past few years the relationships between frozen particles and millimeter-wave observations have become understood well enough to estimate the properties of ice in clouds. This colloquium will start with a broad background of the use of remote sensing of precipitation and then focus on recent research in the estimation of frozen cloud properties, both for ice that will eventually melt into rain and for solid precipitation falling in northern climates. The electromagnetic absorption and scattering properties of liquid rain and frozen particles will be explained. Retrieved cloud particle contents and size distributions for Hurricane Erin (2001 ) and the March 5-6, 2001 New England regional blizzard will be discussed. Future directions and challenges of this work will also be presented.

Gail Skofronick-Jackson↗

Monte Carlo Simulation of Electron Thermalization in Scintillator Materials: Implications for Scintillator Nonproportionality

The lack of reliable quantitative estimates of the length and time scales associated with hot electron thermalization after a gamma-ray induced energy cascade obscures the interplay of various microscopic processes controlling scintillator performance and hampers the search for improved detector materials. We apply a detailed microscopic kinetic Monte Carlo model of the creation and subsequent thermalization of hot electrons produced by gamma irradiation of six important scintillating crystals to determine the spatial extent of the cloud of excitations produced by gamma rays and the time required for the cloud to thermalize with the host lattice. The main ingredients of the model are ensembles of microscopic track structures produced upon gamma excitation (including the energy distribution of the excited carriers), numerical estimates of electron-phonon scattering rates, and a calculated particle dispersion to relate the speed and energy of excited carriers. All these ingredients are based on first-principles density functional theory calculations of the electronic and phonon band structures of the materials. Details of the Monte Carlo model are presented along with results for thermalization time and distance distributions. These results are discussed in light of previous work. It is found that among the studied materials, calculated thermalization distances are positively correlated with measured nonproportionality. In the important class of halide scintillators, the particle dispersion is found to be more influential than the largest phonon energy in determining the thermalization distance.

Phonons, radiation detection, scintillators, thema↗

Lagrangian Investigation of the Precipitation Efficiency of Convective Clouds

The precipitation efficiency of cumulus congestus clouds is explored with a new Lagrangian particle framework for large-eddy simulations. The framework is created to track particles representative of individual water molecules. A Monte Carlo approach facilitates the transition of particles between the different water classes (e.g., vapor, rain, or graupel). With this framework, it is possible to reconstruct the pathways of water as it moves from vapor at a specific altitude to rain at the surface. By tracking water molecules through both physical and microphysical space, the precipitation efficiency can be studied in detail as a function of height. Large-eddy simulations of individual cumulus congestus clouds show that the clouds convert entrained vapor to surface precipitation with an efficiency of around 10%. About two-thirds of all vapor that enters the cloud does so by entrainment in the free troposphere, but free-tropospheric vapor accounts for only one-third to one-half of the surface rainfall, with the remaining surface rainfall originating as vapor entrained through the cloud base. The smaller efficiency with which that laterally entrained water is converted into surface precipitation results from the smaller efficiencies with which it condenses, forms precipitating hydrometeors, and reaches the surface.

54 ENVIRONMENTAL SCIENCES↗

The role of major gas-rich mergers on the evolution of galaxies from the blue cloud to the red sequence

With the aim of exploring the fast evolutionary path from the blue cloud of star-forming galaxies to the red sequence of quiescent galaxies in the local universe, we select a local advanced merging infrared luminous and ultraluminous galaxy (adv-merger (U)LIRGs) sample and perform careful dust extinction corrections to investigate their positions in the star formation rate–M {sub *}, u − r, and NUV − r color–mass diagrams. The sample consists of 89 (U)LIRGs at the late merger stage, obtained from cross-correlating the Infrared Astronomical Satellite Point Source Catalog Redshift Survey and 1 Jy ULIRGs samples with the Sloan Digital Sky Survey DR7 database. Our results show that 74%±5% of adv-merger (U)LIRGs are localized above the 1σ line of the local star-forming galaxy main sequence. We also find that all adv-merger (U)LIRGs are more massive than and as blue as the blue cloud galaxies after corrections for Galactic and internal dust extinctions, with 95%±2% and 81%±4% of them outside the blue cloud on the u − r and NUV − r color–mass diagrams, respectively. These results, combined with the short timescale for exhausting the molecular gas reservoir in adv-merger (U)LIRGs (3×10{sup 7} to 3×10{sup 8} years), imply that the adv-merger (U)LIRGs are likely at the starting point of the fast evolutionary track previously proposed by several groups. While the number density of adv-merger (U)LIRGs is only ∼0.1% of the blue cloud star-forming galaxies in the local universe, this evolutionary track may play a more important role at high redshift.

79 ASTRONOMY AND ASTROPHYSICS↗

Observation of Deep Convective Cloud-Top Height and Vertical Temperature Structure of Hurricane Using Hyperspectral Infrared Sounder and its Single-Field-View Retrieval Products

Hurricanes, severe tropical cyclones (TC), or typhoons are significant natural disasters that often result in substantial loss of life and property damage. Numerous studies have indicated that changes in TC intensity are closely linked to deep convective clouds (DCC), with stronger TCs typically exhibiting higher cloud top heights (CTH) compared to weaker TCs. The CTH can help determine if a tropical depression is at the onset of rapid intensification based on case studies. Therefore, accurate determination of TC CTH will be greatly helpful for monitoring TC development and studying TC dynamics. One traditional and most common method to derive CHT from satellite observations is using the thermal brightness temperature in atmospheric channels to match the sounding temperature profile. However, it was found that thermally derived CTH has a lower bias of approximately 1 km, and this bias tends to worsen for the tallest clouds. A new method using the hyperspectral infrared sounder will be presented. From the measurements of Cross-track Infrared Sounder (CrIS) on S-NPP and J-1, along with radiative transfer simulations, we identified the inverted-V spectral feature in the ozone (O3) band (near 9.6 μm) corresponding to high clouds. The depth of the inverted-V can be used to estimate the CTH. Since the depth is computed using the peak absorption O3 channel and the nearby most transparent O3 channel in this O3 band, the uncertainties associated with cloud emissivity and scattering by cloud particles in the traditional method can be ignored. From several hurricane case studies, we found that the CHT derived using this method can accurately capture the structure of the cloud tops in the eyewall, spiral rainbands, and surrounding regions. For example, Hurricane Dorian on September 2, 2019, showed a nicely outward-sloping and circular shape eye cloud in the early morning, but the circular shape of the eyewall cloud became distorted in the afternoon. For various hurricanes we examined, the distribution of CHT for the eyewall clouds differed significantly. To better study the thermodynamic structure of hurricane clouds, this research will analyze the vertical temperature profiles from a new single Field of View (SFOV) Sounder Atmospheric Products (SiFSAP), derived using CrIS and the Advanced Technology Microwave Sounder (ATMS) onboard SNPP and JPSS-1. SiFSAP has a spatial resolution of 15 km at nadir, which surpasses most global weather and climate models and other current operational sounding products. The combined use of ATMS and CrIS allows for retrievals near hurricane eyewalls and spiral rainbands. Wind fields from NASA’s Modern-Era Retrospective Analysis for Research and Applications Version-2 (MERRA-2) and ERA5 will be used to characterize transport, and comparisons between the model temperature and water vapor profiles with the corresponding SiFSAP products will also be provided.

SiFSAP↗

Above-Cloud Aerosol Radiative Effects based on ORACLES 2016 and ORACLES 2017 Aircraft Experiments

Determining the direct aerosol radiative effect (DARE) of absorbing aerosols above clouds from satellite observations alone is a challenging task, in part because the radiative signal of the aerosol layer is not easily untangled from that of the clouds below. In this study, we use aircraft measurements from the NASA ObseRvations of CLouds above Aerosols and their intEractionS (ORACLES) project in the southeastern Atlantic to derive it with as few assumptions as possible. This is accomplished by using spectral irradiance measurements (Solar Spectral Flux Radiometer, SSFR) and aerosol optical depth (AOD) retrievals (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research, 4STAR) during vertical profiles (spirals) that minimize the albedo variability of the underlying cloud field – thus isolating aerosol radiative effects from those of the cloud field below. For two representative cases, we retrieve spectral aerosol single scattering albedo (SSA) and the asymmetry parameter (g) from these profile measurements and calculate DARE given the albedo range measured by SSFR on horizontal legs above clouds. For mid-visible wavelengths, we find SSA values from 0.80 to 0.85 and a significant spectral dependence of g. As the cloud albedo increases, the aerosol increasingly warms the column. The transition from a cooling to a warming top-of-aerosol radiative effect occurs at an albedo value (critical albedo) just above 0.2 in the mid-visible wavelength range. In a companion paper, we use the techniques introduced here to generalize our findings to all 2016 and 2017 measurements and parameterize aerosol radiative effects.

Cloud aerosol↗

Passive Remote Sensing of Cloud Ice Particles

Hurricanes, blizzards and other weather events are important to understand not only for disaster preparation, but also to track the global energy balance and to improve weather and climate forecasts. For several decades, passive radiometers and active radars on aircraft and satellites have been employed to remotely sense rain rates and the properties of liquid particles. In the past few years the relationships between frozen particles and millimeter-wave observations have become understood well enough to estimate the properties of ice in clouds. A brief background of passive remote sensing of precipitation will be presented followed by a focused discussion of recent research at NASA Goddard Space Flight Center estimating the properties of frozen particles in clouds. The retrievals are for (1) ice that will eventually melt into rain, (2) for solid precipitation falling in northern climates, and (3) cirrus ice clouds. The electromagnetic absorption and scattering properties and differences of liquid rain versus frozen particles will be summarized for frequencies from 6 to 340+ GHz. Challenges of this work including surface emissivity variability, non-linear and under-constrained relationships, and frozen particle unknowns will be discussed. Retrieved cloud particle contents and size distributions for ice above the melting layer in hurricanes, retrieved snowfall rates for a blizzard, and cirrus ice estimates will be presented. Future directions of this work will also be described.

Skofronick-Jackson, Gail↗

Characterizing Greater Houston's Aerosol by Air Mass During TRACER

During the TRacking Aerosol and Convection interaction ExpeRiment (TRACER), a suite of aerosol and cloud measurements were made using the Texas A&M Rapid Onsite Atmospheric Measurement Van (ROAM-V) mobile instrument platform. Joint ROAM-V/radiosonde deployments focused on sampling polluted marine and continental air masses to understand summertime convection along and across the sea-breeze front as it propagated through Houston. The polluted marine air mass at Seawolf Park, Galveston, TX was defined by two characteristic aerosol populations. Although the background total particle concentrations averaged 2,500 cm −3 , the air mass was also influenced by frequent but irregular periods of ship emission with significantly higher aerosol concentrations at times exceeding 34,000 cm −3 . Ship emission influenced periods, typically lasting <10 min, contained smaller, less hygroscopic particles resulting in a 69% relative decline in cloud condensation nuclei (CCN) activated fraction at 1% supersaturation compared to background periods. Measurements in continental air masses northwest of Houston revealed an average aerosol concentration of 5,208 cm −3 with a κ value near 0.1 reasonably describing the CCN population, independent of particle size. In continental air masses, substantial differences in particle size and CCN activation over small distances (<42 miles between sites) suggest considerable site-to-site variability in addition to the expected day-to-day differences. This small-scale variability makes it difficult to generalize continental air mass aerosol properties. Both coastal and inland locations had effective ice nucleating particles, but inland deployments observed the warmest nucleation temperature at −15.6°C compared to −17.8°C close to the coast. These measurements can reduce uncertainties in regional convection allowing models to improve understanding of aerosol-cloud interactions.

54 ENVIRONMENTAL SCIENCES↗

Weather support for the Earth Resources Technology Satellite

The operational plans for ERTS include cloud-cover forecasting as a means of preventing the limited lifetime of the spacecraft's tape recorder to be used up on useless imagery. Each day, a forecast of the cloud cover is prepared for all land areas beneath the satellite's track and some adjacent ocean areas for each of the next day's 14 passes. The forecasts are transmitted by facsimile to the ERTS Operations Control Center at 4:00 p.m. each day, where they are used to plan the next day's operations. The forecasting techniques employed are described.

Moore, W. P.↗

Chemical Observations of a Polar Vortex Intrusion

An intrusion of vortex edge air in D the interior of the Arctic polar vortex was observed on the January 31,2005 flight of the NASA DC-8 aircraft. This intrusion was identified as anomalously high values of ozone by the AROTAL and DIAL lidars. Our analysis shows that this intrusion formed when a blocking feature near Iceland collapsed, allowing edge air to sweep into the vortex interior. along the DC-8 flight track also shows the intrusion in both ozone and HNO3. Polar Stratospheric Clouds (PSCs) were observed by the DIAL lidar on the DC-8. The spatial variability of the PSCs can be explained using MLS HNO3 and H2O observations and meteorological analysis temperatures. We also estimate vortex denitrification using the relationship between N2O and HNO3. Reverse domain fill back trajectory calculations are used to focus on the features in the MLS data. The trajectory results improve the agreement between lidar measured ozone and MLS ozone and also improve the agreement between the HNO3 measurements PSC locations. The back trajectory calculations allow us to compute the local denitrification rate and reduction of HCl within the filament. We estimate a denitrification rate of about lO%/day after exposure to below PSC formation temperature. Analysis of Aura MLS observations made

Schoeberl, M. R.↗

Convective Transport to the Upper Troposphere and Lower Stratosphere Over the Asian Summer Monsoon as Observed During the 2022 ACCLIP Airborne Campaign

Deep convection in the Asian summer monsoon (ASM) rapidly transports boundary layer pollutants including ozone-depleting substances into the upper troposphere and lower stratosphere (UTLS). The confinement of the seasonal anticyclonic circulation in the UTLS over Asia initially traps the pollutants near the tropopause level, but air masses are subsequently transported throughout the global stratosphere and impact Earth’s climate. Characterizing the transport pathways and processes of these pollutants are critical for identifying source regions and quantifying regional contributions to global stratospheric concentrations. The Asian summer monsoon Chemical and Climate Impact Project (ACCLIP) was conducted in summer 2022 using two high-altitude aircraft (NSF NCAR Gulfstream V and the NASA WB-57) to obtain UTLS chemical composition and aerosol distribution for characterizing the impact of the ASM on global chemistry and climate. Backward trajectories from ACCLIP flight tracks were traced through time-varying, satellite-derived global convective cloud top altitude fields to investigate the convective air mass origins of the sampled air parcels. Analyses reveal that air masses lofted by convection within the ASM (South Asian summer monsoon) and near the edge of the of the ASM anticyclone (East Asian summer monsoon) contributed to the airborne observations. In this study, we present a summary of the transport statistics of UTLS air masses sampled during ACCLIP and discuss the implications of these results on our understanding of the role of ASM in global constituent transport.

Convective↗

Raman Lidar Measurements of Water Vapor and Cirrus Clouds During the Passage of Hurricane Bonnie

The NASA/GSFC Scanning Raman Lidar (SRL) was stationed on Andros Island in the Bahamas during August - September, 1998 as a part of the third Convection and Moisture Experiment (CAMEX-3) which focussed on hurricane development and tracking. During the period August 21 - 24, hurricane Bonnie passed near Andros Island and influenced the water vapor and cirrus cloud measurements acquired by the SRL. Two drying signatures related to the hurricane were recorded by the SRL (Scanning Raman Lidar) and other sensors. Cirrus cloud optical depths (at 351 nm) were also measured during this period. Optical depth values ranged from approximately 0.01 to 1.4. The influence of multiple scattering on these optical depth measurements was studied with the conclusion that the measured values of optical depth are less than the actual value by up to 20% . The UV/IR cirrus cloud optical depth ratio was estimated based on a comparison of lidar and GOES measurements. Simple radiative transfer model calculations compared with GOES satellite brightness temperatures indicate that satellite radiances are significantly affected by the presence of cirrus clouds if IR optical depths are approximately 0.02 or greater. This has implications for satellite cirrus detection requirements.

Whiteman, D. N.↗

Raman Lidar Measurements of Water Vapor and Cirrus Clouds During the Passage of Hurricane Bonnie

The NASA/GSFC Scanning Raman Lidar (SRL) was stationed on Andros Island in the Bahamas during August - September, 1998 as a part of the third Convection and Moisture Experiment (CAMEX-3) which focussed on hurricane development and tracking. During the period August 21 - 24, hurricane Bonnie passed near Andros Island and influenced the water vapor and cirrus cloud measurements acquired by the SRL. Two drying signatures related to the hurricane were recorded by the SRL and other sensors. Cirrus cloud optical depths (at 351 nm) were also measured during this period. Optical depth values ranged from approximately 0.01 to 1.4. The influence of multiple scattering on these optical depth measurements was studied with the conclusion that the measured values of optical depth are less than the actual value by up to 20%. The UV/lR cirrus cloud optical depth ratio was estimated based on a comparison of lidar and GOES measurements. Simple radiative transfer model calculations compared with GOES satellite brightness temperatures indicate that satellite radiances are significantly affected by the presence of cirrus clouds if IR optical depths are approximately 0.02 or greater. This has implications for satellite cirrus detection requirements.

Whiteman, D. N.↗