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At least 433 records · Page 24

Analysis of scanner data for crop inventories

Progress and technical issues are reported in the development of corn/soybeans area estimation procedures for use on data from South America, with particular emphasis on Argentina. Aspects related to the supporting research section of the AgRISTARS Project discussed include: (1) multisegment corn/soybean estimation; (2) through the season separability of corn and soybeans within the U.S. corn belt; (3) TTS estimation; (4) insights derived from the baseline corn and soybean procedure; (5) small fields research; and (6) simulating the spectral appearance of wheat as a function of its growth and development. To assist the foreign commodity production forecasting, the performance of the baseline corn/soybean procedure was analyzed and the procedure modified. Fundamental limitations were found in the existing guidelines for discriminating these two crops. The temporal and spectral characteristics of corn and soybeans must be determined because other crops grow with them in Argentina. The state of software technology is assessed and the use of profile techniques for estimation is considered.

Horvath, R.↗

Cultural and environmental effects on crop spectral development patterns as viewed by Landsat

The typical patterns of spectral development (profiles) for corn and soybeans are presented, based on field-collected reflectance data transformed to correspond to Landsat-MSS Tasseled Cap coordinates. Reasonable variations in field conditions and cultural practices are shown to significantly influence profile features. The separability of the two crops is determined to be primarily related to the maximum value of the reflectance equivalent of Greenness, and to the plateau effect seen in corn Greenness profiles. The impact of changes in conditions on separability is described. In addition, association is made between profile features and stages of development for corn and soybeans. Corn is shown to peak at a stage well before tasseling or maximum LAI, while the characteristics of the soybean profile are shown to be unrelated to any particular stage of development.

Crist, E. P.↗

Temporal observations of surface soil moisture using a passive microwave sensor

A series of 10 aircraft flights was conducted over agricultural fields to evaluate relationships between observed surface soil moisture and soil moisture predicted using passive microwave sensor observations. An a priori approach was used to predict values of surface soil moisture for three types of fields: tilled corn, no-till corn with soybean stubble, and idle fields with corn stubble. Acceptable predictions were obtained for the tilled corn fields, while poor results were obtained for the others. The source of error is suspected to be the density and orientation of the surface stubble layer; however, further research is needed to verify this explanation. Temporal comparisons between observed, microwave predicted, and soil water-simulated moisture values showed similar patterns for tilled well-drained fields. Divergences between the observed and simulated measurements were apparent on poorly drained fields. This result may be of value in locating and mapping hydrologic contributing areas.

Jackson, T. J.↗

The Dark Annulus of a Drop in a Hele-Shaw Cell Is Caused by the Refraction of Light through Its Meniscus

Knowing the meniscus shape of confined drops is important for understanding how they make first contact and then coalesce. When imaged from the top view by brightfield microscopy, a liquid drop (e.g., corn syrup) confined in a Hele-Shaw cell, surrounded by immiscible liquid (e.g., mineral oil), had a dark annulus, and the width of the annulus decreased with increasing concentration of corn syrup. Since the difference in the annulus width was presumed to be related to the meniscus shape of the drops, three-dimensional images of the drops with different concentrations were obtained using confocal fluorescence microscopy, and their cross-sectional meniscus profile was determined by image processing. The meniscus of the drops remained circular despite varying concentration. Since the refractive index of corn syrup increased with concentration, while the surface tension coefficient between corn syrup and mineral oil remained unchanged, the observed change in the annulus width was then attributed to the refraction of light passing through the drop’s meniscus. As such, a ray optics model was developed, which predicted that the annulus width of the drop would decrease as the refractive index of the drop approached that of the surrounding liquid. Therefore, the dark annulus of the drops in the Hele-Shaw cell was caused by the refraction of light passing through the circular meniscus of the drop.

Sangjin Ryu↗

The effect of ferrous sulfate pretreatment on the optimal temperature for production of sugars during autothermal pyrolysis

Fast pyrolysis is a promising technology for producing cellulosic sugars from lignocellulosic biomass. Success in this endeavor requires measures that prevent naturally occurring alkali and alkaline earth metals (AAEM) from breaking pyranose and furanose rings in lignocellulosic biomass. This is especially critical for high ash feedstocks like corn stover and other kinds of herbaceous biomass. Pretreating corn stover with ferrous sulfate converts AAEM into thermally stable salts, which passivates the catalytic activity of these metals and dramatically improves sugar yields. AAEM passivation in combination with autothermal (partial oxidative) operation improves the prospects for intensifying the production of sugars via fast pyrolysis. We hypothesized that pretreated biomass pyrolyzed in the presence of oxygen can substantially influence the temperature dependence of pyrolysis kinetics. Here, we found that autothermal (air-blown) pyrolysis of ferrous sulfate pretreated corn stover achieved maximum sugar yield of 15.6 wt% (biomass basis) at 450 °C, whereas the maximum phenolic oil yield of 9.2 wt% (biomass basis) was reached at 500 °C. Considering these tradeoffs in yields of these highly desirable pyrolysis products, the ideal operating temperature is between 450 and 500 °C. These results suggest that two-stage pyrolysis might allow maximum recovery of both sugars and phenolic oil.

09 BIOMASS FUELS↗

Higher than expected N 2 O emissions from soybean crops in the Pampas Region of Argentina: Estimates from DayCent simulations and field measurements

In developing countries, agriculture generally represents a large fraction of GHG emissions reported in National Inventories, and emissions are typically estimated using Tier 1 IPCC guidelines. However, field data and locally adapted simulation models can improve the accuracy of IPCC estimations. In this report we aimed to quantify anthropogenic N2O emissions from croplands of Argentina through field measurements, model simulations and IPCC guidelines. Here we measured N 2 O emissions and their controlling factors in 62 plots of the Pampas Region with corn, soybean and wheat/soybean crops and in unmanaged grasslands. We accounted for gross emissions from crops and background emissions from unmanaged grasslands to calculate net anthropogenic emissions from crops as the difference between them. We calibrated and evaluated the DayCent model and then simulated different weather and management scenarios. Finally, we applied IPCC guidelines to estimate anthropogenic N 2 O emissions at the same plots. The DayCent model accurately simulated annual N 2 O emission for all crops as compared to measured data (RMSE = 1.4 g N ha -1 day -1 ). Measured and simulated emissions in soybean crops were higher than in corn and wheat/soybean crops. Gross N 2 O emissions ranged from 1.4 to 5.1 kg N ha -1 yr -1 for current environmental (soil and weather) and management (crops and fertilizer doses) conditions. Background emissions ranged between 1.1 and 1.3 kg N ha -1 yr -1 , and therefore net anthropogenic emissions ranged from 0.3 to 4.0 kg N ha-1 yr -1 . IPCC Tier 1 emission factors underestimated N2O releases from soybean, that were on average 4.87 times greater when estimated with DayCent and observations (0.53 vs 2.47 and 2.69 kg N ha -1 yr -1 , respectively). On the contrary, IPCC estimates for corn and wheat/soybean crops were similar to modeled and measured values. Our results suggest that N 2 O emissions from the vast 15 million ha of soybean croplands in the Pampas Region may be substantially underestimated.

59 BASIC BIOLOGICAL SCIENCES↗

Biochemical Conversion of Herbaceous Biomass to Renewable Diesel: Biorefinery Marginal Air Quality Impacts and Comparison to Feedstock Production

This study assesses the air quality impacts of an advanced biorefinery that produces renewable diesel blendstock (RDB) from lignocellulosic biomass via aerobic respiration (Davis et al. 2022) by estimating fine particulate matter (PM2.5) impacts from biorefinery emissions. It continues a prior analysis that used a geospatial assessment to identify source regions for biomass feedstocks and studied the impact of feedstock production emissions on air quality (Thind et al. 2022). Thind et al. (2022) identified RDB biorefineries that can use corn stover feedstocks of 2,000; 5,200; and 9,100 dry metric tons per day (DMT/day), based in Iowa, and suggested 7 unique counties can serve as hosts for a biorefinery that draws biomass feedstock from neighboring counties. Given 13 unique county-biorefinery size combinations and two waste lignin end uses at the biorefinery (lignin as a fuel for electricity generation and lignin for pellet production), the air-quality-related sustainability aspects of each of these 26 scenarios are assessed by estimating the annual average impacts of biorefinery emissions on the dispersion and formation of secondary PM2.5 in the atmosphere using a novel reduced-complexity air quality model called the Intervention Model for Air Pollution (InMAP). The 26 biorefinery design combinations help capture how a biorefinery's emissions of air pollutants and their resulting impact on local and regional air quality are influenced by the magnitude of production scale, lignin utilization strategy, and location of a proposed biorefinery. Methods developed in Thind et al. (2022) are applied to estimate the constraints on primary PM2.5 and secondary PM2.5 precursor emissions based on compliance with U.S. Environmental Protection Agency's (EPA's) annual primary National Ambient Air Quality Standard (NAAQS) of PM2.5 (i.e.12.0 micrograms per cubic meter (microgram/m3)) at downwind receptors of a biorefinery. Incremental PM2.5 concentrations caused by the emission of biorefining corn stover into RDB are assessed and compared to those of corn stover production. To illuminate which upstream supply chain stage of renewable diesel production contributes most to air quality impacts, marginal PM2.5 concentrations are compared between both stages at multiple downwind air quality monitor locations. In addition, through a hotspot analysis, we identify the primary contributing factors of emissions within the feedstock production and biorefinery stage operations. In doing so, we provide insights for improving the air pollutant emission-related sustainability of advanced lignocellulosic biofuel production.

09 BIOMASS FUELS↗

Designing Iowa Agricultural Landscapes to Improve Environmental Co-Benefits of Bioenergy Production

Cellulosic bioenergy feedstocks are needed to improve carbon (C) management while provisioning biomass for bioproducts and biofuel. The transition to increased cellulosic biomass production can be guided by land management plans designed to improve economic, environmental, and ecological performance. We constructed a sustainability model to compare landscape designs for biofuel production from corn (Zea mays L.) stover and switchgrass (Panicum virgatum L.) in central Iowa, USA. We used the model to compare environmental and socioeconomic outcomes associated with four landscape management strategies, with and without cellulosic biomass markets. We evaluated (1) a fuelshed area containing over 1.2 million ha (3 million acres) of corn and soybean (Glycine max (L.) Merr.) within 80 km (50 miles) of a commercial-scale cellulosic biorefinery in Nevada, Iowa, and (2) the South Fork watershed containing over 72,000 ha (178,000 acres) of these row crops within eight north central Iowa HUC-12 (hydrologic unit code) watersheds. At both landscape scales, we found that it is possible to achieve multiple environmental and socioeconomic benefits concomitantly with cellulosic biomass production by strategically collecting corn stover and converting the 10% of the lowest-profitability row crop land to perennial switchgrass. Potential benefits from landscape design include increased biodiversity, soil and water quality improvements, increased soil carbon sequestration for climate change mitigation, and reduced fertilizer use and cost. Our model results showed that increasing benefits can accrue when complementary conservation practices (e.g., reduced tillage, use of a rye cover crop) are combined and integrated throughout a fuelshed or watershed area. We conclude that ecologically based landscape designs offer valuable insights about costs and benefits of land management alternatives, with relevance for achieving stakeholder goals.

54 ENVIRONMENTAL SCIENCES↗

Carbon‐negative hydrogen from ethanol via catalytic oxidative reforming

Abstract This study evaluated a commercial technology for producing low‐ or negative‐carbon hydrogen through ethanol catalytic oxidative reforming, focusing on the life cycle greenhouse gas emissions, or carbon intensity (CI). Various scenarios were analyzed: (a) comparing corn ethanol (first‐generation or Gen1 ethanol) and cellulosic ethanol (second‐generation or Gen2 ethanol) as feedstocks; (b) assessing carbon capture and sequestration (CCS) for CO 2 from upstream fermentation; and (c) evaluating oxygen sourcing via air separation units vs. on‐site or off‐site water electrolysis using a proton exchange membrane. Findings indicate that the CI for hydrogen production using Gen2 ethanol from corn stover is lower than that of Gen1 corn ethanol. Additionally, using proton exchange membrane‐generated oxygen results in a lower CI than air separation unit‐generated oxygen, regardless of the sourcing method. Implementing CCS for the hydrogen production plant's evolved CO 2 is essential for achieving a net‐negative CI for hydrogen from Gen1 ethanol. All examined scenarios, including both ethanol generations, oxygen sources, and CCS applications, demonstrated a net‐negative carbon intensity, surpassing the life cycle greenhouse gas emissions threshold of 0.45 kg CO 2 e/kg to enable policy credits as outlined in the Inflation Reduction Act §45V. In comparison, the CI for hydrogen from steam methane reforming stands at 3.4 kg CO 2 e/kg with CCS and 9.4 kg CO 2 e/kg without CCS.

08 HYDROGEN↗

Dredged sediments contain potentially beneficial microorganisms for agriculture and little harmful cyanobacteria

Soils worldwide are degrading, raising concerns about our ability to feed the growing global population. Soil amendments that can alleviate degradation are gaining attention. The application of sediments dredged from waterways to agricultural fields has increasing promise as a means for improving degraded soils. However, herbaceous plant species may have difficulty establishing on dredged material because of low nutrient availability, inhibitory levels of toxins, unsuitable moisture conditions and lack of microorganisms capable of ameliorating these characteristics. To counteract these issues, we sought to understand if the use of a cover crop would increase the abundance, diversity and function of beneficial soil microorganisms compared to harmful microorganisms in dredged sediments. We collected soil samples from two 100% dredged sediment plots, one where winter cereal rye (Secale cereal) was grown as a winter cover crop and one left fallow over the winter, followed by traditional corn (Zea mays) planting. We sampled both plots three times during the growing season: before cover crop application, following cover crop application but before corn planting and following final corn harvest. We then used high-throughput sequencing to identify the bacterial and fungal communities present in the samples. Our data show that cover crop application did not alter the microbial community in these plots. However, sampling time decreased species diversity and altered the composition of both fungal and bacterial communities recovered from these plots. Across both plots, microorganisms associated with carbon cycling were more abundant than those associated with harmful effects, including microcystin-producing cyanobacteria, which were an extremely small portion of the overall community. Our work suggests that dredged sediments have the potential to improve soil function through the addition of microorganisms associated with nutrient cycling, but a cover crop is not necessary to incur these benefits.

54 ENVIRONMENTAL SCIENCES↗

Extracellular DNA Alters Detection of Subtle Bacterial Responses to Soil Rewetting

Microbial communities are often characterized using DNA-based sequencing, but these approaches also capture extracellular DNA (exDNA) released from dead cells, potentially altering inference about microbial responses to environmental change. This may be especially important during pulse disturbances, such as soil drying–rewetting, which can increase microbial mortality and transient necromass pools. We assessed whether exDNA altered inference about bacterial responses to drying–rewetting (an 80 mm simulated rainfall event following a 28-day drought) in conventionally tilled corn and perennial switchgrass soils. We quantified bacterial abundance (16 S rRNA gene copies), alpha diversity, and community composition in paired soil samples with exDNA included (+ exDNA) and in samples treated with propidium monoazide (PMAxx) to reduce amplification of exDNA (− exDNA). At our level of replication (n = 4), PMAxx treatment did not significantly alter overall temporal response patterns (i.e., no significant main effect of DNA treatment or DNA × time interaction). However, PMAxx treatment increased sensitivity to detect some pairwise temporal changes in bacterial abundance and community composition in corn soils following rewetting. exDNA pools were proportionally highest immediately after rewetting in corn soils, suggesting transient extracellular DNA may contribute to masking during disturbance recovery. In contrast, PMAxx treatment had comparatively small effects in switchgrass soils, which exhibited weaker temporal responses overall. Inclusion of exDNA also changed which taxa appeared most responsive to rewetting. Together, our results suggest that exDNA does not uniformly bias soil microbial inference, but may reduce detectability of subtle disturbance-driven shifts in certain soils. Future studies should advance knowledge of microbial turnover and necromass dynamics, particularly using multiple complementary methods, to help predict when exDNA is most likely to influence ecological inference.

drying-rewetting↗

Cultivating clarity: understanding the impact of land cost assumptions on biofuel viability

The transition to sustainable energy has increased interest in biofuel production to reduce greenhouse gas emissions, decrease reliance on imported oil, and ensure energy resilience. Here, this study examines the often-overlooked impact of land cost assumptions on the economic viability of biofuel production. Using a discounted cash flow techno-economic framework, we evaluated three land cost scenarios—no land costs, land rental costs, and land purchase costs—across six bioenergy feedstocks (corn, soybeans, switchgrass, miscanthus, poplar, and microalgae) and three biofuel products (corn ethanol, soybean biodiesel, and sustainable aviation fuel) at the county level for the contiguous United States. The analysis reveals substantial variation in minimum fuel selling prices due to these scenarios. High-yield crops like algae showed low sensitivity to land costs, while low-yield crops such as soybeans were highly sensitive. Geographical differences were significant, with minimum fuel selling price increases most pronounced in high-value land regions like the Corn Belt. Case studies further illustrate the influence of local productivity and land costs on economic outcomes across the United States. These findings emphasize the importance of maintaining consistent land cost assumptions in biofuel economic assessments. By quantifying the interplay between land value, crop productivity, and economic feasibility, this study provides essential insights for policymakers and stakeholders to advance sustainable energy solutions.

09 BIOMASS FUELS↗

An Unmanned Aerial System (UAS) for concurrent measurements of solar-induced chlorophyll fluorescence and hyperspectral reflectance toward improving crop monitoring

Unmanned aerial system (UAS)-based remote sensing can provide high spatial- and temporal-resolution crop monitoring for precision management. Existing crop monitoring UAS primarily use conventional techniques such as multi-spectral broadband vegetation indices (VIs) to track canopy structure/biomass. Recently developed lightweight hyperspectral sensors can track crop physiology and performance via complementary signals such as solar-induced chlorophyll fluorescence (SIF) and photochemical reflectance index (PRI) that can be derived from hyperspectral reflectance. However, few existing UAS can acquire high-quality SIF and hyperspectral reflectance. Here, we designed a novel UAS that simultaneously captures far-red SIF and hyperspectral reflectance, using a single bifurcated fiber and motorized arm to measure downwelling and upwelling irradiance. The UAS was tested over (1) a heterogeneous corn field with spatially varying crop yield potential and (2) a set of soybean and corn plots under differing nutrient treatments. Our UAS can maintain stability under low-to-moderate winds (2–3 m/s) with <0.4 m geolocation accuracy, <0.1 m altitude drift, and <1.5° error of the fiber optic from nadir position during scanning. Weekly seasonal campaigns reveal that SIF outperforms conventional VIs such as the normalized difference vegetation index (NDVI) for distinguishing plots with different crop yield potential, especially after canopy closure when NDVI tends to saturate. The UAS can capture the diurnal dynamics of SIF and PRI for both corn and soybean. At the seasonal scale, SIF acquired from the UAS correlates well with that from a fixed SIF tower system ( R 2 = 0.81), which measured the same target albeit with different footprints, demonstrating the capability of UAS in characterizing the seasonal progression of crop activity. In conclusion, our newly developed UAS provides high-quality SIF and hyperspectral reflectance, facilitating mechanistic understanding of the physiological control on photosynthesis dynamics. Our findings also imply that this UAS could enable extension of fixed tower-based systems to monitor multiple targets from diurnal to seasonal scales and improve monitoring of heterogeneous fields.

59 BASIC BIOLOGICAL SCIENCES↗

Can upscaling ground nadir SIF to eddy covariance footprint improve the relationship between SIF and GPP in croplands?

Ground solar-induced chlorophyll fluorescence (SIF) is important for the mechanistic understanding of the dynamics of vegetation gross primary production (GPP) at fine spatiotemporal scales. However, eddy covariance (EC) observations generally cover larger footprint areas than ground SIF observations (a bare fiber with nadir), and this footprint mismatch between nadir SIF and GPP could complicate the canopy SIF-GPP relationships. Here, we upscaled nadir SIF observations to EC footprint and investigated the change in SIF-GPP relationships after the upscaling in cropland. We included 13 site-years data in our study, with seven site-years corn, four site-years soybeans, and two site-years miscanthus, all located in the US Corn Belt. All sites’ crop nadir SIF observations collected from the automated FluoSpec2 system (a hemispheric-nadir system) were upscaled to the GPP footprint-based SIF using vegetation indices (VIs) calculated from high spatiotemporal satellite reflectance data. We found that SIF-GPP relationships were not substantially changed after upscaling nadir SIF to GPP footprint at our crop sites planted with corn, soybean, and miscanthus, with R 2 change after the upscaling ranging from -0.007 to 0.051 and root mean square error (RMSE) difference from -0.658 to 0.095 umol m –2 s –1 relative to original nadir SIF-GPP relationships across all the site-years. The variation of the SIF-GPP relationship within each species across different site-years was similar between the original nadir SIF and upscaled SIF. Different VIs, EC footprint models, and satellite data led to marginal differences in the SIF-GPP relationships when upscaling nadir SIF to EC footprint. Furthermore, our study provided a methodological framework to correct this spatial mismatch between ground nadir SIF and GPP observations for croplands and potentially for other ecosystems. Our results also demonstrated that the spatial mismatch between ground nadir SIF and GPP might not significantly affect the SIF-GPP relationship in cropland that are largely homogeneous.

54 ENVIRONMENTAL SCIENCES↗

Evapotranspiration of advanced perennial bioenergy grasses produced on marginal land in the U.S. Midwest

The production of dedicated energy crops for biofuel and co-products can help develop a sustainable and viable bioeconomy under a changing climate. The co-production of perennial bioenergy and commodity crops in an agricultural landscape has the potential to reduce greenhouse gas emissions and provide numerous ecosystem services. However, as production of advanced, higher-yielding cultivars occurs, their impact on water resources needs to be considered. Estimates of evapotranspiration (ET) of perennial grasses compared to commodity crops are not always consistent in the literature. In this study, ET was estimated using an energy-balance model with Landsat satellite imagery and ground-based weather data to compare the large-scale production of advanced switchgrass cultivars (‘Independence’, ‘Liberty’, and ‘Carthage’), predecessor cultivars (‘Shawnee’ and ‘Sunburst’), and other perennial grasses (big bluestem and a low-diversity mixture) to corn grown continuously on marginal soils in the U.S. Midwest. Results showed significant differences in ET between corn and perennial grass treatments at four of the five field sites. However, differences between crop treatments were not consistent across sites, nor were the differences between advanced and predecessor switchgrass varieties. Production year played a large role in daily and cumulative ET across all sites. Differences in crop biomass yield between establishment and post-establishment years may contribute to these interannual differences. Site and interannual variations in precipitation and temperature may also be major contributing factors. Overall, the results of this study indicate that differences in ET between perennial bioenergy grasses and corn are likely dependent upon location of production and weather conditions.

09 BIOMASS FUELS↗

Coupling localized Noah-MP-Crop model with the WRF model improved dynamic crop growth simulation across Northeast China

Croplands play a critical role in regulating the energy and moisture exchanges between the land surface and atmosphere. However, the interactions between cropland and climate are usually poorly represented due to a lack of detailed representation in crop types and field management. Here, we coupled the Noah-MP-Crop model with the state-of-the-art Weather Research and Forecasting (WRF) model to explore and evaluate the crop growth dynamics in response to climate variations across Northeast China. The default parameters of the crop model were not exactly suitable for the agricultural ecosystems in Northeast China. The detailed cropland distribution, and crop phenology parameters including growing degree days (GDD) and planting (harvesting) date were first created using multi-source remote sensing products and reanalysis data, and was then successfully used to simulate the growth and yield for corn and soybean and associated energy exchanges. We also optimized and calibrated other crop parameters using the time-series of the Moderate Resolution Imaging Spectroradiometer (MODIS) land surface products. The modified crop model substantially improved the simulation of crop growth, plant physiology, and biomass accumulation for both corn and soybean. Coupling the localized dynamic crop model into the WRF led to considerable decreases in the simulated mean-absolute-errors (MAEs) and biases of the leaf area index, evapotranspiration, and gross primary production compared with the MODIS observed values. Compared with the statistical yield from each province, the modified crop model underestimated the corn yield from 11.1% to 48.6%, whereas overestimated the soybean yield from 16.5% to 162.6%.

54 ENVIRONMENTAL SCIENCES↗

Quantifying cover crop effects on soil health and productivity

The dataset presented here supports the research paper entitled “A calculator to quantify cover crop effects on soil health and productivity”. Soil health (sometimes used synonymously with soil quality) is a concept that describes soil as a living system to sustain plants, animals, and human. Soil physical, chemical, and biological properties, along with their interactions, are required to quantify soil health. The use of cover crops in agricultural rotations may enhance soil health, yet there has been little progress in understanding how external factors such as climate, soil type, and agronomic practices affect soil and cash crop responses. In response, this dataset compiles measurements from 281 studies and provides an analysis of field-measured changes in 38 soil health indicators due to cover crop usage. Environmental and background indicators were also compiled to assess how climatic and management practices affect soil and cash crop responses to cover crops, with specific categories including climate type (tropical, arid, temperate, and continental), soil texture (coarse, medium, and fine), cover crop type (legume, grass, multi-species mixture, and other), and cash crop type (corn, soybean, wheat, vegetable, corn-soybean rotation, corn-soybean-wheat rotation, and other). An unbalanced analysis of variation was used to determine the hierarchy of most to least important factors that affected responsiveness of each soil health indicator. Based on the hierarchy structure, a soil health calculator was then developed to quantify the response of 13 parameters – erosion, runoff, weed suppression, soil aggregate stability, leaching, infiltration, microbial biomass carbon, soil bulk density, soil organic carbon, soil nitrogen, microbial biomass nitrogen, cash crop yield, and saturated hydraulic conductivity – to cover crops. The presented data in the calculator report the mean change in parameter values based on all combinations of climate, soil texture, cover crop type, and cash crop type.

54 ENVIRONMENTAL SCIENCES↗

Life Cycle Analysis of Renewable Natural Gas and Lactic Acid Production from Waste Feedstocks

Producing fuels and chemicals from waste is considered economically favorable, due to low feedstock cost, and environmentally favorable, due to avoided emissions from conventional waste management practices. In this study, we evaluate the life cycle greenhouse gas (GHG) emission reduction benefits of renewable natural gas (RNG) and lactic acid (LA) production from four types of wet waste feedstocks (wastewater sludge, food waste, swine manure, and fats, oil, and grease [FOG]) via anaerobic digestion (AD) and LA fermentation, respectively. RNG can be used as an alternative to fossil natural gas, while LA from waste feedstocks can displace conventional LA production pathways (mainly from corn via fermentation). Providing comprehensive life cycle GHG emissions of the combinations of waste feedstocks and products through different routes helps identify the GHG hotspots and show where emissions savings come from. The results show that the carbon intensities (CIs) of waste-derived RNG and LA are much lower than those of their counterparts. We estimated the life cycle GHG emissions for RNG to be between -146 and 27 g carbon dioxide equivalent (CO2e)/MJ, much lower than the CI of fossil fuels. Waste-derived LA pathways also show substantially lower CIs, ranging from -4.2 to -1.4 kgCO2e/kg LA, compared to the CIs of LA from corn and corn stover (1.2 and 0.3 kgCO2e/kg LA, respectively). We will also discuss that the low CIs of waste-derived products can come from low yields leading to high emission credits. Thus, life cycle analysis results presented per weight of treated waste can be used to support decisions about which waste feedstocks and products are to be used for sustainable waste valorization. In addition, we found that monetary emission reduction credits can play an important role in driving waste valorization.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗