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At least 433 records · Page 24

Decomposition of NO studied by infrared emission and CO laser absorption

A diagnostic technique for monitoring the concentration of NO using absorption of CO laser radiation has been developed and applied in a study of the decomposition kinetics of NO. Simultaneous measurements of infrared emission by NO at 5.3 microns were also made to validate the laser absorption technique. The data were obtained behind incident shocks in NO-N2O-Ar (or Kr) mixtures, with temperatures in the range 2400-4100 K. The rate constant for the dominant reaction of O and NO to yield N and O2 was inferred from comparisons with computer simulations of the reactive flow.

Hanson, R. K.↗

Decomposition of the photoabsorption Schumann-Runge continuum in O2

The photoabsorption Schumann-Runge continuum in O2 has been decomposed into the contribution from states of both valence and Rydberg character. The decomposition of the experimental photoabsorption (or high-energy, zero-angle, electron energy-loss) data contains contributions from three valence states, four Rydberg states, and one state of unknown character. Information on the perturbed valence-state potential-energy curves in the Franck-Condon region obtained by this analysis substantiate the recent theoretical conclusions of strong valence-Rydberg perturbations in the 8-12 eV excitation region. There is presently no unambiguous identification for the state at 8.93 plus or minus 0.04 eV, found in the optical and all the electron energy-loss data.

Cartwright, D. C.↗

NASTRAN computer resource management for the matrix decomposition modules

Detailed computer resource measurements of the NASTRAN matrix decomposition spill logic were made using a software input/output monitor. These measurements showed that, in general, job cost can be reduced by avoiding spill. The results indicated that job cost can be minimized by using dynamic memory management. A prototype memory management system is being implemented and evaluated for the CDC Cyber computer.

Bolz, C. W.↗

A two-level trajectory decomposition algorithm featuring optimal intermediate target selection

A decomposition algorithm is presented which optimizes complex missions by partitioning the trajectory into natural segments such as ascent or entry. Each segment defines a full-rank targeting subproblem. These are solved sequentially using the Newton-Raphson algorithm. The master problem, representing the complete mission, is to determine subproblem targets and master-problem controls that optimize the mission objective subject to intersegment constraints. The gradient projection algorithm solves this problem using derivatives obtained analytically from finite-difference subproblem sensitivities. Thus, the mission is optimized by coordinating the solution of tractible subproblems. Computational results for a synchronous equatorial mission are included.

Petersen, F. M.↗

Delay decomposition at a single server queue with constant service time and multiple inputs

Two network consisting of single server queues, each with a constant service time, are considered. The external inputs to each network are assumed to follow some general probability distribution. Several interesting equivalencies that exist between the two networks considered are derived. This leads to the introduction of an important concept in delay decomposition. It is shown that the waiting time experienced by a customer can be decomposed into two basic components called self-delay and interference delay.

Ziegler, C.↗

Delay decomposition at a single server queue with constant service time and multiple inputs

Two networks consisting of single server queues, each with a constant service time, are considered. The external inputs to each network are assumed to follow some general probability distribution. Several interesting equivalencies that exist between the two networks considered are derived. This leads to the introduction of an important concept in delay decomposition. It is shown that the waiting time experienced by a customer can be decomposed into two basic components called self delay and interference delay.

Ziegler, C.↗

Methanol decomposition bottoming cycle for IC engines

This paper presents the concept of methanol decomposition using engine exhaust heat, and examines its potential for use in the operation of passenger cars, diesel trucks, and diesel-electric locomotives. Energy economy improvements of 10-20% are calculated over the representative driving cycles without a net loss in power. Some reductions in exhaust emissions are also projected.

Purohit, G.↗

Cost decomposition of linear systems with application to model reduction

A means is provided to assess the value or 'cst' of each component of a large scale system, when the total cost is a quadratic function. Such a 'cost decomposition' of the system has several important uses. When the components represent physical subsystems which can fail, the 'component cost' is useful in failure mode analysis. When the components represent mathematical equations which may be truncated, the 'component cost' becomes a criterion for model truncation. In this latter event component costs provide a mechanism by which the specific control objectives dictate which components should be retained in the model reduction process. This information can be valuable in model reduction and decentralized control problems.

Skelton, R. E.↗

Thermal decomposition of a Si3N4-22 wt% Al2O3 alloy

It is pointed out that materials near the Si3N4 corner of the Si3N4-AlN-Al2O3-SiO2 quaternary, termed sialons are candidate materials for high performance applications. Hot pressed alloys in this system are useful because they possess high flexure strengths and good oxidation and creep resistance. The results of the thermal decomposition studies conducted indicate that dissociation and resulting weight loss lead to inhomogeneous specimens. Material loss comes primarily from near the surface (at least initially) thus causing differences between the composition of the surface material and the bulk. In these specimens, the O-prime phase was found to be the least stable to dissociation and the beta-prime phase the most stable. This result is in accord with the conclusions of Mitomo et al. (1979) that Si2N2O has a larger equilibrium SiO partial pressure than either the X phase or the beta-prime phase.

Ditchek, B. M.↗

Effect of particle size on the chemisorption and decomposition of carbon monoxide by palladium and nickel clusters

The chemisorption of gases on well-defined, supported metal particles is a model for basic processes in heterogeneous catalysis. In this study, the chemisorption and decomposition of carbon monoxide on palladium and nickel particles was examined as a function of particle size. Particulate films with average particle sizes ranging from 1 to 10 nm were grown by vapor deposition on UHV-cleaved mica. Successive CO adsorption-desorption cycles resulted in the accumulation of carbon on the particles, which suppressed CO adsorption. The rate of carbon accumulation was strongly dependent on particle size and was higher for Ni than for Pd over the same size range. Carbon was removed from both metals by oxygen treatments at elevated temperatures. However, a mixture of CO and O2 was effective for monitoring the removal of carbon from palladium.

Doering, D. L.↗

Quantitative separation of tetralin hydroperoxide from its decomposition products by high performance liquid chromatography

A method for the separation and analysis of tetralin hydroperoxide and its decomposition products by high pressure liquid chromatography has been developed. Elution with a single, mixed solvent from a micron-Porasil column was employed. Constant response factors (internal standard method) over large concentration ranges and reproducible retention parameters are reported.

Worstell, J. H.↗

Spectral decomposition of a matrix using the generalized sign matrix

An algorithm for spectral decomposition is presented which does not require knowledge of eigenvalues and eigenvectors. A set of eigenprojectors are defined which covers the entire spectrum of a matrix, and special attention is given to the projection on the zero eigenvalue. Some useful applications are discussed in the paper.

Denman, E. D.↗

Sound radiation from annular ducts/nozzles using modal decomposition of in-duct acoustic power

Using a refined acoustic impulse technique, an experimental program was carried out to determine the proper procedure for measuring the acoustic power for both incident and reflected sound fields for annular ducts with and without nozzles at various flow conditions. Several radial and azimuthal pressure measurements were made, and using these complex pressure data, the modal content of the pressure field was determined. A mathematical approach for the modal decomposition of annular duct acoustic power was developed. The acoustic power due to each individual mode and also their total sum were derived. The acoustic characteristics of annular duct-nozzle systems were studied at various flow conditions. The results derived from the experiments include the termination reflection coefficient, the normalized transmission coefficients, the power transfer functions and the power imbalance.

Salikuddin, M.↗

Aerospace engineering design by systematic decomposition and multilevel optimization

A method for systematic analysis and optimization of large engineering systems, by decomposition of a large task into a set of smaller subtasks that is solved concurrently is described. The subtasks may be arranged in hierarchical levels. Analyses are carried out in each subtask using inputs received from other subtasks, and are followed by optimizations carried out from the bottom up. Each optimization at the lower levels is augmented by analysis of its sensitivity to the inputs received from other subtasks to account for the couplings among the subtasks in a formal manner. The analysis and optimization operations alternate iteratively until they converge to a system design whose performance is maximized with all constraints satisfied. The method, which is still under development, is tentatively validated by test cases in structural applications and an aircraft configuration optimization.

Sobieszczanski-Sobieski, J.↗

Singular value decomposition with systolic arrays

Systolic arrays for determining the singular value decomposition of a mxn, m n, matrix A of bandwidth w are presented. After A has been reduced to bidiagonal form B by means of Givens plane rotations, the singular values of B are computed by the Golub-Reinsch iteration. The products of plane rotations form the matrices of left and right singular vectors. Assuming each processor can compute or supply a plane rotation, O(wn) processors accomplish the reduction to bidiagonal form in O(np) steps, where p is the number of superdiagonals. A constant number of processors then determines each singular value in about 6n steps. The singular vectors are computed by rerouting the rotations through the arrays used for the reduction to bidiagonal form, or else along the way by employing another rectangular array of O(wm) processors.

Ipsen, I. C. F.↗

Aerospace engineering design by systematic decomposition and multilevel optimization

This paper describes a method for systematic analysis and optimization of large engineering systems, e.g., aircraft, by decomposition of a large task into a set of smaller, self-contained subtasks that can be solved concurrently. The subtasks may be arranged in many hierarchical levels with the assembled system at the top level. Analyses are carried out in each subtask using inputs received from other subtasks, and are followed by optimizations carried out from the bottom up. Each optimization at the lower levels is augmented by analysis of its sensitivity to the inputs received from other subtasks to account for the couplings among the subtasks in a formal manner. The analysis and optimization operations alternate iteratively until they converge to a system design whose performance is maximized with all constraints satisfied. The method, which is still under development, is tentatively validated by test cases in structural applications and an aircraft configuration optimization. It is pointed out that the method is intended to be compatible with the typical engineering organization and the modern technology of distributed computing.

Sobieszczanski-Sobieski, J.↗

Metalization Patterns by Thermal Decomposition

Metal interconnection pattern deposited on integrated circuit or solar cell economically by thermal decomposition of metallo-organic compound. In proposed process beam from laser or quartz lamp swept over substrate in required metalization pattern; wherever beam impinges on substrate, radiant heat decomposes compound, depositing metal. Process requires less costly equipment and less time than conventional metalization. Process readily adaptable to very-large-scale integrated (VLSI) circuits.

Gallagher, B. D.↗

A computer controlled mass spectrometer system for investigating the decomposition of non-metallic materials under atmospheric conditions

A PDP 11/23 quadrupole mass spectrometer system was coupled to a nondiscriminating gas inlet system permitting gases at atmospheric pressure to be admitted into a high vacuum chamber containing the ion source of the mass spectrometer without separation of the gaseous components. The resolution of related software problems has resulted in a convenient computer-mass spectrometer system capable of generating masses, relative intensities and related data on the gaseous products resulting from the atmospheric thermal decomposition of nonmetallic materials.

Thompson, J. M.↗