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At least 433 records · Page 24

Insights into interfacial effect and local lithium-ion transport in polycrystalline cathodes of solid-state batteries

Interfacial issues commonly exist in solid-state batteries, and the microstructural complexity combines with the chemical heterogeneity to govern the local interfacial chemistry. The conventional wisdom suggests that “point-to-point” ion diffusion at the interface determines the ion transport kinetics. Here, we show that solid-solid ion transport kinetics are not only impacted by the physical interfacial contact but are also closely associated with the interior local environments within polycrystalline particles. In spite of the initial discrete interfacial contact, solid-state batteries may still display homogeneous lithium-ion transportation owing to the chemical potential force to achieve an ionic-electronic equilibrium. Nevertheless, once the interior local environment within secondary particle is disrupted upon cycling, it triggers charge distribution from homogeneity to heterogeneity and leads to fast capacity fading. Our work highlights the importance of interior local environment within polycrystalline particles for electrochemical reactions in solid-state batteries and provides crucial insights into underlying mechanism in interfacial transport.

25 ENERGY STORAGE↗

The mean ionic charge state of solar energetic Fe ions above 200 MeV per nucleon

We have analyzed the geomagnetic transmission of solar energetic Fe ions at approximately 200-600 MeV per nucleon during the great solar energetic particle (SEP) events of 1989 September-October. By comparing fluences from the Chicago charged-particle telescope on IMP-8 in interplanetary space and from NRL's Heavy Ions in Space (HIIS) experiment aboard the Long Duration Exposure Facility (LDEF) in low-Earth orbit, we obtain a mean ionic charge (Q(sub 3)) = 14.2 +/- 1.4. This result is significantly lower than (Q) observed at approximately 1 MeV per nucleon in impulsive, He-3 rich SEP events, indicating that neither acceleration at the flare site nor flare-heated plasma significantly contributes to the high-energy Fe ions we observe. But it agrees well with the (Q) observed in gradual SEP events at approximately 1 MeV per nucleon, in which ions are accelerated by shocks driven by fast coronal mass ejections, and hence shows that particles are accelerated to very high energies in this way. We also note apparent differences between solar wind and SEP charge state distributions, which may favor a coronal (rather than solar wind) seed population or may suggest additional ionization in the ambient shock-region plasma.

Tylka, A. J.↗

Effect of charge and anisotropic diffusivity on ion exchange kinetics in nuclear waste form materials

Motifs of radionuclide absorption particles (absorbers or fillers) for the nuclear waste treatment usually have crystal structures with nano-sized tunnels for fast ion diffusion. On the other hand, the accumulation of ions generates an electric field which affects the ion diffusion. Therefore, the strong anisotropic kinetic properties and the electric field affect ion exchange kinetics, especially in an assembly of these particles which may block the fast diffusion tunnels for each other. In this work, we developed a mesoscale model to describe the effect of anisotropic kinetic properties and electric field on ion exchange kinetics. With the model we simulated the effect of anisotropic diffusivity, electrochemical potential, particle morphology, size and aggregation on ion exchange kinetics during batch experiments. Here, tt is found that 1) ion exchange results in charge accumulation inside the particle because different ions have different diffusivities and different diffusion driving forces. The electric neutrality is not preserved; 2) the electric field speeds up the slower diffusion ions (either uptake or release) and slows down the faster diffusion ions to reduce charge accumulation and maintains charge neutrality; 3) the ion exchange becomes very slow at the later stages because a) diffusion driving force (electrochemical gradient, Cs + concentration in the solution and Na + inside the particle) continuously decreases, as observed in batch experiments; and b) the diffusivity decreases due to the Cs + concentration dependence of ion diffusivity. This can explain the observed experimental phenomena that the radionuclide capacity usually cannot be reached; 4) for needle-like particle and their clusters, both surface area and diffusion distance along the direction with the fastest diffusivities have significant impact on the ion exchange kinetics.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Velocities of windblown particles in saltation: Venus, Earth, and Mars

Particle velocities were determined in environmental wind tunnels capable of simulating aeolian processes on Earth, Mars, and Venus. Comparisons of results for Earth, Mars, and Venus reveal some remarkable differences. Most particles achieve speeds nearly equal to freestream wind speed on Venus, but seldom achieve half the wind speed on Mars; Earth cases are of intermediate values. This is attributed to the differences in atmospheric density and to the threshold wind speeds among the three planetary environments. Particles are more easily moved in the dense venusian atmosphere than on Mars; consequently, threshold speeds are very low, and for the range of wind speeds in which most movement is presumed to occur (just above threshold speeds), the grains need not be moving very fast to achieve 100% of the wind speed. Conversely, particles on Mars must accelerate very rapidly to achieve the speed of the high winds required for threshold, and despite the fact that saltation path lengths are long on Mars, most grains fall to the surface before achieving even 50 to 60% of freestream wind speed.

Greeley, R.↗

The Observational Consequences of Proton-Generated Waves at Shocks

In the largest solar energetic particle (SEP) events, acceleration takes place at shock waves driven out from the Sun by fast coronal mass ejections. Protons streaming away from strong shocks generate Alfven waves that trap particles in the acceleration region, limiting outflowing intensities but increasing the efficiency of acceleration to higher energies. Early in the events, with the shock still near the Sun, intensities at 1 AU are bounded and spectra are flattened at low energies. Elements with different charge-to-mass ratios, Q/A, differentially probe the wave spectra near shocks, producing abundance ratios that vary in space and time. An initial rise in He/H, while Fe/O declines, is a typical symptom of the non-Kolmogorov wave spectra in the largest events. Strong wave generation can cause cross-field scattering near the shock and unusually rapid reduction in anisotropies even far from the shock. At the highest energies, shock spectra steepen to form a "knee." For protons, this spectral knee can vary from approx. 10 MeV to approx. 1 GeV depending on shock conditions for wave growth. In one case, the location of the knee scales approximately as Q/A in the energy/nucleon spectra of other species.

Reames, Donald V.↗

Particle simulation of plasmas on the massively parallel processor

Particle simulations, in which collective phenomena in plasmas are studied by following the self consistent motions of many discrete particles, involve several highly repetitive sets of calculations that are readily adaptable to SIMD parallel processing. A fully electromagnetic, relativistic plasma simulation for the massively parallel processor is described. The particle motions are followed in 2 1/2 dimensions on a 128 x 128 grid, with periodic boundary conditions. The two dimensional simulation space is mapped directly onto the processor network; a Fast Fourier Transform is used to solve the field equations. Particle data are stored according to an Eulerian scheme, i.e., the information associated with each particle is moved from one local memory to another as the particle moves across the spatial grid. The method is applied to the study of the nonlinear development of the whistler instability in a magnetospheric plasma model, with an anisotropic electron temperature. The wave distribution function is included as a new diagnostic to allow simulation results to be compared with satellite observations.

Gledhill, I. M. A.↗

Improvements to the Faraday cup fast ion loss detector and magnetohydrodynamic induced fast ion loss measurements in Joint European Torus plasmas

Upgrades to electronic hardware and detector design have been made to the JET thin-foil Faraday cup fast ion loss detector in anticipation of the upcoming deuterium–tritium (DT) campaign. An improved foil stack design has been implemented, which greatly reduces the number of foil-to-foil shorts, and triaxial cabling has mitigated ambient noise pickup. Initial tests of 200 kHz digitizers, as opposed to the original 5 kHz digitizers, have provided enhanced analysis techniques and direct coherence measurements of fast ion losses with magnetohydrodynamic activity. Here, we present recent loss measurements in JET deuterium plasmas correlated with kink modes, fishbone modes, edge-localized modes, and sawteeth. Sources of systematic noise are discussed with emphasis on capacitive plasma pickup. Overall, the system upgrades have established a diagnostic capable of recording alpha particle losses due to a wide variety of resonant fast ion transport mechanisms to be used in future DT-experiments and modeling efforts.

47 OTHER INSTRUMENTATION↗

Collisionless cooling of perpendicular electron temperature in the thermal quench of a magnetized plasma

Thermal quench of a nearly collisionless plasma against an isolated cooling boundary or region is an undesirable off-normal event in magnetic fusion experiments, but an ubiquitous process of cosmological importance in astrophysical plasmas. Parallel transport theory of ambipolar-constrained tail electron loss is known to predict rapid cooling of the parallel electron temperature $T_{e\Vert}$ although $T_{e\Vert}$ is difficult to diagnose in actual experiments. Instead direct experimental measurements can readily track the perpendicular electron temperature $T_{e\bot}$ via electron cyclotron emission. The physics underlying the observed fast drop in $T_{e\bot}$ requires a resolution. Here two collisionless mechanisms, dilutional cooling by infalling cold electrons and wave-particle interaction by two families of whistler instabilities, are shown to enable fast $T_{e\bot}$ cooling that closely tracks the mostly collisionless crash of $T_{e\Vert}$. These findings motivate both experimental validation and reexamination of a broad class of plasma cooling problems in laboratory, space, and astrophysical settings.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Optical Imaging of Laser-Driven Fast Electron Weibel-like Filamentation in Overcritical Density Plasma

We report on the measurement of filamented transport of laser-generated fast electron beams in near-critical density plasma. A relativistic intensity long-wave-infrared laser irradiated a hydrodynamically shaped helium gas flow at an electron density n e ≃ 10 25 m − 3 , generating a large flux of fast electrons that propagated beyond the critical surface. The beam-to-background electron density ratio was sufficiently high to drive growth of Weibel-like filamentation, which was measured by optical probing to extend up to 800 μ m with radii ∼ 10 μ m . Particle-in-cell simulations reproduce the main features of the filamentation generation, suggesting that collisionless processes are dominant in these interactions. Expansion of the filaments after formation infers a fast electron heated plasma temperature ∼ 400 eV in the overcritical density plasma. Published by the American Physical Society 2025

43 PARTICLE ACCELERATORS↗

Mechanical characterization of fine-grain dispersion-strengthened tungsten as a plasma facing material

Field-Assisted Sintering Technology (FAST) was used to produce fine-grained, dispersion-strengthened tungsten (W) materials. Investigated materials 4138, 4353, and 4355 composed of 3 wt% ZrC sintered at 1800 °C, 5 wt% ZrC sintered at 1800 °C, and 3 wt% ZrC sintered at 2000 °C, respectively. They were compared against ITER-grade W. A series of mechanical and thermal property testing and microstructure studies were conducted to study them as a potential plasma facing material (PFM) for fusion reactors. Hardness testing showed that manufacturing conditions substantially altered hardness. Material 4355 had an average HV10 value of 497.2 ± 16.8, slightly higher than ITER-grade at 378.5 ± 40.3. However, material 4353 was substantially higher with an HV10 value of 738.9 ± 31.7 over the investigated temperature range. Electron Backscatter Diffraction (EBSD) analysis showed that FAST produced substantially smaller grains than the hot-rolled ITER-grade W material, offering notable control over grain size. Materials 4353 and 4355 had grain sizes of 0.44 ± 0.20 µm and 3.67 ± 0.89 µm, respectively, whereas ITER-grade 27.14 ± 19.76 µm at room temperature. The fine grain structures showed no net coarsening after 1 hr. anneals up to 1800 °C, several hundred degrees above the 1100 – 1500 °C recrystallization range reported for conventional W. Inverse application of the Zener pinning relationship to the measured grain sizes indicates that these two FAST sintering conditions produce markedly different effective dispersoid populations, with effective particle diameters of approximately 90 nm at a peak sintering temperature of 1800 °C and approximately 460 nm at 2000 °C, respectively. This result demonstrates that the FAST thermal condition itself, and not the nominal ZrC content alone, governs the pinning effectiveness of the dispersion. Thermal diffusivity measurements support this finding independently. Materials of identical composition sintered at different temperatures differ by approximately 19% in measured thermal diffusivity with statistically indistinguishable density, while materials of different composition and sintering temperature converge to within approximately 2%. At a representative divertor heat flux of 10 MW/m², the lower thermal conductivity of the fine-grained materials corresponds to approximately 28 to 33 °C per millimeter of armor thickness relative to ITER-grade W, traded against a substantially larger margin to recrystallization-driven degradation. While high temperature tensile testing revealed likely contamination that motivates refinement of the manufacturing process, FAST-produced, fine-grained, dispersion-strengthened W offers process-controlled microstructural stability well above the operating temperatures of conventional W and supports its continued development as a PFM for economically viable commercial fusion power.

Parker, Gabe [ORNL] (ORCID:0000000190394100)↗

FAST Observations of Acceleration Processes in the Cusp--Evidence for Parallel Electric Fields

The existence of precipitating keV ions in the Earth's cusp originating at the magnetosheath provide unique means to test our understanding of particle acceleration and parallel electric fields in the lower altitude acceleration region. On numerous occasions, the FAST (The Fast Auroral Snapshot) spacecraft has encountered the Earth's cusp regions near its apogee of 4175 km which are characterized by their signatures of dispersed keV ion injections. The FAST instruments also reveal a complex microphysics inherent to many, but not all, of the cusp regions encountered by the spacecraft, that include upgoing ion beams and conics, inverted-V electrons, upgoing electron beams, and spikey DC-coupled electric fields and plasma waves. Detailed inspection of the FAST data often show clear modulation of the precipitating magnetosheath ions that indicate that they are affected by local electric potentials. For example, the magnetosheath ion precipitation is sometimes abruptly shut off precisely in regions where downgoing localized inverted-V electrons are observed. Such observations support the existence of a localized process, such as parallel electric fields, above the spacecraft which accelerate the electrons downward and consequently impede the precipitating ion precipitation. Other acceleration events in the cusp are sometimes organized with an apparent cellular structure that suggests Alfven waves or other large-scale phenomena are controlling the localized potentials. We examine several cusp encounters by the FAST satellite where the modulation of energetic session on acceleration particle populations reveals evidence of localized acceleration, most likely by parallel electric fields.

Pfaff, R. F.. Jr.↗

What Properties of CMEs are Most Important for Space Weather?

Severe space weather is characterized by intense particle radiation from the Sun and major geomagnetic storm caused by magnetized solar plasmas arriving at Earth. Coronal mass ejections (CMEs) are key players in both these aspects. CMEs traveling at super-Alfv nic speeds drive fast-mode MHD shocks that create the high levels of particle radiation. When a CME arrives at Earth, the CME-associated magnetic fields reconnect with Earth s magnetopause fields resulting in solar plasma entry into the magnetosphere and a geomagnetic storm depending on the magnetic structure of the CME. Particle radiation starts affecting geospace as soon as the CMEs leave the Sun and the geospace may be immersed in the radiation for several days. On the other hand, the geomagnetic storm happens only upon CME arrival at Earth. The requirements for the production of particles and magnetic storms by CMEs are different in a number of respects: solar source location, CME magnetic structure, conditions in the ambient solar wind, and shock-driving ability of CMEs. Intense shocks arriving at Earth have additional space weather effects such as sudden impulse that shrinks the magnetosphere often exposing satellites in geosynchronous orbit to the solar wind and energetic storm particle events. This paper highlights these space weather effects using CME observations space and ground based instruments during of solar cycles 23 and 24.

Gopalswamy, Nat↗

Particle displacement tracking applied to air flows

Electronic Particle Image Velocimeter (PIV) techniques offer many advantages over conventional photographic PIV methods such as fast turn around times and simplified data reduction. A new all electronic PIV technique was developed which can measure high speed gas velocities. The Particle Displacement Tracking (PDT) technique employs a single cw laser, small seed particles (1 micron), and a single intensified, gated CCD array frame camera to provide a simple and fast method of obtaining two-dimensional velocity vector maps with unambiguous direction determination. Use of a single CCD camera eliminates registration difficulties encountered when multiple cameras are used to obtain velocity magnitude and direction information. An 80386 PC equipped with a large memory buffer frame-grabber board provides all of the data acquisition and data reduction operations. No array processors of other numerical processing hardware are required. Full video resolution (640x480 pixel) is maintained in the acquired images, providing high resolution video frames of the recorded particle images. The time between data acquisition to display of the velocity vector map is less than 40 sec. The new electronic PDT technique is demonstrated on an air nozzle flow with velocities less than 150 m/s.

Wernet, Mark P.↗

Particle displacement tracking applied to air flows

Electronic Particle Image Velocimetric (PIV) techniques offer many advantages over conventional photographic PIV methods such as fast turn around times and simplified data reduction. A new all electronic PIV technique was developed which can measure high speed gas velocities. The Particle Displacement Tracking (PDT) technique employs a single CW laser, small seed particles (1 micron), and a single intensified, gated CCD array frame camera to provide a simple and fast method of obtaining two-dimensional velocity vector maps with unambiguous direction determination. Use of a single CCD camera eliminates registration difficulties encountered when multiple cameras are used to obtain velocity magnitude and direction information. An 80386 PC equipped with a large memory buffer frame-grabber board provides all of the data acquisition and data reduction operations. No array processors of other numerical processing hardware are required. Full video resolution (640 x 480 pixel) is maintained in the acquired images, providing high resolution video frames of the recorded particle images. The time between data acquisition to display of the velocity vector map is less than 40 sec. The new electronic PDT technique is demonstrated on an air nozzle flow with velocities less than 150 m/s.

Wernet, Mark P.↗

State-of-the-art and evolution of UFSD sensors design at FBK

Over the past few years, there has been growing interest in the development of silicon sensors able to simultaneously measure accurately the time of passage and the position of impinging charged particles. In this contribution, a review of the progresses in the design of UFSD (Ultra-Fast Silicon Detectors) sensors, manufactured at the FBK (Fondazione Bruno Kessler) Foundry, aiming at tracking charged particles in 4 dimensions, is presented. The state-of-the-art UFSD sensors, with excellent timing capability, are planned to be used in both ATLAS and CMS experiments detector upgrade, in order to reduce the background due to the presence of overlapping events in the same bunch crossing. The latest results on sensors characterization including time resolution, radiation resistance and uniformity of the response are here summarized, pointing out the interplay between the design of the gain layer and the UFSD performances. The research is now focusing on the maximization of the sensor fill factor, to be able to reduce the pixel size, exploring the implementation of shallow trenches for the pixel isolation and the development of resistive AC-coupled UFSD sensors. In conclusion, a brief review on research paths tailored for detection of low energy X-rays or for low material budget applications is given.

47 OTHER INSTRUMENTATION↗

Microstructure of Neutron-Irradiated Al 3 Hf-Al Thermal Neutron Absorber Materials

A thermal neutron-absorbing metal matrix composite (MMC) comprised of Al 3 Hf particles in an aluminum matrix was developed to filter out thermal neutrons and create a fast flux environment for material testing in a mixed-spectrum nuclear reactor. Intermetallic Al 3 Hf particles capture thermal neutrons and are embedded in a highly conductive aluminum matrix that provides conductive cooling of the heat generated due to thermal neutron capture by the hafnium. These Al 3 Hf-Al MMCs were fabricated using powder metallurgy via hot pressing. The specimens were neutron-irradiated to between 1.12 and 5.38 dpa and temperatures ranging from 286 °C to 400 °C. The post-irradiation examination included microstructure characterization using transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy. This study reports the microstructural observations of four irradiated samples and one unirradiated control sample. All the samples showed the presence of oxide at the particle–matrix interface. The irradiated specimens revealed needle-like structures that extended from the surface of the Al 3 Hf particles into the Al matrix. An automated segmentation tool was implemented based on a YOLO11 computer vision-based approach to identify dislocation lines and loops in TEM images of the irradiated Al-Al 3 Hf MMCs. This work provides insight into the microstructural stability of Al 3 Hf-Al MMCs under irradiation, supporting their consideration as a novel neutron absorber that enables advanced spectral tailoring.

36 MATERIALS SCIENCE↗

Radial gradients of ion densities and temperatures observed by SWICS/Ulysses

Mean density and temperature gradients of solar wind protons and alpha-particles between 1 and 5.4 AU are established from SWICS/Ulysses observations. All parameters are classified in speed intervals. au order scheme giving us a natural extension of the Helios observations. which were usually classified according to speed of the wind. The radial gradients show a similar behaviour of both particle species, while the particles radially propagate and thereby cool off in the heliosphere. The slow solar wind is found, for protons as well as a particles. to expand adiabatically all the way out to 5.4 AU, while the fast wind evolves non-adiabatically and is heated by interplanetary sources. It, seems that the heating rate of the a-particles is larger than the heating rate of the protons. The ion temperature ratio and density ratio are determined. They do not indicate any radial dependence. The temperature ratio T(sub alpha)/T(sub p) is on average about 4. It has a maximum of 4.5 in the velocity interval where 400 km/s is less than v(sub p) is less than 500 km/s, while in slow wind with v(sub p) is less than 400 km/s it has a minimum value of 37. and for fast wind with v(sub p) is greater than 500 km/s it is 3.9. The density gradients shows compression effects resulting from fast wind overtaking the slow wind.

Liu, S.↗