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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

The toughest animals of the Earth versus global warming: Effects of long‐term experimental warming on tardigrade community structure of a temperate deciduous forest

Abstract Understanding how different taxa respond to global warming is essential for predicting future changes and elaborating strategies to buffer them. Tardigrades are well known for their ability to survive environmental stressors, such as drying and freezing, by undergoing cryptobiosis and rapidly recovering their metabolic function after stressors cease. Determining the extent to which animals that undergo cryptobiosis are affected by environmental warming will help to understand the real magnitude climate change will have on these organisms. Here, we report on the responses of tardigrades within a five‐year‐long, field‐based artificial warming experiment, which consisted of 12 open‐top chambers heated to simulate the projected effects of global warming (ranging from 0 to 5.5°C above ambient temperature) in a temperate deciduous forest of North Carolina (USA). To elucidate the effects of warming on the tardigrade community inhabiting the soil litter, three community diversity indices (abundance, species richness, and Shannon diversity) and the abundance of the three most abundant species ( Diphascon pingue , Adropion scoticum , and Mesobiotus sp.) were determined. Their relationships with air temperature, soil moisture, and the interaction between air temperature and soil moisture were tested using Bayesian generalized linear mixed models. Despite observed negative effects of warming on other ground invertebrates in previous studies at this site, long‐term warming did not affect the abundance, richness, or diversity of tardigrades in this experiment. These results are in line with previous experimental studies, indicating that tardigrades may not be directly affected by ongoing global warming, possibly due to their thermotolerance and cryptobiotic abilities to avoid negative effects of stressful temperatures, and the buffering effect on temperature of the soil litter substrate.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Accessing a high‐voltage nonaqueous hybrid flow battery with a sodium‐methylphenothiazine chemistry and a sodium‐ion solid electrolyte

Abstract The development of redox flow batteries (RFBs) with nonaqueous electrolytes offers the possibility of accessing a high cell‐operation voltage (no restrain of hydrogen evolution and oxygen evolution potentials) and a low operation temperature (can be operated below the freezing point of water). Therefore, nonaqueous RFBs have recently garnered increasing attention. However, the cross‐mixing of liquid electrode/electrolyte materials has been plaguing the progress of the nonaqueous RFBs. Herein, we present a crossover‐free, high voltage nonaqueous hybrid flow battery (HFB) with a novel sodium‐methylphenothiazine (MPT) chemistry and a single‐ion solid‐electrolyte separator. The Na‐MPT redox couple delivers a high voltage of ~2.6 V when the cell was operated at a medium current density. A NASICON‐type solid electrolyte membrane (Na 3 Zr 2 Si 2 PO 12 ) could circumvent the crossover of the liquids between the positive and negative electrodes, and meanwhile could maintain a single‐ion (Na + ‐ion) conduction between the two electrodes to sustain the electrochemical reactions. Under such an electrochemical mechanism, the nonaqueous Na‐MPT HFB shows remarkable cycling performance.

Yu, Xingwen↗
DOE OSTI2023

Climate Change Risks to Freshwater Subsistence Fisheries in Arctic Alaska: Insights and Uncertainty from Broad Whitefish Coregonus nasus

Arctic freshwater ecosystems and fish populations are largely shaped by seasonal and long-term watershed hydrology. In this paper, we hypothesize how changing air temperature and precipitation will alter freeze and thaw processes, hydrology, and instream habitat to assess potential indirect effects, such as the change to the foraging and behavioral ecology, on Arctic fishes, using Broad Whitefish Coregonus nasus as an indicator species. Climate change is expected to continue to alter hydrologic pathways, flow regimes, and, therefore, habitat suitability, connectivity, and availability for fishes. Warming and lengthening of the growing season will likely increase fish growth rates; however, the exceedance of threshold stream temperatures will likely increase physiological stress and alter life histories. We expect these changes to have mixed effects on Arctic subsistence fishes and fisheries. Management and conservation approaches focused on preserving the processes that create heterogeneity in aquatic habitats, genes, and communities will help maintain the resilience of Broad Whitefish and other important subsistence fisheries. Long-term effects are uncertain, so filling scientific knowledge gaps, such as identifying important habitats or increasing knowledge of abiotic variables in priority watersheds, is key to understanding and potentially mitigating likely impacts to Arctic fishes in a rapidly changing landscape.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

Variability in observed stable water isotopes in snowpack across a mountainous watershed in Colorado

In this study, isotopic information from 81 snowpits was collected over a 5-year period in a large, Colorado watershed. Data spans gradients in elevation, aspect, vegetation, and seasonal climate. They are combined with overlapping campaigns for water isotopes in precipitation and snowmelt, and a land-surface model for detailed estimates of snowfall and climate at sample locations. Snowfall isotopic inputs, describe the majority of δ18O snowpack variability. Aspect is a secondary control, with slightly more enriched conditions on east and north facing slopes. This is attributed to preservation of seasonally enriched snowfall and vapour loss in the early winter. Sublimation, expressed by decreases in snowpack d-excess in comparison to snowfall contributions, increases at low elevation and when seasonal temperature and solar radiation are high. At peak snow accumulation, post-depositional fractionation appears to occur in the top 25 ± 14% of the snowpack due to melt-freeze redistribution of lighter isotopes deeper into the snowpack and vapour loss to the atmosphere during intermittent periods of low relative humidity and high windspeed. Relative depth of fractionation increases when winter daytime temperatures are high and winter precipitation is low. Once isothermal, snowpack isotopic homogenization and enrichment was observed with initial snowmelt isotopically depleted in comparison to snowpack and enriching over time. The rate of δ18O increase (d-excess decrease) in snowmelt was 0.02‰ per day per 100-m elevation loss. Isotopic data suggests elevation dictates snowpack and snowmelt evolution by controlling early snow persistence (or absence), isotopic lapse rates in precipitation and the ratio of energy to snow availability. Hydrologic tracer studies using stable water isotopes in basins of large topographic relief will require adjustment for these elevational controls to properly constrain stream water sourcing from snowmelt.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Drivers of Historical and Future Coastal Runoff Across the Arctic and Sub‐Arctic Subregions of Alaska, USA

This study investigates historical and future coastal runoff across the Arctic and sub-Arctic subregions of Alaska, USA, emphasising changes in terrestrial hydrology and their implications for coastal discharge. Using the physically based SnowModel-HydroFlow framework, historical (1991–2020) and future (2071–2100) coastal discharge climatologies were simulated, incorporating meteorological, topographic, and land cover inputs. Results reveal distinct seasonal and spatial patterns in temperature, precipitation, and snow dynamics across the Beaufort, Chukchi, Yukon, and Bristol subregions. Future projections suggest significant warming and shifts in hydrological regimes, such as increased annual precipitation and coastal discharge totals. Following a high emissions, business as usual pathway (SSP5-8.5), coastal discharge hydrographs in the Beaufort and Yukon subregions remain snow dominated with increases in discharge in nearly all months, while Chukchi and Bristol subregions shift from snow dominated to rain dominated. These changes are linked to rising temperatures, decreasing snow precipitation fractions, and altered freezing levels, with implications for water storage, timing, and availability. This research provides insights into the drivers and consequences of hydrological changes in a rapidly warming Arctic, supporting efforts to predict and mitigate the impacts on coastal and marine ecosystems.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Chemometric optimisation of pressurised liquid extraction for the determination of alliin and S‐allyl‐cysteine in giant garlic ( Allium ampeloprasum L.) by liquid chromatography tandem mass spectrometry

Abstract Introduction Giant garlic is a functional food that contains different kinds of bioactive molecules with beneficial effects on chronic noncommunicable diseases like diabetes and cardiovascular conditions. Considering biosynthesis pathways, abundance, and biological activity, alliin and S‐allyl‐cysteine were used as chemical markers of organosulphur compounds present in giant garlic. Objective To establish a chemometric optimisation of pressurised liquid extraction for the determination of alliin and S‐allyl‐cysteine in giant garlic by liquid chromatography tandem mass spectrometry (LC–MS/MS). Methodology Samples were blanched (ca. 90°C for 10 min) to inactivate alliinase and γ‐glutamyl transpeptidase enzymes and then freeze‐dried. Chemometric optimisation was performed via response surface methodology based on central composite design (CCD). Organosulphur compound yields were determined applying a validated LC–MS/MS method in multiple reaction monitoring (MRM) mode using the following transitions: for alliin m/z 178 → 74 and for S‐allyl‐cysteine m/z 162 → 41. Results According to CCD results, under constant conditions of pressure (1500 psi) and time (20 min), the optimal conditions for pressurised liquid extraction of alliin and S‐allyl‐cysteine were 70.75 and 68.97% v/v of ethanol in extraction solvent and 76.45 and 98.88°C as extraction temperature, respectively. Multiple response optimisation for the simultaneous extraction of both organosulphur compounds was established via desirability function. Under these conditions, 2.70 ± 0.27 mg g −1 dry weight (DW) of alliin and 2.79 ± 0.22 mg g −1 DW of S‐allyl‐cysteine were extracted. Conclusions These results clearly demonstrated that pressurised liquid extraction is an efficient green technique to extract bioactive organosulphur compounds from giant garlic. Extraction yields were significantly ( p < 0.05) higher than those obtained with conventional ultra‐turrax extraction.

Peterssen‐Fonseca, Darlene↗
DOE OSTI2024

Shrubs Strongly Influence Snow Properties in Two Subarctic Watersheds

Understanding changes in snow distribution in permafrost ecosystems is fundamental to predicting their response to future climate change. The expansion of tall shrubs into tundra ecosystems can trap snow and insulate permafrost ecosystems during the winter, but the overall insulation effect is dependent upon many ecosystem properties. To study shrub–snow–ground interactions, small temperature sensors were deployed at two research sites on the Seward Peninsula of Alaska, USA, during the 2019–2020 winter. Snow temperatures were used to extrapolate multiple metrics, including freezing n-factors, the snow insulation effect, snow cover duration, and the length of the snowmelt period. Statistical and spatial analysis showed that shrub patches were a dominant control on all snow metrics. Within shrub patches, average ground temperatures were 2.1°C warmer, snow persisted 50 days longer, snow insulation was double, and a longer, later spring snowmelt period occurred compared to nonshrubby areas. Site-level differences contributed relatively little to variation in snow metrics, indicating that shrub presence is an overarching driver of snow–ground interactions at the locations examined. Shrub expansion, which is anticipated under climate change, will strongly impact future permafrost distribution and Arctic energy, water, and carbon cycles through snow–shrub–ground feedbacks.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

How hydrophobicity, side chains, and salt affect the dimensions of disordered proteins

Abstract Despite the generally accepted role of the hydrophobic effect as the driving force for folding, many intrinsically disordered proteins (IDPs), including those with hydrophobic content typical of foldable proteins, behave nearly as self‐avoiding random walks (SARWs) under physiological conditions. Here, we tested how temperature and ionic conditions influence the dimensions of the N‐terminal domain of pertactin (PNt), an IDP with an amino acid composition typical of folded proteins. While PNt contracts somewhat with temperature, it nevertheless remains expanded over 10–58°C, with a Flory exponent, ν , >0.50. Both low and high ionic strength also produce contraction in PNt, but this contraction is mitigated by reducing charge segregation. With 46% glycine and low hydrophobicity, the reduced form of snow flea anti‐freeze protein (red‐sfAFP) is unaffected by temperature and ionic strength and persists as a near‐SARW, ν ~ 0.54, arguing that the thermal contraction of PNt is due to stronger interactions between hydrophobic side chains. Additionally, red‐sfAFP is a proxy for the polypeptide backbone, which has been thought to collapse in water. Increasing the glycine segregation in red‐sfAFP had minimal effect on ν . Water remained a good solvent even with 21 consecutive glycine residues ( ν > 0.5), and red‐sfAFP variants lacked stable backbone hydrogen bonds according to hydrogen exchange. Similarly, changing glycine segregation has little impact on ν in other glycine‐rich proteins. These findings underscore the generality that many disordered states can be expanded and unstructured, and that the hydrophobic effect alone is insufficient to drive significant chain collapse for typical protein sequences.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Growth Phenomena and Bandgap Shift in Melt-Grown β-(In x Ga 1- x ) 2 O 3 Alloys

β-Ga 2 O 3 is an emerging ultra-wide bandgap semiconductor with great promise for power electronics and optoelectronics. Alloys in the In 2 O 3 -Ga 2 O 3 system are interesting for optoelectronic applications, particularly where bandgap tuning is desirable. Herein, β-(In x Ga 1- x ) 2 O 3 alloys with target compositions x = 0.025 or 0.10 are grown from the melt using the Czochralski and vertical gradient freeze techniques. Growth with 10 mol% In yields only small, needle-like crystals, while 2.5 mol% In allows growth of centimeter-sized single crystals. A substantial degree of indium segregation is unveiled by spatial measurements of lattice parameters and the bandgap. The bandgap decreases by a maximum of 0.28 eV in the case of the highest In content crystals. Z-contrast transmission electron microscopy confirms a solely octahedral coordination of In in the β-Ga 2 O 3 lattice. With indium concentrations higher than 2.5 mol%, samples contain micron-scale voids that impart a dark coloration. All measured crystals are electrically conductive, with carrier concentrations varying 10 16 –10 17 cm -3 depending upon the location of the sample in the growth. Lastly, a unique luminescence with unknown origin centered around 2.0 eV is revealed by photoluminescence spectroscopy.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Hierarchically Structured Vitrimer Biocomposites for Sustainable Manufacturing

Polymers containing dynamic covalent bonds (DCBs) exhibit thermoplastic-like flow above their topology freezing temperature (T v ) while maintaining thermoset-like properties below it, making them promising for sustainable manufacturing. However, their large-scale adoption remains limited due to challenges in accurately determining T v and achieving efficient fiber-matrix bonding in composite applications. Here, hierarchically structured epoxy-anhydride-based polyester vitrimer composites reinforced with cellulosic filaments is demonstrated, where hydroxyl groups on fiber surfaces participate directly in transesterification with the matrix. Further, this dynamic interfacial bonding delivers exceptional mechanical properties, including ≈70 MPa shear strength and >10% strain-to-failure, while enabling thermal malleability. Using a combination of nuclear magnetic resonance and nano-infrared spectroscopies, direct evidence is provided that chemical bond exchange begins well below the conventionally measured T v , supporting the hypothesis that rheologically determined T v reflects a combination of chemical exchange and frictional dynamics rather than a discrete transition. The composites demonstrate excellent processability through vacuum-assisted resin transfer molding and maintain >90% of their mechanical properties after multiple thermal reforming cycles. These findings advance both the fundamental understanding of vitrimeric transitions and the practical development of sustainable, high-performance composite materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Theory Summary at Strangeness in Quark Matter 2019

This is the theory summary of Strangeness in Quark Matter 2019 conference. Here, results include the state-of-the-art updates to the Quantum Chromodynamics (QCD) phase diagram with contributions both from heavy-ion collisions and nuclear astrophysics, studies on the QCD freeze-out lines, and several aspects regarding small systems including collectivity, heavy flavor dynamics, strangeness, and hard probes.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Dark matter from a conformal Dark Sector

We consider theories in which a dark sector is described by a Conformal Field Theory (CFT) over a broad range of energy scales. A coupling of the dark sector to the Standard Model breaks conformal invariance. While weak at high energies, the breaking grows in the infrared, and at a certain energy scale the theory enters a confined (hadronic) phase. One of the hadronic excitations can play the role of dark matter. We study a “Conformal Freeze-In” cosmological scenario, in which the dark sector is populated through its interactions with the SM at temperatures when it is conformal. In this scenario, the dark matter relic density is determined by the CFT data, such as the dimension of the CFT operator coupled to the Standard Model. We show that this simple and highly predictive model of dark matter is phenomenologically viable. The observed relic density is reproduced for a variety of SM operators (“portals”) coupled to the CFT, and the resulting models are consistent with observational constraints. The mass of the COFI dark matter candidate is predicted to be in the keV-MeV range.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

A heavy QCD axion and the mirror world

We study the mirror world with dark matter arising from the thermal freeze-out of the lightest, stable mirror particle — the mirror electron. The dark matter abundance is achieved for mirror electrons of mass 225 GeV, fixing the mirror electroweak scale near 10 8 GeV. This highly predictive scenario is realized by an axion that acts as a portal between the two sectors through its coupling to the QCD and mirror QCD sectors. The axion is more massive than the standard QCD axion due to additional contributions from mirror strong dynamics. Still, the strong CP problem is solved by this ‘heavy’ axion due to the alignment of the QCD and mirror QCD potentials. Mirror entropy is transferred into the Standard Model sector via the axion portal, which alleviates overproduction of dark radiation from mirror glueball decays. This mirror scenario has a variety of signals: (1) primordial gravitational waves from the first-order mirror QCD phase transition occurring at a temperature near 35 GeV, (2) effects on large-scale structure from dark matter self-interactions from mirror QED, (3) dark radiation affecting the cosmic microwave background, and (4) the rare kaon decay, K + → (π + + axion). The first two signals do not depend on any fundamental free parameters of the theory while the latter two depend on a single free parameter, the axion decay constant.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

The Bactrian effect: multiple resonances and light Dirac dark matter

The possibility of light dark matter (DM) annihilating through a dark photon (DP) which kinetically mixes (KM) with the Standard Model (SM) hypercharge field is a very attractive scenario. For DM in the interesting mass range below ~1 GeV, it is well known that bounds from the CMB provide a very strong model building constraint forcing the DM annihilation cross section to be roughly 3 orders of magnitude below that needed to reproduce the observed relic density. Under most circumstances this removes the possibility of an s-wave annihilation process for DM in this mass range as would be the case, e.g., if the DM were a Dirac fermion. In an extra-dimensional setup explored previously, it was found that the s-channel exchange of multiple gauge bosons could simultaneously encompass a suppressed annihilation cross section during the CMB era while also producing a sufficiently large annihilation rate during freeze-out to recover the DM relic density. In this paper, we analyze more globally the necessary requirements for this mechanism to work successfully and then realize them within the context of a simple model with two ‘dark’ gauge bosons having masses of a similar magnitude and whose contributions to the annihilation amplitude destructively interfere. We show that if the DM mass threshold lies appropriately in the saddle region of this destructive interference between the two resonance humps it then becomes possible to satisfy these requirements simultaneously provided several ancillary conditions are met. The multiple constraints on the parameter space of this setup are then explored in detail to identify the phenomenologically successful regions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Dark Radiation Constraints on Heavy QCD Axions

The naturalness problem of PQ symmetry motivates study of the heavy QCD axion, with masses m a > 1 MeV generated at scales above the QCD scale, and low values of the PQ symmetry breaking scale, ƒ a . We compute the abundance of such axions in a model-independent way, assuming only that they freeze-out after reheating from inflation, and are not subsequently diluted by new physics. If these axions decay between neutrino decoupling and the last scatter era of the Cosmic Microwave Background (CMB), they dilute the neutrinos and their abundance is constrained by CMB measurements of the energy density in dark radiation, N eff . We accurately compute this bound using a numerical code to evolve the axion momentum distribution, including many key processes and effects previously ignored. We assume that the only relevant axion decays are to final states involving Standard Model particles. We determine regions of (m a , ƒ a ) that will give a signal in N eff at CMB Stage 4 experiments. We similarly compute the N eff bound and CMB Stage 4 signal for heavy axions that can decay to light mirror photons. Finally, we compute the bounds on heavy axions with mass below 1 MeV that decay after the era of CMB last scatter, from their contribution to cold or hot dark matter or N eff at this era.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Dark matter effective field theory and an application to vector dark matter

The Standard Model Effective Field Theory (SMEFT) and the Low Energy Effective Field Theory (LEFT) can be extended by adding additional spin 0, 1/2 and 1 dark matter particles which are singlets under the Standard Model (SM) gauge group. We classify all gauge invariant interactions in the Lagrangian up to terms of dimension six, and present the tree-level matching conditions between the two theories at the electroweak scale. The most widely studied dark matter models, such as those based on the Higgs portal or on kinetic mixing between the photon and a dark photon, are based on dimension-four interactions with the SM sector. We consider a model with dark vector particles with a $\mathbb{Z}_2$ symmetry, so that the lightest dark matter particle is stable. The leading interaction with the SM is through dimension-six operators involving two dark vector field-strength tensors and the electromagnetic field-strength tensor. This model is a viable dark matter model in the freeze-in scenario for a wide range of parameters.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Cosmological implications of Kalb-Ramond-like particles

The Kalb-Ramond field is an antisymmetric, rank-two tensor field which most notably appears in the context of string theory, but has largely been unexplored in the context of cosmology. In this work, motivated by the Kalb-Ramond field in string theory, and antisymmetric tensor fields that emerge in effective field theories ranging from particle physics to condensed matter, we study the primordial production of interacting massive Kalb-Ramond-like-particles (KRLPs). KRLPs contain features of both dark photon and axion models, which can be appreciated via their duality properties. While the massless non-interacting KRLP is dual to a pseudoscalar, and the massive non-interacting KRLP is dual to a pseudovector, the interacting massive KRLP can be distinguished from its scalar and vector counterparts. We study early-universe production of KRLPs via the freeze-in mechanism, considering a ‘dark photon-like’ interaction, an ‘axion-like’ interaction, and a ‘Higgs portal’ interaction, as well as production via cosmological gravitational particle production. We find that as a dark matter candidate, KRLPs can be produced by all of the above mechanisms and account for the relic density of dark matter today for a wide range of masses. Finally, we comment on the potential to obtain both warm and cold dark matter subcomponents, and speculate on observational and experimental prospects.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

FIMP dark matter from flavon portals

We investigate the phenomenology of a non-thermal dark matter (DM) candidate in the context of flavor models that explain the hierarchy in the masses and mixings of quarks and leptons via the Froggatt-Nielsen (FN) mechanism. A flavor-dependent U(1) FN symmetry explains the fermion mass and mixing hierarchy, and also provides a mechanism for suppressed interactions of the DM, assumed to be a Majorana fermion, with the Standard Model (SM) particles, resulting in its FIMP (feebly interacting massive particle) character. Such feeble interactions are mediated by a flavon field through higher dimensional operators governed by the U(1) FN charges. We point out a natural stabilizing mechanism for the DM within this framework with the choice of half-integer U(1) FN charge n for the DM fermion, along with integer charges for the SM fermions and the flavon field. In this flavon portal scenario, the DM is non-thermally produced from the decay of the flavon in the early universe which becomes a relic through the freeze-in mechanism. We explore the allowed parameter space for this DM candidate from relic abundance by solving the relevant Boltzmann equations. We find that reproducing the correct relic density requires the DM mass to be in the range (100 – 300) keV for n = 7.5 and (3 – 10) MeV for n = 8.5 where n is the U(1) FN charge of the DM fermion.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗