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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Nanostructured Ni—Cd powders

Nanostructured powders of the Ni—Cd system containing 0–50 mol.% Cd obtained by co-reduction of metal salts from aqueous solutions by hydrazine were studied by X-ray diffraction, optical emission spectroscopy and electron microscopy. The reduction leads to formation of polycrystalline particles of 100–350 nm size, consisting of 10–20 nm crystallites. Phase composition of the powders is substantially different from that predicted by equilibrium on the phase diagram. Instead of a two-phase area consisting of Ni—NiCd intermetallide, other phase states are observed. If the system contains up to 6% Cd, the XRD data indicates the presence of a single-phase solid solution with a face centred cubic (fcc)-structure. The increase in the Cd content to ~40% is accompanied by formation of the NiCd{sub 5} intermetallide phase, along with a solid solution. In the 40–50% Cd content range, the main phases are NiCd{sub 5}, as well as a fcc-phase containing up to 18% Cd and characterized by a strong broadening of the diffraction maxima caused by the presence of 2–3 nm crystallites. Furthermore, the system of such composition contains a previously unknown non-stoichiometric phase based on Ni{sub 3}Cd, having a similar to Cu{sub 3}Au structure. The results serve to clarify compositions of reduction products and the character of the structural-phase transformations of the intermediate hydroxides and metal products during the reduction process. Based on the obtained data, we proposed a formation scheme for the phases that are unconventional for the studied composition region of the Ni-Cd system. It has been concluded that the main factors determining formation of the reduction products are particle nanoscale dimensionality and occurrence of the reduction process far from equilibrium.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

Investigation of sodium insertion–extraction in olivine Na x FePO 4 (0 ≤ x ≤ 1) using first-principles calculations

Olivine NaFePO4 has recently attracted the attention of the scientific community as a promising cathode material for Na-ion batteries. In this work we combine density functional theory (DFT) calculations and high resolution synchrotron X-ray diffraction (HRXRD) experiments to study the phase stability of NaxFePO4 along the whole range of sodium compositions (0 ≤ x ≤ 1). DFT calculations reveal the existence of two intermediate structures governing the phase stability at x = 2/3 and x = 5/6. This is in contrast to isostructural LiFePO4, which is a broadly used cathode in Li-ion batteries. Na2/3FePO4 and Na5/6FePO4 ground states both align vacancies diagonally within the ab plane, coupled to a Fe2+/Fe3+ alignment. HRXRD data for NaxFePO4 (2/3 < x < 1) materials show common superstructure reflections up to x = 5/6 within the studied compositions. The computed intercalation voltage profile shows a voltage difference of 0.16 V between NaFePO4 and Na2/3FePO4 in agreement with the voltage discontinuity observed experimentally during electrochemical insertion.

Saracibar, A.↗
DOE OSTI2021

PF-4 Seismic Performance Reassessment Project (P-SPRaP), Interim Risk Methodology and Deliverables [Slides]

Background: Interim Risk was added to P-SPRaP (SPR Phase 2) to produce intermediate results which build confidence, exercise methodology, develop early insights, and (most importantly) mitigate LANL pit production program risk. Status: SPR Phase 2 is actively underway, has P-SPRaP project team priority focus, and is targeting completion in FY21 (September 2021). Deliverable: Presentation of interim risk results (loss of confinement for screened in failure modes), list of potential criticisms of Interim Risk approach / methodology that intervenors could raise, cost and schedule for completion of Final Risk.

58 GEOSCIENCES↗
NASA NTRS1986

Intermediate-Frequency-to-Video-Band Converter

Analog and digital circuits combined to frequency-convert from intermediate frequencies directly to video-band frequencies to meet stringent requirements. IF-to-video-band converter operates on principle of signal-band cancellation in phase-quadrature circuits. Downconverts intermediate frequencies directly to video-band frequencies to near-zero frequency with good image-band rejection and low phase variation within passband.

Ham, N. C.↗
DOE OSTI2018

Utilizing Diselenide Precursors toward Rationally Controlled Synthesis of Metastable CuInSe 2 Nanocrystals

We present that within the past decade, there has been an emergence of reports regarding the synthetic isolation of multinary metal chalcogenide nano-crystals that persist under ambient conditions with metastable crystal structures; however, many of the direct syntheses remain largely serendipitous with respect to the conditions needed to achieve the metastable product. Towards the development of more rational design principles that enable the predictable isolation of metastable nanocrystals, we demonstrate a molecular programming approach for the synthesis of CuInSe 2 nanocrystals utilizing diorganyl diselenide precursors of the structure R-Se-Se-R. Specifically, we show that the kinetics of diselenide precursor conversion are dependent upon C–Se and Se–Se bond dissociation energies, and that the strength of the C–Se bond is the phase-directing variable. When employing dibenzyl and dimethyl selenide precursors with relatively weaker C–Se bonds, the resulting nanocrystals form in the thermodynamically stable chalcopyrite phase of CuInSe 2 . However, precursors like diphenyl diselenide that possess stronger C–Se bonds alter the reaction kinetics so as to steer the reaction towards formation of the metastable wurtzite-like phase. These two phases form via distinct copper selenide intermediates, with chalcopyrite forming through Cu 2-x Se and the wurtzite-like phase forming through Cu 3 Se 2 intermediates, and it was found that the ultimate wurtzite-like phase displays remarkable resistance to relaxation to the chalcopyrite phase. Lastly, this molecular programming approach should be applicable towards the isolation of other metastable phases of metal chalcogenide nanocrystals.

36 MATERIALS SCIENCE↗
NASA NTRS2013

Timescale of Petrogenetic Processes Recorded in the Mount Perkins Magma System, Northern Colorado River Extension Corridor, Arizona

The Miocene Mt. Perkins Pluton is a small composite intrusive body emplaced in the shallow crust as four separate phases during the earliest stages of crustal extension. Phase 1 (oldest) consists of isotropic hornblende gabbro and a layered cumulate sequence. Phase 2 consists of quartz monzonite to quartz monzodiorite hosting mafic microgranitoid enclaves. Phase 3 is composed of quartz monzonite and is subdivided into mafic enclave-rich zones and enclave-free zones. Phase 4 consists of aphanitic dikes of mafic, intermediate and felsic compositions hosting mafic enclaves. Phases 2-4 enclaves record significant isotopic disequilibrium with surrounding granitoid host rocks, but collectively enclaves and host rocks form a cogenetic suite exhibiting systematic variations in Nd-Sr-Pb isotopes that correlate with major and trace elements. Phases 2-4 record multiple episodes of magma mingling among cogenetic hybrid magmas that formed via magma mixing and fractional crystallization at a deeper crustal. The mafic end-member was alkali basalt similar to nearby 6-4 Ma basalt with enriched OIB-like trace elements and Nd-Sr-Pb isotopes. The felsic end-member was a subalkaline crustal-derived magma. Phase 1 isotropic gabbro exhibits elemental and isotopic compositional variations at relatively constant SiO2, suggesting generation of isotropic gabbro by an open-system process involving two mafic end-members. One end-member is similar in composition to the OIB-like mafic end-member for phases 2-4; the second is similar to nearby 11-8 Ma tholeiite basalt exhibiting low epsilon (sub Nd), and depleted incompatible trace elements. Phase 1 cumulates record in situ fractional crystallization of an OIB-like mafic magma with isotopic evidence of crustal contamination by partial melts generated in adjacent Proterozoic gneiss. The Mt Perkins pluton records a complex history in a lithospheric scale magma system involving two distinct mantle-derived mafic magmas and felsic magma sourced in the crust. Mixing and fractional crystallization of these magmas at various levels in the crust generated a suite of intermediate composition magmas. U-Pb zircon SHRIMP ages of phase 1 (15.7 +/- 0.2 Ma), phase 3 (15.8 +/- 0.2 Ma) and phase 4 (15.4 +/- 0.3 Ma) document a 100-300k year timescale for petrogenetic processes recorded in the Mt Perkins magma system.

Danielson, Lisa R.↗
DOE OSTI2023

Impact of peripheral alkyl chain length on mesocrystal assemblies of G2 dendrons

Unique sphere-packing mesophases such as Frank–Kasper (FK) phases have emerged from the viable design of intermolecular interactions in supramolecular assemblies. In this work, a series of C n -G2-CONH 2 dendrons possessing an identical core wedge are investigated to elucidate the impact of peripheral alkyl chain lengths (C n ) on the formation of the close-packed structures. The C 18 and C 14 dendrons, of which the contour lengths of the periphery L p are longer than the wedge length L w , assemble into a uniform sphere-packing phase such as body-centred cubic (BCC), whereas the C 8 dendron with short (L p < L w ) corona environment forms the FK A15 phase. Particularly in the intermediate C 12 and C 10 dendrons (L p ≈ L w ), cooling the samples from an isotropic state leads to cooling-rate-dependent phase behaviours. The C 12 dendron produces two structures of hexagonal columnar and sphere-packing phases (BCC and A15), while the C 10 dendron generates the A15 and σ phases by the fast- and slow-cooling processes, respectively. Our results show the impact of peripheral alkyl chain lengths on the formation of mesocrystal phases, where the energy landscape of the dendrons at L p /L w ≈ 1 must be more complex and delicate than those with either longer or shorter peripheral alkyl chains.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Temperature-independent giant dielectric response in transitional BaTiO 3 thin films

Ferroelectric materials exhibit the largest dielectric permittivities and piezoelectric responses in nature, making them invaluable in applications from supercapacitors or sensors to actuators or electromechanical transducers. The origin of this behavior is their proximity to phase transitions. However, the largest possible responses are most often not utilized due to the impracticality of using temperature as a control parameter and to operate at phase transitions. This has motivated the design of solid solutions with morphotropic phase boundaries between different polar phases that are tuned by composition and that are weakly dependent on temperature. Thus far, the best piezoelectrics have been achieved in materials with intermediate (bridging or adaptive) phases. But so far, complex chemistry or an intricate microstructure has been required to achieve temperature-independent phase-transition boundaries. Here, we report such a temperature-independent bridging state in thin films of chemically simple BaTiO3. A coexistence among tetragonal, orthorhombic, and their bridging low-symmetry phases are shown to induce continuous vertical polarization rotation, which recreates a smear in-transition state and leads to a giant temperature-independent dielectric response. The current material contains a ferroelectric state that is distinct from those at morphotropic phase boundaries and cannot be considered as ferroelectric crystals. We believe that other materials can be engineered in a similar way to contain a ferroelectric state with gradual change of structure, forming a class of transitional ferroelectrics. Similar mechanisms could be utilized in other materials to design low-power ferroelectrics, piezoelectrics, dielectrics, or shape-memory alloys, as well as efficient electro- and magnetocalorics.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Twisted symmetric trilayer graphene. II. Projected Hartree-Fock study

The Hamiltonian of the magic-angle twisted symmetric trilayer graphene (TSTG) can be decomposed into a twisted-bilayer-graphene- (TBG-) like flat band Hamiltonian and a high-velocity Dirac fermion Hamiltonian. We use Hartree-Fock mean field approach to study the projected Coulomb interacting Hamiltonian of TSTG developed in Calugaru et al. [Phys. Rev. B 103, 195411 (2021)] at integer fillings ν = -3, -2, -1, and 0 measured from charge neutrality. We study the phase diagram with w 0 /w 1 , the ratio of AA and AB interlayer hoppings, and the displacement field, which introduces an interlayer potential U and hybridizes the TBG-like bands with the Dirac bands. At small U, we find the ground states at all fillings ν are in the same phases as the tensor products of a Dirac semimetal with the filling ν TBG insulator ground states, which are spin-valley polarized at ν = -3, and fully (partially) intervalley coherent at ν = -2, 0(ν = -1) in the flat bands. An exception is ν = -3 with w 0 /w 1 ≳ 0.7 , which possibly becomes a metal with competing orders at small U due to charge transfers between the Dirac and flat bands. At strong U where the bandwidths exceed interactions, all the fillings ν enter a metal phase with small or zero valley polarization and intervalley coherence. Lastly, at intermediate U, semimetal or insulator phases with zero intervalley coherence may arise for ν = -2, -1, 0. Finally, our results provide a simple picture for the electron interactions in TSTG systems, and reveal the connection between the TSTG and TBG ground states.

2-dimensional systems↗
DOE OSTI2016

Nanoindentation testing as a powerful screening tool for assessing phase stability of nanocrystalline high-entropy alloys

The equiatomic high-entropy alloy (HEA), CrMnFeCoNi, has recently been shown to be microstructurally unstable, resulting in a multi-phase microstructure after intermediate-temperature annealing treatments. The decomposition occurs rapidly in the nanocrystalline (NC) state and after longer annealing times in coarse-grained states. To characterize the mechanical properties of differently annealed NC states containing multiple phases, nanoindentation was used in this paper. The results revealed besides drastic changes in hardness, also for the first time significant changes in the Young's modulus and strain rate sensitivity. Finally, nanoindentation of NC HEAs is, therefore, a useful complementary screening tool with high potential as a high throughput approach to detect phase decomposition, which can also be used to qualitatively predict the long-term stability of single-phase HEAs.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state

Abstract. Secondary organic aerosol (SOA) derived from n-alkanes, as emitted from vehicles and volatile chemical products, is a major component of anthropogenic particulate matter, yet the chemical composition and phase state are poorly understood and thus poorly constrained in aerosol models. Here we provide a comprehensive analysis of n-alkane SOA by explicit gas-phase chemistry modeling, machine learning, and laboratory experiments to show that n-alkane SOA adopts low-viscous semi-solid or liquid states. Our study underlines the complex interplay of molecular composition and SOA viscosity: n-alkane SOA with a higher carbon number mostly consists of less functionalized first-generation products with lower viscosity, while the SOA with a lower carbon number contains more functionalized multigenerational products with higher viscosity. This study opens up a new avenue for analysis of SOA processes, and the results indicate few kinetic limitations of mass accommodation in SOA formation, supporting the application of equilibrium partitioning for simulating n-alkane SOA formation in large-scale atmospheric models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

MC{sup 2}-3/DIF3D Analysis of the ZPPR-15 Axial Expansion Experiments

The Zero Power Physics Reactor (ZPPR) fast critical facility at the Argonne National Laboratory-West (ANLW) site in Idaho was built in 1969 to obtain neutron physics information necessary for the design of fast breeder reactors. The ZPPR-15 phases A through D were part of a series of cores intended to model a 330 MWt Integral Fast Reactor (IFR) concept. The ZPPR-15 assembly consisted of an inner core zone, an outer core zone of higher fissile content, a thin radial blanket and a thick steel reflector. The inner and outer core zones were of approximately equal volumes. The core zones simulated a sodium-cooled, metal-fueled fast reactor with approximately 10 wt.% zirconium in the target fuel composition. Phases A and B simulated an equilibrium cycle UPu-Zr fuel core where plutonium created in the blankets was sufficient to negate the need for enriched {sup 235}U feedstock. Phase D simulated a beginning of life U-Zr fuel core with enriched uranium fuel although approximately 10% of the fuel in the outer zone of the Phase D core was plutonium because {sup 240}Pu was required to provide a neutron source for the modified source multiplication technique used for many reactivity worth measurements such as sodium void worth in ZPPR. Phase C simulated the intermediate state between beginning of life and equilibrium cycle conditions with 50% enriched uranium fuel and 50% plutonium fuel in the inner and outer core zones. These configurations represent the various stages of reactor operating conditions. Phase A did not contain zirconium (metal fuel is typically alloyed with Zr) while Phases B, C and D did contain zirconium although the limited plate inventory restricted the zirconium zone to the inner core zone. This set of experiments was performed between April 1985 and July 1986 and focused on validation of both the concept and modeling. In each phase, there were multiple loadings for sub-critical, critical, and with regard to this manuscript, axial expansion worth measurements. Combined, these cores can be used to assess the accuracy of physics codes and evaluated cross section data for IFR concept reactors. This paper presents a recent effort that was made on retrieving validation data from the ZPPR-15 experiments and on deterministic modeling and analysis using MC{sup 2}-3/DIF3D for code validation. Axial expansion experiments and ZPPR-15D loading 206 were selected for this analysis. An explicit modeling of the axial expansion (introduction of gaps between sections of drawer) of ZPPR-15D loading 206 yielded a 32% over-prediction in the worth of the axial expansion with the MC2-3/DIF3D models. This indicates a consistent bias between ZPPR-15B and ZPPR-15D with regard to the deterministic modeling of the experiments. As part of future work, we intend on investigating whether the cross section processing or homogenization model is to blame, but we note with such small changes in k-effective in a large model, it is rather difficult to obtain zero errors as is typical for other worth measurements. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2022

Identification of a quasi-liquid phase at solid–liquid interface

Abstract An understanding of solid–liquid interfaces is of great importance for fundamental research as well as industrial applications. However, it has been very challenging to directly image solid–liquid interfaces with high resolution, thus their structure and properties are often unknown. Here, we report a quasi-liquid phase between metal (In, Sn) nanoparticle surfaces and an aqueous solution observed using liquid cell transmission electron microscopy. Our real-time high-resolution imaging reveals a thin layer of liquid-like materials at the interfaces with the frequent appearance of small In nanoclusters. Such a quasi-liquid phase serves as an intermediate for the mass transport from the metal nanoparticle to the liquid. Density functional theory-molecular dynamics simulations demonstrate that the positive charges of In ions greatly contribute to the stabilization of the quasi-liquid phase on the metal surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Dynamic Bubbling Balanced Proactive CO 2 Capture and Reduction on a Triple-Phase Interface Nanoporous Electrocatalyst

The formation and preservation of the active phase of the catalysts at the triple-phase interface during CO 2 capture and reduction is essential for improving the conversion efficiency of CO 2 electroreduction toward value-added chemicals and fuels under operational conditions. Designing such ideal catalysts that can mitigate parasitic hydrogen generation and prevent active phase degradation during the CO 2 reduction reaction (CO 2 RR), however, remains a significant challenge. Herein, we developed an interfacial engineering strategy to build a new SnO x catalyst by invoking multiscale approaches. This catalyst features a hierarchically nanoporous structure coated with an organic F-monolayer that modifies the triple-phase interface in aqueous electrolytes, substantially reducing competing hydrogen generation (less than 5%) and enhancing CO 2 RR selectivity (~90%). This rationally designed triple-phase interface overcomes the issue of limited CO 2 solubility in aqueous electrolytes via proactive CO 2 capture and reduction. Concurrently, we utilized pulsed square-wave potentials to dynamically recover the active phase for the CO 2 RR to regulate the production of C1 products such as formate and carbon monoxide (CO). This protocol ensures profoundly enhanced CO 2 RR selectivity (~90%) compared with constant potential (~70%) applied at -0.8 V (V vs RHE). We further achieved a mechanistic understanding of the CO 2 capture and reduction processes under pulsed square-wave potentials via in situ Raman spectroscopy, thereby observing the potential-dependent intensity of Raman vibrational modes of the active phase and CO 2 RR intermediates. Finally, this work will inspire material design strategies by leveraging triple-phase interface engineering for emerging electrochemical processes, as technology moves toward electrification and decarbonization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Plaquette valence bond state in the spin-$\frac{1}{2}$ J 1 –J 2 XY model on the square lattice

Here, we studied the ground-state phase diagram of spin-1/2 J 1 –J 2 XY model on the square lattice with first-neighbor J 1 and second-neighbor J 2 antiferromagnetic interactions using both infinite density matrix renormalization group (iDMRG) and DMRG approaches. We show that a plaquette valence bond phase is realized in an intermediate region 0.50 ≤ J 2 /J 1 < 0.54 between a Néel magnetic ordered phase at J 2 /J 1 < 0.50 and a stripy magnetic ordered phase at J 2 /J 1 ≥ 0.54 . The plaquette valence bond phase is characterized by finite dimer orders in both the horizontal and vertical directions. Contrary to the spin-1/2 J 1 –J 2 Heisenberg model, we do not find numerical evidence for a quantum spin liquid phase in the J 1 –J 2 XY model.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Transmission electron microscopy study of a high burnup U-10Zr metallic fuel

To support the development of U-10 wt.% Zr (U-10Zr) metallic fuel for Gen IV sodium-cooled fast reactors, we analysed a solid, Na-bonded, U-10Zr (by weight percent) fuel cross section that was irradiated to a burnup of ~ 12.4 % at.% at the Fast Flux Test Facility (FFTF). Advanced characterization techniques, including site specific sample preparation by focused ion beam (FIB) and phase/chemical determination by transmission electron microscopy (TEM), were used to reveal the constituent redistribution of Zr, characterize the fuel phases and the secondary phases (such as solid fission products) present at the end of life. It is shown that the fuel pin cross section is divided into three major concentric zones: a Zr-rich central region, a Zr-lean intermediate region, and a Zr intermediate peripherical region. The phase characterization revealed that the irradiation environment enhanced the development and stabilization of phases not predicted by the standard equilibrium U-Zr phase diagrams. Comparing the current results with the ones from previous studies, it is reaffirmed that the irradiation temperature and the time spent in the reactor, rather than the fuel burnup, are the two factors that most influence the formation of redistribution zones and their extension along the fuel cross section. Various solid fission products precipitated inside the fission gas pores, such as lanthanides, ZrRu, BaTe, CsI, and Ba and Sr oxides. Here, this study provides unprecedented nanoscale understandings in the U-10Zr fuel system that may benefit fuel performance modelling and advanced fuel development.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2019

Quasiparticle relaxation dynamics in URu 2 - x Fe x Si 2 single crystals

We investigate quasiparticle relaxation dynamics in URu 2–x Fe x Si 2 single crystals using ultrafast optical-pump optical-probe (OPOP) spectroscopy as a function of temperature and Fe substitution (x), crossing from the hidden-order (HO) phase (x = 0) to the large-moment antiferromagnet (LMAFM) phase (x = 0 .12). Here, at low temperature, the dynamics for x = 0 and x = 0 .12 are consistent with the low-energy electronic structure of the HO and LMAFM phases that emerge from the high-temperature paramagnetic (PM) phase. In contrast, near the bicritical point separating HO and LMAFM (x = 0 .1), two transitions occur over a narrow temperature range (from 15.5–17.5 K). A PM to HO transition occurs at an intermediate temperature followed by a transition to the LMAFM phase at lower temperature. While the data at low temperatures are consistent with the expected coexistence of LMAFM and HO, the data in the intermediate temperature phase are not, and instead suggest the possibility of an unexpected coexistence of HO and PM. Additionally, the dynamics in the PM phase reflect the presence of a hybridization gap as well as strongly interacting spin and charge degrees of freedom. OPOP yields insights into meV-scale electrodynamics with sub-Kelvin temperature resolution, providing a complementary approach to study low-energy electronic structure in quantum materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Kinetic pathways of ionic transport in fast-charging lithium titanate

Fast-charging batteries typically use electrodes capable of accommodating lithium continuously by means of solid-solution transformation because they have few kinetic barriers apart from ionic diffusion. One exception is lithium titanate (Li 4 Ti 5 O 12 ), an anode exhibiting extraordinary rate capability apparently inconsistent with its two-phase reaction and slow Li diffusion in both phases. Through real-time tracking of Li+ migration using operando electron energy-loss spectroscopy, we reveal that facile transport in Li 4+x Ti 5 O 12 is enabled by kinetic pathways comprising distorted Li polyhedra in metastable intermediates along two-phase boundaries. Our work demonstrates that high-rate capability may be enabled by accessing the energy landscape above the ground state, which may have fundamentally different kinetic mechanisms from the ground-state macroscopic phases. This insight should present new opportunities in searching for high-rate electrode materials.

25 ENERGY STORAGE↗