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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Numerical Simulation of Flow Field Within Parallel Plate Plastometer

Parallel Plate Plastometer (PPP) is a device commonly used for measuring the viscosity of high polymers at low rates of shear in the range 10 4 to 10 9 poises. This device is being validated for use in measuring the viscosity of liquid glasses at high temperatures having similar ranges for the viscosity values. PPP instrument consists of two similar parallel plates, both in the range of 1 inch in diameter with the upper plate being movable while the lower one is kept stationary. Load is applied to the upper plate by means of a beam connected to shaft attached to the upper plate. The viscosity of the fluid is deduced from measuring the variation of the plate separation, h, as a function of time when a specified fixed load is applied on the beam. Operating plate speeds measured with the PPP is usually in the range of 10 -3 cm/s or lower. The flow field within the PPP can be simulated using the equations of motion of fluid flow for this configuration. With flow speeds in the range quoted above the flow field between the two plates is certainly incompressible and laminar. Such flows can be easily simulated using numerical modeling with computational fluid dynamics (CFD) codes. We present below the mathematical model used to simulate this flow field and also the solutions obtained for the flow using a commercially available finite element CFD code.

Basil N. Antar↗

Effect of Viscosity on the Crystallization of Undercooled Liquids

There have been numerous studies of glasses indicating that low-gravity processing enhances glass formation. NASA PI s are investigating the effect of low-g processing on the nucleation and crystal growth rates. Dr. Ethridge is investigating a potential mechanism for glass crystallization involving shear thinning of liquids in 1-g. For shear thinning liquids, low-g (low convection) processing will enhance glass formation. The study of the viscosity of glass forming substances at low shear rates is important to understand these new crystallization mechanisms. The temperature dependence of the viscosity of undercooled liquids is also very important for NASA s containerless processing studies. In general, the viscosity of undercooled liquids is not known, yet knowledge of viscosity is required for crystallization calculations. Many researchers have used the Turnbull equation in error. Subsequent nucleation and crystallization calculations can be in error by many orders of magnitude. This demonstrates the requirement for better methods for interpolating and extrapolating the viscosity of undercooled liquids. This is also true for undercooled water. Since amorphous water ice is the predominant form of water in the universe, astrophysicists have modeled the crystallization of amorphous water ice with viscosity relations that may be in error by five orders-of-magnitude.

Source record↗

Alignment Charts for Transport Properties Viscosity, Thermal Conductivity, and Diffusion Coefficients for Nonpolar Gases and Gas Mixtures at Low Density

Alignment charts (nomographs) designed to permit rapid calculations of the low-pressure transport properties of nonpolar gases and gas mixtures are presented. Calculations for pure gases are based on the rigorous kinetic theory of gases as applied to a realistic intermolecular force law. Mixture viscosities and conductivities are calculated from good approximations derived from rigorous theory. The properties are calculable with a precision of 2 percent or better. Accuracy depends on how well the constants characterizing the Intermolecular force law are known; if constants are derived from experimental data, results should be accurate to 5 percent or better. Force constants are tabulated for 65 gases.

Brokaw, Richard S.↗

Laser‐Sintered Silver Metallization for Silicon Heterojunction Photovoltaic Cells

Herein, a novel metallization technique is reported for crystalline silicon heterojunction (SHJ) solar cells in which silver (Ag) fingers are printed on the SHJ substrates by dispensing Ag nanoparticle‐based inks through a needle and then sintered with a continuous‐wave carbon dioxide (CO 2 ) laser. The impact of the Ag ink viscosity on the line quality and the line resistance is investigated on three Ag inks with different viscosities. Increasing ink viscosity yields higher Ag contact heights, larger aspect ratios, and lower line resistance values. The Ag line height increases from less than a micrometer to ≈18.62 ± 3.48 μm with the increasing viscosity. Photoluminescence imaging shows that the low‐resistance Ag metal contacts obtained do not result in any passivation damage of the SHJ substrate. This is because the wavelength of light emitted from the CO 2 laser (i.e., 10.6 μm) leads to optical absorption in the Ag, but this light is effectively transparent to the transparent conductive oxide film, amorphous silicon films, and crystalline silicon substrate. Bulk resistivity values as low as 6.5 μΩ cm are obtained for the laser‐sintered Ag contact and printed using the Ag ink with the highest viscosity in this work.

Mousumi, Jannatul Ferdous↗

The evaporation of various lubricant fluids in vacuum.

The weight-loss rate in vacuum of 18 lubricating liquids and greases is reported for temperatures up to 120 C. Eleven types of 'medium-viscosity' (20 to 52 centistokes at 40 C) fluids were studied. In addition, a variety of perfluoro ether liquids having viscosities of 350 to 500 centistokes at 40 C were investigated, as were some commercial greases based on these liquids. The results showed that a methylchlorophenyl silicone, a high-viscosity-index perfluoro ether research fluid, and a polyoctene have suitably low outgassing properties for long-term space applicaitons requiring a medium-viscosity lubricant. Perfluoro ether greases also displayed low outgassing, but batch-to-batch variation was great. Mass spectrometer measurements indicated that the outgassed species were characterized by much lower molecular weights than that expected for the liquids. This suggests that lubricant transfer techniques which rely on evaporation from a reservoir may not be desirable for long-term space applications.

Hamilton, D. B.↗

Viscosity Measurement via Drop Coalescence: A Space Station Experiment

The concept of using low gravity experimental data together with CFD simulations for measuring the viscosity of highly viscous liquids was recently validated on onboard the International Space Station (ISS). A series of microgravity tests were conducted for this purpose on the ISS in July, 2004 and in May of 2005. In these experiments two liquid drops were brought manually together until they touched and were allowed to coalesce under the action of the capillary force alone. The coalescence process was recorded photographically from which the contact radius speed of the merging drops was measured. The liquid viscosity was determined by fitting the measured data with accurate numerical simulation of the coalescence process. Several liquids were tested and for each liquid several drop diameters were employed. Experimental and numerical results will be presented in which the viscosity of several highly viscous liquids were determined using this technique.

Antar, Basil↗

Viscous Properties of a Degenerate One-Dimensional Fermi Gas

In this paper, we study the viscous properties of a system of weakly interacting spin-1/2 fermions in one dimension. Accounting for the effect of interactions on the quasiparticle energy spectrum, we obtain the bulk viscosity of this system at low temperatures. Our result is valid for frequencies that are small compared with the rate of fermion backscattering. For frequencies larger than this exponentially small rate, the excitations of the system become decoupled from the center of mass motion, and the fluid is described by two-fluid hydrodynamics. We calculate the three transport coefficients required to describe viscous dissipation in this regime.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Nightward ion flow in the Venus ionosphere - Implications of momentum balance

Using global empirical models of Venus ionospheric conditions, the plasma flow field consistent with the horizontal momentum equation in both viscid and inviscid forms is solved for. It is found that plasma viscosity is negligible except at low altitudes and that the observed plasma flows are consistent with the inviscid solution above 300 km but are larger than the calculated flows at lower altitudes. This is probably due to downward momentum advection. The strong vertical shear in the calculated and observed flows just beyond the terminator may produce turbulence there, manifested as the observed transterminator waves in plasma density and magnetic field. The implications of ionospheric superrotation are discussed.

Elphic, R. C.↗

Containment of a silicone fluid free surface in reduced gravity using barrier coatings

In support of the Surface Tension Driven Convection Experiment planned for flight aboard the Space Shuttle, tests were conducted under reduced gravity in the 2.2-sec Drop Tower and the 5.0-sec Zero-G facility at the NASA Lewis Research Center. The dynamics of controlling the test fluid, a 10-cSt viscosity silicone fluid in a low gravity environment were investigated using different container designs and barrier coatings. Three container edge designs were tested without a barrier coating; a square edge, a sharp edge with a 45-deg slope, and a sawtooth edge. All three edge designs were successful in containing the fluid below the edge. G-jitter experiments were made in scaled down containers subjected to horizontal accelerations. The data showed that a barrier coating is effective in containing silicone fluid under g-levels up to 10 sup -1 sub g sub 0. In addition, a second barrier coating was found which has similar anti-wetting characteristics and is also more durable.

Pline, Alexander D.↗

Effects of lubrication on the performance of high speed spur gears

An experimental analysis was conducted to determine power loss and gear noise of high speed spur gears with long addendum under various conditions of load, speed, and oil jet pressure for into mesh lubrication. Power losses were calculated from temperature measurements of lubricating oil, gears, gear box, and oil flow rate. Furthermore, power loss was divided into windage loss, friction loss and churning loss. The results show that windage loss and churning loss were the main components of gear power loss of high gear speed. In addition, lubricating conditions had some influences on gear noise especially under low oil temperature or high viscosity.

Mizutani, Hachiro↗

Effects of lubrication on the performance of high speed spur gears

An experimental analysis was conducted to determine power loss and gear noise of high speed spur gears with long addendum under various conditions of load, speed, and oil jet pressure for into mesh lubrication. Power losses were calculated from temperature measurements of lubricating oil, gears, gear box, and oil flow rate. Furthermore, power loss was divided into windage loss, friction loss and churning loss. The results show that windage loss and churning loss were the main components of gear power loss of high gear speed. In addition, lubricating conditions had some influences on gear noise especially under low oil temperature or high viscosity.

Mizutani, H.↗

Global Simulations of Phase State and Equilibration Time Scales of Secondary Organic Aerosols with GEOS-Chem

The phase state of secondary organic aerosols (SOA) can range from liquid through amorphous semisolid to glassy solid, which is important to consider as it influences various multiphase processes including SOA formation and partitioning, multiphase chemistry, and cloud activation. In this study, we simulate the glass transition temperature and viscosity of SOA over the globe using the global chemical transport model, GEOS-Chem. The simulated spatial distributions show that SOA at the surface exist as liquid over equatorial regions and oceans, semisolid in the midlatitude continental regions, and glassy solid over lands with low relative humidity. The predicted SOA viscosities are mostly consistent with the available measurements. In the free troposphere, SOA particles are mostly predicted to be semisolid at 850 hPa and glassy solid at 500 hPa, except over tropical regions including Amazonia, where SOA are predicted to be low viscous. Phase state also exhibits seasonal variation with a higher frequency of semisolid and solid particles in winter compared to warmer seasons. We calculate equilibration time scales of SOA partitioning (τ eq ) and effective mass accommodation coefficient (α eff ), indicating that τ eq is shorter than the chemical time step of GEOS-Chem of 20 min and αeff is close to unity for most locations at the surface level, supporting the application of equilibrium SOA partitioning. However, τ eq is prolonged and α eff is lowered over drylands and most regions in the upper troposphere, suggesting that kinetically limited growth would need to be considered for these regions in future large-scale model studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Stability, Combustion, and Compatibility of High-Viscosity Heavy Fuel Oil Blends with a Fast Pyrolysis Bio-Oil

Properties related to the combustion, stability, and compatibility of blends composed of high-viscosity heavy fuel oil (HFO) and highly acidic pyrolysis bio-oil were determined to assess the utility of bio-oil as a marine fuel. The addition of bio-oil was shown to be fully stable with HFO at blend levels up to 50 mass % for up to 2 weeks. Bio-oil concentrations as low as 5 mass % significantly reduced the viscosity of HFO at 25 and 50 °C. Aging studies at 50 and 90 °C showed that the HFO inhibited the polymerization of bio-oil. The heating value and lubricity showed a linear dependency with bio-oil content, and combustion quality was acceptable for blends containing up to 15% bio-oil. The highly acidic bio-oil was found to be corrosive to carbon steel, 2.25Cr-1Mo steel, and 409 stainless steels, but not 304L and 316L. When blended into HFO at levels less than 19 mass %, no measurable corrosion was observed on any of the steel materials, but a 50 mass % concentration produced low-to-moderate corrosion in the carbon steel, 2.25Cr-1Mo steel, and 409 stainless steel grades. The combination of good blend stability, polymerization inhibition, reduced viscosity, and acceptable compatibility for low blend levels suggests that bio-oils may be suitable for use as a marine fuel.

09 BIOMASS FUELS↗

Studies for improved high temperature coatings for Space Shuttle application

Improvement of the current Class 2 Space Shuttle Orbiter RCG coating was experimentally investigated.Coatings, which are applied to LI-900 or LI-2200 tiles, were prepared to provide increased performance in thermal expansion, impact, residual strain and increased viscosity. Turbulent duct arc-plasma tests at NASA/Ames Research Center are continuing on two candidates that show improved low residual strain and increased high temperature viscosity. A coating system with lower fusion-temperature (1950 F) was identified which has the potential of improving tile yield through reduced LI-900 shrinkage and distortion since it can be fused at 250 F lower than the present Class 2 coating.

Creedon, J.↗

Bulk viscosity of nuclear matter with pions in the neutrino-trapped regime

Recent work has shown that a population of thermal pions could modify the equation of state and transport properties of hot and dense neutron-rich matter and introduce new reaction pathways to change the proton fraction. In this article we study their impact on the bulk viscosity of dense matter, focusing on the neutrino-trapped regime that would be realized in neutron star mergers and supernovae. We find that the presence of a thermal population of pions alters the bulk viscosity by modifying the EoS (via the susceptibilities) and by providing new reaction pathways to achieve beta equilibrium. In neutron star merger conditions, the bulk viscosity in neutrino-trapped npeμ matter (without pions) has its peak at temperatures of at most a couple MeV and is quite small at temperatures of tens of MeV. We find that thermal pions enhance the low-temperature peak of the bulk viscosity by a factor of a few and shift it to slightly lower temperatures. At higher temperatures, where the pion abundance is large but the bulk viscosity is traditionally small, pions can increase the bulk viscosity by an order of magnitude or more, although it is still orders of magnitude smaller than its peak value.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Dramatic effect of oxide on measured liquid metal rheology

Liquid metals have traditionally been treated as Newtonian liquids, but several researchers have recently suggested that some metals may shear thin. While apparent shear thinning can be caused by surface oxidation, the reports of shear-thinning metals were investigated using cup and bob type rheometers, which are expected to only be weakly impacted by the surface contamination effects. We show here that even small amounts of oxide on the surface of liquid metals can cause dramatic changes to the measured viscosity of the sample. Using a Searle-type rotational rheometer, we measured the viscosity of eutectic gallium indium and tin in a low-oxygen environment. When either metal is slightly oxidized, the measured viscosity increases by orders of magnitude and the liquid displays erroneous shear-thinning behavior. When the oxide is removed via an active flux, the measured viscosity is Newtonian. The findings outlined here provide insight into the difficulties of measuring the viscosity of easily oxidized liquids and confirm that liquid metals are likely best described as Newtonian liquids at all measured shear rates.

36 MATERIALS SCIENCE↗

Fluid Merging Viscosity Measurement (FMVM) Experiment on the International Space Station

The concept of using low gravity experimental data together with fluid dynamical numerical simulations for measuring the viscosity of highly viscous liquids was recently validated on the International Space Station (ISS). After testing the proof of concept for this method with parabolic flight experiments, an ISS experiment was proposed and later conducted onboard the ISS in July, 2004 and subsequently in May of 2005. In that experiment a series of two liquid drops were brought manually together until they touched and then were allowed to merge under the action of capillary forces alone. The merging process was recorded visually in order to measure the contact radius speed as the merging proceeded. Several liquids were tested and for each liquid several drop diameters were used. It has been shown that when the coefficient of surface tension for the liquid is known, the contact radius speed can then determine the coefficient of viscosity for that liquid. The viscosity is determined by fitting the experimental speed to theoretically calculated contact radius speed for the same experimental parameters. Experimental and numerical results will be presented in which the viscosity of different highly viscous liquids were determined, to a high degree of accuracy, using this technique.

Antar, Basil N.↗

Synergistic effect of dual Brønsted acidic deep eutectic solvents for oxidative desulfurization of diesel fuel

Deep eutectic solvents (DESs) are generally used as attractive solvents or extractants rather than catalysts in the field of synthesis and separation. Herein, dual Brønsted acidic DESs were prepared by mixing sulfonated quaternary ammonium and oxalic acid as extractants and catalysts for deep oxidative desulfurization. Compared to the DESs with single acidic group, the dual acidic DESs exhibited much higher catalytic activity likely due to the synergistic effect. The 1 H NMR study indicated that the weak interaction between DES and sulfur compounds led to a low extraction capacity. However, the sulfur removal could reach 97.7% under optimized reaction conditions. Density functional theory (DFT) calculations demonstrated that sulfonic group and carboxylic group are of equal importance to desulfurization performance. Further, the desulfurization efficiency was also strongly affected by the viscosity of DESs. Here, we put forward a new strategy that the reaction time could be sharply shortened to 40 min and 100 min by adding low viscous acetonitrile and polyethylene glycol into DES to form mixing reaction system, respectively.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗