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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1984

An analysis of return flux from the Space Shuttle Orbiter RCS engines

The return flux from the Space Shuttle Orbiter reaction control system (RCS) engines to sensors in the open payload bay has been analyzed on the basis of Shuttle/Payload Contamination Evaluation (SPACE II) model predictions and orbital flight measurements. Model data are presented showing the variations of molecular return flux values with Orbiter orientation and instrument direction. The effects of multiple molecular collisions within RCS engine plumes and in their vicinity are discussed. These collisions significantly influence the amount of plume molecules returning to payload instruments and, therefore, the amount of contaminants received.

Ehlers, H. K. F.↗

NASA NTRS1990

Thermal structure of neutral winds from young stellar objects

The physical processes that control the thermal structure of lightly ionized winds from cool protostars are discussed. Attention is concentrated on the hydrogen gas, and the heating, cooling, and chemical processes that affect the neutral and ionic species of atomic and molecular hydrogen are examined. Warm silicate dust may condense out of the cooling wind and may heat the gas through collisions. Singly ionized sodium atoms, which do not recombine for the mass-loss rates considered, set a lower limit to the ionization fraction in the wind. Magnetic fields, which are presumed to accelerate the wind, couple directly to the ionic component of the gas and transfer momentum and energy to the neutral component through collisions. This process of ambipolar diffusion is found to be the dominant source of heat input to the gas.

Ruden, Steven P.↗

NASA NTRS2003

Capabilities of the Materials Contamination Team at Marshall Space Flight Center

The Materials Contamination Team at the Marshall Space Flight Center (MSFC) has been recognized for its contributions supporting the National Aeronautics and Space Administration (NASA) spacecraft development programs. These programs include the Reusable Solid Rocket Motor (RSRM), Chandra X-Ray Observatory, and the International Space Station (ISS). The Environmental Effects Group, with the Materials Contamination Team and the Space Environmental Effects Team has been an integral part of NASA's success by the testing, evaluation, and qualification of materials, hardware, and processes. This paper focuses on the capabilities of the Materials Contamination Team. The Materials Contamination Team's realm of responsibility includes establishing contamination control during all phases of hardware development, including design, manufacturing, assembly, test, transportation, launch site processing, on-orbit exposure, return, and refurbishment. The team continues its mission of reducing the risk of equipment failure due to molecular or particulate contamination. Contamination is a concern in the Space Shuttle with sensitive bond-lines and reactive fluid (liquid oxygen) compatibility as well as for spacecraft with sensitive optics, such as Hubble Space Telescope and Chandra X-ray Observatory. The Materials Contamination Team has a variety of facilities and instrumentation capable of contaminant detection, identification, and monitoring. The team addresses material applications dealing with environments, including production facilities, clean rooms, and on-orbit exposure. The optically stimulated electron emission (OSEE) system, the Ultraviolet (UV) fluorescence (UVF) surface contamination detection, and the Surface Optics Corporation 400 (SOC 400) portable hand-held Fourier Transform Infrared (FTIR) spectrometer are state-of-the-art tools for in-process molecular contamination detection. The team of engineers and technicians also develop contamination calibration standards and evaluate new surface cleanliness inspection technologies. The team utilizes facilities for on-orbit simulation testing of materials for outgassing and molecular film deposition characteristics in the presence of space environmental effects, such as Atomic Oxygen (AO) and UV radiation exposure. The Materials Contamination Team maintains databases for process materials as well as outgassing and optical compatibility test results for specific environments.

Burns, Howard↗

NASA NTRS2002

The mammalian retina as a clock

Many physiological, cellular, and biochemical parameters in the retina of vertebrates show daily rhythms that, in many cases, also persist under constant conditions. This demonstrates that they are driven by a circadian pacemaker. The presence of an autonomous circadian clock in the retina of vertebrates was first demonstrated in Xenopus laevis and then, several years later, in mammals. In X. laevis and in chicken, the retinal circadian pacemaker has been localized in the photoreceptor layer, whereas in mammals, such information is not yet available. Recent advances in molecular techniques have led to the identification of a group of genes that are believed to constitute the molecular core of the circadian clock. These genes are expressed in the retina, although with a slightly different 24-h profile from that observed in the central circadian pacemaker. This result suggests that some difference (at the molecular level) may exist between the retinal clock and the clock located in the suprachiasmatic nuclei of hypothalamus. The present review will focus on the current knowledge of the retinal rhythmicity and the mechanisms responsible for its control.

Review Literature↗

NASA NTRS2002

A genomic regulatory network for development

Development of the body plan is controlled by large networks of regulatory genes. A gene regulatory network that controls the specification of endoderm and mesoderm in the sea urchin embryo is summarized here. The network was derived from large-scale perturbation analyses, in combination with computational methodologies, genomic data, cis-regulatory analysis, and molecular embryology. The network contains over 40 genes at present, and each node can be directly verified at the DNA sequence level by cis-regulatory analysis. Its architecture reveals specific and general aspects of development, such as how given cells generate their ordained fates in the embryo and why the process moves inexorably forward in developmental time.

Non-NASA Center↗

NASA NTRS2022

A Multi-omics Longitudinal Study of the Murine Retinal Response to Chronic Low-dose Irradiation and Simulated Microgravity

The space environment includes unique hazards like radiation and microgravity which can adversely affect biological systems. We assessed a multi-omics NASA GeneLab dataset where mice were hindlimb unloaded and/or gamma irradiated for 21 days followed by retinal analysis at 7 days, 1 month or 4 months post-exposure. We compared time-matched epigenomic and transcriptomic retinal profiles resulting in a total of 4,178 differentially methylated loci or regions, and 457 differentially expressed genes. Highest correlation in methylation difference was seen across different conditions at the same time point. Nucleotide metabolism biological processes were enriched in all groups with activation at 1 month and suppression at 7 days and 4 months. Genes and processes related to Notch and Wnt signaling showed alterations 4 months post-exposure. A total of 23 genes showed significant changes in methylation and expression compared to unexposed controls, including genes involved in retinal function and inflammatory response. This multi-omics analysis interrogates the epigenomic and transcriptomic impacts of radiation and hindlimb unloading on the retina in isolation and in combination and highlights important molecular mechanisms at different post-exposure stages.

Prachi Kothiyal↗

NASA NTRS2011

Microfabrication of a High-Throughput Nanochannel Delivery/Filtration System

A microfabrication process is proposed to produce a nanopore membrane for continuous passive drug release to maintain constant drug concentrations in the patient s blood throughout the delivery period. Based on silicon microfabrication technology, the dimensions of the nanochannel area, as well as microchannel area, can be precisely controlled, thus providing a steady, constant drug release rate within an extended time period. The multilayered nanochannel structures extend the limit of release rate range of a single-layer nanochannel system, and allow a wide range of pre-defined porosity to achieve any arbitrary drug release rate using any preferred nanochannel size. This membrane system could also be applied to molecular filtration or isolation. In this case, the nanochannel length can be reduced to the nanofabrication limit, i.e., 10s of nm. The nanochannel delivery system membrane is composed of a sandwich of a thin top layer, the horizontal nanochannels, and a thicker bottom wafer. The thin top layer houses an array of microchannels that offers the inlet port for diffusing molecules. It also works as a lid for the nanochannels by providing the channels a top surface. The nanochannels are fabricated by a sacrificial layer technique that obtains smooth surfaces and precisely controlled dimensions. The structure of this nanopore membrane is optimized to yield high mechanical strength and high throughput.

Ferrari, Mauro↗

NASA NTRS2022

Controlling Triboelectrification Effects on Spacecraft Ethernet Cabling

Triboelectric charging of a spacecraft and launch vehicles on ascent may occur due to the process of contact and separation between the vehicle skin and aerosols, dust, ice, water droplets, smoke, and other particulates encountered in the flight path. Depending on characteristics at the atomic and molecular levels of the vehicle skin’s surface and the substances and particulates encountered, electrical charge will transfer between the vehicle and the encountered substances, resulting in an accumulation of electrical charge on the vehicle skin. If the vehicle skin is conductive and electrically bonded such that in its entirety it presents an equipotential surface, then the accumulated electrical charge will spread in a nearly uniform manner leaving all regions with a nearly equal potential with respect to each other and the surrounding environment. Regions that are not electrically bonded as described, or surfaces that have resistivity values, can reach different potentials than the surrounding surfaces. When this happens, the differing potentials may grow to very large magnitudes, leading to electrostatic discharge events between the regions. As the vehicle rises in altitude, the breakdown potential between these regions of differing potential decreases commensurate with decreases in atmospheric density and pressure. If the potential differences between surfaces of the vehicle become equal to or exceed the breakdown potential, one or more discharge events may occur, each of them generating voltage and current transients that can easily damage or interfere with the designed operation of on-board electrical, avionic, and communications and navigation systems. This lesson learned discusses an in-flight anomaly caused by triboelectric discharge events and exacerbated by the lack of adequate cable shielding that affected flight computer communication links. Also discussed are mitigations to prevent this occurrence.

Ethernet↗

NASA NTRSDate not supplied

Particle Seeding Method for Small-Scale, High-Pressure Nozzles

NASA tests new launch and reentry vehicle configurations in wind tunnels, where flow visualizations and quantitative flowfield measurements are often desired. Some of these vehicles have rocket motors for propulsion, retro-propulsion, or reaction control. High-pressure air is used to supply these rocket motor plumes. However, it is difficult to make off-body measurements in these regions, for several reasons. First, the plumes themselves lack seeding particles for flow diagnostics, and at the low pressures after expansion, Rayleigh scattering or other molecular techniques yield insufficient signal for flow velocity measurements. Second, the plumes displace particle-seeded tunnel air, preventing measurements in the vicinity of the plume. Third, the plumes force shock waves ahead of the vehicle, which melts the ice crystal fog commonly used for visualization and measurement techniques in certain facilities. In the current work, a novel method for seeding the flow in these small-scale, high-pressure nozzles has been devised and initially demonstrated, potentially enabling quantitative and qualitative measurements with particle-based instruments such as Doppler global velocimetry or particle image velocimetry. The method involves a Venturi contraction to draw the seed liquid out of a reservoir and into the nozzle channel, wherein shearing forces atomize the seed into particles. The concept was tested with a laser sheet visualization, which demonstrated that the flow rate of liquid spray was controllable; a valve could be adjusted to drop the flow rate by up to 65%. This relatively inexpensive and simple technique may prove useful in wind tunnel experiments involving particle-based laser diagnostics and small, high-pressure nozzles.

Aditya S. Acharya↗

NASA NTRSDate not supplied

Particle Seeding Method for Small-Scale, High-Pressure Nozzles

lasers↗

NASA NTRS1961

Stability of Titanium Nitride and Titanium Carbide When Exposed to Hydrogen Atoms from 298 to 1950 K

Titanium nitride and titanium carbide deposited on tungsten wires were exposed to hydrogen atoms (10(exp -4) atm pressure) produced by the action of microwave radiation on molecular hydrogen. The results of these experiments in the temperature range 298 to 1950 K indicate that no appreciable reaction takes place between atomic hydrogen and TiN or TiC. The formation of reaction products (NH3, CH4, C2H2) should be favored at lower temperatures. However, because of the high catalytic activity of Ti for H atom recombination, the rate of such reactions with H atoms is controlled by the rate of evaporation of Ti from the surface, this rate being low at temperatures below 1200 K. In order to interpret the stability of TiN and TiC in H atoms more fully, the stability of TiN and TiC in vacuum and H2 gas was also studied. The thermodynamic computations conform in order of magnitude to the experimentally found rates of decomposition of TiN and TiC in vacuum and are also consistent with the fact that no appreciable reaction is found with these compounds in molecular H2 at a pressure of 10(exp -3) atmosphere in the temperature range 2980 to 2060 K. When TiN or TiC was heated in atomic H or molecular H2, no reaction products other than those obtained from the simple decomposition of the nitride and carbide were observed. The gaseous products were analyzed in a mass spectrometer.

Philipp, Warren H.↗

NASA NTRS1991

A method of producing high quality oxide and related films on surfaces

Aluminum oxide or aluminum nitride films were deposited on molecular beam epitaxy (MBE) grown GaAS(100) using a novel cryogenic-based reactive thin film deposition technique. The process involves the condensation of molecular oxygen, ammonia, or other gases normally used for reactive thin film deposition on the substrate before the metal is deposited. The metal vapor is deposited into this layer and reacts with the molecular solid to form the desired compound or a precursor that can be thermally decomposed to generate the desired compound. The films produced by this method are free of impurities, and the low temperatures can be used to control the film and interfacial structure. The process can be easily integrated with existing MBE systems. Ongoing research using the same apparatus suggests that photon or electron irradiation could be used to promote the reactions needed to produce the intended material.

Ruckman, Mark W.↗

NASA NTRS2002

Radiation Effect on Human Tissue

Predicting the occurrence of human cancer following exposure of an epidemiologic population to any agent causing genetic damage is a difficult task. To an approximation, this is because the uncertainty of uniform exposure to the damaging agent, and the uncertainty of uniform processing of that damage within a complex set of biological variables, degrade the confidence of predicting the delayed expression of cancer as a relatively rare event within clinically normal individuals. This situation begs the need for alternate controlled experimental models that are predictive for the development of human cancer following exposures to agents causing genetic damage. Such models historically have not been of substantial proven value. It is more recently encouraging, however, that developments in molecular and cell biology have led to an expanded knowledge of human carcinogenesis, and of molecular markers associated with that process. It is therefore appropriate to consider new laboratory models developed to accomodate that expanded knowledge in order to assess the cancer risks associated with exposures to genotoxic agents. When ionizing radiation of space is the genotoxic agent, then a series of additional considerations for human cancer risk assessment must also be applied. These include the dose of radiation absorbed by tissue at different locations in the body, the quality of the absorbed radiation, the rate at which absorbed dose accumulates in tissue, the way in which absorbed dose is measured and calculated, and the alterations in incident radiation caused by shielding materials. It is clear that human cancer risk assessment for damage caused by ionizing radiation is a multidisciplinary responsibility, and that within this responsibility no single discipline can hold disproportionate sway if a risk assessment model of radiation-induced human cancer is to be developed that has proven value. Biomolecular and cellular markers from the work reported here are considered for use in assessing human cancer risk related to exposure to space radiation. This potential use must be integrated within the specified multidisciplinary context in order to create a new tool of molecular epidemiology that can hopefully then realistically assess this cancer risk.

Richmond, Robert C.↗

NASA NTRS2015

Lotus Dust Mitigation Coating and Molecular Adsorber Coating

NASA Goddard Space Flight Center has developed two unique coating formulations that will keep surfaces clean and sanitary and contain contaminants.The Lotus Dust Mitigation Coating, modeled after the self-cleaning, water-repellant lotus leaf, disallows buildup of dust, dirt, water, and more on surfaces. This coating, has been successfully tested on painted, aluminum, glass, silica, and some composite surfaces, could aid in keeping medical assets clean.The Molecular Adsorber Coating is a zeolite-based, sprayable molecular adsorber coating, designed to prevent outgassing in materials in vacuums. The coating works well to adsorb volatiles and contaminates in manufacturing and processing, such as in pharmaceutical production. The addition of a biocide would also aid in controlling bacteria levels.

protective coatings↗

NASA NTRSDate not supplied

25 Years of Contamination Control on the James Webb Space Telescope

The James Webb Space Telescope (JWST) has actively been in process since 1996, and at last, on Christmas Day 2021, it launched. This launch was the fulfillment of an astounding level of work performed by thousands of people across the globe in dozens of disciplines. From the start, effective contamination control (CC) was considered essential for the JWST mission due to the large, exposed optics and tight sensitivity required to measure first light and faint signals at the dawn of the universe. This presentation will present the JWST mission and requirements overview, including mission requirements that led to optimizing performance for collecting light in the Near Infrared (NIR, 0.6μm) – Mid Infrared (MIR, 29μm) range. Molecular films absorb in the IR bands and can alter thermal emissivity, resulting in increased noise at the longer wavelengths (MIRI). Particles increase light scatter and background noise levels at the shorter wavelengths (NIRSpec, NIRCam and FGS). The passively cooled design of JWST led to an open architecture for the optical telescope element (OTE), presenting the challenge of maintaining cleanliness throughout assembly, integration, and test in a multitude of environments for over 2 decades. The presentation will describe CC for the mission starting with the first architecture in 1996, then introducing the specific areas of contamination control developed and advanced to keep JWST clean at an unsurpassed level of cleanliness.

Contamination Control↗

NASA NTRS1986

Characterization of the relationship of the cure cycle chemistry to cure cycle processing properties

Dynamic Dielectric measurements made over a wide range of frequency provide a sensitive and convenient means for monitoring the cure process in thermosets and thermoplastics. The measurement of dielectric relaxation is one of only a few instrumental techniques available for studying molecular properties in both the liquid and solid states. Furthermore, it is probably the only convenient experimental technique for studying the polymerization process of going from a monomeric liquid of varying viscosity to a crosslinked, insoluble, high temperature solid. The objective of the research is to develop on-line dielectric instrumentation for quantitative nondestructive material evaluation and closed loop smart cure cycle control. The key is to relate the chemistry of the cure cycle process to the dielectric properties of the polymer system by correlating the time, temperature, and frequency dependent dielectric measurements with chemical characterization measurements. Measurement of the wide variation in magnitude of the complex permittivity with both frequency and state of cure, coupled with chemical characterization work, have been shown in the laboratory to have the potential to determine: resin quality, composition and age; cure cycle window boundaries; onset of flow and point of maximum flow; extent of and completion of reaction; evolution of volatiles; T sub g; and, crosslinking and molecular weight buildup.

Kranbuehl, D. E.↗

NASA NTRS1970

Atmospheric composition affects heat- and mass-transfer processes

For environmental control system functions sensitive to atmospheric composition, components are test-operated in helium-oxygen and nitrogen-oxygen mixtures, pure oxygen, and air. Transient heat- and mass-transfer tests are conducted for carbon dioxide adsorption on molecular sieve and for water vapor adsorption on silica gel.

Blakely, R. L.↗

NASA NTRS1982

A technology program for the development of the large deployable reflector for space based astronomy

Technologies for the development of the Large Deployable Reflector (LDR), a NASA project for the 1990's, for infrared and submillimeter astronomy are presented. The proposed LDR is a 10-30 diameter spaceborne observatory operating in the spectral region from 30 microns to one millimeter, where ground observations are nearly impossible. Scientific rationales for such a system include the study of ancient signals from galaxies at the edge of the universe, the study of star formation, and the observation of fluctuations in the cosmic background radiation. System requirements include the ability to observe faint objects at large distances and to map molecular clouds and H II regions. From these requirements, mass, photon noise, and tolerance budgets are developed. A strawman concept is established, and some alternate concepts are considered, but research is still necessary in the areas of segment, optical control, and instrument technologies.

Kiya, M. K.↗