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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Named Data Networking for DER Cybersecurity

We present our research findings on the novel NDN protocol. In this work, we defined key attack scenarios for possible exploitation and detail software security testing procedures to evaluate the security of the NDN software. This work was done in the context of distributed energy resources (DER). The software security testing included an execution of unit tests and static code analyses to better understand the software rigor and the security that has been implemented. The results from the penetration testing are presented. Recommendations are discussed to provide additional defense for secure end-to-end NDN communications.

97 MATHEMATICS AND COMPUTING↗

Investigation of potential causes of production limiting fouling within SWPF due to mercury solids formation during pH swings within the SWPF process

The Salt Waste Processing Facility (SWPF) goal to investigate the use a high sodium Salt Batch 5 Qualification sample as the radioactive salt solution for mixing tests meant to evaluate the propensity for solids formation between the 5.6 M sodium clarified salt solution (CSS) and scrub solutions (0.05 M HNO 3 and 0.025 M NaOH solutions) during pH changes has been completed at SRNL. The key results and conclusions from this investigation to evaluate the propensity for solids formation between CSS and scrub solutions because of pH fluctuations include the following: None of the 8 test matrices, involving the mixing/titrating of scrub solution with CSS and vice versa, showed any visible evidence for the formation of solids with pH changes. The average turbidity measurements for these 8 tests, excluding test 7, was 21.6 ± 0.4 NTU. This average turbidity value is within 2 sigma of the baseline turbidity value of 20.5 NTU for the CSS only without added scrub solutions. However, only in test 7, which involved the titrating of CSS into dilute nitric acid scrub solution (0.05 M HNO 3 solution), was a small measurable change in the turbidity of the mixture observed at 31.9 ºC. On the other hand, the equivalent test (instantaneous addition of CSS into 0.05 M HNO 3 ) gave an average turbidity measurement value of 21.6 ± 0.6 NTU at a temperature of 24.0 ºC. This difference in turbidity measurement has been attributed to either instrument performance errors or the effect of temperature. It is recommended that these CSS and scrub solution mixing tests be performed with corresponding simulant solutions in a non-radioactive environment. A simulant environment will aid in the full integration of a pH and turbidity meter equipment with the experimental set up. A new detection method, preferable a laser-based method, may be needed in detecting and confirming the precipitation of fine particulates at the right blending times and pH fluctuations in the solution mixtures. On the other hand, the differing free OH concentrations (~2 M in CSS), H + concentrations (0.05 M HNO 3 ) for the titrants and the bulk solutions, may make it almost impossible to observe a neutral pH or a pH in the range of 7-9, where the potential for solids formation is maximized and leads to possible precipitation of minerals like aluminum hydroxides.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of an MC&A toolbox for liquid-fueled molten salt reactors with online reprocessing (Final Report)

A critical barrier to the deployment of MSRs is the absence of a well-defined nuclear material control and accounting (MC&A) approach, a vital prerequisite to meet NRC licensing requirements as well as facilitating future international exports. Liquid-fueled MSR variants (especially those incorporating online refueling or reprocessing) present a unique set of challenges to traditional nuclear material control and accountancy. Unlike solid-fueled light-water reactors, traditional item-counting methods cannot be applied as an accountancy strategy. Rather, MC&A approaches to MSR variants (including both uranium and thorium fueled designs) are more analogous to bulk material handling facilities (e.g., enrichment and reprocessing); yet further complicating matters is the fact that fuel medium is also highly radioactive. Meanwhile, the space of MSRs covers a broad range of design parameters, including thermal and fast spectra designs; operation in actinide breeder or burner modes, choice of actinide fuel used (e.g., 235 U, 232 Th / 233 U, denatured 233 U, etc.), pool or loop-type configuration, and even different salt chemistry. Each of these design choices introduce significant challenges to MC&A approaches within MSR facilities. We propose to bridge this gap for liquid-fueled MSRs by developing a modular, component-based test framework for evaluating viable process monitoring and MC&A techniques specifically suited to liquid-fueled MSR system variants employing online refueling or reprocessing. This test platform will consist of a toolbox of independent process modules representing discrete physical units (such as the reactor core, off-gas processing, decay tanks, and actinide separation units), each with its own self-contained physics responsive to the input mass flow, along with appropriate measurement models that can be coupled to key flow points. These dynamic physical signatures thus afford the ability to test the viability and efficacy of potential accountancy techniques under the full range of reactor operating conditions. As process modules are connected via mass flows, the result is a reconfigurable, generic MSR mass flow model capable of serving as an MC&A test platform for a broad spectrum of possible MSR configurations. The resulting MSR MC&A toolbox will enable robust assessment of accountancy strategies for this unique facility type, including analysis of physical feedbacks arising both from depletion of the fuel over time as well as from potential off-normal events, including those introduced by equipment failures (e.g., a pump failure) as well as by malicious action (i.e., attempts to divert material). The proposed toolbox both addresses a critical needs area for the MPACT analysis toolkit while leveraging existing MPACT-sponsored tools, especially with respect to simulation of measurement and accountancy techniques for advanced fuel cycle facilities. Beyond enabling new analysis capabilities for MSR systems, the design of this toolbox will be to such to maximize compatibility with existing MPACT tools, such to enhance existing facility MC&A analysis capabilities.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Evaluating dynamic thermal performance of building envelope components using small-scale calibrated hot box tests

The hot box test method has been applied to evaluate both the steady-state (U-value) and dynamic thermal properties of building envelopes. However, the high construction cost of full-scale hot box apparatus and the testing time required (usually several days) may prevent its wider adoption. To overcome the limitations of full-scale hot box tests, here we propose a novel method to evaluate the dynamic thermal performance of building envelope components using a small-scale calibrated hot box and scaled-down specimen. In this paper, the scaling relationships of thermal properties evaluated using a full-size specimen and a scaled-down specimen are established based on the Laplace transform of the heat transfer equations. In addition, dynamic thermal properties obtained from scaled-down experimental tests are compared to the values calculated by the EN ISO13768 (ISO) method. A small-scale hot box with a 355 mm × 355 mm metering area was constructed and calibrated to validate the correlations. Three scaled-down concrete sandwich wall panels were then tested and the scaling relationship was cross-validated using the experimental results, finite difference (FD) simulations, and the ISO method. The results indicate that the dynamic thermal properties obtained from a scaled-down hot box test can be correlated to its full-size counterpart when certain conditions are met. The scaled-down hot box test is demonstrated to be an effective yet economical alternative to a full-scale test with significantly reduced experimentation cost and turn-around time.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Experimental Study of Eutectic Molten Salts NaCl/KCl/ZnCl2 Heat Transfer Inside a Smooth Tube for High-Temperature Application

Abstract Eutectic salts NaCl-KCl-ZnCl2 and NaCl-KCl-MgCl2 are two of the chloride salt systems that are promising for being used as high-temperature heat transfer fluid (HTF) and thermal energy storage (TES) materials in a wide range of temperatures from 230 °C to 750 °C in concentrated solar thermal power systems. To conduct measurement of the heat transfer coefficient of the molten salt at high temperatures, a circulation system and instrumentation of flow and heat transfer was constructed. Experimental measurement of the convective heat transfer coefficients of NaCl-KCl-ZnCl2 (molar fraction: 13.8–41.9–44.3%) inside tubes has been accomplished to find the most suitable heat transfer correlations. Experience of salt processing and operation of the high-temperature heat transfer test system was obtained. Two correlations, Dittus-Boelter equation and Gnielinski’s correlation for Nusselt number against Reynolds number and Prandtl number, are evaluated using the test results, and the latter correlation is recommended due to its better agreement of prediction against tested data.

Energy & Fuels↗

Advanced Multi-Tube Mixer Combustion for 65% Efficiency (Final Report)

This project targeted advanced low NOx combustion for advanced gas turbines capable of 65%, or greater, efficiency in combined cycle application. This technology advancement has further potential to benefit gas turbines used in coal based IGCC applications with pre-combustion carbon capture and hydrogen as the resulting fuel. The program developed and synthesized the most advanced combustion system capable of achieving low NOX emissions up to turbine inlet temperatures of 3100F while also supporting the load-following needs of a modern grid. The combustion system contributes to the overall gas turbine efficiency goal by setting the maximum cycle temperature achievable for a given NOX level and by minimizing the through-combustor air flow pressure drop. Focus areas for this project targeted maximizing the turbine inlet temperature entitlement, as constrained by emissions considerations. The design also minimized parasitic air flow pressure drop by using advanced cooling techniques and performance materials selections and by minimizing hot surface area. These two technology objectives (maximum, emissions-compliant cycle temperature and minimum air flow pressure drop) were integrated into a prototype design. The primarily analytical project sought to identify the most promising technologies to meet these objectives. Additional critical “jugular” data were obtained from multi-tube mixer tests to realize the potential of leveraging “micro flames” for minimizing overall hot surface area. This data was used, in conjunction with an understanding of advanced material and cooling design technologies, to analytically develop multiple design concepts. Phase I focused on in-depth engineering analysis and design, with minimal supporting laboratory testing to enable a selection of the top three combustion architectures for achieving these overall objectives. Phase II of the program developed the selected design through a combination of sub-scale testing and analytical efforts. Early tests included a cold-flow cascade to establish aerodynamic performance characteristics and a sub-scale fired test at GE Global Research in Niskayuna, NY, to establish cooling and heat transfer characteristics in conjunction with combustion performance. The data from these tests validated the analytical models to ultimately design a full-scale, test article to evaluate at prototypical pressure and temperature conditions at GE Gas Power’s Gas Turbine Technology Laboratory in Greenville, SC. GE Gas Power also developed, tested, and recommended a suitable seal design to be applied to the unique features of the combustor. To assess the technology challenges from prospective future production of the combustor from a ceramic matrix composite material, screening tests of Environmental Barrier Coatings were completed.

20 FOSSIL-FUELED POWER PLANTS↗

Report on Thermal Cycling Testing and Bimaterial Weld Development for a Passively Actuated Materials Surveillance Test Article

This report describes the continuation and conclusion of a thermal cycling test program designed to evaluate a family of passively actuated material surveillance test articles. Additionally, the report details a preliminary study of bimetallic welding between 316 stainless steel and TZM (tungsten-zirconium-molybdenum) alloy. The test program was ultimately successful in demonstrating the basic viability of the passively actuated test article concept as well as specifically validating the procedures developed to size specimens to mimic the mechanical response of operating components. The report discusses and summarizes the results of the complete test program which tested samples for more than 1,000 controlled thermal cycles. The weld development program included both stir friction and electron beam joining. The stir friction welding was ultimately successful, while the electron beam welding would require additional development. Ultimately, these test programs pave the way for implementing a materials surveillance program in future molten salt reactors (MSRs). The report conclusions outline a plan for transforming the research and developed described here into a definite set of practices and procedures for a surveillance program at a future operating reactor.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Component Modeling, Co-Optimization, and Trade-Space Evaluation (FY2021 Annual Progress Report)

This project is intended to support the development of new traction drive systems that meet the targets of 100 kW/L for power electronics and 50 kW/L for electric machines with reliable operation to 300,000 miles. To meet these goals, new designs must be identified that make use of state-of-the-art and next-generation electronic materials and design methods. Designs must exploit synergies between components, for example converters designed for high-frequency switching using wide band gap devices and ceramic capacitors. This project includes: (1) a survey of available technologies; (2) the development of design tools that consider the converter volume and performance; (3) exercising the design software to evaluate performance gaps and predict the impact of certain technologies and design approaches, i.e. GaN semiconductors, ceramic capacitors, and select topologies; and (4) building and testing hardware prototypes to validate models and concepts. Early instantiations of the design tools enable co-optimization of the power module and passive elements and provide some design guidance; later instantiations will enable the co-optimization of inverter and machine. Prototype testing begins with evaluation of simpler conversion topologies (i.e. the half-bridge boost converter) and progresses with fabrication of prototype inverter drives.

33 ADVANCED PROPULSION SYSTEMS↗

A Kinetic Model of the Long-Term Corrosion of Glass-Ceramic Materials

Multiphase waste forms show promise for increased waste loading and for the ability to dispose of contaminated solid and particulate waste through direct densification. However, achieving predictive capability for long-term durability of multiphase waste forms, and thus assessing their possible deployment, requires expanding the current, limited knowledge base. Here, we describe the development of a corrosion model of a two-phase waste form consisting of crystals of known volume fraction embedded in a glass matrix. This model accounts for the dissolution of both the crystalline and glass phases as well as the hydration of the glass phase through an ion exchange reaction. Because of the large difference in solubility between the two phases, the reactive surface of the crystalline phase is a function of the extent of dissolution of the glass phase in this model. Model parameterization was performed using corrosion data, such as from single-pass flow-through tests, for the individual phases. The parameterized corrosion model was evaluated against static dissolution test data for a glass-ceramic multiphase waste form. This evaluation demonstrated the model’s ability to reproduce the time-dependent release of key tracers of glass and crystalline phase dissolution. Hence, the development of a kinetic model provides a pathway for long-term durability predictions and thus the use of multiphase waste forms in nuclear cleanup missions.

Kerisit, Sebastien N.↗

An Evaluation of the ASM2000 software

The ASM2000 software is based on the NetCAM3 software (currently installed at RLUOB) with the main difference being enhanced multi-CAM head support. Therefore, as the NetCAM3 software has been previously tested, the current evaluation concentrated on performance related to multi-head operation. In addition, bug fixes and improvements to prior versions of the NetCAM3 code were incorporated into the ASM2000 V2.0.0 software package.

97 MATHEMATICS AND COMPUTING↗

Propagating neutronic uncertainties for FFTF LOFWOS Test #13

The safety evaluation conducted for licensing a Sodium-cooled Fast Reactor (SFR) may require modeling transients with best-estimate calculation tools that must first be validated against real-world measurements. To provide the community with a valuable benchmarking opportunity for validating SFR analysis tools and methods, the International Atomic Energy Agency (IAEA) initiated a coordinated research project (CRP) in 2018 for the analysis of the Fast Flux Test Facility (FFTF) Loss of Flow Without Scram (LOFWOS) Test #13. The impact of nuclear data uncertainties on neutronics parameters was previously investigated based on the COMMARA-2.0 covariance matrix. Since the transient simulation results are very sensitive to certain reactivity coefficients, it was decided to employ rigorous uncertainty propagation methods to quantify the impact of nuclear data uncertainties on the best-estimate predication of FFTF LOFWOS Test #13. The DAKOTA code is used to propagate neutronic uncertainties through SAS4A/SASSYS-1 transient simulations, while taking into account spatial and reaction-wise correlations within these uncertainties. This study shows that the remaining discrepancies observed between the Argonne National Laboratory (ANL) best-estimate results and the experimental measurements can be partly explained by the uncertainty associated with Gas Expansion Module (GEM) worth, which contributes the majority of the overall nuclear data uncertainty on the output from the FFTF LOFWOS Test #13 transient simulation. This study also confirmed the importance of including spatial and reaction-wise correlations of nuclear data uncertainties on feedback coefficients in the uncertainty propagation to avoid under-estimating their impact during the transient simulations.

42 ENGINEERING↗

Comprehensive Evaluation for Protective Coatings: Optical, Electrical, Photoelectrochemical, and Spectroscopic Characterizations

Numerous efficient semiconductors suffer from instability in aqueous electrolytes. Strategies utilizing protective coatings have thus been developed to protect these photoabsorbers against corrosion while synergistically improving charge separation and reaction kinetics. Recently, various photoelectrochemical (PEC) protective coatings have been reported with suitable electronic properties to ensure low charge transport loss and reveal the fundamental photoabsorber efficiency. However, protocols for studying the critical figures of merit for protective coatings have yet to be established. For this reason, we propose four criteria for evaluating the performance of a protective coating for PEC water-splitting: stability, conductivity, optical transparency, and energetic matching. We then propose a flow chart that summarizes the recommended testing protocols for quantifying these four performance metrics. In particular, we lay out the stepwise testing protocols to evaluate the energetics matching at a semiconductor/coating/(catalyst)/liquid interface. Finally, we provide an outlook for the future benchmarking needs for coatings.

36 MATERIALS SCIENCE↗

A Mobile Edge Computing Framework for Traffic Optimization At Urban Intersections Through Cyber-Physical Integration

The stop-and-go traffic pattern on urban roads often results in excessive energy consumption because of unnecessary vehicle braking, idling, and accelerations. With the widespread and increased use of automobiles, this traffic pattern creates many negative impacts (e.g., delayed travel time, air pollution, and additional carbon emission) on the sustainability of our cities. Taking advantage of the recent emerging Internet of Things (IoT) and edge computing paradigms, we propose a mobile edge computing framework that integrates the capability of real-time vehicle-to-infrastructure communication and intelligent speed optimization algorithms into a mobile app to optimize individual vehicles' driving speed at signalized intersections. The optimization aims to mitigate the stop-and-go traffic pattern and its undesirable consequences in urban transportation systems. The framework consists of (1) a cyberinfrastructure-enabled dynamic messaging system for retrieving and delivering real-time traffic and signal phase and timing information from IoT-connected signal controllers and sensors, (2) a real-time speed optimization algorithm for generating intelligent speed advisory using vehicle's information (e.g., GPS and driving directions from mobile sensing) and corresponding signal and traffic information, and (3) an ad-hoc mobile computing environment that converts drivers' smartphones into edge devices to host the speed optimization algorithms for enabling intelligent advisory on the vehicle's driving speed within signalized corridors. The paper presents the design and implementation of the proposed framework. Finally, we demonstrate the feasibility, usefulness, and energy-saving benefits of our proposed framework and its prototyping mobile app on urban transportation systems through traffic simulation, real-vehicle laboratory experiments, an evaluative survey, and field communication tests. The simulation-based energy evaluation results show that the 100% usage of the mobile app can achieve 24% energy savings in the transportation system.

33 ADVANCED PROPULSION SYSTEMS↗

Remaining Life Prediction of SNF Storage Canisters Exposed to CISCC Environments

• DOE Standardized SNF Storage Canisters o DOE designed standard spent nuclear fuel (SNF) storage canisters for storage of DOE SNF. o DOE canisters are significantly different from commercial MultiPurpose Canisters (MPC) in size. o MPC canisters are large, a height = 15.8 ft, OD = 68”, WT = 0.5”. o DOE canisters are small with 18” / 24” diameter, 10’ / 15’ length. • Integrity Evaluation of DOE versus MPC Canisters o Many investigations have been performed for MPC canisters. o Limit investigations were performed for DOE standard canisters. Most were done at Idaho National Lab (INL). o DOE has sponsored integrity studies to evaluate weld integrity using drop tests and FEA simulations. o No evaluation on CISCC/service life of DOE canister in literature. o MPC canister: 4 axial welds, 1 center girth weld, 2 closing welds.

ZHU, Xiankui↗

Recent High Burnup LOCA Testing at Oak Ridge National Laboratory

To improve fuel cycle economics, increasing the fuel burnup limit in light-water reactors requires a solid technical foundation. Observations from experiments at Halden and Studsvik highlighted severe fuel fragmentation during loss-of-coolant-accident (LOCA) conditions, indicating a need for further technical considerations. These experiments suggest that the fragmentation threshold for high-burnup fuel might be influenced by pre-transient power levels. Consequently, additional LOCA test data are essential to complement existing findings and to deepen our understanding. Oak Ridge National Laboratory’s Severe Accident Test Station has been instrumental in advancing knowledge about high-burnup fuel fragmentation, relocation, and dispersal. This milestone report details two high-burnup LOCA tests designed to evaluate the effects of terminal temperature and grid spacers (or cladding restraints) on fuel fragmentation and relocation susceptibility. In addition, BISON fuel performance modeling and out-of-cell benchmark testing were conducted to better interpret the in-cell test results. These tests were developed in collaboration with fuel vendors to ensure that the results provide valuable data for topical reports and support the Nuclear Regulatory Commission’s review.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Predicting EBC Temperature Limits for Industrial Gas Turbines

Higher turbine inlet temperatures may require the use of ceramic matrix composites (CMC) such as SiC/SIC, which require environmental barrier coatings (EBCs) to protect them against the detrimental effect of water vapor. Here, the goal of this project is to determine the maximum bond coating temperature for EBCs for land-based turbines, where the minimum coating lifetime is 25,000 h. If the temperature exceeds the 1414°C melting point of the Si bond coating, then coatings without a bond coating also need to be evaluated. Thus, current Yb 2 Si 2 O 7 EBCs with a Si bond coating and next-generation EBCs without a Si bond coating are being evaluated in laboratory testing using 1-h cycles in air+90%H 2 O. For this initial work, coatings were deposited on CVD SiC coupons. Reaction kinetics at 1250°, 1300° and 1350°C have been evaluated by measuring the thickness of the thermally grown silica scale after 100–500 h exposures. For comparison, scale growth rates for uncoated SiC and Si specimens in dry and wet environments were included as minimum and maximum values, respectively. Based on a critical scale thickness failure criteria, estimated maximum temperatures were calculated for both EBC systems using this initial data.

42 ENGINEERING↗

Gimballed Tracking Mount Pointing Angle Qualification

Tonopah Test Range (TTR), in support of its testing mission and modernization effort acquired a fleet of new gimballed tracking mounts (GTMs) manufactured by BAE Systems. The new GTMs can be operated remotely during flight tests and provide near real-time target tracking data. Furthermore, test vehicle Time-Space-Position-Information (TSPI) is evaluated using post-test synchronized imagery and pointing angle measurements acquired from each tracking mount. To comply with the Nuclear Enterprise Assurance Program (NEAP), all measurements devices must be certified. In keeping with the NEAP program, qualification of the new GTMs have been assessed to confirm that their pointing angle measurements produce acceptable TSPI results. This study only evaluated the four GTMs as a stand-alone solution and found that the GTMs meet their performance requirement of 0.006 degrees RMS error (or less) for post-processed pointing angles and produced TSPI solution with error volumes on the order of one meter or less. The new GTMs will be utilized in combination with existing optical tracking mounts, which will only improve the accuracy of the resulting TSPI data product. Details regarding the approach, analysis, summary results, and conclusions are presented.

42 ENGINEERING↗

Medium Energy Electron Flux in Earth's Outer Radiation Belt (MERLIN): A Machine Learning Model

The radiation belts of the Earth, filled with energetic electrons, comprise complex and dynamic systems that pose a significant threat to satellite operation. While various models of electron flux both for low and relativistic energies have been developed, the behavior of medium energy (120–600 keV) electrons, especially in the MEO region, remains poorly quantified. At these energies, electrons are driven by both convective and diffusive transport, and their prediction usually requires sophisticated 4D modeling codes. In this paper, we present an alternative approach using the Light Gradient Boosting (LightGBM) machine learning algorithm. The Medium Energy electRon fLux In Earth's outer radiatioN belt (MERLIN) model takes as input the satellite position, a combination of geomagnetic indices and solar wind parameters including the time history of velocity, and does not use persistence. MERLIN is trained on >15 years of the GPS electron flux data and tested on more than 1.5 years of measurements. Tenfold cross validation yields that the model predicts the MEO radiation environment well, both in terms of dynamics and amplitudes o f flux. Evaluation on the test set shows high correlation between the predicted and observed electron flux (0.8) and low values of absolute error. The MERLIN model can have wide space weather applications, providing information for the scientific community in the form of radiation belts reconstructions, as well as industry for satellite mission design, nowcast of the MEO environment, and surface charging analysis.

79 ASTRONOMY AND ASTROPHYSICS↗