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2018 Annual Site Environmental Report

Los Alamos National Laboratory’s (the Laboratory’s) annual site environmental reports are prepared annually by the Laboratory’s environmental organizations, as required by U.S. Department of Energy Order 231.1B, Administrative Change 1, Environment, Safety, and Health Reporting, and Order 458.1, Administrative Change 3, Radiation Protection of the Public and the Environment. The following chapters in this report discuss our success in complying with environmental laws, regulations, and orders (Chapter 2, Compliance Summary); how we manage the Laboratory’s environmental performance (Chapter 3, Environmental Programs); how we monitor for air emissions of radioactive materials and climate conditions (Chapter 4, Air Quality); how we monitor for effects of Laboratory operations on groundwater quality (Chapter 5, Groundwater Monitoring); how we monitor the movement of chemicals and radionuclides by storm water runoff and the levels of chemicals and radionuclides in deposited sediment (Chapter 6, Watershed Quality); how we monitor for the presence, levels, and effects of chemicals and radionuclides in plants, animals, soil, and vegetation (Chapter 7, Ecosystem Health); and finally, what radionuclide dose or risk from chemical exposure members of the public may experience as a result of Laboratory operations (Chapter 8, Public Dose and Risk Assessment). This report follows plain language guidelines, as required for federal agencies by the Plain Language Act of 2010. More information about plain language can be found at http://www.plainlanguage.gov/index.cfm. You will notice we have substantially reduced the use of acronyms and abbreviations and are using active voice and personal pronouns. We hope you find this report useful. If you have suggestions for improving this report, additional questions, or want a copy of this report, please contact us at envoutreach@lanl.gov, or call the Communications Office at 505-665-7000. This report, its supplemental tables, and the 2018 Annual Site Environmental Report Summary are available at http://www.lanl.gov/environment/environmental-report.php. Note: This document has been revised since it was initially published on September 23, 2019. The revisions included corrections to figure and table references, changes in heading levels, adding blank pages where appropriate, and changes of an editorial nature.

54 ENVIRONMENTAL SCIENCES↗

GEMINI Case Study

Sandia's GEMINI-Scout Mine Rescue Robot is an unmanned ground vehicle designed to enter potentially hazardous environments to explore, assess, and evaluate dangerous situations first responders may face when conducting a rescue mission. GEMINI is approximately four feet long and two feet tall, which enables the robot to maneuver through small locations on rough terrains caused by earthquakes, fires, or radiological incidents. GEMINI uses track propulsion to climb stairs, travel through gravel and sand pits, pivot in place, and traverse 45-degree climbs with few problems. Furthermore, the vehicle's dual tracked-chassis design allows it to operate in hostile, dark, muddy, high-temperature, and explosive debris-strewn environments, while maintaining efficient ground mobility. The mobility and modularity of the vehicle allow for easy integration of sensors to conduct gas and temperature sensing and offers pan/tilt, zoom color, and thermal camera video streaming capabilities. The vehicle is also able to carry a payload of about 50 pounds of batteries and can handle an additional 200 pounds of payload, whether for additional diagnostics, supplies, or clothing for those trapped in an effected area. GEMINI is remotely operated through a wireless connection and an onboard computer running a customized embedded control application, which directly communicates to all onboard components except for the audio and video systems. When line of sight is not possible, operators use a shockresistant fiber optic cable to ensure continuous functionality of the vehicle. This allows for direct local control of the vehicle, which streams collected data back to the operator for enhanced situational awareness. In addition, the vehicle incorporates safety features such as explosion proof housing to ensure safe electronic operations in hazardous gas or flooded environments; a four-channel video link and two-way audio to ensure located survivors can communicate with operators; and an MSHA-approved multi-gas sensor to monitor air quality.

42 ENGINEERING↗

Sequim Campus Master Plan

Based in Richland, Washington, Pacific Northwest National Laboratory (PNNL) is one of ten U.S. Department of Energy (DOE) Office of Science (SC) national laboratories. PNNL is DOE’s premier chemistry, earth sciences, and data analytics laboratory, delivering vital mission impacts in energy resiliency and national security. PNNL has 19 core capabilities, each a powerful combination of world-class staff, state-of-the- art equipment, and mission-ready facilities. These capabilities represent a collective set of skills and a body of world-leading scientific and engineering work that provides exceptional value and mission delivery to DOE, the National Nuclear Security Administration (NNSA), the U.S. Department of Homeland Security (DHS), and other federal agencies and industry through strategic partnership projects on a not-to-interfere basis. Currently operated by Battelle Memorial Institute, PNNL occupies more than 2.3 million gross square feet (GSF) of buildings and employs approximately 4,700 staff members. PNNL has implemented a rolling 10-year campus strategy, initiated in fiscal year 2013, designed to deliver the foundation for the multidisciplinary science and engineering expertise, equipment, instrumentation, facilities, and infrastructure required to continue providing exceptional value and mission delivery. This strategy is incorporated into PNNL’s annual Laboratory Plan, which serves as DOE-SC’s equivalent of the Five- Year Site Plan required by DOE Order 430.1C Chg. 1, Real Property Asset Management. The PNNL Sequim Campus is located in Clallam County, just outside of Sequim, Washington. PNNL Sequim builds upon a rich history of research related to marine and coastal resources, environmental chemistry, water resources modeling, ecotoxicology, biotechnology, and national security. Facilities at the PNNL Sequim Campus were designed to take advantage of two unique locational assets: the pristine coastal ocean water in Sequim Bay and the region’s exceptionally clean air. Research facilities on the waterfront are supplied with up to 200 gallons per minute (gpm) of seawater and/or groundwater that enables research on aquatic systems ranging from fully seawater to fresh water, with an onsite water treatment system that removes all biological and hazardous chemical residues prior to discharge. Multiple large seawater tanks outside the waterfront laboratories, along with a boat ramp, pier, and floating dock, enable lab-to-field research. The uplands facility takes advantage of the amazing air quality and is built and operated to enable ultratrace chemical/radiological analytical chemistry. This combination of capabilities is not available at any other marine laboratory in the nation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Analysis of the Frequency of Extreme Precipitation Events at Los Alamos National Laboratory

The Environmental Protection and Compliance (EPC) Storm Water Permitting and Compliance Program is currently updating its stormwater compliance standards for the Los Alamos National Laboratory (LANL) Engineering Standards Manual (2015) and is addressing the required current meteorological data needed for storm water applications. Information on the frequency of extreme precipitation events at LANL is needed. In response to this request, LANL Meteorology & Air Quality (MAQ) was tasked to estimate the frequency of extreme precipitation events. An earlier study by Foley (2012) which estimated extreme precipitation rates at LANL for a set of duration periods and average recurrence intervals (return periods) was evaluated. However, it was determined that this study would not be helpful since its technical support documentation was unavailable and the meteorological data and the methodology employed were not well understood. This led to the need to develop a new peer-reviewed methodology. This report documents the development of the new methodology and the application of a temporally representative precipitation dataset from February 1990 through December 2018, monitored at the official LANL meteorological station, Technical Area (TA)-6, to develop the frequency of extreme precipitation events.

54 ENVIRONMENTAL SCIENCES↗

Applying Non-Energy Impacts from Other Jurisdictions in Cost-Benefit Analyses of Energy Efficiency Programs: Resources for States for Utility Customer-Funded Programs

Avoided energy and capacity costs are the primary yardstick utilities use to determine which energy efficiency programs are cost-effective for their customers. But sometimes "non-energy impacts" — not commonly recognized as directly associated with energy generation, transmission and distribution — represent substantial benefits, such as improving comfort, air quality and public health. Considering whether and how to include non-energy impacts is an important part of cost-benefit analyses for these programs. This report offers practical considerations for deciding which non-energy impacts to include and how to apply values or methods from other jurisdictions. Researchers reviewed studies quantifying non-energy impacts used in 30 states and applied a five-point system to indicate transferability of a value or method from each study for 16 categories of non-energy impacts: Water resource costs and benefits; Other fuels costs and benefits; Avoided environmental compliance costs; Environmental impacts; Productivity; Health and safety; Asset value; Energy and/or capacity price suppression effects; Avoided costs of compliance with Renewable Portfolio Standard requirements; Avoided credit and collection costs; Avoided ancillary services; Comfort; Economic development and job impacts; Public health impacts; Energy security impacts; Increased reliability. The U.S. Department of Energy’s Building Technologies Office supported this work.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Final Fugitive Dust Control NOV Causal Report

On June 30, 2020, a Notice of Violation (NOV) was issued by the City of Albuquerque (COA) Environmental Health Department, Air Quality Program. The NOV identified two violations of New Mexico Administrative Code (NMAC) 20.11.20, Fugitive Dust Control, stemming from an August 30, 2019 inspection of the construction site at Sandia/New Mexico (SNL/NM) Building 812. After the August 30 inspection, a Post-Instruction Notification (PIN) was issued to the SNL Construction Facilities Manager. The PIN was acknowledged by Department 4722 and sent to the COA on September 13, 2020 via email. The PIN "Comply by" date was September 13, 2019 was transmitted by National Nuclear Security Administration/ Sandia Field Office (NNSA/SFO) to COA offices on November 12, 2019. The PIN response was 48 business days past due for various reasons which were explored during the causal analysis.

54 ENVIRONMENTAL SCIENCES↗

Preparing Distribution Utilities for Utility-Scale Storage and Electric Vehicles: A Novel Analytical Framework

Emerging distributed energy resources (DERs)—such as solar photovoltaics (PV), battery energy storage systems (BESS), and electric vehicles (EVs)—are expected to increase substantially in India in the coming years following policy-driven targets of the Government of India to modernize its electricity system, reduce greenhouse gas emissions (GHGs), and improve air quality. These emerging technologies can pose challenges to distribution utilities, forcing overhauls in planning and operational practices. They can also create challenges in power system infrastructure planning and cause more frequent system operational violations (e.g., network voltage bounds and loading thresholds) if not properly integrated. The impacts on the localized power distribution grid from these emerging technologies manifest in increased infrastructure investments and erratic shifts in demand patterns. These impacts are not yet well understood, and analytic solutions are not readily available. To address these challenges, the National Renewable Energy Laboratory (NREL), in collaboration with BSES Rajdhani Power Ltd. (BRPL), developed an advanced power distribution system impact analysis framework of BRPL’s distribution system. This framework helps analyze the readiness of the power distribution network to accommodate emerging technologies and the potential opportunities they might introduce. The framework has been predominantly set up to evaluate distributed PV, BESS, and EVs. In this collaboration between NREL and BRPL, we developed and evaluated the framework on two distribution feeders in the BRPL territory for various scenarios of BESS and EVs. BESS are evaluated for their effectiveness on the grid to mitigate present and future feeder overloading scenarios, and they are subsequently analyzed for their costs compared to the costs of traditional upgradation measures. Scenarios include assessing the effects of EV density on grid infrastructure upgrades and interlinking EV management with BESS integration.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Sandia National Laboratories Annual Site Environmental Report, 2019: New Mexico

Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the United States Department of Energy (DOE) National Nuclear Security Administration. The National Nuclear Security Administration’s Sandia Field Office administers the contract and oversees contractor operations at Sandia National Laboratories, New Mexico. Activities at the site support research and development programs with a wide variety of national security missions, resulting in technologies for nonproliferation, homeland security, energy and infrastructure, and defense systems and assessments. DOE and its management and operating contractor are committed to safeguarding the environment, assessing sustainability practices, and ensuring the validity and accuracy of the monitoring data presented in this Annual Site Environmental Report. This report summarizes the environmental protection and monitoring programs in place at Sandia National Laboratories, New Mexico, during calendar year 2019. Environmental topics include air quality, ecology, environmental restoration, oil storage, site sustainability, terrestrial surveillance, waste management, water quality, and implementation of the National Environmental Policy Act. This report is prepared in accordance with and as required by DOE O 231.1B, Admin Change 1, Environment, Safety, and Health Reporting, and has been approved for public distribution.

54 ENVIRONMENTAL SCIENCES↗

Sandia National Laboratories Annual Site Environmental Report, 2019: Tonopah Test Range, Nevada and Kaua'i Test Facility, Hawai'i

Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the United States Department of Energy (DOE) National Nuclear Security Administration. The National Nuclear Security Administration’s Sandia Field Office administers the contract and oversees contractor operations at Sandia National Laboratories, Tonopah Test Range (SNL/TTR) in Nevada and Sandia National Laboratories, Kaua‘i Test Facility (SNL/KTF) in Hawai‘i. Activities at SNL/TTR are conducted in support of DOE weapons programs and have operated at the site since 1957. SNL/KTF has operated as a rocket preparation launching and tracking facility since 1962. DOE and its management and operating contractor are committed to safeguarding the environment, assessing sustainability practices, and ensuring the validity and accuracy of the monitoring data presented in this Annual Site Environmental Report. This report summarizes the environmental protection, restoration, and monitoring programs in place at SNL/TTR and SNL/KTF during calendar year 2019. Environmental topics include air quality, ecology, environmental restoration, oil storage, site sustainability, terrestrial surveillance, waste management, water quality, and implementation of the National Environmental Policy Act. This report is prepared in accordance with and as required by DOE O 231.1B, Admin Change 1, Environment, Safety, and Health Reporting, and has been approved for public distribution.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Catalina Repower Feasibility Study: NREL Phases I & II Summary Report

Engineers at the National Renewable Energy Laboratory (NREL) supported Southern California Edison (SCE) and the United States Environmental Protection Agency (EPA) by conducting technical and economic analyses for energy systems at Santa Catalina (Catalina) Island, which is located 22 miles off the coast of Long Beach, California. This effort was part of a broader Repower Catalina Feasibility Study that was also supported by NV5, an engineering consulting firm and project partner to NREL for this analysis. This document describes NREL’s techno-economic modeling and optimization analysis for the first two phases of this project which focus on supply-side generation and energy storage options for Catalina. SCE’s goal for this analysis is to determine a strategy for electricity generation on Catalina Island that results in lower energy costs, improved energy resiliency, and reduced air emissions. EPA goals for this effort are to reduce emissions of air pollution and encourage renewable energy development on contaminated and formerly contaminated lands when such development is aligned with the community’s vision for the site. Currently, an on-island SCE power plant serves the Catalina Island electrical load with 6 reciprocating diesel generators totaling 9.4 MW; 23 propane-fueled microturbines totaling 1.5 MW; and a 1-MW, 7.2-MWh sodium sulfur battery energy storage system (BESS). In 2017, the electricity consumption on the island was 29.1 GWh, with an average load of 3.3 MW and peak load of approximately 5.5 MW. Considering new environmental standards on diesel generator emissions from California’s South Coast Air Quality Management District, a 60% renewable energy target for 2030 laid out in California’s Senate Bill 100, SCE’s Clean Power Electrification Pathway, and the characteristics of the island’s existing diesel generators, SCE is seeking to evaluate the technical and economic implications of different energy technology options to determine a path forward. Phases I and II of the Repower Catalina Feasibility Study, summarized in this document, evaluated the following: Interconnection with the mainland via an undersea cable; On-island fossil fuel generation, including diesel, propane, and/or liquified natural gas (LNG); On-island renewable energy (RE) technologies, including solar photovoltaics (PV), wind turbines, and wave energy devices; BESS to support the above generation technologies; Initial analysis of the potential impacts of implementing energy efficiency measures. Results indicate strong techno-economic potential for a mix of on-island diesel and/or propane generators, solar PV, BESS, and energy efficiency measures to help SCE and Catalina achieve their goals compliant with California’s emissions and clean energy standards while minimizing electricity life cycle costs (LCC) over the 30-year analysis period. This document summarizes the considerations and findings of Phases I and II, focusing on high-level takeaways from Phase I and more detailed results from Phase II, and discusses a potential path forward for Phase III.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Battery Electric Bus Deployment Considerations in Developing Countries

Electrifying the transportation sector holds many promises and there are numerous strategies for doing so, including the deployment of battery electric buses (BEBs). BEBs can improve air quality (particularly in urban areas), may help curb greenhouse gas emissions, and can have positive impacts on public health and the quality of life for city inhabitants. This fact sheet steps through the six essential BEB considerations: 1) implementation planning, 2) technology selection, 3) economic impacts, 4) charging infrastructure, 5) operational, and 6) maintenance.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Agricultural Impacts on Nitrogen Cycling: Climate and Air Pollution (Final Technical Report)

We have successfully added a parameterization of ammonia emissions from synthetic fertilizer and manure from agriculture to Earth System Models. We have evaluated how emissions change in the future and the processes driving these changes. We have examined the impact of agricultural ammonia emissions on present-day air quality and have evaluated the impact of resolving the emissions with high temporal resolution. We have also examined the impact of how Earth System Models treat the cycling of emissions in soils. Our code, the Flows of Agricultural Nitrogen – version 2 – model (FANv2) has been run in both the CLM framework and the ELM framework. To my knowledge the code has not yet been fully implemented into ELM. Volatilization of ammonia (NH3) from fertilizers and livestock wastes forms a significant pathway of nitrogen losses in agricultural ecosystems and constitutes the largest source of atmospheric emissions of NH3. We have provided a major update to the process model FAN (Flow of Agricultural Nitrogen), which evaluates NH3 emissions interactively within an Earth system model; in this work, the Community Earth System Model (CESM) is used. The updated version (FANv2) includes a more detailed treatment of both physical and agricultural processes, which allows the model to differentiate between the volatilization losses from animal housings, manure storage, grazed pastures, and the application of manure and different types of mineral fertilizers. The modeled ammonia emissions are first evaluated at a local scale against experimental data for various types of fertilizers and manure, and they are subsequently run globally to evaluate NH3 emissions for 2010–2015 based on gridded datasets of fertilizer use and livestock populations. Comparison of regional emissions shows that FANv2 agrees with previous inventories for North America and Europe and is within the range of previous inventories for China. However, due to higher NH3 emissions in Africa, India, and Latin America, the global emissions simulated by FANv2(48 Tg N) are 30 %–40 % higher than in the existing inventories.

54 ENVIRONMENTAL SCIENCES↗

Remote methane sensor for emissions from pipelines and compressor stations using chirped-laser dispersion spectroscopy

Leak rates of methane (CH 4 ) from the natural gas supply chain result in lost profit from unsold product, public safety and property concerns due to potential explosion hazards, and a potentially large source of economic damages from legal liabilities. Yet large measurement challenges exist in identifying and quantifying CH 4 leak rates along the vast number and type of components in the natural gas supply chain. This is particularly true of the “midstream” components involved in the gathering, processing, compression, transmission, and storage of natural gas. This project developed and deployed new advances in chirped laser dispersion spectroscopy (CLaDS) to detect methane leaks from pipelines, compressor stations, and other midstream infrastructure from a remote position (standoff detection). The system was deployed from a van to measure fugitive methane leaks from a local compressor station as a proof-of-concept. The technique was validated through mobile laboratory measurements with in-situ sensors as well as controlled releases of methane. The system also mapped a plume from a controlled release of methane by tracking a small unmanned aerial system (sUAS) that carried a corner cube retroreflector which reflected the beam back to the instrument. The drone-based system quantified a leak rate to within 30% of the actual rate and localized the emission location within 5 m of the actual release location at standoff distances of 25-45 m. This sUAS-reflector tracking approach has benefits for mapping leak locations remotely using small drones flying around a facility. Benefits of a commercial sensor with these capabilities include reductions of leaks for pipeline operators (more profit), earlier detection of leaks to avoid catastrophic explosion hazards for public health and to mitigate property damage, and reduced methane emissions to the atmosphere (improving air quality).

03 NATURAL GAS↗

Co-Generation Wastewater Treatment at Coal-Fired Energy Plants (Final Report)

Steam electric energy generation typically results in the discharge of one or more effluent streams. Coal-fired energy plant air quality regulations have had the effect of transferring pollutants previously in the flue gas to water by means of the flue gas desulfurization (FGD) system. Combined physical-chemical and biological treatment solutions are currently the most economical approach for treating FGD wastewater. Multi-effect evaporators are significantly higher cost but can meet potential upcoming regulations that are more stringent.

01 COAL, LIGNITE, AND PEAT↗

Specifying Calibration of Environmental Sensors

The emergence of the Internet of Things is resulting in an increased ability of devices and systems to share data and is generating increasing interest in integrating sensors into a variety of devices deployed in the built environment. The value of such data is a function of how the data can be used. Data-producing devices and systems that enable valuable use-cases in turn can be seen as more valuable. Lighting systems are particularly interesting platforms for integrated sensors. Both indoor and outdoor lighting devices are becoming more connected, and their location is often ideally suited for hosting environmental sensors that can characterize the properties of indoor or outdoor spaces in ways that support a wide variety of use cases, from improving air quality to supporting fault diagnostics and prediction. The value of environmental-sensor-driven use-cases and the lighting systems that house them is dependent to some degree on sensor accuracy. Environmental sensors utilize a wide variety of sensing techniques or technologies and have varying accuracy. More-accurate, laboratory-grade products or reference standards are often used to characterize, refine, calibrate, adjust, and monitor devices that are deployed, or are intended to be deployed, in physical spaces of interest. Sensors or reference standards need to be calibrated periodically to ensure that their use yields accurate measurements. Calibration needs, however, vary in sophistication, based on user and use-case requirements. This paper provides guidance for evaluating the performance of environmental sensors so as to ensure that they meet user or use-case needs. It describes best practices that have been developed for a) calibrating sensors to ensure some known level of accuracy, and b) determining whether calibration-laboratory accreditation meets user or use-case needs. Excerpts from laboratory scopes of accreditation are shared to reveal the diversity of terminology and format among them. In an effort to aid those who currently have sensors calibrated or who have new or changing needs for sensor calibration, rationale is provided for why a specification might be used to request calibration services that meet specific needs. Commercially available calibration-service providers that are accredited for environmental-sensor calibration are compared and contrasted, and a specification template that might be used for requesting this calibration is presented. The specification template should be tailored to meet each user’s needs. To illustrate, an example set of environmental-sensor test conditions (reflecting the planned usage of the device to be calibrated) is used to develop a customized calibration specification, and commercially available service providers are assessed in terms of their qualifications for calibration to that particular implementation of the specification template.

42 ENGINEERING↗

2020 Annual Site Environmental Report for Sandia National Laboratories, Tonopah Test Range, Nevada, and Kaua'i Test Facility, Hawai'i

Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration. The National Nuclear Security Administration’s Sandia Field Office administers the contract and oversees contractor operations at Sandia National Laboratories, Tonopah Test Range (SNL/TTR) in Nevada and Sandia National Laboratories, Kaua‘i Test Facility (SNL/KTF) in Hawai‘i. Activities at SNL/TTR are conducted in support of U.S. Department of Energy weapons programs and have operated at the site since 1957. SNL/KTF has operated as a rocket preparation launching and tracking facility since 1962. The U.S. Department of Energy and its management and operating contractor are committed to safeguarding the environment, assessing sustainability practices, and ensuring the validity and accuracy of the monitoring data presented in this Annual Site Environmental Report. This report summarizes the environmental protection, restoration, and monitoring programs in place at SNL/TTR and SNL/KTF during calendar year 2020. Environmental topics include air quality, ecology, environmental restoration, oil storage, site sustainability, terrestrial surveillance, waste management, water quality, and implementation of the National Environmental Policy Act. This report is prepared in accordance with and as required by DOE O 231.1B, Admin Change 1, Environment, Safety and Health Reporting , and has been approved for public distribution.

54 ENVIRONMENTAL SCIENCES↗

Studies of Alternative Ventilation Configurations to Mitigate Airborne Exposure Risks in Office Spaces

The objective of this study was to evaluate the impact of alternative ventilation configurations on airflow patterns and potential exposure risks in office spaces. Two existing conference rooms at Sandia NM were modeled using Computational Fluid Dynamics (CFD) simulations to characterize airflow patterns and potential airborne exposure risks in well-mixed and once-through (through-flow) ventilation conditions. Multiple scenarios were studied to evaluate the impact of occupancy, Plexiglass barriers, and a modified-return airflow configuration. Experimental and visualization tests were also conducted to validate the well-mixed and through-flow models and findings. The simulations demonstrated that the modified-return airflow configuration that promoted through-flow conditions reduced pathogen concentrations within the space compared to the well-mixed airflow configuration; occupancy reduction only reduced the number of exposed individuals, and Plexiglass barriers had almost no effect. The experimentally measured air speeds at nine anemometer locations generally matched the simulated airflow velocities, and a fog-purge visualization test was also consistent with simulated results of plume movement and dissipation. The visualization tests demonstrated improvements in air change rate with the modified return, which promoted through-flow conditions, versus the original well-mixed ventilation configuration. The results of this study demonstrate that minor modifications to a space that promote through-flow conditions can improve air quality and reduce pathogen concentrations. Additional airflow modeling and testing of alternative occupied space configurations are recommended to further inform room designs that mitigate airborne exposure risks for occupants.

42 ENGINEERING↗

History of Ethanol Fuel Adoption in the United States: Policy, Economics, and Logistics

Ethanol has the achieved the greatest market share of all the alternative transportation fuels that have been researched, developed, and deployed in the US. There are multiple lessons to be learned from the history of ethanol adoption that can be applied to future fuels and products. Ethanol has replaced portions of gasoline in three main blend levels, with corresponding vehicles, equipment, benefits, and policies. The first is E10, which has replaced nearly all pure gasoline (E0) sold in the United States today (U.S. Energy Information Administration 2015). This was brought about through generations of policies that were motivated by multiple factors related to engine performance, energy security, health, air quality, and climate protection. Ethanol's high octane has been a consistent driver of the fuel because this enables higher performance engines. Early policies (1973-1979) were largely motivated by the desire to reduce dependence on petroleum sourced from members of the Organization of the Petroleum Exporting Countries, or OPEC. Fuel policy in the 1980s was largely in pursuit of promoting octane number enhancers that could replace lead. Criteria pollutant reduction was the overarching goal of actions taken from 1990 to 2005. From 2005 to the present, fuel policy has been largely motivated by energy security and climate protection goals. These policies were usually technology-agnostic and promoted multiple fuels and additives during each period. However, ethanol is the only fuel identified that is cost effective with qualities that enabled it to prosper in the policy environments of all four of these periods.The second market for ethanol is via 85% ethanol (E85). This fuel has the advantage of a greater concentration of ethanol but the disadvantage of not being compatible with regular gasoline vehicles. Instead, it can only be used in flexible-fuel vehicle (FFVs), which can use every blend level from E0 to E85. Therefore, much of the effort to increase E85 consumption has been aimed at incentivizing automakers to manufacture FFVs, drivers to purchase FFVs, and fueling stations to equip themselves to sell E85.The third, and newest, market through which ethanol is consumed is 15% ethanol (E15), which builds upon the E10 market to increase ethanol consumption by common gasoline vehicles. Efforts to create the E15 market consisted largely of testing vehicles and refueling equipment for compatibility, creating waivers to allow the use of E15, placing requirements on E15 retailers, and incentivizing retailers to equip themselves to purchase E15.

09 BIOMASS FUELS↗