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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

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NASA NTRS1978

Stratospheric composition balloon, aircraft and rocket-borne experiments, 28-30 September 1977 (systems, instruments, trajectories, supporting measurements)

The STRATCOM (STRATospheric COMposition) is a long term multipurpose program for integrated, correlated measurements of stratospheric parameters related to composition, thermodynamics, and radiative balance. Balloon 8-b, carrying a solar-pointing grating infrared spectrometer, two CO2 thermal emission radiometers and two in-situ air temperature sensors was launched at 1251 MST on 28 September 1977 to float at an altitude of 39 km from 1521 MST with the instruments making measurements at that altitude through the time of sunset at 1822 MST. Balloon 8-a lifted a payload consisting of four UV filter photometers, two UV spectrometers, two chemiluminescent ozonesondes, dasibi ozone monitor, 14 tube cryogenic sampler, two aluminum oxide H2O sensors, four air temperature sensors, atmospheric pressure sensor, infrared and visible pyranometers, downward-looking camera, blunt-kryton lamp-Gerdien condenser probe, three component anemometer, balloon apex-plate payload and three parachute-borne dropsondes.

Ballard, H. N.↗

NASA NTRS1964

Wedge immersed thermistor bolometers

An immersed thermistor bolometer for the detection of ultraviolet, visible, and infrared radiation is described. Two types of immersed bolometers are discussed. The immersion of thermistor flakes in a lens, or half immersed by optical contact on a lens, is examined. Lens materials are evaluated for optimum immersion including fused aluminum oxide, beryllium oxide, and germanium. The application of the bolometer to instruments in which the entrance pupil of the immersion optics has a high aspect ratio is considered.

Dreyfus, M. G.↗

NASA NTRS1978

Morphology and elemental composition analysis by size of rocket particulate effluent

Particulate samples collected on six stages of a quartz crystal microbalance cascade impactor mounted in an aircraft traversing the plume of a large solid-fueled rocket are analyzed, postflight, by scanning electron microscopy (SEM) and energy dispersed X-ray (EDXRA). The results indicate the morphology and elemental composition of the particles fall into several distinct groups. Those larger than about 0.5 micron in diameter and nearly spherical in shape contain, among elements with atomic numbers of 11 and higher, only aluminum, suggesting they are aluminum oxide formed in the solid rocket fuel combustion. Still larger but less symmetrical particles contain only sodium and chlorine. Particles much smaller than 0.5 micron seem to end up as agglomerates after impaction (or during the impaction process), and show a complex elemental make-up of Na, Al, S, Cl, K, Ca, Fe and Zn. The unagglomerated single particles smaller than 0.2 micron, on the other hand, show no evidence of elements above atomic number 11 at all, suggesting they may be carbon or hydrocarbon particles.

Chuan, R. L.↗

NASA NTRS1978

Properties of the stratospheric aerosol layer studied with a one-dimensional computer model

Aerosol particle effects are often neglected in theoretical studies of stratospheric phenomena. In reality, the particulate matter normally found above the tropopause may influence the terrestrial radiation balance, catalyze heterogeneous chemical interactions, and serve as a tracer of atmospheric motions. The paper proposes a one-dimensional model of the stratospheric aerosol layer, and it is used to compare aerosol theory with observational data. The model considers gaseous sulfur photochemistry and the physical aerosol processes of nucleation, coagulation, sedimentation, and diffusion. Calculations of the effects on the aerosol layer of stratospheric injections of aluminum oxide particles by Space Shuttle engines and of sulfur dioxide molecules by volcanic activity are performed. The relation between measured aerosol variability and changes in stratospheric air temperatures and vertical transport rates are discussed.

Turco, R. P.↗

NASA NTRS1979

Measurements of upper atmosphere water vapor made in situ with a new moisture sensor

A new thin-film aluminum oxide sensor, Aquamax II, has been developed for the measurement of stratospheric and upper tropospheric water vapor levels. The sensor is briefly described with attention given to its calibration and performance. Data obtained from six balloon flights are presented; almost all the results show a constant water vapor mixing ratio, in agreement with other data from midlatitude regions.

Chleck, D.↗

NASA NTRS1980

Alumina barrier for vacuum brazing

Heating platens of vacuum-brazing press will not stick to workpiece if aluminum oxide "paper" is interposed. Paper does not disintegrate in press, will not contaminate braze alloy, and helps form smoothly contoured, regular fillet at brazed edges.

Beuyukian, C. S.↗

NASA NTRS1980

Experimental determination of the admittances of aluminized propellants by the impedance tube method

The adaptation of the impedance tube concept for the determination of the pressure coupled admittances and response functions of burning solid propellants is discussed. The results obtained in experiments with UTP-3001 and UTP-19360 aluminized propellants are presented. It is shown that the admittance Y remains constant during the quasi-steady burn period of a test, indicating constant driving of the gas phase disturbance by the burning solid propellant. The measured real part of the admittance is positive, indicating that the burning aluminized propellant is driving the gas phase oscillations. In addition, the measured high gas phase damping, provided by the aluminum oxide particles in the gas phase, suggests that the latter can significantly increase the damping in unstable solid rockets over the investigated frequency range. Finally, it is shown that the wave structure obtained by numerically solving the impedance tube wave equations which utilize the determined propellant admittance as an initial condition and the determined value of G to describe the gas phase losses is in excellent agreement with the measured wave structure.

Baum, J. D.↗

NASA NTRS1981

Aerosil for the improvement of the flow behavior of powdered substances

The tendency of powdered substances to agglomerate and stick together is studied. The highly dispersed silicic acid Aerosil (tradename) is studied as an agent to improve the free flowing characteristics of powdered materials. It was concluded that the use of Aerosil 200, Aerosil R 972, aluminum oxide C and sylicic acid D 17 as flow agents caused broad improvements in the flow properties of powders. Additionally, the sifting, dispersion, and spray behavior, as well as the grinding and air separation characteristics of powders were improved.

Source record↗

NASA NTRS1982

Surface chemistry, microstructure and friction properties of some ferrous-base metallic glasses at temperatures to 750 C

X-ray photoelectron spectroscopy analysis, transmission electron microscopy, diffraction studies, and sliding friction experiments were conducted with ferrous-base metallic glasses in sliding contact with aluminum oxide at temperatures from room to 750 C in a vacuum of 30 nPa. The results indicate that there is a significant temperature influence on the friction properties, surface chemistry, and microstructure of metallic glasses. The relative concentrations of the various constituents at the surface of the sputtered specimens were very different from the normal bulk compositions. Contaminants can come from the bulk of the material to the surface upon heating and impart boric oxide and silicon oxide at 350 C and boron nitride above 500 C. The coefficient of friction increased with increasing temperature to 350 C. Above 500 C the coefficient of friction decreased rapidly. The segregation of contaminants may be responsible for the friction behavior.

Miyoshi, K.↗

NASA NTRS1982

Plastic deformation and wear process at a surface during unlubricated sliding

The plastic deformation and wear of a 304 stainless steel surface sliding against an aluminum oxide rider with a spherical surface (the radius of curvature: 1.3 cm) were observed by using scanning electron and optical microscopes. Experiments were conducted in a vacuum of one million Pa and in an environment of fifty thousandth Pa of chlorine gas at 25 C. The load was 500 grams and the sliding velocity was 0.5 centimeter per second. The deformed surface layer which accumulates and develops successively is left behind the rider, and step shaped proturbances are developed even after single pass sliding under both environmental conditions. A fully developed surface layer is gradually torn off leaving a characteristic pattern. The mechanism for tearing away of the surface layer from the contact area and sliding track contour is explained assuming the simplified process of material removal based on the adhesion theory for the wear of materials.

Yamamoto, T.↗

NASA NTRS1982

Friction and wear of iron and nickel in sodium hydroxide solutions

A loaded spherical aluminum oxider rider was made to slide, while in various solutions, on a flat iron or nickel surface reciprocate a distance of 1 cm. Time of experiments was 1 hr during which the rider passed over the rider passed over the center section of the track 540 times. Coefficients of friction were measured throughout the experiments. Wear was measured by scanning the track with a profilometer. Analysis of some of the wear tracks included use of the SEM (scanning electron microscrope) and XPS (X-ray photoelectron spectroscopy). Investigated were the effect of various concentractions of NaOH and of water. On iron, increasing NaOH concentration above 0.01 N caused the friction and wear to decrease. This decrease is accompanied by a decrease in surface concentration of ferric oxide (Fe2O3) while more complex iron-oxygen compounds, not clearly identified, also form. At low concentrations of NaOH, such as 0.01 N, where the friction is high, the wear track is badely torn up and the surface is broken. At high concentration, such as 10 N, where the friction is low, the wear track is smooth. The general conclusion is that NaOH forms a protective, low friction film on iron which is destroyed by wear at low concentrations but remains intact at high concentrations of NaOH. Nickel behaves differently than iron in that only a little NaOH gives a low coefficient of friction and a surface which, although roughened in the wear track, remains intact.

Rengstorff, G. W. P.↗

NASA NTRS1982

Plastic deformation at surface during unlubricated sliding

The plastic deformation and wear of 304 stainless-steel surface slid against an aluminum oxide rider were observed by using a scanning electron microscope and an optical microscope. Experiments were conducted in a vacuum of 0.000001 Pa and in an environment of 0.0005 Pa chlorine gas at 25 C. The load was 500 grams and the sliding velocity was 0.5 centimeter per second. The deformed surface layer which accumulates and develops successively is left behind the rider, and step-shaped protuberances are developed even after single pass sliding under both environmental conditions. A fully developed surface layer is gradually torn off leaving a characteristic pattern. These observations result from both adhesion and an adhesive wear mechanism.

Yamamoto, T.↗

NASA NTRS1983

Friction and wear of some ferrous-base metallic glasses

Sliding friction experiments, X-ray photoelectron spectroscopy (XPS) analysis, and electron microscopy and diffraction studies were conducted with ferrous base metallic glasses (amorphous alloys) in contact with aluminum oxide at temperatures to 750 C in a vacuum. Sliding friction experiments were also conducted in argon and air atmospheres. The results of the investigation indicate that the coefficient of friction increases with increasing temperature to 350 C in vacuum. The increase in friction is due to an increase in adhesion resulting from surface segregation of boric oxide and/or silicon oxide to the surface of the foil. Above 500 C the coefficient of friction decreased rapidly. The decrease correlates with the segregation of boron nitride to the surface. Contaminants can come from the bulk of the material to the surface upon heating and impart boric oxide and/or silicon oxide at 350 C and boron nitride above 500 C. The segregation of contaminants is responsible for the friction behavior. The amorphous alloys have superior wear resistance to crystalline 304 stainless steel. The relative concentrations of the various constituents at the surfaces of the amorphous alloys are very different from the nominal bulk compositions.

Miyoshi, K.↗

NASA NTRS1983

Thermodynamics of the potassium-sulfur-oxygen and related systems

The chemical reactions which occur when potassium sulfide, K2S, and potassium sulfite, K2SO3, are heated at temperatures where their vapor pressures are significant, were studied and the vapor pressures and the partial pressures of the chemical products were measured. Mass spectrometry of the vapor of potassium sulfide revealed only K(g). X-ray studies of the solid residues from vaporization experiments revealed K2S2(s) and chemical analyses of the same solid residues showed that the residues approached a composition K2Sx with x in the range 3-4. Vapor pressure of K2S was measured by simultaneous Knudsen-effusion and torsion-effusion (SKETE) in crucibles of aluminum oxide and of graphite. In each such experiment, the vapor pressures agreed initially, but then the apparent pressure by Knudsen-effusion increased suddenly and remained much greater than that by torsion-effusion for the remainder of the experiment. Results of third-law analysis of the torsion pressures imply a delta H (298K) of formation of K2S(s) of -364 + or - 12 kJ/mol. Vapor pressures over K2SO3(s) were measured by simultaneous Knudsen and torsion-effusion and by mass spectrometry. The vapor pressures of both K2S2O5(s) and K2SO3(s) were nonreproducible at a given temperature due to the vaporization reactions of the materials being irreversible under conditions in effusion cells.

Edwards, J. G.↗

NASA NTRS1983

Thermionic energy converters

The efficiency of thermionic energy converters is improved by internal distribution of tiny sorted cesium diodes driven by the thermal gradient between the primary emitter and the collector. The tiny, sorted diode distribution comprises protrusions of the emitter material from the main emitter face which contact the main collector face thermally but not electrically. The main collector ends of the protrusions are separated from the main collector by a thin layer of insulation, such as aluminum oxide. The shorted tiny diode distribution augments cesium ionization through internal thermal effects only within the main diode. No electrical inputs are required. This ionization enhancement by the distribution of the tiny shorted diodes not only reduces the plasma voltage drop but also increases the power output and efficiency of the overall thermionic energy converter.

Morris, J. F.↗

NASA NTRS1983

Plastic deformation and wear process at a surface during unlubricated sliding

Yamamoto, T.↗

NASA NTRS1983

An application of model testing for the study of rocket exhaust cloud properties

The application of the 6.4-percent Shuttle Model Test Facility to the study of the Shuttle exhaust cloud properties is discussed with emphasis on the properties related to the production of the deposition (submillimeter drops composed of an acidic liquid and alumina solids) which occurs with each launch. An analysis of test data suggests that the major fraction of the liquid in the deposition is produced directly through the interaction between the exhaust and the deluge water spray and then modified by rapid scavenging of wet acidic aluminum oxide particles. Based on this conclusion, the possibility arises that the acid in the deposition can be neutralized by addition of a base to the deluge water. Current work with the 6.4-percent model is directed toward verification of this hypothesis.

Anderson, B. J.↗

NASA NTRS1983

Friction and wear of iron and nickel in sodium hydroxide solutions

A loaded spherical aluminum oxider rider was made to slide, while in various solutions, on a flat iron or nickel surface reciprocate a distance of 1 cm. Time of experiments was 1 hr during which the rider passed over the center section of the track 540 times. Coeficients of friction were measured throughout the experiments. Wear was measured by scanning the track with a profilometer. Analysis of some of the wear tracks included use of the SEM (scanning electron microscope) and XPS (X-ray photoelectron spectroscopy). Investigated were the effect of various concentrations of NaOH and of water. On iron, increasing NaOH concentration above 0.01 N caused the friction and wear to decrease. This decrease is accompanied by a decrease in surface concentration of ferric oxide (Fe2O3) while more complex iron-oxygen compounds, not clearly identified, also form. At low concentrations of NaOH, such as 0.01 N, where the friction is high, the wear track is badly torn up and the surface is broken. At high concentration, such as 10 N, where the friction is low, the wear track is smooth. The general conclusion is that NaOH forms a protective, low friction film on iron which is destroyed by wear at low concentrations but remains intact at high conentrations of NaOH. Nickel behaves differently than iron in that only a little NaOH gives a low coefficient of friction and a surface which, although roughened in the wear track, remains intact. Previously announced in STAR as N83-10171

Rengstorff, G. P.↗