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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

The structure of the time-dependent interstellar shocks and grain destruction in the interstellar medium

A new theoretical analysis of the structure of interstellar shocks and the grain dynamics of these shocks is presented. The basic hydrodynamic equations for J-shocks in interstellar gas are given in which shock-driving pressure is allowed to be weakly time-dependent and the grains are treated as a separate two-dimensional fluid. Specific equations for the grain dynamics in the cooling postshock gas are derived. An analytic theory for the propagation of a shock driven into an interstellar cloud by the blast wave of a supernova remnant which sweeps over the cloud is developed. An improved calculation of the grain charge in postshock gas is described, giving a simple analytic approximation for the results. The consequences of including these processes in the numerical code of Seab and Shull (1983) are addressed, including the effect of realistic magnetic fields in low-density gas.

Mckee, Christopher F.↗
NASA NTRS1975

Integration time required to extract accurate static and dynamic data from transonic wind-tunnel tests

Because the forces and pressures on wind-tunnel models tested at transonic speeds are not steady, even for 'static' aerodynamic tests, integration time is required to obtain data of acceptable accuracy. The integration time required for both static and dynamic tests is evaluated analytically and confirmed by experimental measurements. It is shown that, for static and dynamic tests, the accuracy obtained is a function of integration time, frequency content of the signal, and the ratio of the dynamic amplitude to the full signal of interest. In addition, for the dynamic case, the frequency band width used in analysis is important. Results of this study indicate that, for typical data accuracy desired from models in a large transonic wind tunnel (11- by 11-ft), up to the following integration times are required: static force and moment tests, 0.5 sec; static pressure tests, 0.1 sec; flutter tests, 30 to 60 sec; and random-dynamic tests, 10 sec.

Muhlstein, L., Jr.↗
NASA NTRS2007

Thermal Analysis on Plume Heating of the Main Engine on the Crew Exploration Vehicle Service Module

The crew exploration vehicle (CEV) service module (SM) main engine plume heating is analyzed using multiple numerical tools. The chemical equilibrium compositions and applications (CEA) code is used to compute the flow field inside the engine nozzle. The plume expansion into ambient atmosphere is simulated using an axisymmetric space-time conservation element and solution element (CE/SE) Euler code, a computational fluid dynamics (CFD) software. The thermal analysis including both convection and radiation heat transfers from the hot gas inside the engine nozzle and gas radiation from the plume is performed using Thermal Desktop. Three SM configurations, Lockheed Martin (LM) designed 604, 605, and 606 configurations, are considered. Design of multilayer insulation (MLI) for the stowed solar arrays, which is subject to plume heating from the main engine, among the passive thermal control system (PTCS), are proposed and validated.

Wang, Xiao-Yen J.↗
NASA NTRS2008

Deflection Analysis of the Space Shuttle External Tank Door Drive Mechanism

Upon observing an abnormal closure of the Space Shuttle s External Tank Doors (ETD), a dynamic model was created in MSC/ADAMS to conduct deflection analyses of the Door Drive Mechanism (DDM). For a similar analysis, the traditional approach would be to construct a full finite element model of the mechanism. The purpose of this paper is to describe an alternative approach that models the flexibility of the DDM using a lumped parameter approximation to capture the compliance of individual parts within the drive linkage. This approach allows for rapid construction of a dynamic model in a time-critical setting, while still retaining the appropriate equivalent stiffness of each linkage component. As a validation of these equivalent stiffnesses, finite element analysis (FEA) was used to iteratively update the model towards convergence. Following this analysis, deflections recovered from the dynamic model can be used to calculate stress and classify each component s deformation as either elastic or plastic. Based on the modeling assumptions used in this analysis and the maximum input forcing condition, two components in the DDM show a factor of safety less than or equal to 0.5. However, to accurately evaluate the induced stresses, additional mechanism rigging information would be necessary to characterize the input forcing conditions. This information would also allow for the classification of stresses as either elastic or plastic.

Tosto, Michael A.↗
NASA NTRS1984

A fast time domain digital simulation technique for power converters - Application to a buck converter with feedforward compensation

Small signal analysis was performed earlier to demonstrate the marked improvement of dynamic properties and stability margins of a switching regulator employing a novel feedforward input filter compensation scheme. A large signal nonlinear recurrent time domain model is presented for the converter to analyse the transient response due to a step input change with and without the presence of the proposed feedforward loop. The results are verified with experimental data.

Kelkar, S. S.↗
NASA NTRS1993

Space Station flexible dynamics under plume impingement

Assembly of the Space Station requires numerous construction flights by the Space Shuttle. A particularly challenging problem is that of control of each intermediate station configuration when the shuttle orbiter is approaching it to deliver the next component. The necessary braking maneuvers cause orbiter thruster plumes to impinge on the station, especially its solar arrays. This in turn causes both overall attitude errors and excitation of flexible-body vibration modes. These plume loads are predicted to lead to CMG saturation during the approach of the orbiter to the SC-5 station configuration, necessitating the use of the station RCS jets for desaturation. They are also expected to lead to significant excitation of solar array vibrations. It is therefore of great practical importance to investigate the effects of plume loads on the flexible dynamics of station configuration SC-5 as accurately as possible. However, this system possesses a great many flexible modes (89 below 5 rad/s), making analysis time-consuming and complicated. Model reduction techniques can be used to overcome this problem, reducing the system model to one which retains only the significant dynamics, i.e. those which are strongly excited by the control inputs or plume disturbance forces and which strongly couple with the measured outputs. The particular technique to be used in this study is the subsystem balancing approach which was previously developed by the present investigator. This method is very efficient computationally. Furthermore, it gives accurate results even for the difficult case where the structure has many closed-spaced natural frequencies, when standard modal truncation can give misleading results. Station configuration SC-5 is a good example of such a structure.

Williams, Trevor↗
NASA NTRS1971

Concerning the origin of novae and U Geminorum stars

The dynamical stability of the contact component in a semi-detached binary system is investigated by a linear time dependent analysis. The boundary condition imposed on the photosphere by the Roche lobe is assumed to be one of constant pressure over the whole surface of the lobe, which is treated as being spherically symmetric. The eigenvalues of the linear equation of motion are evaluated for sequences of stellar envelope models under the constraint of this boundary condition. An extensive region in the Hertzprung-Russell diagram is found to be dynamically unstable. This region coincides almost precisely with that predicted by a previous quasi-static study. Time scales for the growth of the instability are also evaluated. Color observations of several novae and U Geminorum stars are discussed in an attempt to provide semi-empirical tests of the proposed theoretical model of the outbursts. In particular the track in the H-R diagram of the U Geminorum star, EM Cygni, is shown to be consistent with an outburst which is purely a temperature change at constant radius, as is demanded by the theory.

Bath, G. T.↗
NASA NTRS1977

Ionosonde observations of the northern magnetospheric cleft during December 1974 and January 1975

During December 1974 and January 1975, the northern magnetospheric cleft was monitored by ionosondes at Cape Parry and Sachs Harbor, Northwest Territories, Canada, in support of rocket shots into the cleft. Ionograms were taken nominally at 15-min intervals but as rapidly as two per minute during times of particular interest. Analysis of 5 days of data shows the ionosphere at cleft latitudes to be very complex and dynamic. The ionograms often show considerable structure and can change appearance significantly in a minute or two. The cleft at times appears to move equatorward in response either to a southward turning of the interplanetary magnetic field or to the occurrence of geomagnetic disturbances. This response is in agreement with the conclusions of previous satellite studies. Behavior contrary to this generalization is not uncommon, however, and therefore it may not always hold on time scales considerably shorter than the satellite orbital period of at least 1 hour. The rate of the cleft's motion may vary from about 0.05 to 0.5 deg/min.

Stiles, G. S.↗
DOE OSTI2023

Stochastic Real-Time Second-Order Green’s Function Theory for Neutral Excitations in Molecules and Nanostructures

We present a real-time second-order Green’s function (GF) method for computing excited states in molecules and nanostructures, with a computational scaling of O(N e 3 ), where N e is the number of electrons. The cubic scaling is achieved by adopting the stochastic resolution of the identity to decouple the 4-index electron repulsion integrals. To improve the time propagation and the spectral resolution, we adopt the dynamic mode decomposition technique and assess the accuracy and efficiency of the combined approach for a chain of hydrogen dimer molecules of different lengths. We find that the stochastic implementation accurately reproduces the deterministic results for the electronic dynamics and excitation energies. Furthermore, we provide a detailed analysis of the statistical errors, bias, and long-time extrapolation. Overall, the approach offers an efficient route to investigate excited states in extended systems with open or closed boundary conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Disperse aqueous systems based on (S)-lysine in a wide range of concentrations and physiologically important temperatures

It was shown for the first time using a complex of physicochemical methods (dynamic and electrophoretic light scattering, nanoparticle tracking analysis, transmission electron and atomic force microscopy, conductometry, pH-metry) that in a temperature range of 25—60 °С (S)-lysine aqueous solutions (1•10{sup –17}—1•10{sup –2} mol L{sup –1}) are disperse systems, where the nature and parameters of the disperse phase change with dilution, which affects the nonmonotonic dependences of the specific conductivity and pH of the system. Nanoassociates hundreds of nanometers in size were found to contain ordered water structures that are responsible for the size and ζ-potential of the disperse phase in the aqueous systems and also participate in the formation of spatially organized systems on the support.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Capturing Ring Opening in Photoexcited Enolic Acetylacetone upon Hydrogen Bond Dissociation by Ultrafast Electron Diffraction

Photoinduced biological and chemical reactions are often based on key structural transformations of a molecule driven across multiple electronic states. Acetylacetone (AcAc) is a prototypical system for complex chemical pathways involving several conical intersections (CI) and singlet–triplet intersystem crossings (ISC) characterized by distinct geometries. In the gas phase, AcAc is predominantly in a planar ring-like enolic form stabilized by a strong intramolecular O–H···O hydrogen bond. Following excitation into the S 2 (ππ*) state at 266 nm, acetylacetone undergoes rapid internal conversion followed by intersystem crossing. Such relaxation pathways are associated with structural changes including ring opening, deplanarization, and bond elongation. In this work, ultrafast electron diffraction (UED) at the SLAC MeV-UED setup is employed as a direct structural probe with a time resolution of 160 fs. Together with trajectory surface hopping simulations, analysis of the UED data provides a new perspective on the early time nuclear dynamics in acetylacetone. Specifically, AcAc is observed to undergo ring opening, deplanarization, and bond elongation all within the first 700 fs after photoexcitation. The monitored dynamics is associated mainly with the nuclear motion on the S 1 potential energy surface, formed after very rapid transfer from S 2 to S 1 , allowing AcAc to reach the conical intersection to intersystem crossing. Such time scales of nuclear motion are contrasted with the time scales of electronic transitions in AcAc that were previously characterized with spectroscopic methods, specifically internal conversion (<100 fs) and intersystem crossing (∼1.5 ps).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Trends and drivers of marine fish landings in Portugal since its entrance in the European Union

Abstract Marine landings in Portugal have decreased at a higher rate than fishing effort in the last 20 years. Identifying the variables driving the quantity and composition of landings is pivotal to understand the dynamics of the fisheries sector, which entails complex social and environmental aspects. In this study, we investigate the main drivers of marine fish landings in continental Portugal between 1989 and 2014. To identify common trends in time series, and quantify the importance of environmental factors, we applied a dynamic factor analysis considering four regions and three types of gear (trawling, purse-seine, and a multi-gear fishery). Our results show the importance of fishing effort as the most relevant factor driving marine landings in Portugal, both at the long and short terms. In addition, the effect of environmental factors such as the winter river discharge and the spring East Atlantic Teleconnection index should not be neglected, probably through mechanisms affecting coastal productivity. We provide a comprehensive amount of information that permits to improve our understanding of the trends of the most important commercial species in Portugal during the period of study.

Bueno-Pardo, Juan↗
DOE OSTI2025

Iodine Capture Studies of Copper- and Bismuth-Based Sorbents

The release of radioiodine, one of several radionuclides of concern when recycling used nuclear fuel (UNF), is an important consideration in the fuel cycle. In this study, two sorbent materials, Cu 0 -polyacrylonitrile (PAN) and Bi 0 -PAN, were tested as solid sorbent candidates for iodine capture. Experiments using a thin bed of sorbent material were exposed to vaporized iodine for over 300 hours (~2 weeks) under varied conditions in a dynamic flow environment. The overall performance was monitored in real-time using thermogravimetric analysis, and the materials were subsequently characterized for surface and bulk analysis using scanning electron microscopy – energy-dispersive spectroscopy (SEM-EDS) and powder x-ray diffraction (pXRD), respectively. Iodine (in the form of I 2 ) is expected to be released primarily in the dissolver off-gas (DOG) stream; therefore, this study demonstrates the effects of elemental iodine (I 2 ), water vapor (H 2 O), and nitrogen dioxide (NO 2 ). When exposed to ‘ideal’ conditions (in which I 2 is carried by dry air), Cu 0 -PAN and Bi 0 -PAN behave differently, with TGA analysis indicating that Cu 0 sorption performance is higher than that of Bi 0 , as evidenced by a larger mass change. Under ‘harsh’ conditions—such as a gaseous feed containing I 2 , H 2 O, and NO 2 vapors carried by air,—iodine capture performance for both Cu 0 - and Bi 0 -PAN are affected. SEM-EDS and pXRD analysis of these materials is discussed herein.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Multiplexed Anodic Stripping Voltammetry Detection of Heavy Metals in Water Using Nanocomposites Modified Screen-Printed Electrodes Integrated With a 3D-Printed Flow Cell

In this study, we present multiplexed anodic stripping voltammetry (ASV) detection of heavy metal ions (HMIs)—As(III), Cd(II), and Pb(II)—using a homemade electrochemical cell consisting of dual working, reference and counter screen-printed electrodes (SPE) on polyimide substrate integrated with a 3D-printed flow cell. Working and counter electrodes were fabricated by the screen-printing of graphite paste while the Ag/AgCl paste was screen-printed as a reference electrode (Ag/AgCl quasi-reference electrode). The working electrodes were modified with (BiO) 2 CO 3 -reduced graphene oxide (rGO)-Nafion [(BiO) 2 CO 3 -rGO-Nafion] and Fe 3 O 4 magnetic nanoparticles (Fe 3 O 4 MNPs) decorated Au nanoparticles (AuNPs)-ionic liquid (IL) (Fe 3 O 4 -Au-IL) nanocomposites separately to enhance HMIs sensing. Electrochemical detection was achieved using square wave ASV technique. The desired structure of the flow electrochemical cell was optimized by the computational fluid dynamic (CFD). Different experimental parameters for stripping analysis of HMIs were optimized including deposition time, deposition potential and flow rate. The linear range of calibration curves with the sensing nanocomposites modified SPE for the three metal ions was from 0–50 μg/L. The limits of detection (S/N = 3) were estimated to be 2.4 μg/L for As(III), 1.2 μg/L for Pb(II) and 0.8 μg/L for Cd(II). Furthermore, the homemade flow anodic stripping sensor platform was used to detect HMIs in simulated river water with a 95–101% recovery, indicating high selectivity and accuracy and great potential for applicability even in complex matrices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1982

The Development of a Handbook for Astrobee F Performance and Stability Analysis

An astrobee F performance and stability analysis is presented, for use by the NASA Sounding Rocket Division. The performance analysis provides information regarding altitude, mach number, dynamic pressure, and velocity as functions of time since launch. It is found that payload weight has the greatest effect on performance, and performance prediction accuracy was calculated to remain within 1%. In addition, to assure sufficient flight stability, a predicted rigid-body static margin of at least 8% of the total vehicle length is required. Finally, fin cant angle predictions are given in order to achieve a 2.5 cycle per second burnout roll rate, based on obtaining 75% of the steady roll rate. It is noted that this method can be used by flight performance engineers to create a similar handbook for any sounding rocket series.

Wolf, R. S.↗
NASA NTRS1983

Propagation of sound in highly porous open-cell elastic foams

This work presents both theoretical predictions and experimental measurements of attenuation and progressive phase constants of sound in open-cell, highly porous, elastic polyurethane foams. The foams are available commercially in graded pore sizes for which information about the static flow resistance, thermal time constant, volume porosity, dynamic structure factor, and speed of sound is known. The analysis is specialized to highly porous foams which can be efficient sound absorbers at audio frequencies. Negligible effect of internal wave coupling on attenuation and phase shift for the frequency range 16-6000 Hz was predicted and no experimentally significant effects were observed in the bulk samples studied. The agreement between predictions and measurements in bulk materials is excellent. The analysis is applicable to both the regular and compressed elastic open-cell foams.

Lambert, R. F.↗
NASA NTRS1986

Analytical ultrasonics for characterization of metallurgical microstructures and transformations

The application of contact (piezoelectric) and noncontact (laser generation and detection) ultrasonic techniques for dynamic investigation of precipitation hardening processes in aluminum alloys, as well as crystallization and phase transformation in rapidly solidified amorphous and microcrystalline alloys is discussed. From the variations of the sound velocity and attenuation the precipitation mechanism and kinetics were determined. In addition, a correlation was established between the observed changes in the velocity and attenuation and the mechanical properties of age-hardenable aluminum alloys. The behavior of the elastic moduli, determined ultrasonically, were found to be sensitive to relaxation, crystallization and phase decomposition phenomena in rapidly solidified metallic glasses. Analytical ultrasonics enables determination of the activation energies and growth parameters of the reactions. Therefrom theoretical models can be constructed to explain the changes in mechanical and physical properties upon heat treatment of glassy alloys. The composition dependence of the elastic moduli in amorphous Cu-Zr alloys was found to be related to the glass transition temperature, and consequently to the glass forming ability of these alloys. Dynamic ultrasonic analysis was found to be feasible for on-line, real-time, monitoring of metallurgical processes.

Rosen, M.↗
NASA NTRS1988

Dynamic delamination fracture toughness of a graphite/epoxy laminate under impact

Dynamic delamination fracture toughness in a (90/0)5s T300/934 graphite/epoxy laminate was investigated using impact loading. Delamination cracks of three different sizes were embedded at the midplane of the composite specimen. The threshold impact velocity that causes propagation of the delamination crack was used in the dynamic analysis with the finite element method. From the finite element solution, the time-history of the strain energy release rate was calculated. The critical strain energy release rate was taken to equal the maximum value of the response history.

Sun, C. T.↗