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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

Aggregation of One–Dimensional Wires: The Case of Long Oligoynes

We show an unexpected aggregation phenomenon of a long oligoyne (Py[16]) with 16 contiguous triple bonds and endcapped with bulky 3,5-bi(3,5-bis-tert-butylphenyl)pyridine groups. Aggregation of 1D π-conjugated oligoyne chains is rare given the minimal π–π intermolecular interactions as well as its flexibility that works against self-assembly. In dilute solutions, the reversible aggregation of Py[16] initiates at low temperature in the range of 140–180 K, and is not observed for shorter oligoynes in this series. Cryogenic UV/Vis electronic absorption spectra and vibrational Raman spectra with different laser wavelength lines tuning from in-resonance to off-resonance conditions have been used to extract the vibrational features characterizing the monomer and aggregate species. Theoretical calculations complement the spectroscopic findings.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Segmentation and Classification of Fission as Pores in Reactor Irradiated Annular U–10Zr Metallic Fuel Using Machine Learning Models

Metallic fuels, particularly U—10Zr, are promising candidates for next-generation sodium-cooled fast reactors. Irradiation of nuclear fuels in reactors can lead to the formation of solid and gas fission product which subsequently forms microstructural pores, deteriorating fuel performance. Due to the massive amount of pores and complex phases formed, a quantitative description of fission gas pores is not yet available, preventing the development of microstructure-informed fuel performance modeling for fuel qualification. This paper applied a pre-trained deep learning model to ~10,260 high magnification scanning electron microscopy images. This method increased the accuracy of fission gas pore segmentation and allows statistical features to be extracted which cannot be achieved manually. A pre-trained decision tree model worked on the segemenation results and further classified the pores into different categories to produce a correlation between the pores, movement of lanthanides, and temperature gradient during irradiation. Finally, this paper emphasizes the potentials of machine learning models to accelerate fuel research, development, and qualification for advanced reactors.

36 MATERIALS SCIENCE↗

Dual X-ray computed tomography-aided classification of melt pool boundaries and flaws in crept additively manufactured parts

In metal additive manufacturing (AM), understanding the process-structure-performance relationships requires a combination of multi-scale characterization techniques that allows for the measurement of the melt pool shape and boundary and classifying various defects and flaws in the AM parts. Such approaches can be destructive, only 2D in nature, or have a small field of view and can be complex to co-register and analyze. Here, in this work, we present a non-destructive 3D inspection technique that employs dual-energy X-ray computed tomography (XCT) along with a model-based iterative reconstruction (MBIR) and a new segmentation algorithm. The proposed approach and algorithm are not only capable of classifying and quantifying flaws such as pores, cracks, and inclusions, but they also allow for the extraction of microstructural features such as melt pool boundaries (MPB) and melt pool regions (MPR), that can help understand process-structure-performance relationships for alloys under study. As an exemplar application, we employed the method for characterization of an additively manufactured aluminum alloy crept under tensile stress at 300 °C for 1064 h. Our results demonstrate high quality segmentation and classification of various flaws and MPB and MPR, for the first time, using 3D X-ray CT inspection. The delineated MPB and MPR in the crept samples reveal the preferential growth paths of cracks that formed during creep deformation. The technique was used for successfully quantifying the characteristics (number of defects, their density, volume fraction, etc.) of the manufacturing-induced pores and creep-induced cracks, which is necessary to better understand the creep failure mechanisms of the material.

36 MATERIALS SCIENCE↗

Robust Interpretation of Electrochemical Impedance Spectra Using Numerical Complex Analysis

Electrochemical Impedance Spectroscopy (EIS) is a noninvasive technique widely used for understanding charge transfer and charge transport processes in electrochemical systems and devices. Standard approaches for the interpretation of EIS data involve starting with a hypothetical circuit model for the physical processes in the device based on experience/intuition and then fitting the EIS data to this circuit model. This work explores a mathematical approach for extracting key characteristic features from EIS data by relying on fundamental principles of complex analysis. These characteristic features can suggest the presence of inductors and constant phase elements (nonideal capacitors) from impedance data and enable us to answer questions about the identifiability and nonuniqueness of equivalent circuit models. In certain scenarios such as models with only resistors and capacitors, we are able to enumerate all possible families of circuit models. Finally, we apply the mathematical framework presented here to real-world electrochemical systems and highlight results using impedance measurements from a lithium-ion battery coin cell.

charge transfer↗

Model-based iterative reconstruction with adaptive regularization for artifact reduction in electron tomography

Obtaining high-quality 3D reconstructions from electron tomography of crystalline particles embedded in lighter support elements is crucial for various material systems such as catalysts for fuel cell applications. However, significant challenges arise due to the limited tilt range, sparse and low signal-to-noise ratio of the measurements. In addition, small metal particles can cause strong streaking and shading artifacts in the 3D reconstructions when using conventional reconstruction algorithms due to the presence of Bragg diffraction and the large scattering cross-section difference between the materials of the particles and the background support regions. These artifacts lead to errors in the downstream characterization affecting extraction of critical features such as the size of the metal particles, their distribution and the volume of the lighter support regions. In this paper, we present a two-stage algorithm based on metal artifact reduction, utilizing model-based iterative reconstruction methods with adaptive adjustment of regularization parameters. Our approach yields high-quality 3D reconstructions compared to traditional algorithms, accurately capturing both the metal particles as well as the background support. We demonstrate the effectiveness of our algorithm through simulated and experimental bright-field electron tomography data, showing significant improvements in reconstruction quality compared to traditional methods.

97 MATHEMATICS AND COMPUTING↗

Poster Abstract: Leveraging Large Language Models to Reveal Interpretable Cooling Behaviors from Smart Thermostat Data

Frequent heatwaves and hot summers increasingly challenge occupant comfort, health, and energy grid stability. Addressing these challenges requires a detailed understanding of household cooling behaviors, such as thermostat adjustments and adaptive responses to extreme conditions. Traditional analyses often rely on aggregated numerical metrics that overlook subtle but important household-specific variations. In this study, we introduce a generalizable methodology that integrates large language models (LLMs) with vision capabilities to enable scalable and detailed analysis of residential thermostat data. Using Ecobee's Donate Your Data (DYD) dataset—which provides five-minute records of indoor temperatures, thermostat setpoints, and HVAC runtimes—we focus on two U.S. cities with contrasting summer climates : Austin (TX) and Phoenix (AZ). Because raw time-series data are not well suited for direct LLM analysis, we transform them into visual representations, such as daily indoor temperature trajectories and weekly runtime histograms, to better capture behavioral variations. Leveraging LLMs' visual interpretation, we extract descriptive behavioral features, including temperature preferences, time-of-day cooling orientation, anticipatory versus reactive heatwave responses, and behavioral consistency. These semantic features support unsupervised clustering to identify distinct occupant archetypes at scale, revealing differences—such as morning-centric anticipatory coolers versus households that shift toward warmer setpoints during heatwaves—that can inform demand response, resilience planning, and health-aware interventions. By converting raw numerical data into interpretable behavioral patterns, this methodology enables scalable and practical analysis of occupant behavior, supporting actionable insights for comfort, resilience, and energy management.

Nihar, Kopal↗

Efficient Dimension Reduction of Complex Three-dimensional CO2 Saturation using Deep Learning Models

In the domain of deep learning (DL), dimension reduction is crucial for enhancing training efficiency and mitigating overfitting, particularly when managing complex data such as three-dimensional (3D) saturation data. The 3D saturation data in the context of geological carbon storage (GCS) presents unique challenges due to its inherent sparsity and the abrupt transitions at plume boundaries, known as shock fronts. To address the challenges, we proposed a novel DL framework that integrates dimension reduction with advanced 3D reconstruction techniques. Our model leveraged latent variables derived from 2D average saturation data, offering a robust and efficient solution tailored to the intricate dynamics of 3D saturation fields. The proposed framework can extract the critical features of the high-dimensional data while reducing the variable numbers, which is more tractable for DL models and enhances the model robustness and accuracy. Therefore, it provides a novel approach for modeling and analyses in complex geological scenarios, which finds great potential applications in environmental monitoring and energy storage.

Wang, Hongsheng↗

Remote Sensing Data as an Aid to Resource Management in Northern California

The usefulness of remote sensing data in providing general land use planning information concerning the coastal zone of northern California is evaluated. The degree to which physical land features can be extracted from remote sensing data by human interpretation or automatic methods is determined.

Source record↗

Phase 1 of the earth resources data analysis program

Research completed in the Earth Resources Data Analysis Program is discussed along with recommendations for future study. Projects discussed include use of the Cholesky decomposition in feature selection and classification algorithms; optimal feature selection and extraction, probability density estimation and nonparametric classifiers; use of spatial information in classification; and model for crop row reflectance. The installation of LARSYS on the ICSA's IBM 370/155 is discussed, and a list of technical reports is included.

Source record↗

Relevance of ERTS-1 to the State of Ohio

The author has identified the following significant results. During the first year of project effort the ability of ERTS-1 imagery to be used for mapping and inventorying strip-mined areas in south eastern Ohio, the potential of using ERTS-1 imagery in water quality and coastal zone management in the Lake Erie region, and the extent that ERTS-1 imagery could contribute to localized (metropolitan/urban), multicounty, and overall state land use needs were experimentally demonstrated and reported as significant project results. Significant research accomplishments were achieved in the technological development of manual and computerized methods to extract multi-feature information as well as singular feature information from ERTS-1 data as is exemplified by the forestry transparency overlay. Fabrication of an image transfer device to superimpose ERTS-1 data onto existing maps and other data sources was also a significant analytical accomplishment.

Sweet, D. C.↗

Separation of man-made and natural patterns in high-altitude imagery of agricultural areas

A nonstationary linear digital filter is designed and implemented which extracts the natural features from high-altitude imagery of agricultural areas. Essentially, from an original image a new image is created which displays information related to soil properties, drainage patterns, crop disease, and other natural phenomena, and contains no information about crop type or row spacing. A model is developed to express the recorded brightness in a narrow-band image in terms of man-made and natural contributions and which describes statistically the spatial properties of each. The form of the minimum mean-square error linear filter for estimation of the natural component of the scene is derived and a suboptimal filter is implemented. Nonstationarity of the two-dimensional random processes contained in the model requires a unique technique for deriving the optimum filter. Finally, the filter depends on knowledge of field boundaries. An algorithm for boundary location is proposed, discussed, and implemented.

Samulon, A. S.↗

Joint Classification and Data Compression of multidimensional information sources - Application to ERTS

This paper describes a concept of Joint Classification and Data Compression of multidimensional information sources in the context of applications to Earth Resources Technology Satellites. The concept is used to define an Information Extraction System intended to remove data redundancy early in the sensor to user link in both classification and film interpretation applications. The approach uses cascaded partially supervised clustering to extract spectral intensity features from spatially local sources. Data compression is then used to efficiently represent spatial features within the spectral intensity feature map.

Hilbert, E. E.↗

Precision processing of earth image data

Precise corrections of Landsat data are useful for generating land-use maps, detecting various crops and determining their acreage, and detecting changes. The paper discusses computer processing and visualization techniques for Landsat data so that users can get more information from the imagery. The elementary unit of data in each band of each scene is the integrated value of intensity of reflected light detected in the field of view by each sensor. To develop the basic mathematical approach for precision correction of the data, differences between positions of ground control points on the reference map and the observed control points in the scene are used to evaluate the coefficients of cubic time functions of roll, pitch, and yaw, and a linear time function of altitude deviation from normal height above local earth's surface. The resultant equation, termed a mapping function, corrects the warped data image into one that approximates the reference map. Applications are discussed relative to shade prints, extraction of road features, and atlas of cities.

Bernstein, R.↗

An image-data-compression algorithm

Cluster Compression Algorithm (CCA) preprocesses Landsat image data immediately following satellite data sensor (receiver). Data are reduced by extracting pertinent image features and compressing this result into concise format for transmission to ground station. This results in narrower transmission bandwidth, increased data-communication efficiency, and reduced computer time in reconstructing and analyzing image. Similar technique could be applied to other types of recorded data to cut costs of transmitting, storing, distributing, and interpreting complex information.

Hilbert, E. E.↗

Evaluating computer-drawn ground-cover maps

Computer-generated character maps from LANDSAT data are compared to aerial photos for test sites in Florida. Report Describes extraction of ground features by two analytical techniques: unsupervised clustering algorithm, called LANDSAT Signature Development Program (LSDP), and interactive algorithm based on multispectral image analyzer. Study concluded that computer classification of digital LANDSAT multispectral data, supplemented with certain ground-cover information, is valuable tool for analysis of renewable resources.

Arvanitis, L. G.↗

Principal component analysis of solar flares in the soft X-ray flux

The paper considers principal component analysis of solar flares in the soft X-ray flux, a technique for extracting the salient features from a mass of data. The method applies particularly to the analysis of nonstationary ensembles, and its computations require the evaluation of eigenvalues of matrices. The Eispack matrix eigen system routines were used to analyze full-disk proportional-counter data from the X-ray event analyzer which was part of the Skylab experiment. Empirical orthogonal functions were derived for events in the soft X-ray spectrum between 2.5 and 20 A during different time periods, indicating that about 90% of the cumulative power of each analyzed flare is contained in the largest eigenvector. The first two largest eigenvectors are sufficient for an empirical curve fit through the raw data and a characterization of solar flares in the soft X-ray flux, and power spectra of two largest eigenvectors reveal a reported periodicity of about 5 min.

Teuber, D. L.↗

Agricultural applications for thermal infrared multispectral scanner data

The use of the Thermal Infrared Multispectral Scanner (TIMS) data in agricultural landscapes is discussed. The TIMS allows for narrow-band analysis in the 8.2-11.6 micron range at spatial resolutions down to 5 meters in cell size. A coastal plain region in SE Alabama was studied using the TIMS. The crop/plant vigor, canopy density, and thermal response changes for soils obtained from thermal imagery are examined. The application of TIMS data to hydrologic and topographic issues, inventory and conservation monitoring, and the enhancement and extraction of cartographic features is described.

Pelletier, R. E.↗

An electrostatically and a magnetically confined electron gun lens system

Focal properties, electron trajectory calculations, and geometries are given for two electron 'gun' lens systems that have a variety of applications in, for example, electron-neutral and electron-ion scattering experiments. One nine-lens system utilizes only electrostatic confinement and is capable of focusing electrons onto a fixed target with extremely small divergence angles, over a range of final energies 1-790 eV. The second gun lens system is a simpler three-lens system suitable for use in a uniform, solenoidal magnetic field. While the focusing properties of such a magnetically confined lens systenm are simpler to deal with, the system does illustrate features of electron extraction and Brillouin flow that have not been suitably emphasized in the literature.

Bernius, Mark T.↗