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DOE OSTI2020

PdCu Single Atom Alloys for the Selective Oxidation of Methanol to Methyl Formate at Low Temperatures

The selective catalytic oxidation of methanol to methyl formate (MF) has been considered as an attractive route to produce MF, an important precursor in the chemical industry. Although supported Pd nanoparticles are active for the selective oxidation of methanol to MF, the relatively low MF selectivity and yield remains an unsolved issue. Here in this paper, we show that adding a small amount of Pd into Cu forming PdCu single atom alloy (SAA) catalysts can catalyze the oxidation of methanol to MF selectively at low temperatures, with a high catalyst stability. The atomic dispersion of Pd atoms in the Cu matrix was confirmed by various in-situ characterization techniques. The activity and selectivity of PdCu SAA catalysts were compared to monometallic Cu and Pd catalysts, in a flow reactor at similar conditions. This work may guide the design of new SAA based catalysts for selective oxidation reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Interaction-induced velocity renormalization in magic-angle twisted multilayer graphene

Abstract Twistronics heterostructures provide a novel route to control the electronic single particle velocity and thereby to engineer strong effective interactions. Here we show that the reverse may also hold, i.e. that these interactions strongly renormalize the band structure. We demonstrate this mechanism for alternating-twist magic-angle three- and four-layer graphene at charge neutrality and in the vicinity of a phase transition which can be described by an Ising Gross-Neveu critical point corresponding, e.g. to the onset of valley Hall or Hall order. While the non-interacting model displays massless Dirac excitations with strongly different velocities, we show that interaction corrections make them equal in the infrared. However, the renormalization group flow of the velocities and of the coupling to the critical bosonic mode is strongly non-monotonic and dominated by the vicinity of a repulsive fixed point. We predict experimental consequences of this theory for tunneling and transport experiments and discuss the expected behavior at other quantum critical points, including those corresponding to intervalley coherent ordering.

Classen, Laura↗

NASA NTRS2000

Practical Considerations of Waste Heat Reuse for a Mars Mission Advanced Life Support System

Energy conservation is a key issue in design optimization of Advanced Life Support Systems (ALSS) for long-term space missions. By considering designs for conservation at the system level, energy saving opportunities arise that would otherwise go unnoticed. This paper builds on a steady-state investigation of system-level waste heat reuse in an ALSS with a low degree of crop growth for a Mars mission. In past studies, such a system has been defined in terms of technology types, hot and cold stream identification and stream energy content. The maximum steady-state potential for power and cooling savings within the system was computed via the Pinch Method. In this paper, several practical issues are considered for achieving a pragmatic estimate of total system savings in terms of equivalent system mass (ESM), rather than savings solely in terms of power and cooling. In this paper, more realistic ESM savings are computed by considering heat transfer inefficiencies during material transfer. An estimate of the steady-state mass, volume and crewtime requirements associated with heat exchange equipment is made by considering heat exchange equipment material type and configuration, stream flow characteristics and associated energy losses during the heat exchange process. Also, previously estimated power and cooling savings are adjusted to reflect the impact of such energy losses. This paper goes one step further than the traditional Pinch Method of considering waste heat reuse in heat exchangers to include ESM savings that occur with direct reuse of a stream. For example, rather than exchanging heat between crop growth lamp cooling air and air going to a clothes dryer, air used to cool crop lamps might be reused directly for clothes drying purposes. When thermodynamically feasible, such an approach may increase ESM savings by minimizing the mass, volume and crewtime requirements associated with stream routing equipment.

Levri, Julie↗

NASA NTRS2007

Simulation of Terminal-Area Flight Management System Arrivals with Airborne Spacing

A simulation evaluated the feasibility and potential benefits of using decision support tools to support time-based airborne spacing and merging for aircraft arriving in the terminal area on charted Flight Management System (FMS) routes. Sixteen trials were conducted in each treatment combination of a 2X2 repeated-measures design. In trials 'with ground tools' air traffic controller participants managed traffic using sequencing and spacing tools. In trials 'with air tools' approximately seventy-five percent of aircraft assigned to the primary landing runway were equipped for airborne spacing, including flight simulators flown by commercial pilots. The results indicate that airborne spacing improves spacing accuracy and is feasible for FMS operations and mixed spacing equipage. Controllers and pilots can manage spacing clearances that contain two call signs without difficulty. For best effect, both decision support tools and spacing guidance should exhibit consistently predictable performance, and merging traffic flows should be well coordinated.

Callantine, Todd J.↗

DOE OSTI2026

SimH 2 : an integrated techno-economic modeling framework for hydrogen pipeline infrastructure and network optimization

Large-scale hydrogen (H 2 ) pipeline transport design and network optimization have seldom been reported due to the lack of a cost model accounting for the relationship between transport cost and hydrogen mass flow rate. Here, this work introduced a system-level cost model for hydrogen pipeline transport at supercritical state and integrated it with an existing CO 2 pipeline network tool, SimCCS, for hydrogen-specific pipeline design and optimization. The Intermountain West (I-West) region of the U.S., historically dependent on fossil fuel-based economies, is chosen to demonstrate the capabilities of our H 2 pipeline cost model and transport network optimization platform called SimH 2 . Two scenarios are examined: one where the pipeline is not allowed to pass through disadvantaged communities and the other where it is permitted. The results highlight that incorporating disadvantaged-community constraints lead to longer pipeline routes and increased transport costs, reflecting the trade-offs involved in equitable infrastructure development. It is demonstrated that the newly developed SimH 2 tool not only enables the efficient design of H 2 transportation pipelines but also optimizes the network by accounting for local terrain and the presence of disadvantaged areas.

08 HYDROGEN↗

DOE OSTI2024

Polymer Macrocycles: A novel topology to control dynamics of rubbery materials (Final Report)

One of the current challenges in polymer physics and engineering is to understand the behavior of circular macromolecules. Though such molecules have been made by dilute solution ring closure methods in the past, such procedures have been limited to relatively small, unentangled rings as well as to small sample quantities. Initial studies were also hampered by issues surrounding purity of the rings, though this problem has been somewhat overcome by the use of liquid chromatography at critical conditions (LCCC) methods that separate rings and linear chains. Furthermore, in spite of the continued progress a full understanding of ring dynamics remains elusive. The present work has addressed multiple aspects of the behavior of ring molecules by using a novel synthetic route: reversible radical recombination redox polymerization (R3P) to produce poly(3,6-dioxa-1,8-octanedithiol) (PolyDODT) molecules. The synthesis conditions were chosen to produce linear (LDODT), cyclic (RDODT) and linear-cyclic mixtures (LRDODT) in order to investigate dilute solution and rheological responses of the materials. Importantly, the R3P synthesis makes larger quantities and higher molecular weights than do the dilute solution ring closure methods and also has the potential to be scaled to industrial quantities, thus becoming commercializable. We emphasize two important outcomes of the work. The first is that the rheological investigation shows that very large molecular weight the PolyDODT rings permitted the investigation of ring dynamics from glassy towards terminal flow for molecular sizes corresponding to approximately 300 entanglements of the linear counterpart. At the same time, these very large sized rings could be diluted in a solvent in order to reduce the molecular entanglement density to less than unity. The results demonstrate that ring viscosity follows a Rouse-like linear dependence on molecular weight or entanglement number to approximately 15 entanglements. This range of "Rouse-like" response is greater than what was achieved in all prior works where synthesis conditions have limited the molecular sizes achievable. After the entanglement number $Z_w$ increases beyond approximately 15, we find that the viscosity-molecular weight scaling undergoes a rapid change from the Rouse-like $η\sim{Z}^1_w$ to a very strong power-law scaling that is approximately $η\sim{Z}^{5.8}_w$. This aspect of the work strongly suggests that prior investigations on highly pure rings have invariably been performed on unentangled systems simply because ring molecules have very high entanglement thresholds. The results are further supported by plateau modulus measurements that show that in the "Rouse-like" viscosity regime, for the RDODT samples there is a corresponding lack of a rubbery entanglement plateau and once entanglement coupling is seen, the rubbery plateau also appears in the dynamic modulus data. Furthermore, upon appropriate scaling, we show that the unentangled polyDODT rings (i.e., the diluted high molecular weight rings) show virtually identical dynamics (upon appropriate scaling to account for the chain dilutions) to the dynamics of similarly unentangled LCCC fractionated polystyrene rings.

36 MATERIALS SCIENCE↗

NASA NTRS1992

Indian Ocean analyses

The background and goals of Indian Ocean thermal sampling are discussed from the perspective of a national project which has research goals relevant to variation of climate in Australia. The critical areas of SST variation are identified. The first goal of thermal sampling at this stage is to develop a climatology of thermal structure in the areas and a description of the annual variation of major currents. The sampling strategy is reviewed. Dense XBT sampling is required to achieve accurate, monthly maps of isotherm-depth because of the high level of noise in the measurements caused by aliasing of small scale variation. In the Indian Ocean ship routes dictate where adequate sampling can be achieved. An efficient sampling rate on available routes is determined based on objective analysis. The statistical structure required for objective analysis is described and compared at 95 locations in the tropical Pacific and 107 in the tropical Indian Oceans. XBT data management and quality control methods at CSIRO are reviewed. Results on the mean and annual variation of temperature and baroclinic structure in the South Equatorial Current and Pacific/Indian Ocean Throughflow are presented for the region between northwest Australia and Java-Timor. The mean relative geostrophic transport (0/400 db) of Throughflow is approximately 5 x 106 m3/sec. A nearly equal volume transport is associated with the reference velocity at 400 db. The Throughflow feeds the South Equatorial Current, which has maximum westward flow in August/September, at the end of the southeasterly Monsoon season. A strong semiannual oscillation in the South Java Current is documented. The results are in good agreement with the Semtner and Chervin (1988) ocean general circulation model. The talk concludes with comments on data inadequacies (insufficient coverage, timeliness) particular to the Indian Ocean and suggestions on the future role that can be played by Data Centers, particularly with regard to quality control of data as research bodies are replaced by operational bodies in the Global Ocean Observing System.

Meyers, Gary↗

DOE OSTI2025

Ultralow-temperature cryogenic transmission electron microscopy using a new helium flow cryostat stage

Advances in cryogenic electron microscopy have opened new avenues for probing quantum phenomena in correlated materials. This study reports the installation and performance of a new side-entry condenZero cryogenic cooling system for JEOL (Scanning) Transmission Electron Microscopes (S/TEM), utilizing compressed liquid helium (LHe) and designed for imaging and spectroscopy at ultra-low temperatures. The system includes an external dewar mounted on a vibration-damping stage and a pressurized, low-noise helium transfer line with a remotely controllable needle valve, ensuring stable and efficient LHe flow with minimal thermal and mechanical noise. Performance evaluation demonstrates a stable base temperature of 4.37 K measured using a Cernox bare chip sensor on the holder with temperature fluctuations within ±0.004 K. Complementary in-situ electron energy-loss spectroscopy (EELS) via aluminum bulk plasmon analysis was used to measure the local specimen temperature and validate cryogenic operation during experiments. The integration of cryogenic cooling with other microscopy techniques, including electron diffraction and Lorentz TEM, was demonstrated by resolving charge density wave (CDW) transitions in NbSe2 using electron diffraction, and imaging nanometric magnetic skyrmions in MnSi via Lorentz TEM. In conclusion, this platform provides reliable cryogenic operation below 7 K, establishing a low-drift route for direct visualization of electronic and magnetic phase transformations in quantum materials.

Charge density wave↗

DOE OSTI2024

Hourly dynamic line ratings for existing transmission across the contiguous United States (preliminary results) [Slides]

The thermal rating of a transmission line depends on the rate at which heat generated by current flow through the line can be dissipated into the environment by convective and radiative cooling, keeping the conductor below a maximum operating temperature. Static or seasonal line ratings assume nearly-worst-case weather conditions (high ambient air temperature, high solar irradiance, and low wind speed), resulting in a low risk of "overrating" a line (i.e., allowing more current to flow than the line is designed for) but a high fraction of time when the line is "underrated" (i.e., able to flow more current while staying below the maximum temperature). Dynamic transmission line ratings (DLR) use real-time measurements of weather conditions, line sag, or line temperature to determine the thermal rating of transmission lines at hourly or higher time resolution, allowing for increased ratings during some (cold, windy, and/or dark) periods and correcting for overrating during other (hot, calm, and/or sunny) periods. Many studies have explored the benefits of DLR, but typically for small collections of transmission lines under a limited sample of weather conditions, leaving open the question of how widely applicable the benefits of DLR might be over diverse geographies and weather conditions. Here, we combine geospatial data on tens of thousands of transmission line routes across the contiguous United States with high-resolution hourly historical weather data for 2007-2013 to estimate the impact of DLR and other weather-adjusted rating systems. We compare static and dynamic line ratings to intermediate ratings adjusted by ambient temperature, day/night irradiance, clear-sky irradiance, and/or measured irradiance, illustrating the benefits of incorporating progressively more detailed weather data into the calculated line ratings. Moving from nighttime-adjusted ratings to clear-sky-adjusted ratings provides more benefit than moving from clear-sky-adjusted ratings to measured-irradiance-adjusted ratings. Depending on the assumed static windspeed for irradiance-adjusted-ratings, DLR either corrects for overrated hours or provides substantially increased ratings in the majority of hours on the majority of lines.

14 SOLAR ENERGY↗

DOE OSTI2020

Catchment storage and residence time in a periodically irrigated watershed

Understanding anthropogenic impacts on water storage and water flow pathways in catchments is an ongoing challenge in hydrology. Here, we study the dynamics of subsurface storage and residence time of water in a catchment in Berkeley, California, that is within a regional park but contains diverse land use within its perimeter, including a periodically irrigated golf course. Our study combines several isotopic tracers with water budget data to examine sources of water in a stream draining the site. Irrigation water, applied to a small area of the watershed, is a minor component of the water budget. However, geochemical tracers reveal that irrigation water is a significant fraction of stream flow downstream of the golf course during baseflow and during precipitation events. Isotopic tracers indicate that the watershed has a preference to release young water for stream flow generation, resulting in contrasting tritium ages for stream water and groundwater of 1.3 ± 0.5 year and 8.2 ± 1.7 year, respectively. We determined that the older water is a very small component (0.7%) of the stream water in the tail of an assumed exponential distribution. We used the seasonal variation of stable water isotopes in precipitation and stream water over two water years to explain the damping of the isotopic signature of stream water, which yields information about the catchment's response to the input signal. In conclusion, the methods described here may be applicable to other urban or suburban headwater catchments in areas with a component of non-natural recharge from, for example, leaky infrastructure, storm water routing or dry season irrigation.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2005

How to Control Airline Routes from the Supply Side: The Case of TAP

Competition in the European airline industry is currently fierce in the face of depressed demand conditions, and in the wake of privatizations and liberalization. The Portuguese flag carrier, TAP Air Portugal, operates within this environment. It is a medium sized carrier that was part of the defunct Qualiflyer Group alliance and has recently joined the Star Alliance. It controls more than 50% of the air market between Europe and Brazil and Europe and Angola. Nevertheless, it has been experiencing financial losses. One reason for this is that, following the reasoning of Ronald Coase (1946), it is difficult for any company with decreasing average costs to recover full costs in a highly competitive market. One way of approaching the problem is to establish quasi-monopoly power and airlines have done this through such things as frequent flyer programs and hub-and-spoke operations. Other airlines, notably charter carriers, have sought to adjust capacity and services to meet an anticipated cash flow. In practice, many have used a combination of measures with mixed success. This paper focuses on how TAP has responded to changing conditions by adjusting its supply-side activities in terms of restructuring its network to maximize potential revenues.

Button, Kenneth↗

NASA NTRS2013

Flight Deck Surface Trajectory-based Operations (STBO): Results of Piloted Simulations and Implications for Concepts of Operation (ConOps)

The results offour piloted medium-fidelity simulations investigating flight deck surface trajectory-based operations (STBO) will be reviewed. In these flight deck STBO simulations, commercial transport pilots were given taxi clearances with time and/or speed components and required to taxi to the departing runway or an intermediate traffic intersection. Under a variety of concept of operations (ConOps) and flight deck information conditions, pilots' ability to taxi in compliance with the required time of arrival (RTA) at the designated airport location was measured. ConOps and flight deck information conditions explored included: Availability of taxi clearance speed and elapsed time information; Intermediate RTAs at intermediate time constraint points (e.g., intersection traffic flow points); STBO taxi clearances via ATC voice speed commands or datal ink; and, Availability of flight deck display algorithms to reduce STBO RTA error. Flight Deck Implications. Pilot RTA conformance for STBO clearances, in the form of ATC taxi clearances with associated speed requirements, was found to be relatively poor, unless the pilot is required to follow a precise speed and acceleration/deceleration profile. However, following such a precise speed profile results in inordinate head-down tracking of current ground speed, leading to potentially unsafe operations. Mitigating these results, and providing good taxi RTA performance without the associated safety issues, is a flight deck avionics or electronic flight bag (EFB) solution. Such a solution enables pilots to meet the taxi route RTA without moment-by-moment tracking of ground speed. An avionics or EFB "error-nulling" algorithm allows the pilot to view the STBO information when the pilot determines it is necessary and when workload alloys, thus enabling the pilot to spread his/her attention appropriately and strategically on aircraft separation airport navigation, and the many other flight deck tasks concurrently required. Surface Traffic Management (STM) System Implications. The data indicate a number of implications regarding specific parameters for ATC/STM algorithm development. Pilots have a tendency to arrive at RTA points early with slow required speeds, on time for moderate speeds, and late with faster required speeds. This implies that ATC/STM algorithms should operate with middle-range speeds, similar to that of non-STBO taxi performance. Route length has a related effect: Long taxi routes increase the earliness with slow speeds and the lateness with faster speeds. This is likely due to the" open-loop" nature of the task in which the speed error compounds over a longer time with longer routes. Results showed that this may be mitigated by imposing a small number oftime constraint points each with their own RTAs effectively tuming a long route into a series of shorter routes - and thus improving RTA performance. STBO ConOps Implications. Most important is the impact that these data have for NextGen STM system ConOps development. The results of these experiments imply that it is not reasonable to expect pilots to taxi under a "Full STBO" ConOps in which pilots are expected to be at a predictable (x,y) airport location for every time (t). An STBO ConOps with a small number of intermediate time constraint points and the departing runway, however, is feasible, but only with flight deck equipage enabling the use of a display similar to the "error-nulling algorithm/display" tested.

Foyle, David C.↗

DOE OSTI2023

Hierarchical Control and Stability Analysis for a Nonisolated Grid-Tied DC Energy Router Integrating Energy Storage and Partial Distributed Generation

This article proposes a nonisolated dc converter-based energy router (dc-ER) and its operating strategy. Here, the intent is to integrate energy storage (ES), distributed generation (DG), local load, and dc power grid in an autonomous and more efficient way. The ES/DG power ports are coupled with each other in partial-type connections, which obtains higher voltage supply gain and direct input–output power transmission. High-voltage supply gain allows a wide solar power tracking range and the possibility of optimal battery charging/discharging. Direct input–output power transmission improves the energy conversion efficiency. In this article, the operating modes of dc-ER are first analyzed, followed by the optimal hardware design counting the DG current ripple minimization and the limitation caused by the power flow direction. Second, the mathematical model of dc-ER is deduced. The hierarchical control is then proposed to manage port energy in a flexible manner. The stability is analyzed by using impedance modeling. Finally, experimental and simulation results verify the superiorities of the proposed topology in terms of flexible operating mode transition and high-power conversion efficiency.

25 ENERGY STORAGE↗

DOE OSTI2021

mosartwmpy: A Python implementation of the MOSART-WM coupled hydrologic routing and water management model

mosartwmpy is a Python implementation of the Model for Scale Adaptive River Transport with Water Management (MOSART-WM). This new version retains the functionality of the legacy model (written in FORTRAN) while providing new features to enhance user experience and extensibility. MOSART is a large-scale river-routing model used to study riverine dynamics of water, energy, and biogeochemistry cycles across local, regional, and global scales (Li et al., 2013). The WM component introduced by Voisin et al. (2013) represents river regulation through reservoir storage and release operations, diversions from reservoir releases, and allocation to sectoral water demands. Each reservoir release is independently calibrated using long-term mean monthly inflow into the reservoir, long-term mean monthly demand associated with this reservoir, and reservoir goals (flood control, irrigation, recreation, etc.). Generic monthly pre-release rules and storage targets are set up for individual reservoirs; however, those releases are updated annually for inter-annual variability (dry or wet year) and daily for environmental constraints such as flow minimum release and minimum/maximum storage levels. The WM model allows an evaluation of the impact of water management over multiple river basins at once (global, continental scales) and with consistent representation of human operations over the full domain.

97 MATHEMATICS AND COMPUTING↗

NASA NTRS2004

Pharmacotherapeutic Aspects of Space Medicine

Medications are used for a wide variety of indications during space flight. For example, astronauts have taken drugs in flight to ameliorate or prevent symptoms of space motion sickness, headache, sleeplessness, backache, nasal congestion, and constipation. Russian cosmonauts reportedly take medications to prevent metabolic disturbances of the myocardium and intestinal flora, and to optimize their work capacity. Although the discomfort associated with some acute responses to microgravity (e.g., space motion sickness) is expected to diminish with length of time in flight, other responses that have delayed onset (e.g., maintaining nutritional status, bone and muscle strength, and perhaps immune response) may affect health and quality of life during longer missions. Therefore, as the duration of space flights increases, the need for treatment with medications is expected to increase accordingly. Medications carried on Space Shuttle missions have varied somewhat from flight to flight, depending on the individual needs of the crewmembers. Medications use during Shuttle flights seems to be more prevalent than during earlier programs, perhaps because drugs are provided in easy-to-use forms. In fact, nearly all medications taken to date have been ingested orally in tablet form. However, given that the oral route may not be ideal for those suffering motion-sickness symptoms, intramuscular and intranasal preparations are being tested. For example, intramuscular administration of promethazine hydrochloride (Phenergan(Registered TradeMark)) has been reported to be more effective in alleviating motion-sickness symptoms. The difficulties involved in conducting definitive studies of drug efficacy during U.S. space flights have been compounded by the absence of a systematic approach to determining which drugs were taken by whom and under what circumstances. The use of some drugs in space has been less efficacious than expected. The onset, intensity, and duration of the response produced by any drug depend upon rates of absorption, distribution, metabolism, and elimination of the drug; space flight-induced changes in blood flow and the function of the gastrointestinal (GI) tract, liver, or kidneys may alter these processes. Another important aspect of clinical efficacy of medications in space is the stability of pharmaceuticals. As the U.S. space program is moving toward extended Space Shuttle flights and beyond, to space station missions and planetary explorations, understanding how space flight affects organ systems and clinical pharmacology is necessary to optimize pharmacotherapeutics in space and ensure adequate safety and health of crewmembers.

Putcha, Lakshmi↗

DOE OSTI2022

Analytical Modeling of Biomass Transport and Feeding Systems

The processing of biomass solids in a biorefinery consists of pretreatment, enzyme hydrolysis / concurrent fermentation of sugars to ethanol, product recovery, and drying. Sustainable operation requires a front end that transforms wet solids into a pumpable slurry. Otherwise the biorefinery will suffer unscheduled shut-downs and inefficient operation due to solids that obstruct pumps and other equipment and resist mixing in a bioreactor. Downtime in pioneer biorefineries due to interruptions from materials handling problems has been 50% or more, leading to unsustainable manufacturing processes. This work addresses new technology, predictive computational models, and definition of operational conditions that result in formation of slurries of corn stover at up to 300 g/L using low enzyme loadings (1 to 3 FPU cellulase/g) before the biomass (corn stover) enters the pretreatment step. A team of researchers from Purdue University, Idaho National Laboratory (INL), Forest Concepts, AdvanceBio, Argonne National Laboratory, and DOE BETO have combined their knowledge in agricultural and biological engineering, bioprocess engineering, mechanical engineering, chemical engineering, agricultural economics, materials engineering and enzyme and microbial technology to address the challenge of making lignocellulose flow. This team effort has resulted in the development and validation of conditions that employ low levels of commercial enzyme in an agitated bioreactor to which corn stover pellets are added resulting in formation of slurries at high solids loadings, before pretreatment. This approach overcomes challenges caused by handling of dry, particulate biomass materials at the front end of the biorefinery. The subsequent materials handling issues cause obstruction at pumps, pipes and valves. Formation of high loadings slurries with low yield stress, as reported here, significantly decreases the potential for process interruption and enhances plant operability. Key advances in the knowledge of how slurry formation occurs is reported here and in recently published journal papers. We found that pellets are needed to achieve high solids loading, and that commercial enzymes are effective in forming slurries of corn stover particles from pellets that have not been pretreated. Our work has resulted in models that predict solids behavior for formation of compressed solids and pellets that in turn facilitate slurries made of high concentrations of corn stover particles. A computational model was developed that gives mechanistic insights into properties of particles and mixing process that gives the slurry rheology needed to facilitate pumping. Hence, the corn stover may be pumped into a pretreatment reactor in place of auguring in solids against high pressure which is a root cause of interruptions at the front end of a biorefinery. Subsequent mixing in enzyme and microbial bioreactors results in conversion of lignocellulose to sugars in a biorefinery in agitated bioreactors, with flows in and out of the vessels being less likely to be interrupted due to plugging or materials handling problems. The obtained data coupled to process models, techno-economic assessment (TEA) and Life Cycle Analysis (LCA) were used to assess whether this approach is practical. These results are based on a foundation of laboratory characterization and pilot runs. The NREL biochemical sugar model was utilized to carry out techno-economic analysis of enzyme catalyzed liquefaction followed by enzyme hydrolysis. The minimum sugar selling price was between 17.5 and 18.3 ¢/pound or about the same as calculated by the NREL model for dilute acid pretreatment followed by enzyme hydrolysis. Life cycle analysis (LCA) based on Argonne’s Greet Model showed the enzyme catalyzed route had the lowest greenhouse gas emissions of the three combinations studied (i.e., enzyme, enzyme mimetic, and enzyme + mimetic combined). GHG emissions for enzyme-based corn stover liquefaction step, alone, were about 21 g CO 2 -equivalent/kg of liquefied slurry. We believe this approach will further enhance operability of a pioneer biorefinery, and bring large-scale conversion of lignocellulosic biomass to low carbon footprint biofuels closer to implementation.

09 BIOMASS FUELS↗

NASA NTRS2009

Integrated Traffic Flow Management Decision Making

A generalized approach is proposed to support integrated traffic flow management decision making studies at both the U.S. national and regional levels. It can consider tradeoffs between alternative optimization and heuristic based models, strategic versus tactical flight controls, and system versus fleet preferences. Preliminary testing was accomplished by implementing thirteen unique traffic flow management models, which included all of the key components of the system and conducting 85, six-hour fast-time simulation experiments. These experiments considered variations in the strategic planning look-ahead times, the replanning intervals, and the types of traffic flow management control strategies. Initial testing indicates that longer strategic planning look-ahead times and re-planning intervals result in steadily decreasing levels of sector congestion for a fixed delay level. This applies when accurate estimates of the air traffic demand, airport capacities and airspace capacities are available. In general, the distribution of the delays amongst the users was found to be most equitable when scheduling flights using a heuristic scheduling algorithm, such as ration-by-distance. On the other hand, equity was the worst when using scheduling algorithms that took into account the number of seats aboard each flight. Though the scheduling algorithms were effective at alleviating sector congestion, the tactical rerouting algorithm was the primary control for avoiding en route weather hazards. Finally, the modeled levels of sector congestion, the number of weather incursions, and the total system delays, were found to be in fair agreement with the values that were operationally observed on both good and bad weather days.

Grabbe, Shon R.↗

DOE OSTI2020

Anode Boosted Electrolyzer

The aim of this project is to develop an anode catalyst and anolyte delivery system in renewably powered flow-electrolyzers that utilize waste carbon dissolved in non-potable process water as the anolyte to lower the overall cell potential at which hydrogen is generated (Anode-Boosting) while simultaneously purifying a non-potable water source. This project spans several of the desired aspects in the Renewable Hydrogen Transportation Fuel Pathways of interest: it combines renewably sourced energy with waste hydrocarbons, leading to enhanced water-splitting and eventual delivery and distribution of hydrogen for use in fuel cell powered transportation. Deployment of an Anode-Boosted Electrolysis process will provide a significant improvement in the effective energy efficiency for the generation of hydrogen due to a reduced cell potential and the desirable removal of organic impurities in waste water, offering a route to generating clean hydrogen and clean(er) water.

08 HYDROGEN↗