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At least 451 records · Page 25

Quantitative 3D Textural and Petrofabric Analysis of the Northwest Africa 10645 Nakhlite Using X-Ray Computed Tomography

Martian meteorites are currently the only samples available from Mars to study and are critical for elucidating variability in martian igneous processes over time [e.g., 1]. Quantifying igneous textures and fabrics can help us understand how rocks are formed and emplaced [e.g., 2]. These features are innately three dimensional (3D) and are often strongly heterogeneous in cumulate rocks, like the nakhlites and poikilitic shergottites [2–3], where there can be substantial textural variations between and within individual samples. However, most quantitative textural and fabric analyses on these samples have been limited to two dimensions through measurements made on polished petrographic thin sections. Thus, 3D petrographic measurements are imperative for both representative sample characterization and accurately interpreting magmatic processes. The emplacement of martian meteorites at or near the surface of Mars (i.e., extrusive or intrusive, respectively) remains enigmatic due to the innate lack of geologic context [e.g., 1], but conducting 3D quantitative textural and fabric analyses can help elucidate emplacement mechanisms and settings on Mars.

S. Ramsey↗

An experimental investigation on the CO 2 storage capacity of the composite confining system

Assuring secure containment of stored CO 2 is of paramount importance—for climate change mitigation, for permitting, and for reassuring the public. Regional seals, such as those sealing petroleum accumulations, have proven to be effective for securing CO 2 . However, the goal of permanent sequestration can also be satisfied with “composite confining systems” consisting of multiple, possibly discontinuous flow barriers that, in aggregate, create a system with very high permeability anisotropy and effectively retard the vertical migration of CO 2 . This study focuses on investigating the barrier characteristics necessary for effective containment of CO 2 , using both physical flow experiments and modified invasion percolation simulations. The simulations are calibrated to the physical experiments and are used to further extend the analysis. Results show that for a composite confining system, a) even barriers with low capillary entry pressure contrast to the underlying flow unit can divert rising CO 2 ; b) curved or anticlinal barrier topography can enhance CO 2 trapping; c) fining-upward gradations make little difference to barrier effectiveness or CO 2 retention; d) longer barriers retain more CO 2 regardless of barrier topography. Finally, field-scale simulations have demonstrated the importance of barrier length for increasing CO 2 storage capacity. Furthermore, the results presented can be used to inform the development of new screening criteria for characterization and effectiveness of composite confining systems.

58 GEOSCIENCES↗

Quantitative investigations of geologic surfaces utilizing airborne visible/infrared imaging spectrometer (AVIRIS) and polarimetric radar (AIRSAR) data for Death Valley, California

Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and polarimetric radar (AIRSAR) data were collected over Death Valley, California, USA, in September 1989. These two data sets were used to quantitatively characterize both the mineralogy and surface structure of the valley floor. Field mapping and characterization of the salt flats across the valley identified 16 separate units. The AVIRIS data were calibrated using the 'empirical line' method, and spectra extracted for the 16 units. A water vapor map was generated from the AVIRIS data and showed spatial variations in its distribution due to evaporation of surface water. Unmixing of the 16 spectral units produced maps of endmember abundance.

Kierein-Young, Kathryn S.↗

Applicability of Electrical and Electroanalytical Techniques to Detect Water and Characterize the Geochemistry of Undisturbed Planetary Soils

The search for life is a primary goal of NASA s planetary exploration program. The search is, of necessity, tiered in both the detection approach (looking for evidence of microbial fossils or the presence of water in the geological history of a planetary body and/or looking for evidence of water, energy sources, precursors to life, signatures of life and/or life itself in the present day planetary environment) and in the survey method (scale, range, specificity) employed. Terrestrial investigations suggests that life as we know it requires water. Thus, the search for extant microbial life and habitats requires identifying water-bearing soils. Determining Reduction-Oxidation (REDOX) couples present in water, once it is found, provides information on soil geochemistry and identifies potential chemical energy sources for life. Mars offers a near-term target for conducting this search. The identification of gully formation [1], layered deposits [2] and elemental ratios of bromine and chlorine [3] present indirect evidence that water was abundant locally in the Martian past. Additionally, Viking images of polar ice and frost formation on the surface of Mars demonstrate that water can exist in at least some near-surface regions of present-day Mars. Atmospheric pressure data further suggest that liquid water may be stable for short periods of time in the mid-latitudes of the Martian surface. [4] Measurements of the global distribution of hydrogen in the Martian regolith offer tantalizing indirect evidence that water may at least exist in near-surface soils. [5] Evidently, any water to be found is likely to exist as soil mixtures at levels ranging between approx.0.5% and approx.5 %.

Seshadri, S.↗

Chemical differentiation on one-plate planets: Predictions and geologic observations for Venus

Recent studies have examined the partial melting of planetary interiors on one-plate planets and the implications for the formation and evolution of basaltic crust and the complementary residual mantle layer. In contrast to the Earth, where the crust and residual layer move laterally and are returned to the interior following subduction, one-plate planets such as Venus are characterized by vertical accretion of the crust and residual layer. The residual mantle layer is depleted and compositionally buoyant, being less dense than undepleted mantle due to its reduced Fe/Mg and dense Al-bearing minerals; its melting temperature is also increased. As the crust and depleted mantle layer grow vertically during the thermal evolution of the planet, several stages develop. As a step in the investigation and testing of these theoretical treatments of crustal development on Venus, we investigate the predictions deriving from two of these stages (a stable thick crust and depleted layer, and a thick unstable depleted layer) and compare these to geologic and geophysical observations, speculating on how these might be interpreted in the context of the vertical crustal accretion models. In each case, we conclude with an outline of further tests and observations of these models.

Head, James W., III↗

Ground-based observation of near-Earth asteroids

An increased ground-based observation program is an essential component of any serious attempt to assess the resource potential of near-Earth asteroids. A vigorous search and characterization program could lead to the discovery and description of about 400 to 500 near-Earth asteroids in the next 20 years. This program, in conjunction with meteorite studies, would provide the data base to ensure that the results of a small number of asteroid-rendezvous and sample-return missions could be extrapolated with confidence into a geological base map of the Aten, Apollo, and Amor asteroids. Ground-based spectral studies of nearly 30 members of the Aten/Apollo/Amor population provide good evidence that this class includes bodies composed of silicates, metal-silicates, and carbonaceous assemblages similar to those found in meteorites. The instruments that are being used or could be used to search for near-Earth asteroids are listed. Techniques useful in characterizing asteroids and the types of information obtainable using these techniques are listed.

Gaffey, Michael J.↗

Solid earth as a recycling systems and the lateral growth of Precambrian North America

If plotted on mass vs time diagrams, geologic entities (for example, continental and oceanic crust, sediments, and mineral resources) display an exponential (power law) relationship, with entity per unit time increasing toward the present. This relationship is consistent with the concept of recycling and can be simulated mathematically. The approach is based on the plate tectonic theory and considers area-age or mass-age distributions of crystalline basement and sediments for major global tectonic realms. Each tectonic realm is characterized by a specific lifespan, which is an inverse function of its recycling rate. The estimated average half-area of half-mass ages are given. The corresponding parameters for continental crust are 690 Ma for K/Ar, and approximately 1200 Ma for Rb/St and U-Th/Pb dating pairs. Tectonic diversity preserved in the geologic record is therefore a function of time, with oceanic tectonic realms, because of their rapid recycling, underrepresented in the rocks older than approximately 300 Ma. The Sm/Nd isotopic systematic of sediments suggest that, for a near steady-state post-Archean sedimentary mass, recycling is approximately 90 + or - 5 percent cannibalistic. This yields an estimated upper limit on crust-mantle exchange via sediment subduction of approximately 1.1 + or - 0.5 x 10 g a(sup -1) considerably less than demanded by isotopic constraints. The discrepancy may indicate the existence of additional loci, such as orogenic belts, for significant crust-mantle interaction.

Veizer, Jan↗

Quartz Dissolution Effects on Flow Channelization and Transport Behavior in Three‐Dimensional Fracture Networks

We perform a set of reactive transport simulations in three-dimensional fracture networks to characterize the impact of geochemical reactions on flow channelization. Flow channelization, a frequently observed phenomenon in porous and fractured subsurface rock formations, results from the spatially variable hydraulic resistance offered by a geological structure. In addition to geo-structural features such as network connectivity, geometry, and hydraulic resistance, geochemical reactions, for example, dissolution and precipitation, can dynamically inhibit or enhance flow channelization. These geochemical processes can change the fracture permeability leading to increased flow channelization, which are localized connected regions of high volumetric flow rates that are seemingly ubiquitous in the subsurface. In our simulations, fractures partially filled with quartz are gradually dissolved until quasi-steady state conditions are obtained. We compare the flow field's initial unreacted and final dissolved states in terms of flow and transport observations. We observe that the dissolved fracture networks provide less resistance to flow and exhibit increased flow channelization when compared to their unreacted counterparts. However, there is substantial variability in the magnitude of these changes which implies that the channelization strongly depends on the network structure. In turn, we identify the interplay between the particular network structure and the impact of geochemical dissolution on flow channelization. The presented results indicate that geological systems that have been weathering or reactive for longer times in older landscapes are likely to have increased flow channelization compared to their equivalent but younger counterparts, which implies a time dependence on flow channelization in fractured media.

Hyman, Jeffrey D.↗

Magnetic anomalies

The implications and accuracy of anomaly maps produced using Magsat data on the scalar and vector magnetic field of the earth are discussed. Comparisons have been made between the satellite maps and aeromagnetic survey maps, showing smoother data from the satellite maps and larger anomalies in the aircraft data. The maps are being applied to characterize the structure and tectonics of the underlying regions. Investigations are still needed regarding the directions of magnetization within the crust and to generate further correlations between anomaly features and large scale geological structures. Furthermore, an increased data base is recommended for the Pacific Ocean basin in order to develop a better starting model for Pacific tectonic movements. The Pacific basin was large farther backwards in time and subduction zones surround the basin, thereby causing difficulties for describing the complex break-up scenario for Gondwanaland.

Harrison, C. G. A.↗

Physical characteristics and evolutionary trends of continental rifts

Rifts may be defined as zones beneath which the entire lithosphere has ruptured in extension. They are widespread and occur in a variety of tectonic settings, and range up to 2,600 m.y. in age. The object of this review is to highlight characteristic features of modern and ancient rifts, to emphasize differences and similarities in order to help characterize evolutionary trends, to identify physical conditions favorable for initiation as well as termination of rifting, and to provide constraints for future modeling studies of rifting. Rifts are characterized on the basis of their structural, geomorphic, magmatic and geophysical features and the diverse character of these features and their evolutionary trends through time are discussed. Mechanisms of rifting are critically examined in terms of the physical characteristics and evolutionary trends of rifts, and it is concluded that while simple models can give valuable insight into specific processes of rifting, individual rifts can rarely, if ever, be characterized by well defined trends predicted by these models. More data are required to clearly define evolutionary trends, and the models require development to incorporate the effects of lithospheric heterogeneities and complex geologic histories.

Ramberg, I. B.↗

Gaussian analysis of temperature effects on the reflectance spectra of mafic minerals in the 1-micron region

Gaussian band-fitting analysis has been applied to the reflectance spectra of mafic silicates, which are of geologic importance throughout much of the solar system. Reflectance spectra obtained over a sample temperature range of about 80 to 448 K of olivine, clinopyroxene, and orthopyroxene were used in order to characterize the spectral changes in the 1-micron wavelength region of these minerals as a function of temperature. Four Gaussians are required to characterize the olivine, while two Gaussians are necessary to characterize both the orthopyroxene. The trends of the individual Gaussian parameters (integrated area, width, and center position) are presented as a function of temperature for each mineral. The characterization by Gaussian analysis of the 1-micron absorption feature of all minerals yields consistent trends in center position, integrated area, and width that may prove useful in quantitative determination of these minerals in mineral mixtures.

Roush, T. L.↗

Thermal emission from particulate surfaces: A comparison of scattering models with measured spectra

Emissivity spectra of particulate mineral samples are highly dependent on particle size when that size is comparable to the wavelength of light emitted (5-50 micrometers for the midinfrared). Proper geologic interpretation of data from planetary infrared spectrometers will require that these particle size effects be well understood. To address this issue, samples of quartz powders were produced with narrow, well-characterized particle size distributions. Mean particle diameters in these samples ranged from 15 to 227 micrometers. Emission spectra of these powders allow the first detailed comparison of the complex spectral variations with particle size observed in laboratory data with the predictions of radiative transfer models. Four such models are considered here. Hapke's relectance theory (converted to emissivity via Kirchoff's law) is the first model tested. Hapke's more recently published emission theory is also employed. The third model, the 'Mie/Conel' model, uses Mie single scattering with a two-stream approximation for multiple scattering. This model, like the first, is a converted reflec- tance model. Mie scattering assumes particles are both spherical and well separated, which is not true for the quartz powders, but includes diffraction effects. The fourth model uses the Mie solution for single scattering by spheres and inputs those results into the multiple scattering formalism of Hapke's emission theory. The results of the four models are considered in relation to the values of the optical constants n and k. We have grouped these as class 1 (k large), class 2 (k moderate, n is approximately 2), class 3 (k small, n is approximately 2), and class 4 (k small, n is approximately 1). In general, the Mie/Hapke hybrid model does best at predicting variations with grain size. In particular, it predicts changes of the correct pattern, although incorrect magnitude, for class 1 bands, where large increases in emissivity with decreasing grain size are observed. This model also does an excellent job on moderate (class 2) and very weak and intraband (class 3) regions, and correctly predicts the emission maximum and its invariance with grain size near the Christiansen frequency (class 4). The Mie/Hapke hybrid model also has the fewest free parameters of the four models examined, while maintaining the most physical treatment of the radiative transfer. The Mie/Conel model performs as well as the Mie/Hapke hybrid model in strong bands (class 1) but does not accurately model the behavior of moderate (class 2) and very weak (class 3) bands.

Moersch, J. E.↗

Geochemical and spectral characterization of naturally altered rock surfaces

The possibility of using the visible-near infrared region for compositional analysis of remotely sensed rock surfaces is studied. This would allow mapping rock type both on the Earth's surface and on other planetary surfaces. Reflectance spectroscopy, economic geology, optical depth determination, and X-ray diffraction mineralogy are discussed.

Chang, L. L. Y.↗

Geologic Mapping of the Meridiani Region, Mars

The light toned bedrock that has been observed at the Mars Exploration Rover Opportunity landing site is an upper layer in a sequence >600 m thick in places. These outcrops contain mineral and textural signatures that require interaction of, and possibly formation from, water. Many distinct layers are visible in the remote sensing data (e.g. Figure 1) and no work has ever characterized the full set of these materials that cover an area >3 105 km2 spanning 20 of longitude. Thus, whatever water-related process( es?) altered, and possibly formed, the rocks at the Opportunity landing site extended over a vast region of Mars. Yet many questions remain to be answered, such as: (1) in what capacity did water form and alter the deposits?, (2) what are the temporal and spatial relations with other major events known from ancient Mars?, and (3) would this type of environment have been conducive to the development of life? To address these questions we are completing a detailed geologic, stratigraphic, and thermophysical properties study of this widespread terrain. Specifically, we are drafting a 1:2M-scale geological map covering the full extent of these water-related deposits. In tandem with the mapping, Hynek and Phillips [1] have conducted a preliminary stratigraphic analysis of the stack of materials. After mapping is complete, we will study the thermophysical properties of the varied layers to derive possible compositional information of the materials. These tasks serve several purposes including gaining an understanding of the complex nature of these materials, their potential source region(s), and their timing of emplacement. All of these efforts are necessary to place the observations by the Opportunity Rover in a broader context and prepare for potential future landed missions to the region. Understanding the large-scale paleohydrology of Mars is central to NASA s goals and vital for determining if life ever arose on the planet.

Hynek, B. M.↗

3-D Geological Modeling for Numerical Flow Simulation Studies of Gas Hydrate Reservoirs at the Kuparuk State 7-11-12 Pad in the Prudhoe Bay Unit on the Alaska North Slope

Accurate reservoir evaluation requires reliable three-dimensional (3-D) geological models. Here, this study conducted 3-D geological modeling for numerical flow simulation of the B1 sand gas hydrate reservoir at the Kuparuk State 7-11-12 pad, Prudhoe Bay Unit, Alaska North Slope. The model integrates well logs, core, and seismic data to address spatial heterogeneity in geological structures and reservoir properties. Two modeling types were performed: structural framework modeling and petrophysical property modeling. For structural framework modeling, seismic data and well log markers were used to reproduce subsurface structures characterized by a normal fault system. A volume-based modeling algorithm and stair-stepping grid were applied. The resulting 3-D model comprised 2,640,000 grid cells across 264 layers, including seven fault grids. For petrophysical property modeling, total porosity was initially modeled using sequential Gaussian simulation with collocated cokriging. To reproduce the upward coarsening of the B1 sand, upscaled log-derived total porosity and a three-dimensional (3-D) trend depicting total porosity variation were used as primary and secondary data, respectively. Gas hydrate saturation distribution was modeled similarly, with secondary data from estimated porosity distribution and seismic-derived acoustic impedance map enhancing accuracy. Results indicate higher gas hydrate saturation in the upper part of the B1 sand and areas with higher acoustic impedance. Intrinsic permeability was modeled from the total porosity and clay-bound water volume, and effective permeability was derived from the gas hydrate saturation and intrinsic permeability distributions based on the “Tokyo model”. Effective permeability distributions were influenced by the total porosity, gas hydrate saturation, and intrinsic permeability. Within the same layer, higher gas hydrate saturation leads to decreased effective permeability. In total, 100 sets of multiple scenarios were prepared, providing input data for dynamic flow simulations to evaluate the effects of lateral heterogeneity in reservoir properties and the hydraulic characteristics of faults on production behavior for preassessment before the long-term production test.

58 GEOSCIENCES↗