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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Enhancing analytical merits of laser-induced breakdown spectroscopy of hydrogen isotopes using an orthogonal double-pulsing scheme

Accurate detection and quantification of hydrogen isotopes in solid materials are vital for diverse applications, including fusion energy, hydrogen storage, and tritium production. Laser-induced breakdown spectroscopy (LIBS) is a well established, rapid, standoff method for this purpose, but it faces challenges related to the analytical merits required for isotopic analyses. In this study, we enhance the analytical and detection capabilities of traditional single-pulse LIBS by implementing an orthogonal double pulsing approach, focusing on the analysis of a range of 2 H concentrations in Zircaloy-4 substrates (acting as a proxy for 3 H). The double-pulse experiments employed an orthogonal re-heating configuration with two nanosecond Nd:YAG lasers. We systematically evaluated critical parameters affecting the signal intensity in double-pulse LIBS, including interpulse delay, ambient gas pressure, and heating laser energy. Finally, our results demonstrate that employing an orthogonal double-pulse scheme significantly enhances 2 H α emission while minimizing line broadening and self-absorption, ultimately improving the technique’s analytical capabilities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Interplay between London Dispersion, Hubbard U , and Metastable States for Uranium Compounds

High-throughput computational studies of lanthanide and actinide chemistry with density-functional theory are complicated by the need for Hubbard U corrections, which ensure localization of the f-electrons, but can lead to metastable states. This work presents a systematic investigation of the effects of both Hubbard U value and metastable states on the predicted structural and thermodynamic properties of four uranium compounds central to the field of nuclear fuels: UC, UN, UO 2 , and UCl 3 . We also assess the impact of the exchange-hole dipole moment (XDM) dispersion correction on the computed properties. Overall, the choice of Hubbard U value and inclusion of a dispersion correction cause larger variations in the computed geometric properties than result from metastable states. Further, the weak dependence of structure optimization on metastable states should simplify future high-throughput calculations on actinides. Conversely, addition of the dispersion correction is found to offset the repulsion introduced by the Hubbard U term and provides greatly improved agreement with experiment for both cell volumes and heats of formation. The XDM dispersion correction is largely invariant to the chosen U value, making it a robust dispersion correction for actinide systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Synthetic Access to a Framework-Stabilized and Fully Sulfided Analogue of an Anderson Polyoxometalate that is Catalytically Competent for Reduction Reactions

Polyoxometalates (POMs) featuring 7, 12, 18, or more redox-accessible transition metal ions are ubiquitous as selective catalysts, especially for oxidation reactions. The corresponding synthetic and catalytic chemistry of stable, discrete, capping-ligand-free polythiometalates (PTMs), which could be especially attractive for reduction reactions, is much less well developed. Among the challenges are the propensity of PTMs to agglomerate and the tendency for agglomeration to block reactant access of catalyst active sites. Nevertheless, the pervasive presence of transition metal sulfur clusters metalloenzymes or cofactors that catalyze reduction reactions and the justifiable proliferation of studies of two-dimensional (2D) metal-chalcogenides as reduction catalysts point to the promise of well-defined and controllable PTMs as reduction catalysts. Here, we report the fabrication of agglomeration-immune, reactant-accessible, capping-ligand-free Co II Mo 6 IV S 24 n– clusters as periodic arrays in a water-stable, hierarchically porous Zr-metal–organic framework (MOF; NU1K) by first installing a disk-like Anderson polyoxometalate, Co III Mo 6 VI O 24 m– , in size-matched micropores where the siting is established via difference electron density (DED) X-ray diffraction (XRD) experiments. Flowing H 2 S, while heating, reduces molybdenum(VI) ions to Mo(IV) and quantitatively replaces oxygen anions with sulfur anions (S 2– , HS – , S 2 2– ). DED maps show that MOF-templated POM-to-PTM conversion leaves clusters individually isolated in open-channel-connected micropores. Importantly, the structure of the immobilized cluster as determined, in part, by X-ray photoelectron spectroscopy (XPS), X-ray absorption fine structure (XAFS) analysis, and pair distribution function (PDF) analysis of total X-ray scattering agrees well with the theoretically simulated structure. PTM@MOF displays both electrocatalytic and photocatalytic competency for hydrogen evolution. Nevertheless, the initially installed PTM appears to be a precatalyst, gaining competency only after the loss of ~3 to 6 sulfurs and exposure to hydride-forming metal ions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Annealing of ion tracks in apatite under pressure characterized in situ by small angle x-ray scattering

Fission track thermochronology is routinely used to investigate the thermal history of sedimentary basins, as well as tectonic uplift and denudation rates. While the effect of temperature on fission track annealing has been studied extensively to calibrate the application of the technique, the effect of pressure during annealing is generally considered to be negligible. However, a previous study suggested elevated pressure results in a significantly different annealing behaviour that was previously unknown. Here, we present a method to study track annealing in situ under high pressure by using synchrotron- based small angle x-ray scattering (SAXS). To simulate fission tracks in a controlled environment, ion tracks were created in apatite from Durango, Mexico using 2 GeV Au or Bi ions provided by an ion accelerator facility. Samples were annealed at 250°C at approximately 1 GPa pressure using diamond anvil cells (DAcs) with heating capabilities. Additional in situ annealing experiments at ambient pressure and temperatures between 320 and 390°C were performed for comparison. At elevated pressure a significantly accelerated annealing rate of the tracks was observed compared with annealing at ambient pressure. However, when extrapolated to geologically relevant temperatures and pressures, the effects become very small. The measurement methodology presented provides a new avenue to study materials behaviour in extreme environments.

58 GEOSCIENCES↗
DOE OSTI2021

Entropy generation from hydrodynamic mixing in inertial confinement fusion indirect-drive targets

The increase in entropy from the physical mixing of two adjacent materials in inertial confinement fusion (ICF) implosions and gas-filled hohlraums is analytically assessed. An idealized model of entropy generation from the mixing of identical ideal-gas particles across a material interface in the presence of pressure and temperature gradients is applied. Physically, mix-driven entropy generation refers to the work done by the gases in expanding into a larger common volume from atomic mixing under the condition of no internal energy change, or work needed to restore the initial unmixed state. Furthermore, the effect of a mix-generated entropy increase is analytically shown to lead to less compression of the composite ICF fluid under adiabatic conditions. The amount of entropy generation is estimated to be ~10 J for a Rayleigh–Taylor-induced micrometer-scale annular mixing layer between the solid deuterium–tritium fuel and (undoped) high-density carbon pusher of an imploding capsule at the National Ignition Facility (NIF). This level of entropy generation is consistent with lower-than-expected fuel compressions measured on the NIF [Hurricane et al., Phys. Plasmas 26, 052704 (2019)]. The degree of entropy increase from mixing of high-Z hohlraum wall material and low-Z, moderate- to high-density gas fills is estimated to lead to ~100 kJ of heat generation for NIF-scale experiments [Moody et al., Phys. Plasmas 21, 056317 (2014)]. This value represents a significant fraction of the inferred missing x-ray drive energy based on observed delays in capsule implosion times compared with mainline simulations [Jones et al., Phys. Plasmas 19, 056315 (2012)].

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

The MuFusE large-volume diamond anvil cell for exploring muon-catalyzed fusion at higher pressures and temperatures

A new large-volume diamond anvil cell (DAC) has been developed for the Muon-catalyzed Fusion (μCF) Experiment (MuFusE), enabling the compression and heating of deuterium–tritium (d–t) mixtures to pressures and temperatures needed to advance μCF research. The MuFusE DAC achieves the large sample volumes necessary for high-precision fusion measurements while integrating cryogenic loading, all-metal sealing, and flexible bellows to maintain a secure environment during cell compression. Combined with remote pneumatic actuation and secondary containment, the DAC safely managed a 25 Ci tritium inventory while providing a clear optical path for in situ measurements of sample pressure and composition via laser spectroscopy. Utilizing 5 mm diameter diamond anvils oriented in the path of a high-intensity muon beam, the apparatus achieved a stable sample volume of 19.2 mm 3 at liquid density, pressures up to 933 MPa and temperatures up to 400 K—benchmarks that significantly exceed previously reported limits for static d–t targets.

Kalow, J. D. [Acceleron Fusion, Inc., Cambridge, M↗
DOE OSTI2022

Evidence for superionic H 2 O and diffusive He–H 2 O at high temperature and high pressure

In this work, we present the evidence of superionic phase formed in H 2 O and, for the first time, diffusive H 2 O–He phase, based on time-resolved x-ray diffraction experiments performed on ramp-laser-heated samples in diamond anvil cells. The diffraction results signify a similar bcc-like structure of superionic H 2 O and diffusive He–H 2 O, while following different transition dynamics. Based on time and temperature evolution of the lattice parameter, the superionic H 2 O phase forms gradually in pure H 2 O over the temperature range of 1350–1400 K at 23 GPa, but the diffusive He–H 2 O phase forms abruptly at 1300 K at 26 GPa. We suggest that the faster dynamics and lower transition temperature in He–H 2 O are due to a larger diffusion coefficient of interstitial-filled He than that of more strongly bound H atoms. This conjecture is then consistent with He disordered diffusive phase predicted at lower temperatures, rather than H-disordered superionic phase in He–H 2 O.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Avalanche transport of energetic-ions in magnetic confinement plasmas: nonlinear multiple wave-number simulation

Large burst activity, identified as toroidal Alfvén eigenmode (TAE) avalanche, occurs frequently in neutral-beam heated plasmas in National Spherical Torus Experiment (NSTX). Based on the typical experimental observation of TAE avalanche on NSTX, a self-consistent nonlinear multiple wave-number (k ∥ ≃ n/R, where n toroidal mode-number and R major radius) simulation associated with TAE avalanches is performed using the experimental parameters and profiles before the occurrence of TAE avalanche as the M3D-K input. The wave–wave nonlinear coupling among different modes and the resonant interaction between different modes and energetic-ions during TAE avalanches are identified in the nonlinear multiple wave-number simulations. The resonance overlap during the TAE avalanche is clearly observed in the simulation. It is found that the effective wave–wave coupling and a sufficiently strong drive are two important ingredients for the onset of TAE avalanches. TAE avalanche is considered to be a strongly nonlinear process and it is always accompanied by the simultaneous rapid frequency-chirping and large amplitude bursting of multiple modes and significant energetic-ion losses. The experimental phenomenon is observed on NSTX and is qualitatively reproduced by the simulation results in this work. These findings indicate that the onset of avalanche is triggered by nonlinearity of the system, and are also conducive to understanding the underlying mechanism of avalanche transport of energetic particles in the future burning plasmas, such as International Thermonuclear Experiment Reactor.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Preliminary Experiences with the Rexon UL-320-FDR: An Automated Thermoluminescent Dosimeter Reader with Removable Contact Heating Planchets and an Infrared Temperature Feedback System

The Rexon UL-320 FDR is a novel resistive-heating thermoluminescent dosimeter reader with a unique temperature measurement system and an automated dosimeter processing mechanism. The removable contact heating planchets have black-body adhesives on the back for capturing temperature information with infrared sensors. A heating cycle feedback loop ensures accurate, precise, and reproducible heating sequences. Heating rates between 0.8 and 40°C s -1 for up to 1,000 s are possible. Photomultiplier tube sensitivity and drift, dark current counts, and planchet glow were measured experimentally. Additionally, 25 LiF:Mg,Ti dosimeters were calibrated to demonstrate reader performance. Sensitivity was optimized at 1,200 V, which produced the highest reference light count to dark current count ratio while extending photomultiplier tube life. Dark current counts measured with typical time-temperature profiles for LiF:Mg,Ti were below 10 counts per channel but increased by up to 2.5% for more extreme heating cycles. Reader sensitivity drifts of up to 10% were observed during extended automated operations with typical time-temperature profiles. Total counts resulting from planchet glow decreased with faster heating rates. Calibrations performed with LiF:Mg,Ti dosimeters yielded results comparable to more established reader designs. Spikes were observed in ~3% of the glow curves from planchet dust and oil burning off at elevated temperatures. The use of N 2 gas and sensitivity drift corrections are recommended to improve dosimetry performance for the UL-320 FDR reader.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2023

Structural and double magnetic transitions in the frustrated spin- 1 2 capped-kagome antiferromagnet ( RbCl ) Cu 5 P 2 O 10

The structural and magnetic properties of the geometrically frustrated spin- 1 2 capped-kagome antiferromagnet (RbCl) Cu 5 P 2 O 10 are investigated via temperature-dependent x-ray diffraction, magnetization, heat capacity, and 31 P NMR experiments on a polycrystalline sample. It undergoes a structural transition at around T t ≃ 310 K from a high-temperature trigonal (P ¯3m1) to a low-temperature monoclinic (C2/c) unit cell, where the low-temperature structure features the capped-kagome geometry of Cu 2+ ions. Interestingly, it shows the onset of two successive magnetic transitions at T N1 ≃ 20 K and T N2 ≃ 7 K. The shape of the 31 P NMR spectra unfolds the possible nature of the transitions below T N1 and T N2 to be of incommensurate and commensurate antiferromagnetic type, respectively. A large value of the Curie-Weiss temperature as compared to T N1 sets the frustration parameter f ≃ 8, ensuring strong magnetic frustration in the compound. From the 31 P NMR spin-lattice relaxation rate, the leading antiferromagnetic exchange coupling is estimated to be J/k B ≃ 117 K. Furthermore, these unusual double magnetic transitions make this compound beguiling for further investigations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Numerical Improvements in Magnetohydrodynamic, Pulsed Power Simulations of Near-Target Plasmas

Magnetohydrodynamic (MHD) simulations of pulsed power experiments frequently result in unphysical runaway heating when extended to low values of mass density. Traditionally, this has been addressed by the use of conductivity floors below which the plasma is given an arbitrarily low conductivity value. Here, a low-density treatment is presented that allows for low-density material to carry current while maintaining a stable temperature. This treatment is implemented in the Ares multiphysics code. Numerical modifications to the conventional vacuum treatment include an energy-conserving density floor, a modified averaging procedure to determine the thermal conductivity at the edge of adjacent zones, and a modified averaging procedure for determining the thermal conductivity in mixed zones that contain material from differing regions. Additionally, anomalous resistivity and Bohm diffusion models are implemented as simplified models for microphysics-induced enhancement of collisional transport. Importantly, the advantage of these various improvements are illustrated in a simple 1-D pulsed power target where the combined changes result in stable temperatures within the lower density regions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Granular Flow in Novel Octet Shape–Based Lattice Frame Material

Moving packed-bed heat exchangers in concentrated solar power (CSP) plants involves heat transfer between heated falling particles and supercritical carbon dioxide. The overall effective thermal conductivity of the moving packed bed and particle-side channel contact resistances are still the bottlenecks in achieving the desirable thermal transport levels. To this end, a novel moving packed bed heat exchanger consisting of an Octet lattice packed between the walls of the particle-side channel is proposed in this study. Granular flow analysis in Octet lattice moving packed bed heat exchanger (OLHX) was conducted through experiments and discrete element method (DEM)-based numerical simulations. The experimental images clearly demonstrated stagnation regions upstream of lattice fibers, void regions downstream of the fiber junctions, and wavy-type unobstructed flow on the lateral sides of the fibers. DEM simulations were successful in capturing all these critical flow phenomena. Larger flow velocities were observed on the lateral sides of the fibers in the simulations. Also, when the particles in the silo were emptied, the final images showed an accumulation of particles on the inter-fiber as well as fiber–channel wall junctions. Moreover, the fiber connections resulted in some regions devoid of particle contact on the channel endwall, which means that these regions would suffer from poor thermal exchange. Finally, the overall mass flowrate increased with increasing porosity for a fixed particle diameter.

14 SOLAR ENERGY↗
DOE OSTI2020

ASSESSING FUEL PROPERTY EFFECTS ON CAVITATION AND EROSION PROPENSITY USING A COMPUTATIONAL FUEL SCREENING TOOL

To advance compression ignition combustion strategies, researchers have evaluated fuel property effects and their impact on achieving higher efficiencies and lower emissions levels relative to current capabilities. Within the Department of Energy's Co-Optima initiative, there has been a recent focus on understanding the influence of fuel properties on fuel injection performance. To help identify candidate fuels that can meet desired injector performance metrics, a computational fuel screening tool is under development that can link fuel properties with the tendency of a given fuel to cavitate and lead to cavitation-induced erosion. In the initial development of this tool, five liquid fuel properties were selected to represent candidate fuels, namely density, viscosity, vapor pressure, surface tension, and heat of vaporization. A design of experiments methodology was employed to generate a set of pseudo fuel cases, which can represent the main effects and interactions among the fuel properties and be related to cavitation erosion predictions. Large eddy simulations were performed using a mixture modeling approach to predict the cavitation and erosion propensity of these pseudo-fuels in terms of the mean fuel vapor mole fraction and stored impact energy from repeated cloud collapse events. The low order regression models generated from this study revealed the importance of liquid fuel density on cavitation formation, whereas liquid viscosity was found to have a strong negative correlation with erosion severity. The surrogate models were then used in the fuel screening tool to rank the cavitation and erosion tendency of four candidate single-component fuels: methyl decanoate, isooctane, ethanol and n-dodecane. While the fuel screening tool was not able to quantitatively predict the cavitation and erosion response metrics, the tool was able to accurately rank the relative cavitation and erosion propensity of the four fuels. Overall, ethanol and iso-octane were observed to produce the highest levels of cavitation and erosion, respectively.

cavitation-induced erosion↗
DOE OSTI2023

Picosecond spin-orbit torque–induced coherent magnetization switching in a ferromagnet

Electrically controllable nonvolatile magnetic memories show great potential for the replacement of conventional semiconductor-based memory technologies. Here, we experimentally demonstrate ultrafast spin-orbit torque (SOT)-induced coherent magnetization switching dynamics in a ferromagnet. We use an ultrafast photoconducting switch and a coplanar strip line to generate and guide a ~9-picosecond electrical pulse into a heavy metal/ferromagnet multilayer to induce ultrafast SOT. We then use magneto-optical probing to investigate the magnetization dynamics with sub-picosecond resolution. Ultrafast heating by the approximately 9 picosecond current pulse induces a thermal anisotropy torque which, in combination with the damping-like torque, coherently rotates the magnetization to obtain zero-crossing of magnetization in ~70 picoseconds. A macro-magnetic simulation coupled with an ultrafast heating model agrees well with the experiment and suggests coherent magnetization switching without any incubation delay on an unprecedented time scale. Our work proposes a unique magnetization switching mechanism toward markedly increasing the writing speed of SOT magnetic random-access memory devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Analysis of an Arctic cold air outbreak during autumn and related air mass transformations forced by surface changes and advection in higher altitudes

During marine cold air outbreaks (MCAOs), cold and dry Arctic air masses are transported from the central Arctic southward across the closed sea ice and much warmer open oceans. They experience significant transformations including a rapid heating and moistening, often leading to cloud formation. While intense wintertime MCAOs have been analyzed widely, the air mass transformations during other seasons have been studied sparsely. We address this gap by investigating an MCAO case observed in September 2020. To study the transformation processes, we combine the fifth generation of atmospheric reanalyses of the global climate (ERA5), trajectory calculations, as well as shipborne and airborne measurements. In the central Arctic, observations acquired from aboard the research vessel (RV) Polarstern during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition characterized the initial state of the air mass over closed sea ice. Trajectories indicated the pathway the air mass took from RV Polarstern southward to the Fram Strait. For the first 24 h of the southbound drift, the air masses remained quasi-stationary. Then, still 15 h ahead of the marginal sea ice zone, differential advection across the boundary layer flow introduced humidity and clouds at higher altitudes between 1.5 and 2.5 km. ERA5-derived temperature and humidity tendencies indicated complex vertical interactions. Radiative cloud-top cooling, entrainment, and turbulence were significantly reduced in the lower and enhanced in the upper advected cloud layer. Eventually, the lower cloud deck dissipated. After this confluence of 2 different air masses, observations gathered by Polar 5 in Fram Strait as part of the MOSAiC Airborne observations in the Central Arctic campaign revealed cloudy, moist layers throughout the lowest 3.5 km and an increasing boundary layer height. Comparing the initial with the final state 48 h later, the largest net heating of +8 K was found close to the surface, yet the largest net moistening of +2.5 g kg -1 at an altitude of 1 km, as the initial profile was exceptionally dry here. We conclude that the observed air mass transformations were driven by the surface changes from sea ice to open ocean but additionally strongly impacted by the differential advection of clouds and moisture across the near-surface MCAO flow.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Stability Functions in the Stable Surface Layer Derived from the Mellor–Yamada–Nakanishi–Niino (MYNN) Scheme

It is desirable that a surface layer scheme in an atmospheric numerical model is consistent with an atmospheric boundary layer scheme incorporated in the same model. In this study, stability functions based on Monin–Obukhov similarity theory for momentum and heat, φ m and φ h , in the stable surface layer are derived from the Mellor–Yamada–Nakanishi–Niino (MYNN) scheme. The resulting stability functions are approximated by φ m = 1 + 4.8z/L and φ h = 0.74 + 6.0z/L, which can be analytically integrated with respect to height z to obtain momentum and heat fluxes, where L is the Obukhov length. The fluxes thus, obtained are compared with those acquired from stability functions in four previous studies: they are nearly the same as those from two of them, and show better agreement with observational data of the Surface Heat Budget of the Arctic Ocean experiment (SHEBA) over sea ice than those from the other two studies. Detailed comparisons of the results of the MYNN scheme with the SHEBA data suggest that significant variations of the fluxes observed during “winter” when the ice was covered with dry snow may have been caused by those of the surface roughness around the observational site. The stability functions obtained from the MYNN scheme predict that the bulk and flux Richardson numbers approach critical values of 0.26 and 0.21, respectively, in the limit of z/L → ∞. These critical values result from the Kolmogorov hypothesis applied to the turbulent dissipation in the MYNN scheme and are considered to correspond to a transition from Kolmogorov to non-Kolmogorov turbulence.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Thermal Characterization of Acid Treated Anion Exchange Resins

Anion exchange is a chemical separation and purification technique in which a solid phase ion exchanging material (i.e., anion exchange resin beads) interchanges its anions with the desired anions from a solution phase. Typical anion exchange resins (e.g., Bio-Rad AG 1-X8 strongly basic anion exchange resin) consist of a polymer resin bead of cross-linked polystyrene with quaternary ammonium functional groups (Figure 1). Anion exchange occurs at the resin functional groups by exchange of the counter ion of the quaternary ammonium (typically chloride or nitrate) for the anionic species of interest. Other resin polymers have been developed—such as cross-linked vinylpyridine/divinylbenzene utilized in Reillex HPQ anion exchange resin—to improve the resins’ resistance against degradation by oxidizing agents, strong acids, and radiation. Anion exchange is performed for the separation of transuranic (TRU) elements throughout the Department of Energy complex. At the Los Alamos National Laboratory (LANL), production scale quantities of these resins are handled at the Chemistry and Metallurgy Research Facility, the Plutonium Facility, and the Transuranic Waste Facility. Spent anion exchange resin will eventually be disposed of as TRU waste. This has prompted concerns regarding its safe disposal under potential hazard scenarios, in particular a thermal excursion of a TRU waste drum. There is a concern that a potential thermal excursion of a TRU waste drum containing anion exchange resin previously contacted with nitric acid may result in energetic side reactions and pressure buildup due to resin degradation by nitric acid and heat. Therefore, the objective of the experiments described in this report was to gather qualitative and quantitative data to support decisions regarding the thermal stability and safe disposal strategy of nitric acid treated anion exchange resins utilized in TRU processing operations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Towards an Era of Low-Temperature Integral Critical Experiments: Surrogate Testing of Low-Temperature TEX Configurations

United States and IAEA regulations for the transportation of radioactive materials require that fissile materials must be subcritical under expected ambient temperatures ranging from -40°C to 38°C. While historical experiments have been conducted at room and elevated temperatures, no criticality integral benchmarks exist for temperatures below room temperature. The Low-Temperature Thermal Epithermal eXperiments (LT-TEX) aim to provide benchmark evaluations down to -40°C. The LT-TEX design incorporates stacked HEU plates interspersed with varying thicknesses of polyethylene disks to provide varying levels of moderation, with five configurations at 20°C having already been benchmarked. A novel vacuum/cryogenic chamber was fabricated to contain the LT-TEX configurations in a thermally isolated environment and cool it to -40°C. Prior to testing with fissile materials, testing with surrogate fuel plates was performed to characterize the thermal properties of the system, ensure no condensation forms on the stack, and to test that the uranium plates would not warp, or fracture during the thermal cycling. Surrogate testing has characterized the cryogenic chamber and verified its viability to perform the benchmark experiments, allowing for the next steps in the LT-TEX experimental campaign. The results of the surrogate testing are discussed and compared to heat transfer calculations performed as part of the experiment design process, to establish confidence in the thermal behavior of the system.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗