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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Lunar Meteorite Queen Alexandra Range 93069 and the Iron Concentration of the Lunar Highlands Surface

Lunar meteorite Queen Alexandra Range 93069 is a clast-rich, glassy-matrix regolith breccia of ferroan, highly aluminous bulk composition. It is similar in composition to other feldspathic lunar meteorites but differs in having higher concentrations of siderophile elements and incompatible trace elements. Based on electron microprobe analyses of the fusion crust, glassy matrix, and clasts, and instrumental neutron activation analysis of breccia fragments, QUE 93069 is dominated by nonmare components of ferroan, noritic- anorthosite bulk composition. Thin section QUE 93069,31 also contains a large, impact-melted, partially devitrified clast of magnesian, anorthositic-norite composition. The enrichment in Fe, Sc, and Cr and lower Mg/Fe ratio of lunar meteorites Yamato 791197 and Yamato 82192/3 compared to other feldspathic lunar meteorites can be attributed to a small proportion (5-10%) of low-Ti mare basalt. It is likely that the non- mare components of Yamato 82192/3 are similar to and occur in similar abundance to those of Yamato 86032, with which it is paired. There is a significant difference between the average FeO concentration of the lunar highlands surface as inferred from the feldspathic lunar meteorites (mean: approx. 5.0%; range: 4.3-6.1 %) and a recent estimate based on data from the Clementine mission (3.6%).

Korotev, Randy L.↗
NASA NTRS2014

Geologic History of Asteroid 4 Vesta

Some types of meteorites - most irons, stony irons, some achondrites - hail from asteroids that were heated to the point where magmatism occurred within a very few million years of the formation of the earliest solids in the solar system. The largest clan of achondrites, the howardite, eucrite and diogenite (HED) meteorites, represent the crust of their parent asteroid]. Diogenites are cumulate harzburgites and orthopyroxenites from the lower crust whilst eucrites are basalts, diabases and cumulate gabbros from the upper crust. Howardites are impact-engendered breccias mostly of diogenites and eucrites. There remains only one large asteroid with a basaltic crust, 4 Vesta, which is thought to be the source of the HED clan. Differentiation models for Vesta are based on HED compositions. Proto-Vesta consisted of chondritic materials containing Al-26, a potent, short-lived heat source. Inferences from compositional data are that Vesta was melted to high degree (≥50%) allowing homogenization of the silicate phase and separation of a metallic core. Convection of the silicate magma ocean allowed equilibrium crystallization, forming a harzburgitic mantle. After convective lockup occurred, melt collected between the mantle and the cool thermal boundary layer and underwent fractional crystallization forming an orthopyroxene-rich (diogenite) lower crust. The initial thermal boundary layer of chondritic material was replaced by a mafic upper crust through impact disruption and foundering. The mafic crust thickened over time as additional residual magma intrudes and penetrates the mafic crust forming plutons, dikes, sills and flows of cumulate and basaltic eucrite composition. This magmatic history may have taken only 2-3 Myr. This magma ocean scenario is at odds with a model of heat and magma transport that indicates that small degrees of melt would be rapidly expelled from source regions, precluding development of a magma ocean. Constraints from radiogenic Mg-26 distibutions suggest that the parent asteroid of HEDs was much smaller than Vesta. Thus, first-order questions regarding asteroid differentiation remain.

Mittlefehldt, David W.↗
NASA NTRS1974

Asteroids - Surface composition from reflection spectroscopy

Minerals partly composing the surfaces of 14 asteroids are determined by using asteroid reflectance spectra and optical properties of meteorites and other materials. Individual electronic absorption features are identified in the asteroids' spectra. The energies, relative strengths, and shapes of these features are interpreted by using laboratory and theoretical studies. Analysis of the initial 14 asteroid reflectance spectra indicates the presence of the following types of surface materials: six carbonaceous chondrite-like; two stony-iron-like (metal/silicate ratio approximately equal to 1); one iron meteorite-like; one basaltic achondrite-like; and four silicate-metal assemblages (metal/silicate ratio approximately equal to 0.25). These results support the conclusion that the asteroid belt is a source of at least some meteoritic material, and they show a relation between certain asteroids and certain classes of meteorites.

Mccord, T. B.↗
DOE OSTI2025

Creation of an Fe 3 P Schreibersite Density Functional Tight Binding Model for Astrobiological Simulations

The mineral schreibersite, e.g., Fe 3 P, is commonly found in iron-rich meteorites and could have served as an abiotic phosphorus source for prebiotic chemistry. However, atomistic calculations of its degradation chemistry generally require quantum simulation approaches, which can be too computationally cumbersome to study sufficient time and length scales for this process. In this regard, we have created a computationally efficient semiempirical quantum density functional tight binding (DFTB) model for iron and phosphorus-containing materials by adopting an existing semiautomated workflow that represents many-body interactions by linear combinations of Chebyshev polynomials. Here, we have utilized a relatively small training set to optimize a DFTB model that is accurate for schreibersite physical and chemical properties, including its bulk properties, surface energies, and water absorption. We then show that our model shows strong transferability to several iron phosphide solids as well as multiple allotropes of iron metal. Our resulting DFTB parametrization will allow us to interrogate schreibersite aqueous decomposition at longer time and length scales than standard quantum approaches, providing for more detailed investigations of its role in prebiotic chemistry on early Earth.

36 MATERIALS SCIENCE↗
NASA NTRS2010

Hematite-Rich Fracture Fill at Meridiani Planum, Mars: Implications for Fluid Chemistry

The Mars Exploration Rover Opportunity has been operating at the surface of Mars for over 2100 sols and has driven a distance of approximately 20 km. Throughout the traverse, outcrop rocks with margins and fracture fill resistant to erosion have been imaged and analyzed in detail by the Moessbauer (MB) spectrometer and the Alpha Particle X-ray Spectrometer (APXS). A recent APXS analysis of an outcrop block excavated by a young impact crater shows a coating with the highest concentration of iron measured by either rover, not including the iron-nickel meteorites. Texturally, this sample (referred to as "Chocolate Hills -Aloya") appears as a cemented collection of partially fragmented \blueberries." With the exception of an elevated sulfur content, the elemental chemistry of this particular sample is entirely consistent with other analyses of hematite spherules at Merdiani Planum. As a result, it is difficult to determine whether this coating, which may have been filling a fracture in outcrop rocks prior to disruption by the impact, was simply an agglomeration of spherules or a result of a more complicated aqueous process. In contrast, a number of other fracture-filling exposures and erosion-resistant rinds have been analyzed by the APXS and MB instruments showing significant concentrations of iron in the form of hematite without the texture of spherule fragments. In one of these samples, a broken piece of fracture fill within Victoria crater referred to as "Dorsal," showed over 50% of the iron in hematite, the highest Mn concentration of any sample measured by the rovers, and elevated levels of Cl and Br. While the Fe:Mn ratio of the Dorsal analyses are comparable to that of Gusev and Meridiani basalts, it is clear that chemistry of this sample cannot be completely explained by a simple mixing of outcrop and blueberry compositions

Yen, Albert↗
NASA NTRS1987

The 1986 DA and 1986 EB: M-class asteroids in near-Earth orbits

The Earth-approaching asteroid population is composed of asteroids in orbits with short lifetimes compared with the age of the solar system. These objects which are comprised of Aten, Apollo, and Amor asteroids must be replenished from either cometary or mainbelt asteroid sources since lifetimes against collision with or ejection by a planet are on the order of 10 to 100 million years. The physical study of Earth-approaching asteroids is constrained by the generally long period between favorable apparitions and poorly known orbits. Broadband spectrophotometry on the Johnson UBVR system and the Eight-Color Asteroid Survey system were obtained at Kitt Peak National Observatory and on the Johnson JHK system and at 10 and 20 microns at the NASA Infrared Telescope Facility at Mauna Kea Observatory. These observations were used to determine the absolute visual magnitudes and to derive the visual geometric albedos and diameters on the IRAS system. The spectral reflectance properties and geometric albedos of the M-class asteroids are consistent compositions analogous to the iron nickel meteorites or the enstatite-metal assemblages of the enstatite chondrites. The issue of the source(s) of the near-Earth asteroids population was examined by comparing the classifications on the scheme employed by Gradie and Tedesco of 38 such asteroids. Most of the near-Earth objects is indeed the asteroid belt as the observations suggest, then a method for removing extinct nuclei of short period comets must be found since the rate of production of short period comets from the long period comets is relatively large.

Gradie, Jonathan↗
NASA NTRS2008

The Miniaturized Moessbauer Spectrometers MIMOS II on MER: Four Years of Operation - A Summary

The two Miniaturized Moessbauer Spectrometers (MIMOS II) on board the two Mars Exploration Rovers Spirit and Opportunity have now been collecting important scientific data for more than four years. The spectrometers provide information about Fe-bearing mineral phases and determine Fe oxidation states. The total amount of targets analized exceeds 600, the total integration time exceeds 260 days for both rovers. Since landing, more than five half-lives of the Co-57 MB sources have past (intensity at the time of landing approx. 150 mCi). Current integration times are about 50 hours in order to achieve reasonable statistics as opposed to 8 hours at the beginning of the mission. In total, 13 different mineral phases were detected: Olivine, pyroxene, hematite, magnetite and nanophase ferric oxide were detected at both landing sites. At Gusev, ilmenite, goethite, a ferric sulfate phase and a yet unassigned phase (in the rock Fuzzy Smith) were detected. At Meridiani, jarosite, metallic iron in meteoritic samples (kamacite), troilite, and an unassigned ferric phase were detected. Jarosite and goethite are of special interest, as these minerals are indicators for water activity. In this abstract, an overview of Moessbauer results will be given, with a focus on data obtained since the last martian winter. The MER mission has proven that Moessbauer spectroscopy is a valuable tool for the in situ exploration of extraterrestrial bodies and for the study of Febearing samples. The experience gained through the MER mission makes MIMOS II a obvious choice for future missions to Mars and other targets. Currently, MIMOS II is on the scientific payload of two approved future missions: Phobos Grunt (Russian Space Agency; 2009) and ExoMars (European Space Agency; 2013).

Fleischer, I.↗
NASA NTRSDate not supplied

Preliminary Modeling of Potential Interstellar Bolide (08 Jan 2014) Suggests Further Examination is Worthwhile

The purpose of this abstract is to share data from preliminary modeling of meteor dynamics of the 08 Jan 2014 bolide which occurred north of Papua New Guinea as reported by US Department of Defense (DoD) sensors. A hypothesis has been proposed that this event was of interstellar origin. DoD data indicate that this bolide was produced by a meteor moving 44.8 km/s at only 18.7 km altitude, which describes a velocity profile that is exceptional in velocity, much less at such a low altitude. The Jörmungandr model developed by the author for dark flight modeling was adapted to estimate the luminous flight profile of this body. While this model has significant limits in use for luminous flight and all results must be viewed as preliminary, analysis indicates there is a compelling need for further investigation. Calculation of ram pressure by this object indicate that an iron or iron-rich meteorite 0.5m in diameter is a possible explanation for the reported DoD data.

M Fries↗
NASA NTRS2004

A Quantitative NMR Analysis of Phosphorus in Carbonaceous and Ordinary Chondrites

Phosphorus is important in a number of biochemical molecules, from DNA to ATP. Early life may have depended on meteorites as a primary source of phosphorus as simple dissolution of crustal apatite may not produce the necessary concentration of phosphate. Phosphorus is found in several mineral phases in meteorites. Apatite and other Ca- and Mg phosphate minerals tend to be the dominant phosphorus reservoir in stony meteorites, whereas in more iron-rich or reduced meteorites, the phosphide minerals schreibersite, (Fe, Ni)3P, and perryite, (Ni, Fe)5(Si, P)2 are dominant. However, in CM chondrites that have experienced significant aqueous alteration, phosphorus has been detected in more exotic molecules. A series of phosphonic acids including methyl-, ethyl-, propyl- and butyl- phosphonic acids were observed by GC-MS in Murchison. Phosphorian sulfides are in Murchison and Murray. NMR spectrometry is capable of detecting multiple substances with one experiment, is non-destructive, and potentially quantitative, as discussed below. Despite these advantages, NMR spectrometry is infrequently applied to meteoritic studies due in large part to a lack of applicability to many compounds and the relatively high limit of detection requirements. Carbon-13 solid-state NMR has been applied to macromolecular carbon in Murchison. P-31 NMR has many advantages over aqueous carbon-13 NMR spectrometry. P-31 is the only isotope of phosphorus, and P-31 gives a signal approximately twice as strong as C-13. These two factors together with the relative abundances of carbon and phosphorus imply that phosphorus should give a signal approximately 20 as strong as carbon in a given sample. A discussion on the preparation of the quantitative standard and NMR studies are presented

Pasek, M. A.↗
NASA NTRS1978

Infrared /JHK/ photometry of meteorites and asteroids

The paper reports JHK colors observed for ten asteroids and synthesized JHK colors for seven meteorite groups, samples of iron and nickel metal, pyroxene, olivine, feldspar, a lunar anorthite and some terrestrial mineral samples. Pronounced differences are apparent between the chondritic and achondritic meteorite classes; the chondritic classes show less subdued trends in J-H color which reflect their metamorphic grade. We find small but significant differences between the JHK colors of the predominant C and S classes of asteroids. All JHK colors of asteroids observed here fall within the limited domain defined by the various chondritic and iron-rich meteorites but are strikingly different from those of most achondritic meteorites.

Leake, M.↗