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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Forbidden transition probabilities for ground terms of ions with p or p5 configurations

Forbidden transition probabilities are given for ground term transitions of ions in the isoelectronic sequences with outer configurations 2s2 2p (B I), 2p5 (F I), 3s2 3p (Al I), and 3p5 (Cl I). Tables give, for each ion, the ground term interval, the associated wavelength, the quadrupole radial integral, the electric quadrupole transition probability, and the magnetic dipole transition probability. Coronal lines due to some of these ions have been observed, while others are yet to be observed. The tales for the Al I and Cl I sequences include elements up to germanium.

Kastner, S. O.↗
NASA NTRS1986

Quantitative modeling of the 'convection surge' mechanism of ion acceleration

To explore the properties of the 'convection surge' mechanism postulated by Quinn and Southwood (1982), a quantitative computer model of the mechanism is constructed. The model incorporates the dipolarization of the field line shapes as well as the results of recent transient electric field measurements by the AST-6 satellite. The computer model numerically integrates the equations of motion of ensembles of ions populating a single flux tube that goes through the convection surge or 'dipolarization' transformation. The numerical results confirm that the mechanism easily generates the bounce-phase-bunched ion distributions in question, and show that the convection surge can generate dramatically field-aligned ion distributions. It is hypothesized that the convection surge mechanism is fundamentally associated with the processes responsible for transporting tail ion populations to the geosynchronous regions of the earth's magnetosphere.

Mauk, B. H.↗
NASA NTRS1996

Studies of Westward Electrojets and Field-Aligned Currents in the Magnetotail During Substorms: Implications for Magnetic Field Models

This section outlines those tasks undertaken in the final year that contribute integrally to the overarching project goals. Fast, during the final year, it is important to note that the project benefited greatly with the addition of a Boston University graduate student, Ms. Karen Hirsch. Jointly, we made substantial progress on the development of and improvements to magnetotail magnetic field and plasma models. The ultimate aim of this specific task was to assess critically the utility of such models for mapping low-altitude phenomena into the magnetotail (and vice-versa). The bulk of this effort centered around the finite-width- magnetotail convection model developed by and described by Spence and Kivelson (J. Geophys. Res., 98, 15,487, 1993). This analytic, theoretical model specifies the bulk plasma characteristics of the magnetotail plasma sheet (number density, temperature, pressure) across the full width of the tail from the inner edge of the plasma sheet to lunar distances. Model outputs are specified by boundary conditions of the source particle populations as well as the magnetic and electric field configuration. During the reporting period, we modified this code such that it can be interfaced with the auroral particle precipitation model developed by Dr. Terry Onsager. Together, our models provide a simple analytic specification of the equatorial distribution of fields and plasma along with their low-altitude consequences. Specifically, we have built a simple, yet powerful tool which allows us to indirectly 'map' auroral precipitation signatures (VDIS, inverted-V's, etc.) measured by polar orbiting spacecraft in the ionosphere, to the magnetospheric equatorial plane. The combined models allow us to associate latitudinal gradients measured in the ion energy fluxes at low-altitudes with the large-scale pressure gradients in the equatorial plane. Given this global, quasi-static association, we can then make fairly strong statements regarding the location of discrete features in the context of the global picture. We reported on our initial study at national and international meetings and published the results of our predictions of the low-altitude signatures of the plasma sheet. In addition, the PI was invited to contribute a publication to the so-called 'Great Debate in Space Physics' series that is a feature of EOS. The topic was on the nature of magnetospheric substorms. Specific questions of the when and where a substorm occurs and the connection between the auroral and magnetospheric components were discussed in that paper. This paper therefore was derived exclusively from the research supported by this grant. Attachment: Empirical modeling of the quite time nightside magnetosphere.' 'CRRES observations of particle flux dropout event.' The what, where, when, and why of magnetospheric substorm triggers'. and 'Low altitude signature of the plasma sheet: model prediction of local time dependence'.

Spence, Harlan E.↗
DOE OSTI2023

Challenges and Prospects of Sodium‐Ion and Potassium‐Ion Batteries for Mass Production

The exponential growth of the lithium‐ion (LIB) market is causing a significant disparity between the supply chain and demand for its resources. In this regard, sodium‐ion and potassium‐ion batteries are promising alternatives to LIBs due to their low cost. However, the larger sizes of Na + and K + ions create challenges that prevent them from achieving energy densities comparable to LIBs while maintaining an acceptable cycle life. Here, in this perspective, the aim is to evaluate the status of Na‐ion and K‐ion batteries and the challenges associated with them on both fundamental and commercial levels. The focus is on the structural instability arising from phase transitions during cycling, intricate chemical degradation processes, and potential avenues for enhancing their performance with a specific goal of improving their viability for grid‐scale energy storage. Materials production and abundance limitations for the chemistries of the state‐of‐the‐art materials and account for critical parameters from both the perspective of researchers and investors are analyzed. This analysis aims to provide insights into the strategic trade‐offs required to effectively implement the technology in real‐world applications, such as grid‐scale storage and other areas. Furthermore, the utilization of metals with low or no supply‐chain problems as an important aspect of these trade‐offs is considered.

25 ENERGY STORAGE↗
NASA NTRS1985

Electric field effects on ion currents in satellite wakes

Small currents associated with satellite spin, dielectric conduction, or trace concentrations of H+, can have a substantial effect on the potential of a satellite and the particle currents reaching its surface. The importance of such small currents at altitudes below about 300 km stems from the extremely small 0+ currents impinging on the wake-side of the spacecraft. The particle current on the downstream side of the AE-C satellite is considered. Theoretical estimates based on a newly described constant of the motion of a particle indicate that accounting for small concentrations of H+ remove a major discrepancy between calculated and measured currents.

Parks, D. E.↗
NASA NTRS2023

Arguments for the Physical Nature of the Triggered Ion-Acoustic Waves Observed on the Parker Solar Probe

Triggered ion-acoustic waves are a pair of coupled waves observed in the previously unexplored plasma regime near the Sun. They may be capable of producing important effects on the solar wind. Because this wave mode has not been observed or studied previously and it is not fully understood, the issue of whether it has a natural origin or is an instrumental artifact can be raised. This paper discusses this issue by examining 13 features of the data such as whether the triggered ion-acoustic waves are electrostatic, whether they are both narrowband, whether they satisfy the requirement that the electric field is parallel to the k-vector, whether the phase difference between the electric field and the density fluctuations is 90°, whether the two waves have the same phase velocity as they must if they are coupled, whether the phase velocity is that of an ion-acoustic wave, whether they are associated with other parameters such as electron heating, whether the electric field instrument otherwise performed as expected, etc. The conclusion reached from these analyses is that triggered ion-acoustic waves are highly likely to have a natural origin although the possibility that they are artifacts unrelated to processes occurring in the natural plasma cannot be eliminated. This inability to absolutely rule out artifacts as the source of a measured result is a characteristic of all measurements.

Electric fields↗
DOE OSTI2024

Effects of wave damping and finite perpendicular scale on three-dimensional Alfvén wave parametric decay in low-beta plasmas

Shear Alfvén wave parametric decay instability (PDI) provides a potential path toward significant wave dissipation and plasma heating. However, fundamental questions regarding how PDI is excited in a realistic three-dimensional (3D) open system and how the finite perpendicular wave scale—as found in both laboratory and space plasmas—affects the excitation remain poorly understood. Here, we present the first 3D, open-boundary, hybrid kinetic-fluid simulations of kinetic Alfvén wave PDI in low-beta plasmas. Key findings are that the PDI excitation is strongly limited by the wave damping present, including electron–ion collisional damping (represented by a constant resistivity) and geometrical attenuation associated with the finite-scale Alfvén wave, and ion Landau damping of the child acoustic wave. The perpendicular wave scale alone, however, plays no discernible role: waves of different perpendicular scales exhibit similar instability excitation as long as the magnitude of the parallel ponderomotive force remains unchanged. These findings are corroborated by theoretical analysis and estimates. This new understanding of 3D kinetic Alfvén wave PDI physics is essential for laboratory study of the basic plasma process and may also aid future evaluation of the relevance/role of PDI in low-beta space plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1995

Stormtime ring current and radiation belt ion transport: Simulations and interpretations

We use a dynamical guiding-center model to investigate the stormtime transport of ring current and radiation-belt ions. We trace the motion of representative ions' guiding centers in response to model substorm-associated impulses in the convection electric field for a range of ion energies. Our simple magnetospheric model allows us to compare our numerical results quantitatively with analytical descriptions of particle transport, (e.g., with the quasilinear theory of radial diffusion). We find that 10-145-keV ions gain access to L approximately 3, where they can form the stormtime ring current, mainly from outside the (trapping) region in which particles execute closed drift paths. Conversely, the transport of higher-energy ions (approximately greater than 145 keV at L approximately 3) turns out to resemble radial diffusion. The quasilinear diffusion coefficient calculated for our model storm does not vary smoothly with particle energy, since our impulses occur at specific (although randomly determined) times. Despite the spectral irregularity, quasilinear theory provides a surprisingly accurate description of the transport process for approximately greater than 145-keV ions, even for the case of an individual storm. For 4 different realizations of our model storm, the geometric mean discrepancies between diffusion coefficients D(sup sim, sub LL) obtained from the simulations and the quasilinear diffusion coefficient D(sup ql, sub LL) amount to factors of 2.3, 2.3, 1.5, and 3.0, respectively. We have found that these discrepancies between D(sup sim, sub LL) and D(sup ql, sub LL) can be reduced slightly by invoking drift-resonance broadening to smooth out the sharp minima and maxima in D(sup ql, sub LL). The mean of the remaining discrepancies between D(sup sim, sub LL) and D(sup ql, sub LL) for the 4 different storms then amount to factors of 1.9, 2.1, 1.5, and 2.7, respectively. We find even better agreement when we reduce the impulse amplitudes systematically in a given model storm (e.g., reduction of all the impulse amplitudes by half reduces the discrepancy factor by at least its square root) and also when we average our results over an ensemble of 20 model storms (agreement is within a factor of 1.2 without impulse-amplitude reduction). We use our simulation results also to map phase-space densities f in accordance with Liouville's theorem. We find that the stormtime transport of approximately greater than 145-keV ions produces little change in f-bar the drift-averaged phase-space density on any drift shell of interest. However, the stormtime transport produces a major enhancement from the pre-storm phase-space density at energies approximately 30-145 keV, which are representative of the stormtime ring current.

Lyons, Larry R.↗
NASA NTRS1985

Supersonic ion outflows in the polar magnetosphere via the geomagnetic spectrometer

Observations of 'supersonic' O(+) outflows by DE-1 in the polar magnetosphere are interpreted as a velocity-filter effect resulting from the transport of these low energy ions from a horizontally narrow source associated with the polar cleft topside ionosphere into the polar cap magnetosphere. Under certain simplifying circumstances, it is shown that the 'Mach number' for the flow is essentially a geometrically determined quantity, approximately the ratio of the horizontal distance of the observation location to the source over the horizontal width of the source. A recently developed two-dimensional kinetic model of ion transport in the polar magnetosphere is used to calculate distribution functions and the associated bulk flow parameters, and these calculated quantities are compared with measured flow parameters from DE-1.

Horwitz, J. L.↗
DOE OSTI2021

Surface Dynamics of Charge Transport in LaAlO 3 /SrTiO 3 with Time-Resolved Kelvin Probe Force Microscopy

Time-resolved Kelvin probe force microscopy (tr-KPFM) was used to map surface potential dynamics in LAO/STO under its critical thickness, where it acts as an insulator, as polarizing and depolarizing electric fields were applied to planar electrodes in ambient conditions. Two time constants, for polarization and relaxation (i.e., depolarization) each, were derived and were shown to be independent of the direction of electrical field, revealing the reproducibility and recovery of the surfaces. Ambient aging or recent electrical history did not change the surface kinetics as determined by tr-KPFM. During polarization, the faster time constant (~3–6 s) is likely associated with the transport of H+ ions through the full length of the channel. The slower time constant (~40–50 s), on the other hand, is observed across only half the channel width near the higher-potential–more positive–electrode, which is likely associated with an electrochemical reaction such as the dissociation of water. This slower time constant drops to ~10–20 s toward the middle of the channel which could represent the transport of OH– ions. Furthermore, during relaxation, the fast time constant is consistent with polarization and is correlated to the same mechanism while the slower time constant is higher than it was during polarization and may represent the reabsorption of moisture from the atmosphere.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Nondestructively Visualizing and Understanding the Mechano-Electro-chemical Origins of “Soft Short” and “Creeping” in All-Solid-State Batteries

All-solid-state Li-metal batteries (ASLMBs) represent a significant breakthrough in the quest to overcome limitations associated with traditional Li-ion batteries, particularly in energy density and safety aspects. However, widespread implementation is stymied due to a lack of profound understanding of the complex mechano-electro-chemical behavior of Li metal in the ASLMBs. Herein, operando neutron imaging and X-ray computed tomography (XCT) are leveraged to nondestructively visualize Li behaviors within ASLMBs. This approach offers real-time observations of Li evolutions, both pre- and post- occurrence of a “soft short”. The coordination of 2D neutron radiography and 3D neutron tomography enables charting of the terrain of Li metal deformation operando. Concurrently, XCT offers a 3D insight into the internal structure of the battery following a “soft short”. Despite the manifestation of a “soft short”, the persistence of Faradaic processes is observed. To study the elusive “soft short”, phase field modeling is coupled with electrochemistry and solid mechanics theory. The research unravels how external pressure curbs dendrite growth, potentially leading to dendrite fractures and thus uncovering the origins of both “soft” and “hard” shorts in ASLMBs. Furthermore, by harnessing finite element modeling, it dive deeper into the mechanical deformation and the fluidity of Li metal.

25 ENERGY STORAGE↗
DOE OSTI2026

Wireless Bioelectronic Modulation of Membrane Potential in Glioblastoma Using Carbon Nanotube Porins

Disruption of membrane potential (V mem ) can activate pathways associated with cancer proliferation. Manipulating ion channels may therefore present an effective strategy for treating cancers that fail to respond to conventional therapies. One approach to target these channels is to manipulate the membrane charge, which involves the use of wireless bipolar electrodes such as carbon nanotube porins (CNTPs) inserted into cell membranes to modulate membrane charge and ionic flux. By utilizing membrane dyes, we observed alterations in V mem induced by CNTPs and externally applied voltages. Analyses of cellular behaviors and processes indicated that V mem is more receptive to stimuli in invasive cancers, while it leads to increased metabolism in less invasive cancers, with notable changes in the cell cycle occurring at approximately 48 h post-treatment in Glioblastoma (GB) cell lines. This work shows that CNTPs, in combination and with externally applied voltages, can modulate V mem and alter cancer cell processes, supporting their potential as a therapeutic.

bioelectricity↗
DOE OSTI2026

Organic colloid composition in variable-redox porewaters within a mountainous floodplain

Redox gradients, often driven by changes in sediment moisture levels in porous, heterogeneous groundwater systems, create dynamic conditions that may promote the production and transport of colloids within natural waters. While much research has focused on the inorganic composition of colloids, the organic composition remains less well understood. Organic matter (OM) in colloids may associate with minerals, complex metal ions, and serve as an electron donor for microbial respiration; therefore, its composition is of high interest. We examined the composition of porewater OM along a redox gradient in a riparian soil located along the Slate River in Crested Butte, Colorado, USA as a function of depth (90, 130, 200, and 350 cm below ground surface). All depths were oxic to suboxic, except 200 cm, where the products of iron and sulfate reduction were observed concomitant with an increase in dissolved and/or colloidal OM, pH, alkalinity, and conductivity. We investigated the composition of porewater using correlated scanning transmission X-ray microscopy and transmission electron microscopy. We observed a change in the OM chemistry from carboxylate-rich at the 200 cm depth (where it was also enmeshed with non-crystalline iron) to phenol- and substituted-aromatic-rich at other depths. Radiocarbon dating revealed carbon in porewater at 200 cm was younger than depths above and below. Soil porewater can flow down into the underlaying gravel bed during baseflow conditions, thus we speculate whether riparian porewater could transport iron- and carboxylate-rich organic colloids into surrounding surface waters through the gravel bed conduit.

Alpine floodplain↗
DOE OSTI2024

Slow Electron Holes in the Earth's Magnetosheath

Here, we present a statistical analysis of electrostatic solitary waves observed aboard Magnetospheric Multiscale spacecraft in the Earth's magnetosheath. Applying single-spacecraft interferometry to several hundred solitary waves collected in about 2-minute interval, we show that almost all of them have the electrostatic potential of positive polarity and propagate quasi-parallel to the local magnetic field with plasma frame velocities of the order of 100 km/s. The solitary waves have typical parallel half-widths from 10 to 100 m that is between 1 and 10 Debye lengths and typical amplitudes of the electrostatic potential from 10 to 200 mV that is between 0.01% and 1% of local electron temperature. The solitary waves are associated with quasi-Maxwellian ion velocity distribution functions, and their plasma frame velocities are comparable with ion thermal speed and well below electron thermal speed. We argue that the solitary waves of positive polarity are slow electron holes and estimate the time scale of their acceleration, which occurs due to interaction with ions, to be of the order of one second. The observation of slow electron holes indicates that their lifetime was shorter than the acceleration time scale. We argue that multi-spacecraft interferometry applied previously to these solitary waves is not applicable because of their too-short spatial scales. The source of the slow electron holes and the role in electron-ion energy exchange remain to be established.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Algebra of invariants for the Vlasov–Maxwell system

The algebra of invariants for both the relativistic and nonrelativistic multispecies Vlasov–Maxwell system is examined, including the case with a fixed ion background. Invariants and their associated fluxes are obtained directly from the Vlasov–Maxwell system. The invariants are shown to Poisson commute with the Hamiltonian and the rest of the Poisson bracket algebra of invariants is identified. Special attention is given to the role played by the monopole condition, ∇ · B.

Fundamental invariants↗
DOE OSTI2024

Assessing Nonlinear Polarization in Electrochemical Cells using AC Impedance Spectroscopy

AC impedance spectroscopy is widely used to evaluate performance limitations in energy storage and conversion devices (e.g., batteries, supercapacitors, and fuel cells). This work shows that integrating the resistive elements in an equivalent circuit as functions of steady-state current enables one to recover overpotentials associated with different processes (e.g., ion migration, charge transfer, and diffusion) in nonlinear electrochemical power supplies. Closed form expressions for diffusion overpotentials are derived using this method for transmissive and reflective boundary conditions and three electrode symmetries (planar, cylindrical, and spherical). Discussion is also extended to macroscopically homogenous porous electrodes which are relevant for most real-world devices. Overall, the approach described herein is a powerful tool to identify rate-limiting steps and guide material/component design.

25 ENERGY STORAGE↗
DOE OSTI2025

Pyrogenic Organic Matter Laboratory Experiment: Aerobic Respiration and Geochemistry from Variably Inundated Stream Sediments (v3)

This dataset supports a broader study examining the effects of variable inundation and pyrogenic organic matter on ecosystem respiration. The dataset provides data generated from a laboratory batch experiment investigating the interaction between variable inundation conditions (wet and dry sediment) and pyrogenic organic matter (burned and unburned treatments). The contents include time series dissolved oxygen, sediment geochemistry data, and field metadata (including qualitative information on instream and river corridor characteristics). This data package was originally published in November 2025. It was updated in April 2026 (v2; new and modified files) and May 2026 (v3; modified files). See the change history section in the readme for more details For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. This dataset is comprised of (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) international generic sample number (IGSN) mapping file; (5) readme; (6) field protocol; (7) sample name metadata; (8) an environmental context picture for the dry and inundated sampling locations; and (9) a subfolder with sample data from the sediment incubation experiment. The sample data subfolder contains (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC); (2) total nitrogen (TN); (3) gravimetric moisture; (4) partial pressure and production rates of carbon dioxide, methane, and nitrous oxide; (5) field wet sediment mass, dry sediment mass, water mass, and field wet sediment volume in incubation and sediment NPOC/TN vials; (6) methods codes; (7) respiration rates, pH, and temperature from after the incubation, raw time series dissolved oxygen and temperature, and a subfolder containing associated plots and scripts; (8) ions; (9) FTICR-MS methods; and (10) a subfolder of 12 Tesla (12T) FTICR-MS data. This folder contains the CoreMS processed data and three subfolders, one containing the .xml files, one containing the CoreMS output files, and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .xml, .html, .Rmd, .py, .cal, .json, or .jpg.

54 ENVIRONMENTAL SCIENCES↗