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At least 451 records · Page 25

Pervasive aqueous alteration in the early Solar System revealed by potassium isotopic variations in Ryugu samples and carbonaceous chondrites

C-type asteroids are the presumed home to carbonaceous chondrites, some of which contain abundant life-forming volatiles and organics. For the first time, samples from a C-type asteroid (162173 Ryugu) were successfully returned to Earth by JAXA’s Hayabusa2 mission. These pristine samples, uncontaminated by the terrestrial environment, allow a direct comparison with carbonaceous chondrites. This study reports the stable K isotopic compositions (expressed as δ 41 K) of Ryugu samples and seven carbonaceous chondrites to constrain the origin of K isotopic variations in the early Solar System. Three aliquots of Ryugu particles collected at two touchdown sites have identical δ 41 K values, averaged at -0.194 ± 0.038‰ (2SD). The K isotopic composition of Ryugu falls within the range of δ 41 K values measured on representative CI chondrites, and together, they define an average δ 41 K value of -0.185 ± 0.078‰ (2SE), which provides the current best estimate of the K isotopic composition of the bulk Solar System. Samples of CI chondrites with δ 41 K values that deviate from this range likely reflect terrestrial contaminations or compositional heterogeneities at sampled sizes. In addition to CI chondrites, substantial K isotopic variability is observed in other carbonaceous chondrites and within individual chondritic groups, with δ 41 K values inversely correlated with K abundances in many cases. These observations indicate widespread fluid activity occurred in chondrite parent bodies, which significantly altered the original K abundances and isotopic compositions of chondrules and matrices established at their accretion.

Asteroid Ryugu↗

Apatite geochemistry as a tool for understanding the petrogenesis of layered mafic-ultramafic rocks in the Bushveld Complex, South Africa

The sources of the magmas that formed the Rustenburg Layered Suite of the Bushveld Complex in South Africa remain debated, despite decades of research. Vertical and lateral variation in bulk rock and mineral separate Sr-Nd isotopic compositions, which generally indicate enriched sources, demonstrate that the layered sequence was formed by the emplacement of multiple batches of magma, crucially resulting in episodes of PGE-Cr-V mineralisation. The Lu-Hf isotope compositions of zircon are, however, at odds with the bulk rock Sr-Nd isotopic heterogeneity as they show near homogeneous compositions throughout the layered sequence (εHf (2.06 Ga) =−8). This lack of variation in Hf isotope composition has been attributed to deep, continental lithospheric mantle-related and/or crustal contamination of plume-derived Bushveld magmas. In this study, we analysed the major, trace element and Sr-Nd isotope geochemistry of apatite in the Rustenburg Layered Suite. Apatite occurs as an intercumulus mineral in the lowermost regions and a cumulus mineral in the uppermost regions of the layered sequence and can therefore be used to test existing models for the isotopic disequilibrium between bulk rock Sr-Nd and zircon Hf isotopic compositions. Apatite is largely chlorapatite in the lowermost regions and fluorapatite in the uppermost regions of the layered sequence. The Merensky Reef is unusual in that it comprises both chlorapatite and fluorapatite. Apatite throughout the layered sequence is generally unzoned and shows no evidence of late-stage alteration. Trace element data show that apatite is enriched in L/HREE, with common negative Eu-Sr anomalies. These trace element signatures are consistent with a magmatic origin for the apatite grains, with prior, or concurrent, plagioclase crystallization from the same melt. Variability in in situ Sr and Nd isotope compositions of apatite is recorded throughout the layered sequence with εNd (2.06 Ga) compositions varying between −2.5 and − 10.2 and initial 87 Sr/ 86 Sr compositions varying between 0.7079 and 0.7103 (for the Marikana dikes only). The variability in Sr-Nd isotope compositions of apatite is consistent with the bulk rock (and mineral separate) variation in Sr-Nd isotope compositions, suggesting apatite preserves primary magmatic compositions in the Rustenburg Layered Suite.

Apatite↗

Spatially Resolved, In Situ Carbon Isotope Analysis of Archean Organic Matter

Spatiotemporal variability in the carbon isotope composition of sedimentary organic matter (OM) preserves information about the evolution of the biosphere and of the exogenic carbon cycle as a whole. Primary compositions, and imprints of the post-depositional processes that obscure them, exist at the scale of individual sedimentary grains (mm to micron). Secondary ion mass spectrometry (SIMS) (1) enables analysis at these scales and in petrographic context, (2) permits morphological and compositional characterization of the analyte and associated minerals prior to isotopic analysis, and (3) reveals patterns of variability homogenized by bulk techniques. Here we present new methods for in situ organic carbon isotope analysis with sub-permil precision and spatial resolution to 1 micron using SIMS, as well as new data acquired from a suite of Archean rocks. Three analytical protocols were developed for the CAMECA ims1280 at WiscSIMS to analyze domains of varying size and carbon concentration. Average reproducibility (at 2SD) using a 6 micron spot size with two Faraday cup detectors was 0.4 %, and 0.8 % for analyses using 1 micron and 3 micron spot sizes with a Faraday cup (for C-12) and an electron multiplier (for C-13). Eight coals, two ambers, a shungite, and a graphite were evaluated for micron-scale isotopic heterogeneity, and LCNN anthracite (delta C-13 = -23.56 +/- 0.1 %, 2SD) was chosen as the working standard. Correlation between instrumental bias and H/C was observed and calibrated for each analytical session using organic materials with H/C between 0.1 and 1.5 (atomic), allowing a correction based upon a C-13H/C-13 measurement included in every analysis. Matrix effects of variable C/SiO2 were evaluated by measuring mm to sub-micron graphite domains in quartzite from Bogala mine, Sri Lanka. Apparent instrumental bias and C-12 count rate are correlated in this case, but this may be related to a crystal orientation effect in graphite. Analyses of amorphous Archean OM suggest that instrumental bias is consistent for 12C count rates as low as 10% relative to anthracite. Samples from the ABDP-9 (n=3; Mount McRae Shale, approximately 2.5 Ga), RHDH2a (n=2; Carrawine Dolomite and Jeerinah Fm, approximately 2.6 Ga), WRL1 (n=3; Wittenoom Fm, Marra Mamba Iron Formation, and Jeerinah Fm, approximately 2.6 Ga), and SV1 (n=1; Tumbiana Fm, approximately 2.7 Ga) drill cores, each previously analyzed for bulk organic carbon isotope composition, yielded 100 new, in situ data from Neoarchean sedimentary OM. In these samples, delta C-13 varies between -53.1 and -28.3 % and offsets between in situ and bulk compositions range from -8.3 to 18.8%. In some cases, isotopic composition and mode of occurrence (e.g. morphology and mineral associations) are statistically correlated, enabling the identification of distinct reservoirs of OM. Our results support previous evidence for gradients of oxidation with depth in Neoarchean environments driven by photosynthesis and methane metabolism. The relevance of these findings to questions of bio- and syngenicity as well as the alteration history of previously reported Archean OM will be discussed.

Williford, Kenneth H.↗

Constraints on chondrule origin from petrology of isotopically characterized chondrules in the Allende meteorite

The petrologic and chemical properties of the ferromagnesian chondrules in the Allende carbonaceous chondrite were examined in terms of the isotopic composition and the correlations between isotopic patterns. Areas of thin sections were studied with a SEM and bulk chemical fractions of 12 constituents were quantified to calculate correlations with petrologic features. A possible correlation between (CaO + Al2O2)/MgO and oxygen isotopes imply the formation of oxygen isotopic compositions in the chondrules by exchanges between isotopically heavy nebular gases and O-16 enriched solids. Different rates of gaseous exchange occurred with the various types of chondrules. Factors which may have controlled the exchanges are discussed.

Mcsween, H. Y., Jr.↗

Cryogenic Calcite: A Morphologic and Isotopic Analog to the ALH84001 Carbonates

Martian meteorite ALH84001 carbonates preserve large and variable microscale isotopic compositions, which in some way reflect their formation environment. These measurements show large variations (>20%) in the carbon and oxygen isotopic compositions of the carbonates on a 10-20 micron scale that are correlated with chemical composition. However, the utilization of these data sets for interpreting the formation conditions of the carbonates is complex due to lack of suitable terrestrial analogs and the difficulty of modeling under non-equilibrium conditions. Thus, the mechanisms and processes are largely unknown that create and preserve large microscale isotopic variations in carbonate minerals. Experimental tests of the possible environments and mechanisms that lead to large microscale isotopic variations can help address these concerns. One possible mechanism for creating large carbon isotopic variations in carbonates involves the freezing of water. Carbonates precipitate during extensive CO2 degassing that occurs during the freezing process as the fluid s decreasing volume drives CO2 out. This rapid CO2 degassing results in a kinetic isotopic fractionation where the CO2 gas has a much lighter isotopic composition causing an enrichment of 13C in the remaining dissolved bicarbonate. This study seeks to determine the suitability of cryogenically formed carbonates as analogs to ALH84001 carbonates. Specifically, our objective is to determine how accurately models using equilibrium fractionation factors approximate the isotopic compositions of cryogenically precipitated carbonates. This includes determining the accuracy of applying equilibrium fractionation factors during a kinetic process, and determining how isotopic variations in the fluid are preserved in microscale variations in the precipitated carbonates.

Niles, P. B.↗

A Chlorine Isotope Transect Across the Sudbury Impact Deposits Reveals Enigmatic Isotopic Fractionation

Volatile elements play an important role in a variety of cosmochemical and geochemical processes. As such, there has been significant interest in their abundance and isotopic composition. Chlorine is an important element for tracing these processes because it is incompatible in nearly all minerals, extremely volatile, and strongly hydrophilic [1]. The Cl isotope composition ( 37 Cl/ 35 Cl) of meteoritic components, therefore, can provide useful information regarding the isotopic reservoirs that were present in the early Solar System and any secondary processes that may have occurred on different parent bodies (e.g., [2-4]). There is a relatively narrow range in the Cl isotope compositions of terrestrial, Martian, and chondritic meteorites (δ 37 Cl ~ −6 to +4‰) (e.g., [2,3,5,6]), with exceptions to this being the Moon and Vesta (up to ~ +81‰ and ~ +40‰, respectively) [4, 5, 7-10]. One hypothesis for the extreme Cl isotope fractionation observed on the Moon is degassing following large-scale (possibly even crust-breaching) impact events [7-9]. The role of hypervelocity impacts and impact-generated magmatism in the isotopic evolution of planetary materials, however, has been until recently an area of limited published research with the majority of works focusing on the effects of impact shock (e.g., [10-13]). The ~ 1.85 Ga Sudbury impact crater [14] located in Ontario, Canada, is one of the three largest impact craters on Earth with good exposures of its impact melt sheet and overlying breccias [15,16]. The impact melt sheet, called the Sudbury Igneous Complex (SIC), is up to 5 km thick [17], with an estimated original volume of >10 4 km 3 [18], and differentiated. Recent work demonstrated evaporative loss and isotope fractionation of the moderately volatile element zinc and suggest melt sheets produced by impacts could have a significant effect on the Earth’s volatile inventory [19]. In this study we investigate the abundance and isotopic composition of Cl as well the water abundance of apatite from the SIC and the overlying crater-fill to test the hypothesis that large-scale impacts may have generated the extensive Cl isotopic fractionation observed on the Moon.

Sudbury↗

On the Origin of GEMS

GEMS (glass with embedded metal and sulfides) are a major component of anhydrous interplanetary dust particles (IDPs) their physical and chemical characteristics show marked similarities to contemporary interstellar dust. Recent oxygen isotopic measurements confirm that at least a small fraction (less than 5%) of GEMS are demonstrably presolar, while the remainder have ratios that are indistinguishable from solar values. GEMS with solar oxygen isotopic compositions either (1) had their isotopic compositions homogenized through processing in the interstellar medium (ISM), or (2) formed in the early solar system. Isotopic homogenization necessarily implies chemical homogenization, so (interstellar) GEMS compositions should reflect the average composition of dust in the local ISM. We performed a systematic examination of the bulk chemistry of GEMS in primitive IDPs in order to test this hypothesis.

Keller, L. P.↗

Boron isotopes in blue diamond record seawater-derived fluids in the lower mantle

Boron is a quintessential crustal element but its conspicuous presence in diamond – a mantle mineral – raises questions about potential subduction pathways for boron and other volatiles. It has been a long-standing goal to characterize the isotopic composition of boron in blue, boron-bearing (Type IIb) diamonds to reveal its origin. Mineral inclusions indicate that Type IIb diamonds crystallize at transition zone to lower mantle depths, meaning that if the boron is subducted it would trace a pathway of volatile elements into the deep mantle. Here, using off-line laser ablation sampling, we present the first boron isotope compositions, along with trace element contents and carbon isotope compositions, of a suite of blue diamonds mainly sourced from the Cullinan diamond mine in South Africa. The ten analyzed blue diamonds have a wide range in δ 11 B, between -9.2 ± 2‰ and -0.5 ± 2‰, compared to the more restricted range for mid-ocean ridge basalts (-7.1 ± 0.9‰). Carbon isotope values for the blue diamonds range between -20.6 and -1.8‰, with a mode at -17‰, significantly more negative than the main mantle mode at -5‰. Combined, the boron and carbon isotope compositions require fluid input from subducted oceanic lithosphere down into deep mantle source regions of blue diamonds. This finding highlights a deep subduction pathway for volatiles to stoke the source regions of deeply-derived magmas.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Isotopic, optical, and trace element properties of large single SiC grains from the Murchison meteorite

Ion probe mass spectrometry is used to analyze 41 large SiC grains from the Murchison CM2 chondrite, ranging up to 15 x 26 microns, for the isotopic compositions of C, N, Mg, and Si, and the concentrations of Al, Ti, V, Fe, Zr, and Ba. The majority were found to have large isotopic anomalies. Only two grains, characterized by extremely heavy carbon, give evidence for fossil Mg-26. On the basis of C and Si isotopic composition, 29 of the grains fall into three compact clusters, presumably from three discrete sources. The clustering of coarse-grained SiC stands in sharp contrast to the quasi-continuous distribution of finer-grained SiC and suggests that the top 0.1 percent of the mass distribution is a distinct population. The C and N isotopic compositions of the anomalous grains are not very diagnostic, being consistent with H-burning in the CNO cycle. The Si-isotopic compositions qualitatively show the signature of neutron capture in He-burning shells of highly evolved stars.

Virag, Alois↗

Isotopic inferences of ancient biochemistries - Carbon, sulfur, hydrogen, and nitrogen

In processes of biological incorporation and subsequent biochemical processing sizable isotope effects occur as a result of both thermodynamic and kinetic fractionations which take place during metabolic and biosynthetic reactions. In this chapter a review is provided of earlier work and recent studies on isotope fractionations in the biogeochemical cycles of carbon, sulfur, hydrogen, and nitrogen. Attention is given to the biochemistry of carbon isotope fractionation, carbon isotope fractionation in extant plants and microorganisms, isotope fractionation in the terrestrial carbon cycle, the effects of diagenesis and metamorphism on the isotopic composition of sedimentary carbon, the isotopic composition of sedimentary carbon through time, implications of the sedimentary carbon isotope record, the biochemistry of sulfur isotope fractionation, pathways of the biogeochemical cycle of nitrogen, and the D/H ratio in naturally occurring materials.

Schidlowski, M.↗

Predictive isotopic biogeochemistry: hydrocarbons from anoxic marine basins

Carbon isotopic compositions were determined for individual hydrocarbons in water column and sediment samples from the Cariaco Trench and Black Sea. In order to identify hydrocarbons derived from phytoplankton, the isotopic compositions expected for biomass of autotrophic organisms living in surface waters of both localities were calculated based on the concentrations of CO2(aq) and the isotopic compositions of dissolved inorganic carbon. These calculated values are compared to measured delta values for particulate organic carbon and for individual hydrocarbon compounds. Specifically, we find that lycopane is probably derived from phytoplankton and that diploptene is derived from the lipids of chemoautotrophs living above the oxic/anoxic boundary. Three acyclic isoprenoids that have been considered markers for methanogens, pentamethyleicosane and two hydrogenated squalenes, have different delta values and apparently do not derive from a common source. Based on the concentration profiles and isotopic compositions, the C31 and C33 n-alkanes and n-alkenes have a similar source, and both may have a planktonic origin. If so, previously assigned terrestrial origins of organic matter in some Black Sea sediments may be erroneous.

Non-NASA Center↗

A large area experiment to determine cosmic ray isotopic abundances

Measurements of the isotopic composition of cosmic rays have shown that the cosmic ray isotope ratios, Ne-22/Ne-20 and (Mg-25 + Mg-26)/Mg-24, exceed the solar abundance ratios by factors of 2.7 and 1.8, respectively. There are several processes which could be responsible for the observed excess of neutron-rich isotopes. The considered models imply neutron enrichment in the case of other, less abundant species, and a measurement of the involved isotopic abundances could provide a basis for the determination of the dominating processes occurring in cosmic ray sources. However, an experiment utilizing special equipment is necessary to conduct the required measurements. Such an experiment, the Aluminum Isotopic Composition Experiment (Alice), is being designed in a joint effort involving NASA and a West German university. Alice uses a Cherenkov-range technique to determine the isotopic composition of elements from oxygen through argon.

Mauger, B. G.↗

Relationships Between HED's, Mesosiderites, and Ungrouped Achondrites: Trace Element Analyses of Mesosiderite RKPA 79015 and Ungrouped Achondrite QUE 93148

Achondritic meteorites are a diverse group of meteorites that formed by igneous activity in asteroids. These meteorites can provide important information about early differentiation processes on asteroidal bodies. The howardite-eucrite-diogenite (HED) meteorites, the largest group of achondrites, are the only group of meteorites for which a potential parent body has been identified (4 Vesta) [e.g., 1]. Mesosiderites are stony-iron meteorites composed of roughly equal amounts of metal and silicates and silicates are broadly similar to HED meteorites [2]. They may have been formed by impact-mixing of crustal and core materials of differentiated meteorite parent bodies. Chemical and oxygen isotopic compositional data suggest that the HED meteorites and silicate portions of mesosiderites originated on the same or closely related parent bodies. Pallasites and IIIAB irons also have similar oxygen isotope compositions and have been thought to be related to the HEDs [3,4]. However, recent high resolution analyses have shown that pallasites and HED's have different oxygen isotopic values, but mesosiderites and HED s have the same isotope compositions implying a close connection [5]. QUE 93148 is a small (1.1g) olivine-rich (mg 86) achondrite that contains variable amounts of orthopyroxenene (mg 87) and kamacite (6.7 wt% Ni), with minor augite [6]. This meteorite was originally classified as a lodranite [7], but it s oxygen isotopic composition precludes a genetic relationship to the acapulcoites and lodranites. And also this meteorite has a lower Mn/Mg ratio than any major group of primitive or evolved achondrites and suggested that QUE 93148 may be a piece of the deep mantle of the HED parent body [6]. To better understand the relationship between HED s, mesosiderites and related achondrites, we have measured trace elements in the individual metallic and silicate phases. In this study, abundances of a suite of elements were measured for the unusual mesosiderite RKPA 79015 and a ungrouped achondrite QUE93148.

Righter, M.↗

Methane transport mechanisms and isotopic fractionation in emergent macrophytes of an Alaskan tundra lake

The stable carbon isotopic composition of methane associated with and emitted by the two dominant emergent macrophytes abundant in the many Alaskan tundra lakes, Carex rostrata and Arctophila fulva, is determined. The carbon isotopic composition of the methane was -58.6 +/- 0.5 (n=2) for Arctophila and -66.6 +/- 2.5 (n=6) for Carex. The methane emitted by these species is depleted in C-13 by 12 per mil for Arctophila and 18 per mil for Carex relative to methane withdrawn from plant stems 1-2 cm below the waterline. The results suggest more rapid transport of (C-12)H4 relative to (C-13)H4 through plants to the atmosphere. Plant stem methane concentrations ranged from 0.2 to 4.0 percent in Arctophila, with an isotopic composition of -46.1 +/- 4.3 percent (n=8). Carex stem methane concentrations ranged from 150 to 1200 ppm, with an isotopic composition of -48.3 +/- 1.4 per mil (n=3).

Chanton, Jeffrey P.↗

Constraints on Chondrule Generation, Disk Dynamics, and Asteroid Accretion from the Compositions of Carbonaceous Meteorites

The elemental and isotopic compositions of meteorites are expected to reflect several key processes that occurred in the early solar system, including the migration of gas and dust throughout the protoplanetary disk, the formation of chondrules, and the accretion of the first planetary bodies. However, the specific origins of the various compositions measured among these rocks are currently poorly constrained, limiting our understanding of these processes. Here, we use previously measured elemental and isotopic compositions of chondrites and iron meteorites to identify that carbonaceous (CC) meteorites are mixtures of noncarbonaceous (NC) material, calcium–aluminum-rich inclusion (CAI) material, and CI (Ivuna-like) material, in varying proportions. These trends indicate that chondrules in CO (Ornans-like), CM (Mighei-like), CV (Vigarano-like), and TL (Tagish Lake) chondrites share near-identical average proportions of CI material, arguing that they were generated through the remelting of preexisting NC chondrules all in the same disk environment. Because this proportion likely evolved over space and time throughout the disk, this similarity argues that these chondrules originate from a restricted spatial region and time interval, favoring their generation through a localized event. Moreover, the compositions of CR (Renazzo-like) chondrites indicate that their constituents formed through mechanisms different from those in CO, CM, CV, and TL chondrites. Furthermore, the recovered proportions of CI material in CC iron meteorites and chondrites together also argue for evolution in either the predominant direction of dust and gas motion in the first ~10 au of the disk or the radial distance of planetesimal accretion throughout the CC reservoir.

58 GEOSCIENCES↗

Trace element distributions in primitive achondrites

The primitive achondrites have approximately chondritic bulk chemical composition but achondritic textures. Clayton et al. show that nine of these meteorites, the acapulcoites and the lodranites, have similar oxygen isotopic compositions. The acapulcoites appear to be highly metamorphosed, but undifferentiated meteorites of chondritic composition; whereas, the lodranites appear to have lost a feldspathic partial melt. In order to learn more about metamorphic processes and partial melt removal, we have measured the trace element compositions of constituent phases of a number of primitive achondrites by ion microprobe. We have analyzed two acapulcoites, Acapulco and ALH81261 (paired with ALH77081), and three londranites, Lodran, LEW88280, and MAC88177. In addition, we analyzed LEW88663, which has the bulk composition, mineral chemistry, and oxygen isotopic composition of L-chondrites, but is metal-free and has an achondrite texture; and Divnoe, a plagioclase-poor, olivine-rich primitive achondrite with an oxygen isotopic composition similar to that of the group IAB iron meteorites. These meteorites show a variety of REE patterns in their constituent phases, and there are consistent differences between acapulcoites and lodranites that are consistent with removal of a LREE- and Eu-enriched melt that is apparently responsible for the low plagioclase content of lodranites.

Davis, Andrew M.↗

Compound-specific Isotope Analysis of Cyanobacterial Pure cultures and Microbial Mats: Effects of Photorespiration?

Microbial mats are considered modern homologs of Precambrian stromatolites. The carbon isotopic compositions of organic matter and biomarker lipids provide clues to the depositional environments of ancient mat ecosystems. As the source of primary carbon fixation for over two billion years, an understanding of cyanobacterial lipid biosynthesis, associated isotopic discriminations, and the influence of physiological factors on growth and isotope expression is essential to help us compare modern microbial ecosystems to their ancient counterparts. Here, we report on the effects of photorespiration (PR) on the isotopic composition of cyanobacteria and biomarker lipids, and on potential PR effects associated with the composition of various microbial mats. The high light, high O2 and limiting CO2 conditions often present at the surface of microbial mats are known to support PR in cyanobacteria. The oxygenase function of ribulose bisphosphate carboxylase/oxygenase can result in photoexcretion of glycolate and subsequent degration by heterotrophic bacteria. We have found evidence which supports an isotopic depletion (increased apparent E) scaled to O2 level associated with growth of Phormidium luridum at low CO2 concentrations (less than 0.04%). Similar to previous studies, isotopic differences between biomass and lipid biomarkers, and between lipid classes were positively correlated with overall fractionation, and should provide a means of estimating the influence of PR on overall isotopic composition of microbial mats. Several examples of microbial mats growing in the hydrothermal waters of Yellowstone National Park and the hypersaline marine evaporation ponds at Guerrero Negro, Baja Sur Mexico will be compared with a view to PR as a possible explanation of the relatively heavy C-isotope composition of hypersaline mats.

Jahnke, L. L.↗

230 Th/ 234 U Model Age of International Atomic Energy Agency Sample 27107-14-04 Measured at Los Alamos National Laboratory

This report details the uranium age-dating of International Atomic Energy Agency (IAEA) bulk environmental cotton swipe sample 27107-14-04 at Los Alamos National Laboratory (LANL). The 230 Th/ 234 U radiochronometer was used to determine sample model age requiring the following analyses: U assay, U isotope composition, Th assay and Th isotope composition. Sample 27107-14-04 was received at LANL on November 3, 2025, along with cotton swipe blank 30124-24-20.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗