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129 I and 99 Tc Distribution Coefficients of Subsurface Sediments Collected from the Proposed Site of the Environmental Manage Disposal Facility

Performance Assessment calculations are presently underway to evaluate the Environmental Management Disposal Facility (EMDF), a proposed new low-level radioactive waste (LLW) disposal facility on the U.S. Department of Energy’s Oak Ridge Reservation (ORR). Among the large number of input parameters needed for such calculations, are distribution coefficients (K d values; radionuclide concentration solid:liquid ratio) that provide a measure of the tendency of radionuclides to bind to sediments. The objective of this study was to measure K d values of two radionuclides that may pose a disproportionately large amount of risk, 129 I and 99 Tc. The average I K d value for the 10 geological materials recovered from the proposed EMDF site was 52.3 mL/g and ranged from 2.7 to 140.9 mL/g. These values were consistent, but somewhat larger than previous measurements made with ORR sediments and were about an order of magnitude greater than those used in previous EMDF PA calculations. The median Tc K d value was 807.2 mL/g, much greater than previously reported using ORR geological materials. Five of the ten tested geological materials sorbed large quantities of Tc, suggesting that the weakly sorbing Tc(VII) species had been reduced to the very strongly binding and sparingly soluble Tc(IV) species. The five strongly sorbing sediment had apparent solubility values of approximately <10 -8 mol/L. Based on sediment properties and general ORR geological considerations, it was proposed that much of the I and Tc sorption could be attributed to the low pH (average pH = 4.94), low redox status, and/or the elevated levels of iron oxides, manganese oxides, and natural organic matter. An implication of this study is that the areas of the EMDF subsurface environment may have natural properties for attenuating I and Tc movement, thereby potentially reducing risk posed by burial of LLW at this site.

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The Science of the Bomb

Uranium is a naturally occurring element with wo isotopes of interest – U238 and U235; U235 is useful for its ability to sustain a chain reaction; Chain reactions are the fundamental way that nuclear reactors work, as well as how bombs work; Enrichment of U235 is important for both nuclear energy as well as nuclear weapons; A safety focus is at the center of all nuclear operations in the United States

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Requirements for Cataloging Hanford Geophysical Datasets

Environmental management activities at the Hanford Site produce extensive data about site conditions, contaminants, cleanup, and more. Managing and archiving that data requires a high degree of collaboration among site contractors and a high level of awareness by project managers and staff. Part of that effort is developing a Hanford Environmental Information and Data Index (HEIDI) to organize the data and maximize its value by making it findable and available for reuse. The objective is to catalog the disparate data sets collected to address the evolving needs of planning, executing, and documenting cleanup over several decades up to the present day, including links to active data sources when available. A properly implemented data catalog makes finding environmental datasets related to an area or theme a routine, reliable process, without requiring the searcher to have special knowledge that a data set exists and where it may be stored. In this project, a working group, including the U.S. Department of Energy, the Hanford Site contractors, and Pacific Northwest National Laboratory staff, identified needs and requirements for handling complex site data. Geophysical data was chosen as a test case because it can be large and complex and often involves multiple processing steps to extract the information incorporated into deliverables. The ability to document those steps was one of the requirements identified for the catalog. In addition to developing requirements, other activities included selecting a metadata schema and initial testing with the objective of determining whether the workflow and capabilities of selected data catalog software platforms were sufficient to implement and impose the identified requirements. This initial testing involved running the default catalog instance using the software platform of interest and altering the configuration to achieve each requirement, if possible. Where configuration alone was insufficient, the possibility of modifying the software by changing the code was examined, but not implemented. A follow-on task is planned to reprogram the code as necessary to implement requirements in a prototype catalog.

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National Laboratories for Environmental Management and Stewardship (NNLEMS) National Lab Capabilities in Unmanned Aerial Systems (UAS) (Revision 1)

The Network of National Laboratories for Environmental Management and Stewardship (NNLEMS) formed an Unoccupied Aircraft Systems (UAS) topical team in spring 2025 for the purpose of documenting the capabilities of the National Laboratories relevant to the goals and needs of the Department of Energy (DOE) Office of Legacy Management (LM). The team was comprised of representatives from eight National Laboratories (Table 1), thereby bringing diverse skillsets from across the DOE complex. Recognizing that LM has extensive experience working with UAS contractors and using data collected from UAS, the topical team focused on the National Laboratories’ unique capabilities and types of scientific investigations that are not yet commercially available or easily contracted as services.

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Panel Session 133: Integrating Economic Redevelopment and Workforce Transition Into DOE Site Closure Planning (R1.18)

This panel focused on post-closure impacts to the long-term site workforce and communities in DoE's approach to accelerated site cleanup and expedited reduction of long-term financial liabilities. At sites where Cold-War workers shifted from weapons production to the cleanup effort, a more holistic approach to the workforce transition Post-EM cleanup is needed. This holistic approach would include incentives for expedited closure, trade re-training, and a vision for future site commercial activities. The panel discussed the importance of the right workforce incentives that includes appropriate training for displaced workers so that they can be integrated into a next job. A key aspect of this discussion was to re-assess the current and future land use opportunities related to land re-use concepts. By re-arranging cleanup sequencing is it possible to divest land sooner than originally projected for productive commercial use hence reducing the DOE long-term liability and consequently increasing an economic soft landing for those Cold-War workers. Panelists with presentations: Integrating Economic Redevelopment and Workforce Transition Into DOE Site Closure Planning (Sean Todd); Sustaining, Growing and Re-Developing DOD/DOD Facilities and Assets (Jonathan Taylor)

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Refining the Approach to Process Flowsheet Development and Maturation at Hanford - 20049

Rigorous process flowsheet management strategies form the basis of an enduring approach to refining the River Protection Project Integrated Process Flowsheet. Incorporation of lessons learned, recognizing upstream and downstream impacts and understanding barriers to implementation of process flowsheets from the outset of the decision-making process will help future revisions to the River Protection Project Integrated Process Flowsheet be more robust, technically defensible, cost effective, and time efficient, ultimately leading to an improved environmental stewardship of the Hanford site. (authors)

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Panel Session 90: US DOE Mixed Waste: Proposals for Dealing with Problematic Waste Streams and Policy Changes

This panel focused on generation and management of low level and mixed low-level radioactive wastes, challenges for disposition, innovative solutions applied at DOE sites, and collaboration among sites to ensure that waste disposition pathways are understood. In addition, potential policy initiatives were discussed including depleted uranium, elemental mercury, and treatment of legacy mixed waste components. As part of the introduction, Theresa Kliczewski provided an overview of why this panel is relevant: problematic mixed waste streams still exist across the DOE cleanup complex. Theresa noted that the DOE EM Headquarters Office of Waste and Materials Management (EM-4.2), for which she is employed with, continues to work with the DOE cleanup sites on a path forward for these problematic mixed waste streams. As part of this effort, EM-4.2 requested that the Energy Facility Contractors Group (EFCOG) perform a review of all the DOE sites problematic mixed waste streams. Panelists with presentations: Challenging Waste Streams: Disposition of Depleted Uranium Oxide Conversion Product (Douglas Tonkay); EFCOG WMWG Challenging Waste Subgroup (Tammy Monday); Mercury Waste Challenges (John Wrapp); Legacy Large Mixed Waste Components (Kalli Shupe)

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The Importance of Inventory for Informing Waste Strategy - 20280

A waste inventory aims to present the best available information about the nature, quantity and location of radioactive wastes and materials at a facility, site or in a country. Quality inventory data is necessary for developing appropriate strategies and plans for managing radioactive wastes and materials, with high standards of protection for people and the environment. The inventory of wastes will change over time due to a wide range of technical, commercial or policy reasons, for example, if reactor lifetimes are extended, if decommissioning strategies change or if new technologies are introduced for managing waste. Inventory information can also improve as better waste characterisation data becomes available. At a facility or site level, good quality inventory data are needed to underpin decision making about the waste management options and to demonstrate compliance with the chosen treatment or disposal route. At a site and country level, knowledge of the inventory can drive the improvement to waste strategy; waste management asset and service planning; and implementation. (authors)

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The Port Hope Areas Initiative's Port Granby Project: The Decontamination of Site Equipment from a Low Level Waste Facility - 20330

The Port Hope Area Initiative (PHAI) is the Government of Canada's response to the community recommended solutions for the remediation and safe, long-term management of historic low-level radioactive waste (LLRW) that was the result of uranium and radium processing operations in the Municipality of Port Hope, Ontario from the 1930's to the 1980's. The Eldorado refinery, on the shores of Lake Ontario, began refining radium-226 from pitchblende ore, later transitioning to the refining of uranium ore. Process residues were deposited at the Welcome Waste Management Facility in Port Hope until the mid-1950's switching to the Port Granby Waste Management Facility (PGWMF), which continued to accept waste until the late 1980's. The Port Granby Project involves the construction of a new, secure long-term waste management facility (LTWMF) and supporting infrastructure, and the excavation and relocation of approximately 1,200,000 m{sup 3} of historic low-level radioactive waste and marginally contaminated soil from the PGWMF to the newly constructed LTWMF. Since the project's inception in 2016, the bulk of the material has since been moved to the final long term storage cell. This has taken over 500,000 person-hours and a large amount of one site heavy equipment to accomplish including excavators, bulldozers, rock trucks, baker tanks and vacuum trucks. While many of the pieces of heavy equipment and water management equipment has further work to do on site, several of the sites larger items have already undergone the decontamination process prior to release from the site. This process has posed a serious challenge as the waste has a caustic nature to it and over the last few years it has had time to work its way into the metallic structures and framework of the equipment. Coupled with the tight work spaces and in some cases confined work areas there have been many issues that needed to be addressed to successfully reach a state where items can be free released to the unrestricted limits of the sites license. This ongoing process has led to a more refined decontamination program at the Port Granby Facility and has had a rather high success rate considering the length of time the equipment has been exposed to the waste materials on site. This paper discusses the varied challenges of decontamination faced at a low-level radioactive waste facility with a focus on the following aspects: - Challenges faced regarding different equipment types and the solutions implemented by Wood to address these challenges; - An examination of various decontamination methods employed throughout the project; and - Lessons learned over three years of remediation work and how they impact the decontamination process. (authors)

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Advanced Reactors Spent Fuel and Waste Streams Disposition Strategies

This report describes research and development (R&D) activities conducted during Fiscal Year 2023 (FY23) in the Advanced Fuels and Advanced Reactor Waste Streams Strategies work package in the Spent Fuel Waste Science and Technology (SFWST) Campaign supported by the United States (U.S.) Department of Energy (DOE). This report is focused on evaluating and cataloguing Advanced Reactor Spent Nuclear Fuel (AR SNF) and Advanced Reactor Waste Streams (ARWS) and creating Back-end Nuclear Fuel Cycle (BENFC) strategies for their disposition. The R&D team for this report is comprised of researchers from Sandia National Laboratories and Enviro Nuclear Services, LLC.

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DPC Disposal Concepts of Operations. Final Report

The U.S. Department of Energy supports an R&D program for evaluating approaches to direct disposal of commercial spent fuel in dual-purpose canisters (DPCs). The major thrusts include alternative measures for treating the possibility of internal criticality events in DPC-based waste packages after thousands of years in a repository. These measures include: 1) injectable fillers, 2) analysis of the consequences of criticality events in a repository should they occur, and 3) options for modifying fuel assemblies or baskets in DPCs at the time they are loaded. This report presents a snapshot of progress in each of these areas drawing on deliverable reports generated during FY18 through FY20. Another aspect of the R&D program is to develop concepts of operations for repositories that would permanently dispose of DPC-based waste packages, considering different generic host media (not site-specific). The idea is to examine whether the disposal of large, heavy, heat-generating waste packages is technically feasible, and to identify the engineering challenges that would arise during implementation of the different disposal concepts. Descriptions of repository features are presented for repositories in salt media, argillite (clay/shale) media, crystalline (e.g., granitic) media, and unsaturated media (considering either alluvium or hard rock). Thermal management criteria for each concept are presented in terms of the maximum waste package thermal power at emplacement, when the repository could be opened, and the duration of repository emplacement operations. The overall message of this report is that direct disposal of commercial spent fuel is technically feasible in different types of geologic host media, but that thermal management and postclosure criticality impose different constraints on each concept. Engineering challenges are recognized and discussed. Treatment of postclosure criticality is identified as an important technical question that receives the majority of attention in the R&D program.

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Modeling gas migration through clay-based buffer material using coupled multiphase fluid flow and geomechanics with stress-dependent gas permeability

A model for gas migration through clay-based buffer material is developed for modeling gas generation and migration associated with deep geologic nuclear waste disposal. The model is based on a multiphase fluid flow and geomechanics simulator that is adapted to consider enhanced gas flow when gas pressure is high enough to approach the confining stress magnitude. A key feature in the model is a direct coupling between gas permeability and stress, through a non-linear stress-dependent permeability function. The model was first tested and calibrated by modelling two different laboratory gas migration tests on Wyoming (MX-80) bentonite samples. The calibrated model was then applied to model gas migration through a bentonite buffer of a large-scale gas injection test (Lasgit) conducted at the Äspö Hard Rock Laboratory in Sweden. Observed preferential gas migration along interfaces (between compacted blocks and along the canister surface) required explicit representation of such interfaces in the model. The model with the stress-dependent gas permeability accurately captured observed experimental responses in terms of gas breakthrough time, peak gas pressure, and cumulative gas flow rates. The calibrated model was finally applied to simulate migration of hydrogen gas generated within a breached nuclear waste canister over 10,000 years, involving migration of much larger gas volumes. For the considered gas generation rate and host rock properties, the generated gas could migrate through the bentonite buffer and released into the surrounding host rock at a maximum gas pressure somewhat higher than the initial total stress, though a significant amount of hydrogen remained within the buffer. This modelling sets the stage for further detailed analysis of the impact of hydrogen gas generation on the long-term performance of nuclear waste repositories.

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Advanced Retrieval and Disposition Techniques for Remote Handled Mixed Low-Level Waste - 20319

Legacy waste generated by the sodium-cooled fast reactor, EBR-II, program at the Idaho National Laboratory (INL) (owned by the U.S. Department of Energy and managed and operated by Battelle Energy Alliance, LLC) is challenging to treat and disposition using conventional methods. As a result, Veolia Nuclear Solutions is under contract with the Idaho National Laboratory to demonstrate an integrated retrieval and disposition solution for Remote-Handled Mixed Low-Level Waste currently stored in underground liners at INL. Delivery of the integrated solution builds on the expertise and successes of Veolia Nuclear Solutions under its Problematic Waste Treatment Initiative with INL. This initiative focuses solely on the treatment of problematic (reactive metal containing) waste streams using the Veolia Nuclear Solutions GeoMelt{sup R} In-Container Vitrification (ICV{sup TM}) technology. Under the contract, Veolia Nuclear Solutions will provide a fully commissioned prototype remote retrieval system to semi-remotely retrieve and size-reduce problematic waste liners into a safe and consolidated package for transport. The consolidated package will be shipped to Richland, Washington for demonstration treatment using the robust GeoMelt Richland system at Perma-Fix Northwest. The treated waste will ultimately be disposed of as a vitrified Low-Level Waste glass monolith. Veolia Nuclear Solutions has delivered countless remotely operated systems globally to solve some of the industry's most challenging problems. To ensure risk is mitigated in the best possible manner, a methodical phased approach is being utilized to validate the integrated solution. This contract focuses on the delivery and deployment of the prototype retrieval system onsite and the treatment of a single liner. Following successful demonstration treatment using GeoMelt ICV, the project is planning to make prototype enhancements before retrieving and treating another liner. Establishing a new integrated approach for retrieval and disposition of waste offers many benefits to INL and the U.S. Department of Energy. It is anticipated that the integrated solution will provide significant cost and schedule savings by increasing the number of liners dispositioned per year. In addition, the complexity of the overall waste disposition process will be reduced. Remotely retrieving and size-reducing waste in the field will provide additional safety to operational personnel and allow critical resources, such as hot cells, to focus on the primary missions at hand. Vitrification (using the GeoMelt ICV technology) allows for the direct processing of metal clad waste thereby significantly reducing pretreatment steps while providing a robust waste form for long-term disposal. The results from this ongoing contract are presented in this paper. (authors)

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Presentation on the INL Remote-Handled Low-Level Waste Disposal Facility FY-2024 Annual Summary Report

The abstract below is from the report INL/RPT-24-82600. The powerpoint presentation contains information taken from the report. This Fiscal Year (FY) 2024 annual summary report (ASR) documents the continued adequacy of the performance assessment (PA), the composite analysis (CA), and associated operating disposal authorization statement (ODAS) technical basis documents for the Remote Handled Low Level Waste (RHLLW) Disposal Facility at Idaho National Laboratory (INL). Annual review of the adequacy of the PA and CA for RHLLW Disposal Facility ensures that conclusions of the analyses remain valid in accordance with requirements of the U.S. Department of Energy (DOE) Order 435.1, “Radioactive Waste Management.” In FY 2024, no significant operational changes or other activities occurred that would cause deviation from the assumptions in the PA and CA pertaining to disposal geometry, verification of waste characteristics, tracking disposal inventories against total limits, facility closure design, or institutional controls. Nineteen waste canister shipments were received at the RHLLW Disposal Facility, and all nineteen waste canisters were emplaced in disposal vaults.

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Nontraditional Sensors for Aqueous Separation Research & Workforce Development

Idaho National Laboratory’s (INL) nuclear fuel cycle capabilities enable the deployment of technologies that sustain the current reactor fleet, support demonstration and deployment of new advanced reactors, and facilitate management and disposition of existing and future radiological waste materials. INL focuses on deploying nuclear energy systems with confidence by decreasing proliferation risk through research that demonstrates process transparency and supports safeguards and security by design. An example of these capabilities is the Beartooth test bed, set to begin operations toward the end of fiscal year 2026. Beartooth will include a cascade of centrifugal contactors, glove box lines, and solidification and dissolution equipment to aid in the progression of novel separation techniques and to provide hands-on experience to cultivate and maintain a robust workforce of experts. To support Beartooth’s enhanced instrumentation and monitoring equipment needs, several nontraditional sensors are being considered for future deployment. The non-traditional sensors include accelerometers, acoustic microphones, and infrared cameras. These nontraditional sensors have the potential to not only help monitor the process but also enhance nuclear safeguards.

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Panel Session 115: Collaboration Across Borders to Deliver Cleanup and Decommissioning Challenges

This panel focused on where multiple countries have collaborated to solve difficult remediation and cleanup challenges through either formal or informal means. The focus was to share real examples of where collaboration has accelerated cleanup saving time and money. This could be through policy or process improvements, technology transfer or sharing R and D, or other means of collaborative efforts. Panelists with presentations: Canada-AECL Collaboration Across Borders (Richard Sexton, Alastair MacDonald); Collaboration Across Borders to Deliver Cleanup and Decommissioning Challenges (Anthony Banford); IAEA Perspective on International Collaboration in D and ER (Horst Monken Fernandes); How, Why and Benefits of Collaboration (Kurt Gerdes)

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