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At least 451 records · Page 25

Multiple ferroelectric nematic phases of a highly polar liquid crystal compound

Ferroelectric nematic liquid crystals represent not only fascinating, fundamental science, but they also hold promise for new technologies including high-density power storage or sub-millisecond switching information displays. In this work, we describe the synthesis and measurements of the physical properties of a new compound, 4-nitrophenyl 4-[(2,4-dimethoxylbenzoyl)oxy]-2-fluorobenzoate (RT11001). This material exhibits multiple, highly polar, ferroelectric nematic phases that have not been previously reported. Here we employ a wide range of physical characterisation methods including differential scanning calorimetry (DSC), mass density measurement, optical birefringence, polarising optical microscopy (POM), dielectric spectroscopy, electric current analysis, electro-optical switching, small-angle and wide-angle x-ray scattering measurements to show that RT11001 has multiple, distinct ferroelectric phases. We argue that the highest temperature phase is a polar nematic fluid with non-polar smectic clusters. Directly below appears to be a transition to another polar nematic phase containing polar positionally ordered clusters. Lastly, there are indications of an additional, polar biaxial liquid crystal phase at lower temperatures.

36 MATERIALS SCIENCE↗

Skylab program payload integration. TO27 sample array

The objective of the TO27 sample array was to determine the change in optical properties of various transmissive windows, mirrors, and diffraction gratings caused by the deposition of contaminants found about the orbital assembly. The expected information to be obtained from the total TO27 sample array program is as follows: (1) effect of space contaminants on transmittance, reflectance, grating efficiency, and polarization; (2) variations in deposition of contaminants due to substrate, solar radiation, period of exposure, direction of exposure, and geometry effects; (3) identification of contaminants and source of evolution; (4) time of contaminant evolution and lingering time; and (5) guidelines for a model of spacecraft contamination.

Muscari, J. A.↗

JPL activities on development of acousto-optic tunable filter imaging spectrometer

Recent activities of JPL in the development of a new type of imaging spectrometers for earth observation and planetary exploration are reported. This instrument uses the acousto-optic tunable filter (AOTF) as high resolution and fast programmable bandpass filter. AOTF operates in the principle of acousto-optic interaction in an anisotropic medium. This filter can be tuned in sequential, random, and multiwavelength access modes, providing observational flexibility. The diffraction process in the filter generates two diffracted monochromatic beams with polarization orthogonal to each other, creating a unique capability to measure both polarimetric and spectral properties of the incoming light simultaneously with a single instrument. The device gives wide wavelength operations with reasonably large throughput. In addition, it is in a compact solid-state structure without moving parts, providing system reliability. These attractive features give promising opportunities to develop a new generation of airborne/spaceborne and ground, real-time, imaging spectrometer systems for remote sensing applications.

Cheng, Li-Jen↗

New Satellite Measurements of Aerosol Direct Radiative Forcing from MODIS, MISR, and POLDER

New set of satellites, MODIS and MISR launched on EOS-Terra and POLDER launched on ADEOS-1, and scheduled for ADEOS-II and PARASOL in orbit with EOS-AQUA, open exciting opportunities to measure aerosol and their radiative forcing of climate. Each of these instruments has a different approach to invert remote sensing data to derive the aerosol properties. MODIS is using wide spectral range 0.47-2.1 micron. MISR is using narrower spectral range (0.44 to 0.87 micron) but observing the same spot from 9 different angles along the satellite track. POLDER using similar wavelengths, uses two dimensional view with a wide angle optics and adds polarization to the inversion process. Among these instruments, we expect to measure the global distribution of aerosol, to distinguish small pollution particles from large particles from deserts and ocean spray. We shall try to measure the aerosol absorption of solar radiation, and their refractive index that indicates the effect of liquid water on the aerosol size and interaction with sunlight. The radiation field measured by these instruments in variety of wavelengths and angles, is also used to derive the effect of the aerosol on reflection of sunlight spectral fluxes to space. When combined with flux measurements at the ground, it gives a complete characterization of the effect of aerosol on solar illumination, heating in the atmosphere and reflection to space.

Kaufman, Y.↗

Clouds and Aerosols in the Climate System

Remote sensing of cloud and aerosol properties from space is reviewed for present and planned international satellite sensors. Techniques that are being used to enhance our ability to characterize the global distribution of cloud and aerosol properties include well-calibrated multispectral radiometers that rely on visible, near-infrared, and thermal infrared channels, sometimes including polarization as well. The availability of thermal channels to aid in cloud screening for aerosol properties is an important additional piece of information that has not always been incorporated into sensor designs. In this paper, we describe the radiative properties of clouds as currently determined from satellites (cloud fraction, optical thickness, cloud top pressure, and cloud effective radius), and highlight the global and regional cloud microphysical properties currently available for assessing climate variability and forcing. In addition, we will frustrate the radiative and microphysical properties of aerosol particles that are currently available from space-based observations, as well as enhancements to aerosol remote sensing over bright-reflecting surfaces that is anticipated in the next couple of years. Finally, we will describe the aerosol optical and radiative properties available from the globally distributed AERONET network of ground-based sun-sky radiometers.

King, Michael D.↗

TPSAS-NF1676L-23428-DND

Recent theoretical advances now enable accurate characterization of both the single scattering and multiple scattering contributions to the lidar backscatter signals obtained from opaque water clouds (Hu et al., 2006). As a consequence, lidar measurements of opaque water clouds have increasingly broad applications, especially for space-based polarization-sensitive lidars such as CALIOP. Among the most prominent and useful of these are (1) calibration and assessments of calibration accuracy (e.g., O'Connor et al., 2004; Hu et al., 2006); (2) accurate estimates of extrinsic (e.g., optical depths) and intrinsic (e.g., extinction-to-backscatter ratios) optical properties of clouds and aerosol layers lying above opaque water clouds (Hu et al., 2007; Liu et al., 2015); and (3) retrievals of water cloud microphysical properties such as cloud droplet number concentrations (Hu et al., 2007; Li et al., 2011; Zeng et al., 2014). In the first part of this presentation we give an overview of the recent advances in this subject area. The second part introduces several new studies of water clouds using the multi-wavelength depolarization measurement capabilities of NASA's airborne high spectral resolution lidars (HSRL). We use these measurements to assess existing theory, validate the measurement concept and explore several new application concepts. The third part discusses changes in Arctic water clouds using CALIOP measurements. The HSRL water cloud study is supported by NASA's atmospheric composition program.

Y Hu↗

Radar Studies in the Solar System

We aid in study of the solar system by means of ground-based radar. We have concentrated on: (1) developing the ephemerides needed to acquire radar data at Arecibo Observatory and (2) analyzing the resultant data to: test fundamental laws of gravitation; determine the size , shape, topography, and spin vectors of the targets; and study the surface properties of these objects, through their scattering law and polarization characteristics. We are engaged in radar observations of asteroids and comets, both as systematically planned targets and as "targets of opportunity." In the course of the program, we have prepared ephemerides for about 80 asteroids and three comets, and the radar observations have been made or attempted at the Arecibo Observatory, in most cases successfully, and in some cases on more than one apparition. The results of these observations have included echo spectra for the targets and, in some cases, delay - Doppler images and measurements of the total round-trip delay to the targets. Perhaps the most dramatic of these results are the images obtained for asteroids (4179) Toutatis and 1989PB (Castalia), which were revealed to be double-lobed objects by the radar images. Besides these direct results, the radar observations have furnished information on the sizes and shapes of the targets through analysis of the Doppler width of the echoes as a function of time, and on the surface properties (such as composition, bulk density, and roughness) through analysis of the reflectivity and of the polarization state of the echoes. We have also refined the orbits of the observed asteroids as a result of the Doppler (and in some cases delay) measurements from the radar observations. Although the orbits of main-belt asteroids accessible to ground-based radar are quite well known from the available optical data, some near-Earth objects have been seen by radar very soon after their optical discovery (for example, 199OMF, just eight days after discovery). In such cases. the radar results ensure that the object in question can be anticipated and identified at the next apparition. We have also participated in radar studies of the terrestrial planets. The results of these studies have included both planetary topography profiles from the analysis of round-trip delays to points along the target Doppler equator and determinations of the target spin state. The latter is of special interest in the case of Venus, which is very close to, but not on, a multi-body spin-orbit resonance such that Venus rotates 12 times for every 8 Earth orbits and 13 Venus orbits. As a result, Venus presents nearly the same face toward Earth at each inferior conjunction. Our latest results confirm that the spin state of Venus is slightly off the resonance. The delay measurements from planetary 2 ranging have also been used in combination with other types of range data in testing general relativity with increasing accuracy. We have also been engaged in radar studies of planetary satellites. Using our ephemerides, Arecibo made radar observations of the Galilean satellites of Jupiter and of Mars' satellite Phobos during the favorable opposition seasons (1988-1992 for Jupiter and 1990 for Mars). An attempt was also made to observe Deimos, but without detecting an echo. In 1997, an attempt was made to observe Saturn's satellite Titan, using the newly upgraded Arecibo radar system for transmitting and the Goldstone radar for receiving, but no echo was detected. The study of satellites by radar is in many ways similar to that of asteroids. The results from these observations have included characterization of the surface properties from the reflectivity and polarization ratio, as well as (in the case of the large satellites of Jupiter) the variation of reflectivity with incidence angle.

Shaprio, Irwin I.↗

X-ray linear dichroic ptychography

Biominerals such as seashells, coral skeletons, bone, and tooth enamel are optically anisotropic crystalline materials with unique nanoscale and microscale organization that translates into exceptional macroscopic mechanical properties, providing inspiration for engineering new and superior biomimetic structures. Using Seriatopora aculeata coral skeleton as a model, here, we experimentally demonstrate X-ray linear dichroic ptychography and map the c-axis orientations of the aragonite (CaCO 3 ) crystals. Linear dichroic phase imaging at the oxygen K-edge energy shows strong polarization-dependent contrast and reveals the presence of both narrow (<35°) and wide (>35°) c-axis angular spread in the coral samples. These X-ray ptychography results are corroborated by four-dimensional (4D) scanning transmission electron microscopy (STEM) on the same samples. Evidence of co-oriented, but disconnected, corallite subdomains indicates jagged crystal boundaries consistent with formation by amorphous nanoparticle attachment. We expect that the combination of X-ray linear dichroic ptychography and 4D STEM could be an important multimodal tool to study nano-crystallites, interfaces, nucleation, and mineral growth of optically anisotropic materials at multiple length scales.

4D scanning transmission electron microscopy↗

Nonreciprocal directional dichroism at telecom wavelengths

Magnetoelectrics with ultra-low symmetry and spin-orbit coupling are well known to display a number of remarkable properties including nonreciprocal directional dichroism. As a polar and chiral magnet, Ni 3 TeO 6 is predicted to host this effect in three fundamentally different configurations, although only two have been experimentally verified. Inspired by the opportunity to unravel the structure-property relations of such a unique light-matter interaction, we combined magneto-optical spectroscopy and first-principles calculations to reveal nonreciprocity in the toroidal geometry and compared our findings with the chiral configurations. We find that formation of Ni toroidal moments is responsible for the largest effects near 1.1 eV—a tendency that is captured by our microscopic model and computational implementation. At the same time, we demonstrate deterministic control of nonreciprocal directional dichroism in Ni 3 TeO 6 across the entire telecom wavelength range. This discovery will accelerate the development of photonics applications that take advantage of unusual symmetry characteristics.

36 MATERIALS SCIENCE↗

Effect of molecular anisotropy on the intensity and degree of polarization of light scattered from model atmospheres

Computations of the properties of sunlight scattered from models of the earth-atmosphere system are presented to show the effect of molecular anisotropy on the intensity, flux, and degree of polarization of the scattered light. The values of these parameters change significantly when the anisotropy factor is neglected in the molecular optical thickness and scattering phase matrix. However, if the Rayleigh scattering optical thickness is kept constant and the molecular anisotropy factor is included only in the Rayleigh phase matrix, the flux does not change, the intensity changes by a small amount, but the changes in the degree of polarization are still significant.

Bahethi, O. P.↗

High resolution lunar radar studies: Preliminary results

High resolution radar data for the lunar surface were acquired over 14 sites in June and November 1990 using the new 10 MHz data taking system at the Arecibo Observatory. The raw data collected for each site covers an area approximately 100 by 400 km and will be processed using delay-Doppler techniques into images of backscatter cross section with three fo four independent looks. All observations transmitted a circularly polarized signal and both senses of circular polarization were received containing the polarized and depolarized component of the backscatter signal. The relative power in these two polarizations provides useful information on properties of the surface, in particular surface roughness. The effort to date focused on the initial data analysis with new software written to perform a full synthetic aperture focusing on the raw radar data. This analysis will involve the use of complementary high resolution optical and topographic data sets to aid interpretation of surface scattering mechanisms.

Stacy, Nicholas J. S.↗

MinMap: An imaging spectrometer for high resolution compositional mapping of the Moon

MinMap has been selected by the Lunar Scout program to characterize and map the mineral composition of the Moon. The instrument will be built as a collaborative effort between Brown University, SETS Technology Inc., and Ball Aerospace Corp. MinMap is a visible to near-infrared imaging spectrometer that contains 192 spectral channels from 0.35-2.4 microns with signal to noise greater than 200 and 256 cross-track spatial elements. The spectrometer design has a 6 deg field of view (FOV) and utilizes grating dispersive elements and two dimensional detectors (no moving parts). An 'image cube' of data is produced that contains two dimensions of spatial information and one dimension of spectral information. All spectral channels and cross-track spatial elements are recorded simultaneously with spacecraft motion scanning the second spatial dimension. The high spectral resolution and continuous spectral range of MinMap are designed to measure the diagnostic absorption features of principal lunar minerals and their lithologic mixtures. Since the optical properties of lunar materials change in a regular manner upon exposure to the space environment, this spectral range is also quite sensitive to variations in exposure history (soil maturity). Nominal measurement stragegy is to obtain full global data of the Moon at 180 m/pixel from a 450 km polar orbit during the first month or two of operation. A 100 km orbit is anticipated for the remaining part of a 1 year mission allowing higher resolution data (approx. 80 m/pixel) to be obtained for targeted regions. MinMap exceeds LE x SWG's measurement recommendations and will provide the highest spatial resolution compositional map of lunar rocks and soils currently planned for orbital missions. Since all spectral channels are co-registered and obtained simultaneously, 'image cube' data swaths will be available for analysis almost immediately.

Pieters, C. M.↗

Indium Tin Oxide-Magnesium Fluoride Co-Deposited Films for Spacecraft Applications

Highly transparent coatings with a maximum sheet resistivity between 10(exp 8) and 10(exp 9) ohms/square are desired to prevent charging of solar arrays for low Earth polar orbit and geosynchronous orbit missions. Indium tin oxide (ITO) and magnesium fluoride (MgF2) were ion beam sputter co-deposited onto fused silica substrates and were evaluated for transmittance, sheet resistivity and the effects of simulated space environments including atomic oxygen (AO) and vacuum ultraviolet (VUV) radiation. Optical properties and sheet resistivity as a function of MgF2 content in the films will be presented. Films containing 8.4 wt.% MgF2 were found to be highly transparent and provided sheet resistivity in the required range. These films maintained a high transmittance upon exposure to AO and to VUV radiation, although exposure to AO in the presence of charged species and intense electromagnetic radiation caused significant degradation in film transmittance. Sheet resistivity of the as-fabricated films increased with time in ambient conditions. Vacuum beat treatment following film deposition caused a reduction in sheet resistivity. However, following vacuum heat treatment, sheet resistivity values remained stable during storage in ambient conditions.

Dever, Joycer A.↗

Compact programmable photonic variable delay devices

Optical variable delay devices for providing variable true time delay to multiple optical beams simultaneously. A ladder-structured variable delay device comprises multiple basic building blocks stacked on top of each other resembling a ladder. Each basic building block has two polarization beamsplitters and a polarization rotator array arranged to form a trihedron; Controlling an array element of the polarization rotator array causes a beam passing through the array element either going up to a basic building block above it or reflect back towards a block below it. The beams going higher on the ladder experience longer optical path delay. An index-switched optical variable delay device comprises of many birefringent crystal segments connected with one another, with a polarization rotator array sandwiched between any two adjacent crystal segments. An array element in the polarization rotator array controls the polarization state of a beam passing through the element, causing the beam experience different refractive indices or path delays in the following crystal segment. By independently control each element in each polarization rotator array, variable optical path delays of each beam can be achieved. Finally, an index-switched variable delay device and a ladder-structured variable device are cascaded to form a new device which combines the advantages of the two individual devices. This programmable optic device has the properties of high packing density, low loss, easy fabrication, and virtually infinite bandwidth. The device is inherently two dimensional and has a packing density exceeding 25 lines/cm.sup.2. The delay resolution of the device is on the order of a femtosecond (one micron in space) and the total delay exceeds 10 nanosecond. In addition, the delay is reversible so that the same delay device can be used for both antenna transmitting and receiving.

Yao, X. Steve↗

Photonic variable delay devices based on optical birefringence

Optical variable delay devices for providing variable true time delay to multiple optical beams simultaneously. A ladder-structured variable delay device comprises multiple basic building blocks stacked on top of each other resembling a ladder. Each basic building block has two polarization beamsplitters and a polarization rotator array arranged to form a trihedron; Controlling an array element of the polarization rotator array causes a beam passing through the array element either going up to a basic building block above it or reflect back towards a block below it. The beams going higher on the ladder experience longer optical path delay. An index-switched optical variable delay device comprises of many birefringent crystal segments connected with one another, with a polarization rotator array sandwiched between any two adjacent crystal segments. An array element in the polarization rotator array controls the polarization state of a beam passing through the element, causing the beam experience different refractive indices or path delays in the following crystal segment. By independently control each element in each polarization rotator array, variable optical path delays of each beam can be achieved. Finally, an index-switched variable delay device and a ladder-structured variable device are cascaded to form a new device which combines the advantages of the two individual devices. This programmable optic device has the properties of high packing density, low loss, easy fabrication, and virtually infinite bandwidth. The device is inherently two dimensional and has a packing density exceeding 25 lines/cm2. The delay resolution of the device is on the order of a femtosecond (one micron in space) and the total delay exceeds 10 nanosecond. In addition, the delay is reversible so that the same delay device can be used for both antenna transmitting and receiving.

Yao, X. Steve↗

Enhanced Emission from Bright Excitons in Asymmetrically Strained Colloidal CdSe/Cd x Zn 1– x Se Quantum Dots

Colloidal CdSe quantum dots (QDs) designed with a high degree of asymmetric internal strain have recently been shown to host a number of desirable optical properties including subthermal room-temperature line widths, suppressed spectral diffusion, and high photoluminescence (PL) quantum yields. It remains an open question, however, whether they are well-suited for applications requiring emission of identical single photons. Here we measure the low-temperature PL dynamics and the polarization-resolved fluorescence line narrowing spectra from ensembles of these strained QDs. Our spectroscopy reveals the radiative recombination rates of bright and dark excitons, the relaxation rate between the two, and the energy spectra of the quantized acoustic phonons in the QDs that can contribute to relaxation processes. In comparison to conventional colloidal CdSe/ZnS core/shell QDs, we find that in asymmetrically strained CdSe QDs over six times more light is emitted directly by the bright exciton. Furthermore, these results are therefore encouraging for the prospects of chemically synthesized colloidal QDs as emitters of single indistinguishable photons.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improved Self-Assembly of P3HT with Pyrene-Functionalized Methacrylates

A block copolymer with discotic liquid crystalline behavior was synthesized using Grignard metathesis polymerization (GRIM) and initiators for continuous activator regeneration atom transfer radical polymerization (ICAR-ATRP). A novel discotic liquid crystalline mesogen, 6-(pyren-1-yloxy)hexyl methacrylate (PyMA), comprises a block that is attached to regioregular poly(3- hexylthiophene) (rr-P 3 HT) generated by GRIM and subjected to end-group modification. Due to the continuous regeneration of Cu + in the reaction mixture in ICAR-ATRP compared to conventional methods, the synthesis was successfully performed with less catalyst. The purity and yield of the final product are increased by eliminating rigorous post-synthesis purification. Stacked pyrene units have contributed to the enhanced long-range π-π interactions and aligning of the P 3 HT block as observed in thin-film X-ray diffraction (XRD). Furthermore, field-effect mobilities in the order of 10 -2 cm 2 V -1 s -1 in bottom-gate, top-contact organic field-effect transistors (OFETs) suggest an enhancement in charge transport due to the discotic electron-rich pyrene units that help mitigate the insulating effect of the methacrylate backbone. The formation of uniform microdomains of P 3 HT-bpoly(PyMA) observed with tapping mode atomic force microscopy (TMAFM) on the channel regions of OFETs indicates the unique packing of the block copolymer in comparison to pristine P 3 HT. Thermotropic properties of the novel discotic mesogen in the presence and absence of P3HT were observed with both the poly(3-hexylthiophene)-b-poly(6-(pyren-1-yloxy)hexyl methacrylate) (P3HT-b-poly(PyMA)) block copolymer and poly(6-(pyren-1-yloxy)hexyl methacrylate) (poly(PyMA)) homopolymer using polarized optical microscopy (POM) and differential scanning calorimetry (DSC).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Performance characterization of freeform finished surfaces of potassium dihydrogen phosphate using fluid jet polishing with a nonaqueous slurry

Abstract Potassium dihydrogen phosphate (KDP) and its deuterated analog (DKDP) are unique nonlinear optical materials for high power laser systems. They are used widely for frequency conversion and polarization control by virtue of the ability to grow optical-quality crystals at apertures suitable for fusion-class laser systems. Existing methods for freeform figuring of KDP/DKDP optics do not produce surfaces with sufficient laser-induced–damage thresholds (LIDT’s) for operation in the ultraviolet portion of high-peak-power laser systems. In this work, we investigate fluid jet polishing (FJP) using a nonaqueous slurry as a sub-aperture finishing method for producing freeform KDP surfaces. This method was used to selectively polish surface areas to different depths on the same substrate with removals ranging from 0.16 μm to 5.13 μm. The finished surfaces demonstrated a slight increase in roughness as the removal depth increased along with a small number of fracture pits. Laser damage testing with 351 nm, 1 ns pulses demonstrated excellent surface damage thresholds, with the highest values in areas devoid of fracture pits. This work demonstrates, for the first time, a method that enables fabrication of a waveplate that provides tailored polarization randomization that can be scaled to meter-sized optics. Furthermore, this method is based on FJP technology that incorporates a nonaqueous slurry specially designed for use with KDP. This novel nonaqueous FJP process can be also used for figuring other types of materials that exhibit similar challenging inherent properties such as softness, brittleness, water-solubility, and temperature sensitivity.

36 MATERIALS SCIENCE↗