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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

Colloidal Quantum Dot Solar Cells: Progressive Deposition Techniques and Future Prospects on Large-area Fabrication

Colloidally grown nanosized semiconductors yield extremely high-quality optoelectronic materials. Many examples have pointed to near perfect photoluminescence quantum yields, meaning non-radiative optical processes (losses) can be completely suppressed allowing for technology-leading materials as high purity color centers in display technology and emitters in LEDs. Furthermore, because of high chemical yield, and improved understanding of the surfaces, these materials, particularly colloidal quantum dots (QDs) can also be ideal candidates for other optoelectronic applications. Given the strong drive toward carbon neutrality and limiting climate change, electricity from solar photovoltaics will play a large role in the power generation sector. QDs have been developed and shown dramatic improvements over the past 15 years as photoactive materials in photovoltaics and have unique potential with various innovative deposition properties which could lead to exceptionally low-cost and high-performance devices. Once the key issues related to charge transport in optically thick arrays are addressed, QD-based photovoltaic technology could become a better candidate for practical application. In this article, w e show how the possibilities of different deposition techniques could bring QD-based solar cells to the industrial level and discuss the challenges for perovskite QD solar cells in particular, to achieve large-area fabrication for further advancing technology to solve pivotal energy and environmental issues.

14 SOLAR ENERGY↗

Solar PV Oil and Gas Pipeline Setbacks: Ordinances (2022) and Extrapolated Trends

This dataset represents solar energy setback requirements from oil and gas pipelines. A setback requirement is a minimum distance from a pipeline that an energy project may be developed. As of April 2022, no ordinances were discovered for any counties. Such ordinances are likely to arise as regulations continue to expand. Therefore, this dataset applies a 30-meter setback, sourced from trends in other infrastructure. A TIF data file and a PNG map of the data are provided, showing areas where solar energy is prohibited or permitted across the contiguous United States. For further details and citation, please refer to the publication linked below: Lopez, Anthony, Pavlo Pinchuk, Michael Gleason, Wesley Cole, Trieu Mai, Travis Williams, Owen Roberts, Marie Rivers, Mike Bannister, Sophie-Min Thomson, Gabe Zuckerman, and Brian Sergi. 2024. Solar Photovoltaics and Land-Based Wind Technical Potential and Supply Curves for the Contiguous United States: 2023 Edition. Golden, CO: National Renewable Energy Laboratory. NREL/TP-6A20-87843.

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A DECAMETER STATIONARY TYPE IV BURST IN IMAGING OBSERVATIONS ON 2014 SEPTEMBER 6

First-of-its-kind radio imaging of a decameter solar stationary type IV radio burst has been presented in this paper. On 2014 September 6 the observations of type IV burst radio emission were carried out with the two-dimensional heliograph based on the Ukrainian T-shaped radio telescope (UTR-2), together with other telescope arrays. Starting at ∼09:55 UT and for ∼3 hr, the radio emission was kept within the observational session of UTR-2. The interesting observation covered the full evolution of this burst, “from birth to death.” During the event lifetime, two C-class solar X-ray flares with peak times 11:29 UT and 12:24 UT took place. The time profile of this burst in radio has a double-humped shape that can be explained by injection of energetic electrons, accelerated by the two flares, into the burst source. According to the heliographic observations, we suggest that the burst source was confined within a high coronal loop, which was part of a relatively slow coronal mass ejection. The latter has been developed for several hours before the onset of the event. Through analysis of about 1.5 × 10{sup 6} heliograms (3700 temporal frames with 4096 images in each frame that correspond to the number of frequency channels), the radio burst source imaging shows a fascinating dynamical evolution. Both space-based ( GOES , SDO , SOHO , STEREO ) data and various ground-based instrumentation (ORFEES, NDA, RSTO, NRH) records have been used for this study.

79 ASTRONOMY AND ASTROPHYSICS↗

Synthesis and optical characterization of carbon nanotube arrays

Highlights: • Controlling metallicity and vertical alignment of CNT forest by changing hydrogen catalyst annealing time and growth pressure. • Verifying metallicity using Raman spectroscopy of top CNT layer. • Optical characterization of CNT forest using UV–vis–NIR spectrophotometer. - Abstract: Catalyst annealing time and growth pressure play a crucial role in the chiral selective and high-efficiency growth of single-walled carbon nanotubes (SWCNTs) during low pressure chemical vapor deposition (LPCVD). We achieved a high growth rates for SWCNTs and a change the chiral distribution towards metallic (n, m) increasing the catalyst annealing time in hydrogen. A strong correlation is revealed between the catalyst annealing time at lower growth pressures and the shape of the G band, which indicates the metallic or semiconducting nature of the SWCNT and predict the chirality distribution. Under a 15 min annealing time and 10 mbar of growth pressure, the bottom of the G band is broadened with a sharp G{sup −} peak, and the G-band exhibited asymmetrical Breit–Wigner–Fano (BWF) shape. In addition, the growth of SWCNTs with smaller diameters and rich in metallic character is confirmed by the shift of the G-band to a smaller Raman frequency. Homogeneity and vertical alignment of as-grown SWCNT arrays are optically studied using UV/vis/NIR Spectrophotometer. Wavelength-independent and low reflectance resulted from the growth of uniform arrays of SWCNTs. Because of their tunable electronic and optical properties, selective growth of SWCNTs promises great application potential, particularly in electronics and solar industries.

36 MATERIALS SCIENCE↗

EMISSA (Exploring Millimeter Indicators of Solar-Stellar Activity): I. The initial millimeter–centimeter main-sequence star sample

Due to their wide wavelength coverage across the millimeter to centimeter (mm–cm) range and their increased sensitivity, modern interferometric arrays facilitate observations of the thermal and non-thermal radiation that is emitted from different layers in the outer atmospheres of stars. We study the spectral energy distribution (S obs (ν)) of main-sequence stars based on archival observations in the mm–cm range with the aim to study their atmospheric stratification as a function of stellar type. The main-sequence stars with significant detection in mm bands were identified in the ALMA Science Archive. These data were then complemented with spectral flux data in the extreme ultraviolet to cm range as compiled from various catalogues and observatory archives. We compared the resultant S obs (ν) of each star with a photospheric emission model (S mod (ν)) calculated with the PHOENIX code. The departures of S obs (ν) from S mod (ν) were quantified in terms of a spectral flux excess parameter (ΔS/S mod ) and studied as a function of stellar type. The initial sample consists of 12 main-sequence stars across a broad range of spectral types from A1 to M3.5 and the Sun-as-a-star as reference. The stars with T eff = 3000–7000 K (F–M type) showed a systematically higher S obs (ν) than S mod (ν) in the mm–cm range. Their ΔS/S mod exhibits a monotonic rise with decreasing frequency. The steepness of this rise is higher for cooler stars in the T eff = 3000–7000 K range, although the single fully convective star (T eff ~ 3000 K) in the sample deviates from this trend. Meanwhile, Sobs(ν) of the A-type stars agrees with S mod (ν) within errors. The systematically high ΔS/S mod in F–M stars indicates hotter upper atmospheric layers, that is, a chromosphere and corona in these stars, like for the Sun. The mm–cm ΔS/S mod spectrum offers a way to estimate the efficiency of the heating mechanisms across various outer atmospheric layers in main-sequence stars, and thereby to understand their structure and activity. We emphasise the need for dedicated surveys of main-sequence stars in the mm–cm range.

79 ASTRONOMY AND ASTROPHYSICS↗

Integrated Solar-Driven Device with a Front Surface Semitransparent Catalysts for Unassisted CO 2 Reduction

Monolithic integrated photovoltaic-driven electrochemical (PV-EC) artificial photosynthesis is reported for unassisted CO 2 reduction. The PV-EC structures employ triple junction photoelectrodes with a front mounted semitransparent catalyst layer as a photocathode. The catalyst layer is comprised of an array of microscale triangular metallic prisms that redirect incoming light toward open areas of the photoelectrode to reduce shadow losses. Full wave electromagnetic simulations of the prism array (PA) structure guide optimization of geometries and length scales. An integrated device is constructed with Ag catalyst prisms covering 35% of the surface area. The experimental device has close to 80% of the transmittance with a catalytic surface area equivalent 144% of the glass substrate area. Experimentally this photocathode demonstrates a direct solar-to-CO conversion efficiency of 5.9% with 50 h stability. Selective electrodeposition of Cu catalysts onto the surface of the Ag triangular prisms allows CO2 conversion to higher value products enabling demonstration of a solar-to-C 2+ product efficiency of 3.1%. This design featuring structures that have a semitransparent catalyst layer on a PV-EC cell is a general solution to light loss by shadowing for front surface mounted metal catalysts, and opens a route for the development of artificial photosynthesis based on this scalable design approach.

14 SOLAR ENERGY↗

Achieving Challenge Home in Affordable Housing in the Hot - Humid Climate

The Building America Partnership for Improved Residential Construction (BA-PIRC), one of the Building America research team leads, has partnered with two builders as they work through the Challenge Home certification process in one test home each. The builder partners participating in this cost-shared research are Southeast Volusia County Habitat for Humanity near Daytona, Florida and Manatee County Habitat for Humanity near Tampa, Florida. Both are affiliates of Habitat for Humanity International, a non-profit affordable housing organization. This research serves to identify viable technical pathways to meeting the CH criteria for other builders in the region. A further objective of this research is to identify gaps and barriers in the marketplace related to product availability, labor force capability, code issues, cost effectiveness, and business case issues that hinder or prevent broader adoption on a production scale. The builder partners participating in this cost-shared research are Southeast Volusia County Habitat for Humanity (SEVHFH) near Daytona, Florida and Manatee County Habitat for Humanity (MCHFH) near Tampa, Florida. Both are affiliates of Habitat for Humanity International (HFHI), a nonprofit affordable housing organization. Manatee Co Habitat for Humanity Challenge home - Ellenton, FL 34222 S. Sarasota Challenge Home - Sarasota, FL Southeast Volusia co Habitat for Humanity's Challenge Home - Edgewater, FL 32141 Several iterations of home, Challenge Home as built, Challenge Home without solar, and Challenge Home configured to just meet Florida Code. All houses redone in BEOpt 2.1.0.2

affordable housing↗

The Internal Compound Parabolic Concentrator (ICPC): a Novel Low Cost Solar Thermal Collection System for Desalination Processes

The research team at UC Merced designed, prototyped, and tested (1) a novel low cost non-tracking solar thermal collector/concentrator called the Integrated Compound Parabolic Concentrator (ICPC) and (2) a low-cost phase-change thermal energy storage system. Together these technologies can significantly reduce the levelized cost of heat from solar thermal sources while also incorporating features of dispatchability and portability. The ICPC allows elevated temperature and efficiency in a low cost, non-tracking collector. The collector has demonstrated 60% ±4% solar to thermal modules efficiency at fluid outlet temperature of 120°C. The raw material cost of the collector system is reduced by utilizing low cost aluminum minichannels. The collector design is also amenable to economic mass production. A 200 tube, 10 kW prototype array was constructed and tested, yielding over 6 kWh/day on average at outlet fluid temperature exceeding 120°C.

14 SOLAR ENERGY↗

Defect Quantification in Metal Halide Perovskites Anticipates Photoluminescence and Photovoltaic Performance

Semiconductor material optimization requires quantification of performance and stability-dependent near-valence maximum and near-conduction minimum defects with sufficient energy resolution and sensitivity. In this work, we utilize a spectroscopy-electrochemistry approach to resolve the energy-distinct donor and acceptor defect concentrations in wide-gap (Cs .05 FA .79 MA .16 )Pb(I .87 Br .13 ) 3 perovskites, benchmarked against photoluminescence and photovoltaic device performance. Monitoring charge transfer events to electron acceptor and donor molecules within solid electrolyte top contacts enables defect quantification below 10 15 cm –3 at an energy resolution of 10 meV under device-relevant bias, well below levels reported by other methods. Further method sensitivity is demonstrated for defects arising from <2% formamidinium concentration modifications, mimicking compositional imperfections resulting from nonoptimized processing. This method provides the first complete perovskite energetic diagrams with small changes in composition, is nondestructive, compatible with in-line processing characterization, and will enable the semiconductor community to link molecular origins of defects with limitations in device performance across a wide array of optoelectronic platforms.

14 SOLAR ENERGY↗

Metal-Tipped and Electrochemically Wired Semiconductor Nanocrystals: Modular Constructs for Directed Charge Transfer

In our 2017 proposal to the Solar Photochemistry division of DOE/BES/Office of Science we targeted the creation, characterization and integratation of new II-IV semiconductor heterostructured nanomaterials into ultra-thin film (tethered) nanocrystalline arrays on transparent metal oxide (TCO) supports. Materials were to include CdSe quantum dots (QDs), asymmetric CdSe@CdS tetrapods (TPs) and CdSe@CdS nanorods (NRs), into unique photoelectrochemical platforms. The ultimate goal was to tether these new nanomaterials to either electron- or hole-selective oxide interlayers that would afford vectoral photo-induced charge transfer and ultimately formation of molecular products such as H 2 . This was an ambitious set of goals but integrated well with our previous work in this general area.

14 SOLAR ENERGY↗

Diagnosing Model Errors in Simulation of Solar Radiation on Inclined Surfaces

Transposition models have been widely used in the solar energy industry to simulate solar radiation on inclined PV panels. Following numerous studies comparing the performance of transposition models, this paper aims to understand the quantitative uncertainty in the state-of-the-art transposition models and the sources leading to the uncertainty. Our results show significant differences between two highly used isotropic transposition models with one substantially underestimating the diffuse plane-of-array (POA) irradiances when diffuse radiation is perfectly isotropic. In the empirical transposition models, the selection of empirical coefficients and land surface albedo can both result in uncertainty in the output. This study can be used as a guide for future development of physics-based transposition models.

14 SOLAR ENERGY↗

U.S. Wind and Solar PV Supply Curves with Future Land-use Change

This dataset provides future supply curves representing the total resource potential for land-based wind and solar photovoltaic (PV) deployment in the conterminous United States after accounting for the impact of land-use and land-cover change (LULC). We use LULC projections from 2010 to 2050 developed based on the Intergovernmental Panel on Climate Change (IPCC) Special Report on Emission Scenarios. The LULC projections are subsequently fed into the renewable energy potential model (reV), which estimates total available wind and solar capacity after excluding non-developable land. Supply curves are provided for four IPCC scenarios in 2050: A1B, A2, B1, and B2. As a baseline, we also provide the supply curve from the B2 scenario in 2010. In addition to the supply curves, we also provide representative wind and solar generation profiles for each supply curve point. These generation profiles are provided as capacity factors and are based on a 2012 weather year using NSRDB and WindToolkit resource data. For more details on the supply curve and profile datasets included here please refer to README. Additional information on the supply curves and the LULC projections used to generate them, as well as an analysis of their impact on wind and solar deployment under decarbonization can be found in the publication linked below: "U.S. Wind and Solar PV Supply Curves with Future Land-use Change Publication".

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Visible light broadband perfect absorbers

The visible light broadband perfect absorbers based on the silver (Ag) nano elliptical disks and holes array are studied using finite difference time domain simulations. The semiconducting indium silicon dioxide thin film is introduced as the space layer in this sandwiched structure. Utilizing the asymmetrical geometry of the structures, polarization sensitivity for transverse electric wave (TE)/transverse magnetic wave (TM) and left circular polarization wave (LCP)/right circular polarization wave (RCP) of the broadband absorption are gained. The absorbers with Ag nano disks and holes array show several peaks absorbance of 100% by numerical simulation. These simple and flexible perfect absorbers are particularly desirable for various potential applications including the solar energy absorber.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Swift and NuSTAR observations of GW170817: Detection of a blue kilonova

With the first direct detection of merging black holes in 2015, the era of gravitational wave (GW) astrophysics began. However, a complete picture of compact object mergers requires the detection of an electromagnetic (EM) counterpart. Here, we report ultraviolet (UV) and x-ray observations by Swift and the Nuclear Spectroscopic Telescope ARray (NuSTAR) of the EM counterpart of the binary neutron star merger GW 170817. The bright, rapidly fading ultraviolet emission indicates a high mass (≈ 0.03 solar masses) wind-driven outflow with moderate electron fraction (Ye ≈ 0.27). Combined with the x-ray limits, we favor an observer viewing angle of ≈30° away from the orbital rotation axis, which avoids both obscuration from the heaviest elements in the orbital plane and a direct view of any ultra-relativistic, highly collimated ejecta (a γ-ray burst afterglow).

79 ASTRONOMY AND ASTROPHYSICS↗

Will Solar Panels Help When the Power Goes Out? Planning for PV Resilience

PV systems, like all energy systems, must chart a difficult course in order to improve resilience. They need to simultaneously withstand extreme conditions that cause grid power disruptions, be configured in a way that allows electricity to be delivered to meet the PV user's needs, and overcome disruptions arising from solar resource intermittency. Certain considerations reveal themselves as key to a PV system's resilience benefits. Choice of hardware is critical, as is site selection for the PV array. Voluminous evidence in a hurricane context demonstrates that durable hardware, properly maintained and sited, leads to PV systems surviving extreme weather with their functionality intact. Structurally weak or poorly maintained PV equipment, on the other hand, has demonstrated failures during extreme weather events. PV system stakeholders should ensure that best practices are followed for hardware procurement and siting. It is also important to understand that PV systems are not one-size-fits-all. While incorporating islanding capabilities and energy storage into the system's electrical topology will typically enhance resilience, the user's needs will determine the optimally resilient conformation of any given system. These factors - appropriate hardware, siting, maintenance, and system design - are the primary drivers of PV resilience. PV systems possess high potential for resilient energy generation due to their distributed, abundant, and free fuel supply, but the technology itself does not inherently lead to resilient outcomes. Realizing PV's potential for resilience requires consideration of these determinative factors.

14 SOLAR ENERGY↗

Aerodynamic Analysis of Wind Loading on Parabolic Trough Collectors Using High-Fidelity CFD Modeling

Wind loading on parabolic solar collector support structures is the key driver for material costs. As identified by NREL's CSP Best Practices project [1], ability to predict wind-loading in deep-arrays and the impact of edge effects has potential to decrease levelized cost of electricity (LCoE) by 15%. In this study, we present a high-fidelity computational model that can model the flow around deep arrays of parabolic troughs under varying turbulent inflow conditions. Ability to accurately reproduce atmospheric boundary layer (ABL) profiles is first demonstrated through Large Eddy Simulation (LES) simulations and compared against wind tunnel measurements. Thereafter, unsteady turbulent flow past single row and six row configurations is computed using hybrid RANS/LES simulations. Investigations of wind loading, through parametric tilt angle variations of single row and on waked collectors in six-row configuration, are used to highlight design considerations for parabolic troughs only possible through high-fidelity unsteady calculations.

aerodynamics↗

SiN{sub x} layers on nanostructured Si solar cells: Effective for optical absorption and carrier collection

We compared nanopatterned Si solar cells with and without SiN{sub x} layers. The SiN{sub x} layer coating significantly improved the internal quantum efficiency of the nanopatterned cells at long wavelengths as well as short wavelengths, whereas the surface passivation helped carrier collection of flat cells mainly at short wavelengths. The surface nanostructured array enhanced the optical absorption and also concentrated incoming light near the surface in broad wavelength range. Resulting high density of the photo-excited carriers near the surface could lead to significant recombination loss and the SiN{sub x} layer played a crucial role in the improved carrier collection of the nanostructured solar cells.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Solar Energy Implementation Strategies on Picuris Pueblo

Picuris Pueblo is a small tribal community in Northern New Mexico consisting of about 306 members and 86 homes. Picuris Pueblo has made advances with renewable energy implementation, including the installation of a 1 megawatt photovoltaic (PV) array. This array has provided the tribe with economic and other benefits that contribute toward the tribe's goal of tribal sovereignty. The tribe is seeking to implement more PV generation as well as battery energy storage systems. Picuris Pueblo is considering different implementation methods, including the formation of a microgrid system. This report studies the potential implementation of a PV and battery storage microgrid system and the associated benefits and challenges. The benefits of a microgrid system include cost savings, increased resiliency, and increased tribal sovereignty and align with the tribe's goals of becoming energy independent and lowering the cost of electricity.

14 SOLAR ENERGY↗