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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

White-light interferometry for early-stage metal oxide growth characterization

Oxidation of metals can provide a functional oxide film or an oxide layer that can lead to material degradation causing performance limiting concerns. Because of the technological and economic impacts of oxidation, understanding early-stage oxidation growth and its mechanisms is of high importance. Unfortunately, poor empirical data during early-stage oxidation has left our current understanding of oxidation incomplete and woefully inadequate. Measurement techniques previously used for oxidation kinetics characterization include microbalance, x-ray diffraction, Fourier-transform infrared spectroscopy, and spectroscopic ellipsometry. However, these techniques lack the necessary time-resolution or vertical resolution in addition to not providing any spatial data, which is essential to early-stage oxidation studies to understand both oxidation kinetics and mechanisms. Here, a novel rapid and surface-sensitive data collection technique that provides three-dimensional spatial data of a growing oxide layer with sub-nanometer thickness resolution using white-light interferometry has been developed. This technique will be the first technique capable of providing real-time spatial results of early-stage oxidation growth. The effectiveness of this characterization tool is shown by observing the early-stage oxidation kinetics and film cracking of uranium heated to 90 °C under 500 torr of pure O 2 . Initially a parabolic oxidation growth is observed. Once the oxide layer reaches ≈ 30 nm, the epitaxial stresses between the uranium substrate and oxide film layer causes localized cracking in addition to the observed transition of the parabolic growth rate to a linear growth rate. The results of the white-light interferometry are verified by glancing incidence x-ray diffraction.

47 OTHER INSTRUMENTATION↗

MicroBooNE NS Timing Corrections

MicroBooNE has achieved a neutrino interaction timing resolution of O(1 ns), enabling improved background rejection and new physics searches. We identify a systematic bias in the reconstructed times of NCpi0 and nueCC events, which appear earlier than numuCC events, with a strong dependence on drift distance (reco_nuvtxX). An empirical correction, applied to high-energy showers, removes this spatial bias and aligns timing across topologies. The correction is validated across data runs and event selections, though the root cause remains under investigation.

Chan, Andrew [Michigan U.]↗

Spatially coordinated airborne data and complementary products for aerosol, gas, cloud, and meteorological studies: the NASA ACTIVATE dataset

The NASA Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) produced a unique dataset for research into aerosol–cloud–meteorology interactions, with applications extending from process-based studies to multi-scale model intercomparison and improvement as well as to remote-sensing algorithm assessments and advancements. ACTIVATE used two NASA Langley Research Center aircraft, a HU-25 Falcon and King Air, to conduct systematic and spatially coordinated flights over the northwest Atlantic Ocean, resulting in 162 joint flights and 17 other single-aircraft flights between 2020 and 2022 across all seasons. Data cover 574 and 592 cumulative flights hours for the HU-25 Falcon and King Air, respectively. The HU-25 Falcon conducted profiling at different level legs below, in, and just above boundary layer clouds (< 3 km) and obtained in situ measurements of trace gases, aerosol particles, clouds, and atmospheric state parameters. Under cloud-free conditions, the HU-25 Falcon similarly conducted profiling at different level legs within and immediately above the boundary layer. The King Air (the high-flying aircraft) flew at approximately ~ 9 km and conducted remote sensing with a lidar and polarimeter while also launching dropsondes (785 in total). Collectively, simultaneous data from both aircraft help to characterize the same vertical column of the atmosphere. In addition to individual instrument files, data from the HU-25 Falcon aircraft are combined into “merge files” on the publicly available data archive that are created at different time resolutions of interest (e.g., 1, 5, 10, 15, 30, 60 s, or matching an individual data product's start and stop times). This paper describes the ACTIVATE flight strategy, instrument and complementary dataset products, data access and usage details, and data application notes. The data are publicly accessible through https://doi.org/10.5067/SUBORBITAL/ACTIVATE/DATA001 (ACTIVATE Science Team, 2020).

54 ENVIRONMENTAL SCIENCES↗

Statistical properties of the interplanetary microscale fluctuations

Results are reported for a statistical study of short-period fluctuations in the interplanetary plasma velocity and magnetic field. The data base used consists of measurements of the interplanetary plasma and magnetic field by Pioneer 6 with a time resolution of 72 sec and by Mariner 5 with a resolution of 5 min. The analysis is conducted to characterize the parent population from which all individual microscale events on these time scales are drawn. The microscale changes are grouped according to their energy densities relative to the energy density of the background magnetic field, and it is found that each grouping exhibits certain statistical properties within the limits of observational uncertainty. It is noted that these statistical properties are purely observational and independent of any physical model which may be used to interpret them. The results are discussed in the context of MHD discontinuity theory for a thermally anisotropic plasma.

Belcher, J. W.↗

Steepening of Waves at the Duskside Magnetopause

Surface waves at the magnetopause flanks typically feature steeper, i.e., more inclined leading (antisunward facing) than trailing (sunward facing) edges. This is expected for Kelvin-Helmholtz instability (KHI) amplified waves. Very rarely, during northward interplanetary magnetic field (IMF) conditions, anomalous inverse steepening has been observed. The small-scale tetrahedral configuration of the Magnetospheric Multiscale spacecraft and their high time resolution measurements enable us to routinely ascertain magnetopause boundary inclinations during surface wave passage with high accuracy by four-spacecraft timing analysis. At the dusk flank magnetopause, 77%/23% of the analyzed wave intervals exhibit regular inverse steepening. Inverse steepening happens during northward IMF conditions, as previously reported and, in addition, during intervals of dominant equatorial IMF. Inverse steepening observed under the latter conditions may be due to the absence of KHI or due to instabilities arising from the alignment of flow and magnetic fields in the magnetosheath.

Plaschke, F.↗

Spatially-Coordinated Airborne Data and Complementary Products for Aerosol, Gas, Cloud, and Meteorological Studies: the Nasa Activate Dataset

The NASA Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) produced a unique dataset for research into aerosol–cloud–meteorology interactions, with applications extending from process-based studies to multi-scale model intercomparison and improvement as well as to remote-sensing algorithm assessments and advancements. ACTIVATE used two NASA Langley Research Center aircraft, a HU-25 Falcon and King Air, to conduct systematic and spatially coordinated flights over the northwest Atlantic Ocean, resulting in 162 joint flights and 17 other single-aircraft flights between 2020 and 2022 across all seasons. Data cover 574 and 592 cumulative flights hours for the HU-25 Falcon and King Air, respectively. The HU-25 Falcon conducted profiling at different level legs below, in, and just above boundary layer clouds (< 3 km) and obtained in situ measurements of trace gases, aerosol particles, clouds, and atmospheric state parameters. Under cloud-free conditions, the HU-25 Falcon similarly conducted profiling at different level legs within and immediately above the boundary layer. The King Air (the high-flying aircraft) flew at approximately ∼ 9 km and conducted remote sensing with a lidar and polarimeter while also launching dropsondes (785 in total). Collectively, simultaneous data from both aircraft help to characterize the same vertical column of the atmosphere. In addition to individual instrument files, data from the HU-25 Falcon aircraft are combined into “merge files” on the publicly available data archive that are created at different time resolutions of interest (e.g., 1, 5, 10, 15, 30, 60 s, or matching an individual data product's start and stop times). This paper describes the ACTIVATE flight strategy, instrument and complementary dataset products, data access and usage details, and data application notes. The data are publicly accessible through https://doi.org/10.5067/SUBORBITAL/ACTIVATE/DATA001 (ACTIVATE Science Team, 2020).

Aerosol Cloud meTeorology Interactions oVer the we↗

Capturing Ring Opening in Photoexcited Enolic Acetylacetone upon Hydrogen Bond Dissociation by Ultrafast Electron Diffraction

Photoinduced biological and chemical reactions are often based on key structural transformations of a molecule driven across multiple electronic states. Acetylacetone (AcAc) is a prototypical system for complex chemical pathways involving several conical intersections (CI) and singlet–triplet intersystem crossings (ISC) characterized by distinct geometries. In the gas phase, AcAc is predominantly in a planar ring-like enolic form stabilized by a strong intramolecular O–H···O hydrogen bond. Following excitation into the S 2 (ππ*) state at 266 nm, acetylacetone undergoes rapid internal conversion followed by intersystem crossing. Such relaxation pathways are associated with structural changes including ring opening, deplanarization, and bond elongation. In this work, ultrafast electron diffraction (UED) at the SLAC MeV-UED setup is employed as a direct structural probe with a time resolution of 160 fs. Together with trajectory surface hopping simulations, analysis of the UED data provides a new perspective on the early time nuclear dynamics in acetylacetone. Specifically, AcAc is observed to undergo ring opening, deplanarization, and bond elongation all within the first 700 fs after photoexcitation. The monitored dynamics is associated mainly with the nuclear motion on the S 1 potential energy surface, formed after very rapid transfer from S 2 to S 1 , allowing AcAc to reach the conical intersection to intersystem crossing. Such time scales of nuclear motion are contrasted with the time scales of electronic transitions in AcAc that were previously characterized with spectroscopic methods, specifically internal conversion (<100 fs) and intersystem crossing (∼1.5 ps).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Raw ERCOT 60-Day SCED Disclosure Reports

This dataset contains ERCOT plant-level wind power production data at a 15-minute time resolution. Data at ERCOT are called 60-Day SCED Disclosure Report; data product number NP3-965-ER. Raw data are in local time. DST is handled as "skip hour" (12a, 1a, 3a,...) in spring, "extra hour" (12a, 1a, 2a, 2a, 3a,...) in fall.

17 WIND ENERGY↗

A moderate-resolution, wide-band, astronomical echelle spectrograph

An echelle spectrograph is described which is specifically designed for use on a 52-in. f/7.6 telescope as an instrument optimally suited for studying spectra of the faint optical counterparts to X-ray stars at moderate spectral resolution. The spectrograph is also able to accomodate a two-dimensional photon-tagging panoramic image detector so that high-time-resolution studies of the spectra of variable stars can be carried out. The equations for echelle spectrographs are summarized, and some features of the present instrument are discussed. These include its prism cross-disperser, small elliptical flat mirror, and unusually high efficiency. An iron-argon calibration spectrum obtained by pressing the film against the output fiber optics of a three-stage electrostatically focused image intensifier, a spectrum of P Cygni taken by placing the film directly in the image plane of the spectrograph, and a photon-counted image of a small section of an echellogram produced during an observation of the Ring nebula in Lyra are provided to illustrate the performance of the instrument.

Bardas, D.↗

Millisecond variability of Cygnus X-1

The May 7, 1978 HEAO 1 spacecraft observations of Cygnus X-1 with a 10 microsec time resolution have revealed 3 ms variability, as well as a 300 ms component and features which extend to 6 s. Emission on time scales shorter than 1 s can be approximately modeled as a superposition of uncorrelated 3 ms and 300 ms shot contributions, both with peak luminosities near 10 to the 37th ergs/s, and with shot rates of about 10/s and 0.2/s, respectively. The 3 ms variability is consistent with the time scales expected for variability near the inner edge of a viscous accretion disk that surrounds a 10-solar mass black hole.

Meekins, J. F.↗

A Search for Short-Period Accreting Pulsars with BATSE

Accreting X-ray pulsar systems can be detected and monitored by the BATSE Pulsar Monitor at full sensitivity only above the Nyquist period of 2.048 s, since it uses the DISCLA data type. Systems with shorter periods than 2 s can be observed, but with a reduced sensitivity, since only the aliased power is measured. While persistent sources in the period range below that have been found by earlier spacecraft, transient systems may still be undiscovered, due to limited time coverage of the galactic plane with all-sky instruments. BATSE data with a time resolution of 31 ms (PSR single-sweep mode) has been collected for four energy channels spanning 20-50 keV , at scheduled times for particular detectors and detector combinations which view the galactic plane. The data spans Nov 1993 to present, with a typical exposure of 15000 s per day to approximately 1/8 of the plane. An accelerated FFT-based search is in progress on these data. Data are segmented into approximately 300 second intervals, barycentered for 3 possible source directions spaced by 30 degrees about the detector normal, with the time series accelerated for each of 15 steps, each spaced by 5 x 10(exp -5). To avoid loss of coherence due to system orbital velocities, FFTs are averaged over each 1/4 day interval separately. Results of this search are presented, including examples of detection of Her X-1, Cen X-3, and other pulsars.

Wilson, R. B.↗

Observational Definition of Future AGN Echo-Mapping Experiments

We describe numerical simulations we have begun in order to determine the observational requirements for future echo-apping experiments. We focus on two particular problems: (1) determination of the structure and kinematics of the broad-line region through emission- line reverberation mapping, and (2) detection of interband continuum lags that may be used as a probe of the continuum source, presumably a temperature-stratified accretion disk. Our preliminary results suggest the broad-line region can be reverberation-mapped to good precision with spectra of signal-to-noise ratio per pixel S/N approx. = 30, time resolution (Delta)t approx. = 0.1 day, and duration of about 60 days (which is a factor of three larger than the longest time scale in the input models); data that meet these requirements do not yet exist. We also find that interband continuum lags of approx. greater than 0.5 days can be detected at approx. greater than 95% confidence with at least daily observations for about 6 weeks, or rather more easily and definitively with shorter programs undertaken with satellite-based observatories. The results of these simulations show that significant steps forward in multiwavelength monitoring will almost certainly require dedicated facilities.

Collier, Stefan↗

Time resolved spectra in the infrared absorption and emission from shock heated hydrocarbons

The wavelength range of a previously constructed multichannel fast recording spectrometer was extended to the mid-infrared. With the initial configuration, light intensities were recorded simultaneously with a silicon-diode array simultaneously at 20 adjacent wavelengths, each with a 20-micron time resolution. For studies in the infrared, the silicon diodes were replaced by a 20-element PbSe array of similar dimensions, cooled by a three-stage thermoelectric device. It is proposed that infrared emissions could be due to shock-heated low molecular-weight hydrocarbons. The full Swan band system appeared in time-integrated emission spectra from shock-heated C2H2; no soot was generated. At low resolution, the profiles on the high-frequency side of the black body maximum show no distinctive features. These could be fitted to Planck curves, with temperatures that declined with time from an initial high that was intermediate between T5 (no conversion) and T5(eq).

Bauer, S. H.↗

Entangled Photon Pair Source Demonstrator Using the Quantum Instrumentation Control Kit System

Here, we report the first demonstration of using the Quantum Instrumentation and Control Kit (QICK) system on RFSoC-FPGA technology to drive the electro-optic intensity modulator that generate time-bin entangled photon pairs and to detect the photon signals. With the QICK system, we achieve high levels of performance metrics including coincidence-to-accidental ratio exceeding 150, and entanglement visibility exceeding 95%, consistent with performance metrics achieved using conventional waveform generators. We also demonstrate simultaneous detector readout using the digitization functional of QICK, achieving internal system synchronization time resolution of 3.2 ps. The work reported in this paper represents an explicit demonstration of the feasibility for replacing commercial waveform generators and time taggers with RFSoC-FPGA technology in the operation of a quantum network, representing a cost reduction of more than an order of magnitude.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Quantum Instrumentation and Control Kit (QICK) for Quantum Networks

We report the first demonstration of using the Quantum Instrumentation and Control Kit (QICK) system on RFSoC FPGA technology to drive an entangled photon pair source and to detect the photon signals. With the QICK system, we achieve high levels of performance metrics including coincidence-to-accidental ratio exceeding 150, and entanglement visibility exceeding 95%, consistent with performance metrics achieved using conventional waveform generators. We also demonstrate simultaneous detector readout using the digitization functional of QICK, achieving internal system synchronization time resolution of 3.2 ps. The work reported in this paper represents an explicit demonstration of the feasibility for replacing commercial waveform generators and time taggers with RFSoC-FPGA technology in the operation of a quantum network, representing a cost reduction of more than an order of magnitude.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The table mountain 8-mm-wavelength interferometer

The system components, performance, and calibration of two element radio interferometer operating at 8.33 mm wavelength are discussed. The interferometer employs a 5.5 m and a 3 m diameter antenna on an east-west baseline of 60 or 120 m, yielding fringe spacings at transit of 28 or 14 in. respectively. The broad intermediate frequency bandpass of 100 to 350 MHz and the system noise temperature of 500 K provide high sensitivity for the measurement of continuum sources. The interferometer has been used for high resolution studies of the planets and the Sun, and it is currently being adapted to study solar flare emissions at high spatial and time resolution.

Janssen, M. A.↗

The Table Mountain 8-mm wavelength interferometer

A two-element radio interferometer operating at 8.33-mm wavelength has been developed at the Jet Propulsion Laboratory's Table Mountain Observatory near Wrightwood, CA. The interferometer employs a 5.5-m and a 3-m diameter antenna on an east-west baseline of 60 or 120 m, yielding fringe spacings at transit of 28 or 14 arcsec, respectively. The broad intermediate-frequency bandpass of 100-350 MHz and the system noise temperature of 500 K provide high sensitivity for the measurement of continuum sources. The interferometer has been used for high-resolution studies of the planets and the sun, and it is currently being adapted to study solar flare emissions at high spatial and time resolution.

Janssen, M. A.↗

Rapid X-ray variability in the Seyfert galaxy NGC 6814

In contrast with the Tennant et al (1981) sample of over 30 active galactic nuclei, HEAO 1 A-2 high time resolution X-ray observations of the X-ray emitting Seyfert 1 galaxy NGC 6814 show strong X-ray variability on time scales of less than 3 hr. On a time scale of 90 min, the mean flux varied by a factor of about 2.5, and a characteristic time for variability of 100 + 60 or - 25 sec is obtained by autocorrelation analysis. There is no indication of spectral variability with an upper limit on a change in the power law spectral index of less than about 0.37, for a factor 2 change in intensity. The constraints of such rapid variability on a range of X-ray source mechanisms is discussed.

Tennant, A. F.↗