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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

Observation of Mountain Lee Waves with MODIS NIR Column Water Vapor

Mountain lee waves have been previously observed in data from the Moderate Resolution Imaging Spectroradiometer (MODIS) "water vapor" 6.7 micrometers channel which has a typical peak sensitivity at 550 hPa in the free troposphere. This paper reports the first observation of mountain waves generated by the Appalachian Mountains in the MODIS total column water vapor (CWV) product derived from near-infrared (NIR) (0.94 micrometers) measurements, which indicate perturbations very close to the surface. The CWV waves are usually observed during spring and late fall or some summer days with low to moderate CWV (below is approx. 2 cm). The observed lee waves display wavelengths from3-4 to 15kmwith an amplitude of variation often comparable to is approx. 50-70% of the total CWV. Since the bulk of atmospheric water vapor is confined to the boundary layer, this indicates that the impact of thesewaves extends deep into the boundary layer, and these may be the lowest level signatures of mountain lee waves presently detected by remote sensing over the land.

satellite remote sensing↗

Convective Influence on the Lower Stratospheric Water Vapor in the Boreal Summer Asian Monsoon Region

Processes maintaining the localized maxima in lower stratospheric watervapor over the boreal summer Asian monsoon region are investigated usingtrajectory and cloud models that resolve the detailed cloudmicrophysical processes, with observation-based convection and radiationschemes. We examine the impact of convective influence along parceltrajectories on cloud formation and dehydration by tracing thetrajectories through time-dependent fields of convective cloud topheights estimated from global rainfall and geostationary brightnesstemperatures. Parameters such as the rainfall threshold used foridentification of deep convection are derived by comparison with theCloudSat deep convective cloud top product as enhanced by colocatedCALIOP measurements. The simulated water vapor field at the 100 hPalevel and cloud occurrence frequencies in the tropical tropopause layer(TTL) are constrained by corresponding observations from MLS andCALIPSO, respectively. The observed maximum in the 100 hPa level watervapor field over the Asian monsoon region is only present in thesimulation with convective influence, indicating the importance ofconvective hydration for the summertime water vapor distribution.Convection moistens the 100 hPa level over the Asian monsoon by 1 ppmv,where 75 of this moistening is due to convection occurring locallywithin the monsoon region. Convection also increases the cloudoccurrence frequency in the TTL over the southern sector of the Asianmonsoon anticyclone by 20. Parcels are convectively hydrated in thesoutheastern sector of the anticyclone, transported westward by theanticyclonic circulation, and dehydrated in the southwestern sector. Therelative importance of extreme convective events that inject ice andwater vapor near or above the tropopause will also be examined.

convection↗

Dropsonde Observations of Total Integrated Water Vapor Transport within North Pacific Atmospheric Rivers

A0.0ircraft dropsonde observations provide the most comprehensive measurements to date of horizontal water vapor transport in atmospheric rivers (AR). The CalWater experimen0 t 0.0recently more than tripled the number of ARs probed with the required measurements. This study uses vertical profiles of water vapor, wind, and pressure obtained from 304 dropsondes across 21 ARs. On average, total water vapor transport (TIVT) in an AR was 4.7108 2108 kg s-1. This magnitude is 2.6 times larger than the average discharge of liquid water from the Amazon River. The mean AR width was 890 270 km. Subtropical ARs contained larger IWV but weaker winds than midlatitude ARs, although average TIVTs were nearly the same. Mean TIVTs calculated by defining the lateral edges of ARs using an IVT-threshold versus an IWV-threshold produced results that differed by less than 10 across all cases, but did vary between midlatitudes and subtropical regions.

water vapor↗

Vapor Cooling of a Structural Skirt for a Large-Scale Hydrogen Tank

The demonstration of vapor cooling on a structural skirt was one of the main objectives of the Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER) testing. SHIIVER consisted of a 4-meter diameter stainless steel tank with an aluminum forward skirt. The forward skirt was cooled by directing effluent vapor from the tank through two flow channels that each went 360 degrees around the interior of the skirt in a helical pattern. Flow rates, temperatures, and pressures in the system were measured allowing for the calculation of heat load removed via cooling stream and heat load reduction into the tank. Testing occurred at fill levels between 25% and 90% full using both liquid hydrogen and liquid nitrogen. Boil-off rate was varied independent of the skirt performance by adding multilayer insulation over the spray-on-foam insulation on the tank domes, while leaving the barrel insulated only with spray-on-foam. The results from the testing, which demonstrate vapor cooling reversed heat flow from the skirt into the tank and reduces total propellant heat load by as much as 19%, are analyzed and discussed.

Cryogenic Fluid Management↗

Microgravity Flow Boiling Experiments With Liquid-Vapor Mixture Inlet Onboard the International Space Station

This article is part of a series of studies culminating from the multi-objective Flow Boiling and Condensation Experiment (FBCE) onboard the International Space Station, which utilized the Flow Boiling Module (FBM) for experiments between February and July 2022. This study investigates microgravity flow boiling of n-Perfluorohexane with liquid-vapor mixture (two-phase) inlet conditions to the FBM with either one or two opposite walls heated. The FBM’s channel has a rectangular cross-sectional area of 5.0 × 2.5 mm 2 and a heated length of 114.6 mm. Key parameters of interest include mass velocity (180 – 2400 kg/m 2 s), inlet quality (-0.01 – 0.87), inlet pressure (120 – 200 kPa), and heat flux (1.8 W/cm 2 to critical heat flux), and a large database is amassed. The flow is visualized via a high-speed video camera and photographs are recorded at each heating increment to assess the periodic flow patterns within the channel and the near-wall interfacial behavior. Flow patterns are complex and mainly characterized by high- and low-density fronts alternately traversing the channel to yield high- and low-density-dominant periods of boiling. At all operating conditions, high-density fronts are faster during high-density-dominant periods. At low inlet qualities, the flow is annular near the channel inlet with a central vapor core surrounded by an annular liquid layer. Each high-density front having a high liquid fraction leaves a thin liquid layer sheared onto the heated walls. Boiling occurs within the liquid layer and a vapor layer is formed next to the heated wall. Inlet quality and mass velocity most dictate the overall flow patterns followed by heating configuration, and to a much lesser extent, heat flux and inlet pressure. Heat transfer characteristics are assessed via averaged boiling curves, streamwise profiles of wall temperature and heat transfer coefficient, and parametric curves of local and averaged heat transfer coefficients. Inlet pressure has an insignificant effect on heat transfer. At similar operating conditions, both the heating configurations yield similar trends and values of heat transfer coefficient and critical heat flux (CHF, slightly higher for single-sided) even though double-sided heating adds twice the heat to the fluid and doubly raises local quality. The heat fluxes required for both onset of nucleate boiling degradation and CHF are larger at high mass velocities and low inlet qualities. For a fixed inlet quality, high mass velocities yield higher average heat transfer coefficients at both lower and higher heat fluxes, while the nucleate boiling regime at intermediate heat fluxes is unaffected. For a fixed mass velocity, higher inlet qualities yield higher and lower average heat transfer coefficients at lower and higher heat fluxes, respectively.

Microgravity↗

Localized Heterogeneous Nucleation for Vapor‐Assisted Sequential Deposition of Metal Halide Perovskites

Vapor-assisted hybrid two-step deposition, which combines thermally evaporated inorganic layers with solution-processed organic halides to form halide perovskites, has emerged as a scalable and industry-compatible route for textured tandem photovoltaics. However, this process is often hindered by reaction-limited phase formation, particularly when compact, non-porous, and highly crystalline inorganic layers formed by thermal evaporation restrict subsequent conversion, resulting in incomplete reaction and pronounced depth-dependent heterogeneity. In this study, we introduce a strategy to regulate the inorganic precursor layer by incorporating localized heterogeneous nucleation sites. Sparsely distributed hydrophilic metal oxide species serve as effective nucleation centers during vapor deposition, enabling effective control over film morphology and crystal orientation from the early stages of growth. This tailored inorganic framework facilitates the subsequent incorporation of organic halides, alleviating reaction limitations and suppressing residual unreacted precursors. Consequently, the perovskite films exhibit improved stoichiometric uniformity and enhanced optoelectronic quality, enabling wide-bandgap perovskite solar cells with markedly improved performance and operational stability. This work provides important mechanistic insight into crystal growth engineering of vapor-deposited perovskite thin films.

nucleation↗

Effect of Oxidizing Impurities on the Corrosion Behavior of Structural Alloys Exposed to MgCl 2 Molten Salt Vapor

The corrosion behavior of structural alloys SS304 and IN617 when exposed to vapors of MgCl 2 molten salt at 764 °C for 100 h in an argon atmosphere was investigated as a function of the level of oxidizing impurities (e.g., NaOH) present in the salt. Increasing the concentration of oxidizing impurities in the salt caused an increase in corrosion in both structural alloys, as measured by Cr depletion layers. A poorly adhered oxide scale layer containing Mg, Al, and Cr was observed on the surface of the metals, and local attack was observed as well. The Ni-based IN617 showed lower Cr depletion and less scale formation than the Fe-based SS304. These results demonstrate that oxidizing impurities in the molten salt will impact the vapor phase corrosion for structural members exposed to the molten salt headspace. This finding is highly relevant for understanding the effects of the vapor phase in molten salt applications, including molten salt thermal energy storage, molten salt nuclear reactors, and molten salt electrochemistry.

25 ENERGY STORAGE↗

Liquid–Vapor Phase Equilibrium in Molten Aluminum Chloride (AlCl 3 ) Enabled by Machine Learning Interatomic Potentials

Molten salts are promising candidates in numerous clean energy applications, where knowledge of thermophysical properties and vapor pressure across their operating temperature ranges is critical for safe operations. Due to challenges in evaluating these properties using experimental methods, fast and scalable molecular simulations are essential to complement the experimental data. In this study, we developed machine learning interatomic potentials (MLIP) to study the AlCl 3 molten salt across varied thermodynamic conditions (T = 473–613 K and P = 2.7–23.4 bar), which allowed us to predict temperature-surface tension correlations and liquid–vapor phase diagram from direct simulations of two-phase coexistence in this molten salt. Two MLIP architectures, a Kernel-based potential and neural network interatomic potential (NNIP), were considered to benchmark their performance for AlCl 3 molten salt using experimental structure and density values. The NNIP potential employed in two-phase equilibrium simulations yields the critical temperature and critical density of AlCl 3 that are within 10 K (∼3%) and 0.03 g/cm 3 (∼7%) of the reported experimental values. An accurate correlation between temperature and viscosities is obtained as well. In doing so, we report that the inclusion of low-density configurations in their training is critical to more accurately represent the AlCl 3 system across a wide phase-space. The MLIP trained using PBE-D3 functional in the ab initio molecular dynamics (AIMD) simulations (120 atoms) also showed close agreement with experimentally determined molten salt structure comprising Al 2 Cl 6 dimers, as validated using Raman spectra and neutron structure factor. Furthermore, the PBE-D3 as well as its trained MLIP showed better liquid density and temperature correlation for AlCl 3 system when compared to several other density functionals explored in this work. Overall, the demonstrated approach to predict temperature correlations for liquid and vapor densities in this study can be employed to screen nuclear reactors-relevant compositions, helping to mitigate safety concerns.

Ab initio molecular dynamics↗

Analysis of thermal grooving effects on vortex penetration in vapor-diffused Nb 3 Sn

While Nb 3 Sn theoretically offers better superconducting radio-frequency (RF) cavity performance (Q 0 and E acc ) to Nb at any given temperature, peak RF magnetic fields consistently fall short of the ~400 mT prediction. The relatively rough topography of vapor-diffused Nb 3 Sn is widely conjectured to be one of the factors that limit the attainable performance of Nb 3 Sn-coated Nb cavities prepared via Sn vapor diffusion. Here we investigate the effect of coating duration on the topography of vapor-diffused Nb 3 Sn on Nb and calculate the associated magnetic field enhancement and superheating field suppression factors using atomic force microscopy topographies. It is shown that the thermally grooved grain boundaries are major defects which may contribute to a substantial decrease in the achievable accelerating field. Further, the severity of these grooves increases with total coating duration due to the deepening of thermal grooves during the coating process.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Amphiphilic nanopores that condense undersaturated water vapor and exude water droplets

Condensation of water vapor in confined geometries, known as capillary condensation, is a fundamental phenomenon with far-reaching implications. While hydrophilic pores enable liquid formation from undersaturated vapor without energy input, the condensate typically remains confined, limiting practical utility. Here, we explore the use of amphiphilic nanoporous polymer-infiltrated nanoparticle films that condense and release liquid water under isothermal and undersaturated conditions. By tuning the polymer fraction and nanoparticle size, we optimize condensation and droplet formation. As vapor pressure increases, voids fill with condensate, which subsequently exudes onto the surface as microscopic droplets. This behavior, enabled by a balance of polymer hydrophobicity and capillarity, reveals how amphiphilic nanostructures can drive accessible water collection. Our findings provide design insights for materials supporting energy-efficient water harvesting and heat management without external input.

Science & Technology - Other Topics↗

In situ atomic-resolution imaging of water vapor–driven multistep oxidation dynamics in strontium cobaltite

Understanding how water vapor interacts with transition metal oxides (TMOs) is critical for tailoring material properties to improve performance and enable new technologies. Despite extensive research efforts, atomic-scale mechanisms underpinning dynamic reactions and reaction-induced phase transitions remain elusive. Here, we use in situ environmental transmission electron microscopy to investigate how water vapor oxidizes vacancy-ordered SrCoO 2.5 at moderately elevated temperatures, demonstrating that water molecules can initiate oxidation more effectively than oxygen under comparable conditions. We discover a distinct “staging” behavior during the oxidation process: A fully ordered intermediate phase, SrCoO 2.75 , forms before transitioning into a near-perovskite SrCoO 3−δ . In addition, antiphase boundaries, originating at step terraces of SrTiO 3 , alleviate strain by creating reversible nanoscale “gaps” during lattice contraction under oxidation, providing a pathway for preserving structural integrity throughout redox cycling. This work provides atomic-level guidance for engineering TMOs by leveraging water vapor to control their redox behavior and tailor functional properties.

Science & Technology - Other Topics↗

Thermochemical Modeling of Radionuclide Vapor-Liquid Equilibria in Sodium Pools for SFR Mechanistic Source Term Analysis

Mechanistic source term (MST) analysis of sodium fast reactors (SFR) requires understanding of various radionuclide (RN) transport phenomena influencing potential releases from the fuel to the environment. One such phenomenon includes the retention or release of RNs from the sodium coolant pool, representing the step after possible fuel failures and influencing transport to the cover gas region. Thermodynamic vapor-liquid equilibria (VLE) calculations were performed on systems representing SFR sodium pools containing oxygen impurities and radionuclide (RN) inventories. First, an assessment and recreation of a previously developed thermodynamic database was completed, including updates to thermodynamic parameters. The RN inventories used in VLE calculations represented hypothetical source terms that might be released to the pool during previously analyzed fuel failure scenarios. The calculations were performed for all possible combinations of sodium pool size (i.e., total oxygen) and number of failed fuel pins (i.e., total RNs). In this way, multiple ratios of the RN relative to the oxygen impurity (RN:O) were compared for their impact on RN volatility, which is discussed in terms of the vapor fraction (VF), defined as the fraction of the RN that is calculated to exist in the vapor phase at equilibrium above condensed phases of that element. Similar trends in VLE behavior are seen in the equilibrium calculation results for elements of similar chemistry, and for some element types, it was found that the RN:O ratio can be important due to oxide formation, which typically exist in the condensed phase.

Shahbazi, Shayan↗

Separating Sensible and Latent Cooling with Electrically Charged Rotating Vortexes and Vapor Capturing Air Handler Technology

The dehumidification of air is a highly energy-intensive process, typically requiring vapor compression systems to cool the air below its dew point temperature. This project investigated air dehumidification achieved by electrostatic and dielectrophoresis forces in electrosprays and centrifugal principles in cyclone separators. As a practical implementation of these processes, Electrospray Vortical Flow eXchanger (EVFX) prototypes were designed, fabricated, and tested. Electrosprays were employed to energize water droplets, which then captured water vapor via dielectrophoresis. A cyclone separator was positioned downstream of the electrosprays. This combination increased the dehumidification efficiency and controlled the flow of the water vapor condensate removed from the air.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Liquid Hydrogen Pooling and Vaporization Experiments

A comprehensive investigation into the pooling and vaporization of liquid hydrogen spills onto concrete and steel surfaces in a steady cross-wind is presented in this work. This is the first instance of liquid hydrogen pooling and dispersion in a steady environment. A high-capacity fan in a large tunnel was used to generate the steady cross-winds while spilling roughly 10-20, or 40 l/min of liquid hydrogen onto substrates. Temperature and extractive concentration measurements were made, in addition to visible and infrared imaging, to understand development of the pool and down-wind dispersion of the vaporized hydrogen. Overall, the results enhance the understanding of liquid hydrogen pooling and dispersion dynamics and provide critical data for validating models of pooling and vapor dispersion under various conditions.

08 HYDROGEN↗

OH density and water vapor concentration gradients during plasma-droplet interactions

Plasma-droplet interactions significantly promote the reactivity transfer of gas phase species from the plasma to the liquid phase. Nonetheless, experimental studies on the impact of droplet evaporation on reactive species generation in such systems remain scarce. We report the spatial distribution of water vapor and OH radical densities around a droplet (∼41 μm in diameter) in He and He-Ar plasma using laser-induced fluorescence. The results reveal a significant gradient in both water vapor and OH radical concentrations near the droplets. Mutiple droplets present in the plasma can lead to a significant accumulation of water vapor and even local quenching of the discharge. The findings are critical for developing a quantitative understanding of plasma-liquid interactions for a broad range of plasma-enabled applications in the liquid phase often involving OH radicals.

42 ENGINEERING↗

Vapor pressure measured with inflatable plastic bag

Deflated plastic bag in a vacuum chamber measures initial low vapor pressures of materials. The bag captures the test sample vapors and visual observation of the vapor-inflated bag under increasing external pressures yields pertinent data.

Source record↗

Combustion chamber inlet manifold separates vapor from liquid

Circular manifold with tangential orifices at the inner circumference provides for the vapor constituent of a vaporized cryogenic propellant to enter a rocket combustion chamber before the liquid constituent. The vapor is separated from the liquid by centrifugal action and precedes it into the chamber through carefully positioned orifices.

Baker, D. I.↗