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At least 451 records · Page 25

Investigation of the effect of atmospheric dust on the determination of total ozone from the earth's ultraviolet reflectivity measurements, 1

Two computer algorithms are described. These algorithms were used for computing the aximuth-independent component of the intensity of the monochromatic radiation emerging at the top of a pseudo-spherical atmosphere with arbitrary vertical distribution of ozone, and with any arbitrary height distribution of up to two different kinds of aerosol. This atmospheric model was assumed to rest on a surface obeying Lambert's law of reflection.

Dave, J. V.↗

Measurements and analysis of ozone variations

The techniques that were used for total ozone and vertical distribution including measurement accuracy and precision are briefly discussed. A description of data availability is provided, and sample total ozone and stratospheric data are presented to illustrate the trends that were deduced from the data.

Source record↗

Infrared heterodyne spectrometer measurements of vertical profile of tropospheric ammonia and ozone

Remote sensing of the concentration and vertical distribution of atmospheric gases has been carried out using a dual CO2 laser multichannel infrared heterodyne spectrometer (IHS). The high specificity and nearly quantum-noise-limited sensitivity of the IHS provide the capability of scanning individual signature lines of selected atmospheric constituents in the 9 to 11 micron region. A comprehensive investigation of the spectral overlap between CO2 laser local oscillator transitions and selected atmospheric constituents was performed; measurements of the atmospheric absorption of solar radiation from the ground were carried out at selected laser transitions for ammonia and ozone.

Peyton, B. J.↗

Venus cloud structure and water vapor abundance from Mariner 10 observations

Observations of the Venus atmosphere with the infrared radiometer on Mariner 10 have been analyzed by Taylor (1975) in terms of the vertical distribution of opacity at wavelengths near 11 microns and 45 microns in the thermal infrared. In this paper, we discuss models of the Venus atmosphere which are consistent with the inferred opacity structure. Either a two-layer cloud structure, or a single cloud deck overlaid by a layer containing approximately 40 precipitable microns of water vapor, would have the required limb-darkening characteristics at the wavelengths of observation.

Taylor, F. W.↗

An extension to the Chahine method of inverting the radiative transfer equation

An extension of the Chahine relaxation method (1970) for inverting the radiative transfer equation is presented. This method is superior to the original method in that it takes into account in a realistic manner the shape of the kernel function, and its extension to nonlinear systems is much more straightforward. A comparison of the new method with a matrix method due to Twomey (1965), in a problem involving inference of vertical distribution of ozone from spectroscopic measurements in the near ultraviolet, indicates that in this situation this method is stable with errors in the input data up to 4%, whereas the matrix method breaks down at these levels. The problem of non-uniqueness of the solution, which is a property of the system of equations rather than of any particular algorithm for solving them, remains, although it takes on slightly different forms for the two algorithms.

Twomey, S.↗

Inverse solution of the pseudoscalar transfer equation through nonlinear matrix inversion

Nonlinear matrix inversion operators have been developed which, applied to observed radiances, infer maximal information regarding atmospheric scattering parameters and vertical distribution of radiant sources and sinks. The algorithm has the attractive feature of noise discrimination, attributing instrumental errors to extra-atmospheric sources.

King, J. I. F.↗

Stratospheric sounding by infrared heterodyne spectroscopy

Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution. The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes, and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described and applications to synthetic lines of O3, CO2, CH4 and N2O are given.

Abbas, M. M.↗

A model for dispersion from area sources in convective turbulence

Four independent estimates of the vertical distribution of the eddy coefficient for dispersion of a passive contaminant from an extensive area source in a convective layer have been presented. The estimates were based on the following methods: (1) a second-order closure prediction, (2) field data of pollutant concentrations over Los Angeles, (3) lab measurements of particle dispersion, and (4) assumption of equality between momentum and mass transfer coefficients in the free convective limit. It is suggested that K-values estimated both from second-order closure theory and from Los Angeles measurements are systematically underestimated.

Crane, G.↗

The abundance of acetylene in the atmosphere of Jupiter

The Q and R branches of the C2H2 nu(5) fundamental, observed in emission in an aircraft spectrum of Jupiter near 750/cm, have been analyzed with the help of an improved line listing for this band. The line parameters have been certified in the laboratory with the same interferometer used in the Jovian observations. The maximum mixing ratio of C2H2 is found to be between 5 times 10 to the -8th and 6 times 10 to the -9th power, depending on the form of its vertical distribution and the temperature structure assumed for the lower stratosphere. Most consistent with observations of both Q and R branches are: (1) distributions of C2H2 with a constant mixing ratio in the stratosphere and a cutoff at a total pressure of 100 mbar or less, and (2) the assumption of a temperature at 0.01 bar which is near 155 K.

Orton, G. S.↗

Ultraviolet absorption cross sections of hydrogen peroxide

Absorption cross-sections of hydrogen peroxide vapor and of neutral aqueous solutions of hydrogen peroxide were measured in the wavelength range from 195 to 350 nm at 296 K. The spectrophotometric procedure is described, and the reported cross-sections are compared with values obtained by other researchers. Photodissociation coefficients of atmospheric H2O2 were calculated for direct absorption of unscattered solar radiation, and the vertical distributions of these coefficients are shown for various solar zenith angles.

Lin, C. L.↗

Global and regional N2O measurements

Real-time N2O measurements have been made in situ at the South Pole, Antarctica, north and south of the equator from on board the Alpha Helix and over the Pacific Ocean on several aircraft flights from the U.S. to New Zealand, Australia and 90 deg S. In addition, an automated EC-GC has been operated for the past year intermittently monitoring N2O in surface air at a rural site in the wheatlands of eastern Washington state. The data obtained are consistent and in agreement with the data obtained from the analyses of a large number of samples collected both from ground stations and a variety of aircraft flights made in the southern and northern hemisphere. The observed global data show no interhemispheric differences. The present concentration of N2O in the troposphere is measured to be 330 + or - 3 ppbv. Its vertical distribution in the troposphere is very uniform. A small decrease (2-3 percent) across the tropopause is characteristically observed in the high-altitude flights.

Rasmussen, R. A.↗

Error analysis of an aircraft-mounted backscatter ultraviolet experiment

An experiment has been proposed to measure the zenith sky intensity and directly transmitted solar flux density at several wavelengths in the near ultraviolet from an aircraft platform located at about 15 km. From these measurements, the vertical distribution of ozone above the platform is to be inferred, by inversion of the equation of radiative transfer. The present study is an analysis of the errors to be expected in a real experiment, due to atmospheric fluctuations, numerical procedures, and ignorance of various parameters necessary for the calculation of the intensities and fluxes to be expected. These errors are found to vary from 17% at the shorter wavelengths to about 3% at the longer wavelengths used. It is shown elsewhere (Twomey et al., 1977) that unacceptable levels of instability and non-uniqueness of results will be found if the error levels in the measurements upon which we wish to invert exceed 3%. On the basis of this, it is concluded that with the present instrumentation and the present knowledge of necessary ancillary parameters, this experiment will not be feasible.

Rabinoff, R.↗

Possible fossil H2O liquid-ice interfaces in the Martian crust

The extensive chaotic and fretted terrains in the equatorial regions of Mars are explained on the basis of the vertical distribution of H2O liquid and ice which once existed in the crust. This account assumes that below the permafrost containing water ice, there was a second zone in which liquid water resided for at least a time. Diagenetic alteration and cementation characterized the material in the subpermafrost zone; above, pristine fragmented material with various ice concentrations was found. Later, the ice-laden zone was stripped away by a number of erosional processes, exposing the former ice-liquid water interface.

Soderblom, L. A.↗

Remote measurement of atmospheric pollutants

The concentration and vertical distribution of atmospheric ammonia and ozone are remotely sensed, using dual-C02-laser multichannel infrared Heterodyne Spectrometer (1HS). Innovation makes atmospheric pollution measurements possible with nearly-quantum-noise-limited sensitivity and ultrafine spectral resolution.

Allario, F.↗

Asymmetries in ozone depressions between the polar stratospheres following a solar proton event

Ozone depletions in the polar stratosphere during the energetic solar proton event on 4 August 1972 were observed by the backscattered ultraviolet (BUV) experiments on the Nimbus 4 satellite. The observed ozone contents, the ozone depressions and their temporal variations above the 4 mb level exhibited distinct asymmetries between the northern and southern hemispheres. Since the ozone destroying solar particles precipitate rather symmetrically into the two polar atmospheres, due to the geomagnetic dipole field, it is suggested that these asymmetries may be explained in terms of the differences in dynamics between the summer and the winter polar atmospheres. In the summer (northern) hemisphere, the stratospheric and mesospheric ozone depletion and recovery are smooth functions of time due to the preponderance of undistributed orderly flow in this region. On the other hand, the temporal variation of the upper stratospheric ozone in the winter polar atmosphere (southern hemisphere) exhibits large amplitude irregularities. These characteristic differences between the two polar atmospheres are also evident in the vertical distributions of temperatures and winds observed by balloons and rocket soundings.

Maeda, K.↗

Stratospheric Aerosol Measurement (SAM 2) experiment

The Stratospheric Aerosol Measurement 2 (SAM 2) is used to map the concentration and optical properties of stratospheric aerosols as a function of altitude, latitude, and longitude. The vertical distribution of the stratospheric aerosols in the polar regions of both hemispheres is provided.

Mccormick, M. P.↗

Trace constituent mixing ratios in the lower stratosphere during the 1977 intertropical convergence zone experiment

Minor constituents in the atmosphere can play an important role as tracers in studies of atmospheric transport and mixing. Simultaneous measurements of the vertical distribution of trace constituents in the troposphere and lower stratosphere were conducted in the region of the Intertropical Convergence Zone (ITCZ). An effort was made to measure the mixing ratios of selected trace constituents. A cryogenic sampling system on board a U-2 aircraft was used to acquire whole-air samples and to cryogenically collect samples at 13.7 to 21.3 km. Simultaneous tropospheric measurements using whole-air sampling canisters on board a Learjet aircraft were also carried out.

Vedder, J. F.↗