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At least 451 records · Page 25

Preventing Failures By Dataset Shift Detection in Safety-Critical Graph Applications

Dataset shift refers to the problem where the input data distribution may change over time (e.g., between training and test stages). Since this can be a critical bottleneck in several safety-critical applications such as healthcare, drug-discovery, etc., dataset shift detection has become an important research issue in machine learning. Though several existing efforts have focused on image/video data, applications with graph-structured data have not received sufficient attention. Therefore, in this paper, we investigate the problem of detecting shifts in graph structured data through the lens of statistical hypothesis testing. Specifically, we propose a practical two-sample test based approach for shift detection in large-scale graph structured data. Our approach is very flexible in that it is suitable for both undirected and directed graphs, and eliminates the need for equal sample sizes. Using empirical studies, we demonstrate the effectiveness of the proposed test in detecting dataset shifts. We also corroborate these findings using real-world datasets, characterized by directed graphs and a large number of nodes.

97 MATHEMATICS AND COMPUTING↗

Unique Tuft Test Facility Dramatically Reduces Brush Seal Development Costs

Brush seals have been incorporated in the latest turbine engines to reduce leakage and improve efficiency. However, the life of these seals is limited by wear. Studies have shown that optimal sealing characteristics for a brush seal occur before the interference fit between the brush and shaft is excessively worn. Research to develop improved tribopairs (brush and coating) with reduced wear and lower friction has been hindered by the lack of an accurate, low-cost, efficient test methodology. Estimated costs for evaluating a new material combination in an engine company seal test program are on the order of $100,000. To address this need, the NASA Lewis Research Center designed, built, and validated a unique, innovative brush seal tuft tester that slides a single tuft of brush seal wire against a rotating shaft under controlled loads, speeds, and temperatures comparable to those in turbine engines. As an initial screening tool, the brush seal tuft tester can tribologicaly evaluate candidate seal materials for 1/10th the cost of full-scale seal tests. Previous to the development of the brush seal tuft tester facility, most relevant tribological data had been obtained from full-scale seal tests conducted primarily to determine seal leakage characteristics. However, from a tribological point of view, these tests included the confounding effects of varying contact pressures, bristle flaring, high-temperature oxidation, and varying bristle contact angles. These confounding effects are overcome in tuft testing. The interface contact pressures can be either constant or varying depending on the tuft mounting device, and bristle wear can be measured optically with inscribed witness marks. In a recent cooperative program with a U.S. turbine engine manufacturer, five metallic wire candidates were tested against a plasma-sprayed Nichrome-bonded chrome carbide. The wire materials used during this collaboration were either nickel-chrome- or cobaltchrome-based superalloys. These tests corroborated full-scale seal test results and provided insight into previously untested combinations. As the cycle temperature for improved efficiency turbine engines increases, new brush seal materials combinations must be considered. Future brush seal tuft testing will include both metallic and ceramic bristles versus commercial and NASA-developed shaft coatings. The ultimate goal of this work is to expand the current data base so that seal designers can tailor brush seal materials to specific applications.

Fellenstein, James A.↗

Evidence from Hydrogen Isotopes in Meteorites for a Subsurface Hydrogen Reservoir on Mars

The surface geology and geomorphology of Mars indicates that it was once warm enough to maintain a large body of liquid water on its surface, though such a warm environment might have been transient. The transition to the present cold and dry Mars is closely linked to the history of surface water, yet the evolution of surficial water is poorly constrained. We have conducted in situ hydrogen isotope (D/H) analyses of quenched and impact glasses in three Martian meteorites (Yamato 980459, EETA79001, LAR 06319) by Cameca ims-6f at Digital Terrain Models (DTM) following the methods of [1]. The hydrogen isotope analyses provide evidence for the existence of a distinct but ubiquitous water/ice reservoir (D/H = 2-3 times Earth's ocean water: Standard Mean Ocean Water (SMOW)) that lasted from at least the time when the meteorites crystallized (173-472 Ma) to the time they were ejected by impacts (0.7-3.3 Ma), but possibly much longer [2]. The origin of this reservoir appears to predate the current Martian atmospheric water (D/H equals approximately 5-6 times SMOW) and is unlikely to be a simple mixture of atmospheric and primordial water retained in the Martian mantle (D/H is approximately equal to SMOW [1]). Given the fact that this intermediate-D/H reservoir (2-3 times SMOW) is observed in a diverse range of Martian materials with different ages (e.g., SNC (Shergottites, Nakhlites, Chassignites) meteorites, including shergottites such as ALH 84001; and Curiosity surface data [3]), we conclude that this intermediate-D/H reservoir is likely a global surficial feature that has remained relatively intact over geologic time. We propose that this reservoir represents either hydrated crust and/or ground ice interbedded within sediments. Our results corroborate the hypothesis that a buried cryosphere accounts for a large part of the initial water budget of Mars.

Usui, Tomohiro↗

Spectroscopic and Theoretical Studies of Ruthenium Complexes with a Noninnocent N 2 S 2 Ligand in Different Redox States

Herein we report an electronic structure investigation of neutral and oxidized Ru complexes containing a redox noninnocent N 2 S 2 ligand derived from o-phenylenediamide (L1). UV–vis spectroelectrochemistry (SEC) studies were conducted on the square pyramidal complex [Ru I I(L1)(PPh 3 )] (1) and the six-coordinate complexes [Ru I I(μ-BH 3 )(L1)(PPh 3 )] (2) – which has BH 3 bound in a metal–ligand cooperative (MLC) fashion across Ru and L1 – and [Ru II (L1)(PPh 3 )(MeCN)] (3). The SEC results yielded spectra assigned to singly and doubly oxidized 1 and 3, revealing electronic structure changes as a function of oxidation state and in response to the presence and absence of bound MeCN. By contrast, the SEC results of 2 showed that it rapidly loses MLC-bound BH 3 upon oxidation. The SEC results for 1 and 3 were compared to single-crystal XRD data and UV–vis, EPR, and P K-edge, S K-edge, and Ru L 3 -edge X-ray absorption spectroscopy (XAS) data collected on isolated samples of chemically oxidized 3. The data revealed that the first two oxidations are primarily localized on the ligand, which was supported by DFT and TDDFT calculations. DFT calculations for the doubly oxidized species revealed a singlet ground state with a singlet–triplet gap of 8.9 kcal/mol. CASPT2 calculations corroborated the DFT calculations and further revealed that the singlet ground state is multiconfigurational with 21% radical character. Collectively, the results establish redox formalisms and the underlying electronic structure of Ru complexes containing a noninnocent tetradentate ligand in different oxidation states.

electronic structure↗

D-T gamma-to-neutron branching ratio determined from inertial confinement fusion plasmas

A new deuterium-tritium (D-T) fusion gamma-to-neutron branching ratio [{sup 3}H(d,{gamma}){sup 5}He/{sup 3}H(d,n){sup 4}He] value of (4.2 {+-} 2.0) Multiplication-Sign 10{sup -5} was recently reported by this group [Y. Kim et al. Phys. Rev. C (submitted)]. This measurement, conducted at the OMEGA laser facility located at the University of Rochester, was made for the first time using inertial confinement fusion (ICF) plasmas. Neutron-induced backgrounds are significantly reduced in these experiments as compared to traditional beam-target accelerator-based experiments due to the short pulse nature of ICF implosions and the use of gas Cherenkov {gamma}-ray detectors with fast temporal responses and inherent energy thresholds. It is expected that this ICF-based measurement will help resolve the large and long-standing inconsistencies in previously reported accelerator-based values, which vary by a factor of approximately 30. The reported value at ICF conditions was determined by averaging the results of two methods: (1) a direct measurement of ICF D-T {gamma}-ray and neutron emissions using absolutely calibrated detectors and (2) a separate cross-calibration against the better known D-{sup 3}He gamma-to-proton branching ratio [{sup 3}He(d, {gamma}){sup 5}Li/{sup 3}He(d,p){sup 4}He]. Here we include a detailed explanation of these results, and introduce as a corroborative method an in-situ{gamma}-ray detector calibration using neutron-induced {gamma}-rays. Also, by extending the established techniques to two additional series of implosions with significantly different ion temperatures, we test the branching ratio dependence on ion temperature. The data show a D-T branching ratio is nearly constant over the temperature range 2-9 keV. These studies motivate further investigation into the {sup 5}He and {sup 5}Li systems resulting from D-T and D-{sup 3}He fusion, respectively, and result in improved ICF {gamma}-ray reaction history diagnosis at the National Ignition Facility.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ultrafast dynamics of a near-solid-density layer in an intense femtosecond laser-excited plasma

We report on the picosecond dynamics of a near-solid-density plasma generated by an intense, infrared (λ = 800 nm) femtosecond laser using time-resolved pump-probe Doppler spectrometry. An initial red-shift is observed in the reflected third harmonic (λ = 266 nm) probe pulse, which gets blue-shifted at longer probe-delays. A combination of particle-in-cell and radiation-hydrodynamics modelling is performed to model the pump laser interaction with the solid target. The results are post-processed to predict the Doppler shift. An excellent agreement is found between the results of such modelling and the experiment. The modelling suggests that the initial inward motion of the critical surface observed in the experiment is due to the passage of a shock-wave-like disturbance, launched by the pump interaction, propagating into the target. Furthermore, in order to achieve the best possible fit to the experimental data, it was necessary to incorporate the effects of bulk ion-acceleration resulting from the electrostatic field set up by the expulsion of electrons from the laser envelope. We also present results of time-resolved pump-probe reflectometry, which are corroborated with the spectrometry results using a 1-D reflectivity model.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

SU-E-I-27: Establishing Target Exposure Index Values for Computed Radiography

Purpose: To develop a standard set of target exposure index (TEI) values to be applied to Agfa Computed Radiography (CR) readers in accordance with International Electrotechnical Committee 62494-1 (ed. 1.0). Methods: A large data cohort was collected from six USAF Medical Treatment Facilities that exclusively use Agfa CR Readers. Dose monitoring statistics were collected from each reader. The data was analyzed based on anatomic region, view, and processing speed class. The Agfa specific exposure metric, logarithmic mean (LGM), was converted to exposure index (EI) for each data set. The optimum TEI value was determined by minimizing the number of studies that fell outside the acceptable deviation index (DI) range of +/− 2 for phototimed techniques or a range of +/−3 for fixed techniques. An anthropomorphic radiographic phantom was used to corroborate the TEI recommendations. Images were acquired of several anatomic regions and views using standard techniques. The images were then evaluated by two radiologists as either acceptable or unacceptable. The acceptable image with the lowest exposure and EI value was compared to the recommended TEI values using a passing DI range. Results: Target EI values were determined for a comprehensive list of anatomic regions and views. Conclusion: Target EI values must be established on each CR unit in order to provide a positive feedback system for the technologist. This system will serve as a mechanism to prevent under or overexposures of patients. The TEI recommendations are a first attempt at a large scale process improvement with the goal of setting reasonable and standardized TEI values. The implementation and effectiveness of the recommended TEI values should be monitored and adjustments made as necessary.

60 APPLIED LIFE SCIENCES↗

The Origin of the Compositional Diversity of Mercury's Surface Constrained From Experimental Melting of Enstatite Chondrites

Mercury is known as an endmember planet as it is the most reduced terrestrial planet with the highest core/mantle ratio. MESSENGER spacecraft has shown that its surface is FeO-poor (2-4 wt%) and Srich (up to 6-7 wt%), which confirms the reducing nature of its silicate mantle. Moreover, high resolution images revealed large volcanic plains and abundant pyroclastic deposits, suggesting important melting stages of the Mercurian mantle. This interpretation was confirmed by the high crustal thickness (up to 100 km) derived from Mercury's gravity field. This is also corroborated by a recent experimental result that showed that Mercurian partial melts are expected to be highly buoyant within the Mercurian mantle and could have risen from depths as high as the core-mantle boundary. In addition MESSENGER spacecraft provided relatively precise data on major elemental compositions of Mercury's surface. These results revealed important chemical and mineralogical heterogeneities that suggested several stages of differentiation and re-melting processes. However, the extent and nature of compositional variations produced by partial melting remains poorly constrained for the particular compositions of Mercury (very reducing conditions, low FeO-contents and high sulfur-contents). Therefore, in this study, we investigated the processes that lead to the various compositions of Mercury's surface. Melting experiments with bulk Mercury-analogue compositions were performed and compared to the compositions measured by MESSENGER.

Boujibar, A.↗

Oil-Pressure Based Apparatus for In-Situ High-Energy Synchrotron X-Ray Diffraction Studies During Biaxial Deformation

Background: Understanding biaxial loading response at the microstructural level is crucial in helping better design sheet manufacturing processes and calibrate/validate material deformation models. Objective: The objective of this work was to develop a low-cost testing apparatus to probe, with sufficient spatial resolution, the micro-mechanical response of a sheet material in-situ under biaxial loading conditions. Methods: The testing apparatus fabricated as a part of this study operates in a similar fashion to a standard bulge test and uses oil pressure to generate biaxial loading conditions. This biaxial testing apparatus was operated within a synchrotron beamline to characterize the mechanical response of a flash-processed steel sheet using in-situ high-energy X-ray diffraction (XRD) measurements. Further, the GSAS-II package was utilized to develop a workflow for the analysis of the large volume of diffraction data acquired. The workflow was then used to extract the peak position, width, and integrated intensity of the XRD peaks corresponding to the major body-centered cubic phase. Results: The equi-biaxial nature of the loading in the measured area was independently corroborated using experimental (XRD) and simulation (finite element analysis) methods. Furthermore, we discuss the evolution of elastic strain in the major body-centered cubic phase as a function of applied oil pressure and location on the steel sheet. Conclusions: A key advantage of the biaxial apparatus fabricated in this synchrotron study is demonstrated using the results obtained for the flash-processed steel sheet – i.e., mapping the lattice plane-dependent response to biaxial loading for a relatively large sample area in a spatially resolved manner.

36 MATERIALS SCIENCE↗

Dust Formation, Evolution, and Obscuration Effects in the Very High-Redshift Universe

The evolution of dust at redshifts z > or approx. 9, and consequently the dust properties, differs greatly from that in the local universe. In contrast to the local universe, core collapse supernovae (CCSNe) are the only source of thermally-condensed dust. Because of the low initial dust-to-gas mass ratio, grain destruction rates are low, so that CCSNe are net producers of interstellar dust. Galaxies with large initial gas mass or high mass infall rate will therefore have a more rapid net rate of dust production comported to galaxies with lower gas mass, even at the same star formation rate. The dust composition is dominated by silicates, which exhibit a strong rise in the UV opacity near the Lyman break. This "silicate-UV break" may be confused with the Lyman break, resulting in a misidentification of a galaxies' photometric redshift. In this paper we demonstrate these effects by analyzing the spectral energy distribution (SED) of MACS1149-JD, a lensed galaxy at z = 9.6. A potential 2mm counterpart of MACS1149-JD has been identified with GISMO. While additional observations are required to corroborate this identification, we use this possible association to illustrate the physical processes and the observational effects of dust in the very high redshift universe. Subject headings: galaxies: high-redshift - galaxies: evolution - galaxies: individual (MACS1149- JD) - Interstellar medium (ISM), nebulae: dust, extinction - physical data and processes: nuclear reactions, nucleosynthesis, abundances.

galaxies: high-redshift↗

Phosphorus diffusion and deactivation during SiGe oxidation

Dopant profiles near the semiconductor–oxide interface are critical for microelectronic device performance. As the incorporation of Si 1−x Ge x into transistors continues to increase, it is necessary to understand the behavior of dopants in Si 1−x Ge x . In this paper, the diffusion and electrical activation of phosphorus within a strained, single-crystal Si 0.7 Ge 0.3 layer on Si during oxidation are reported. Both layers were uniformly doped, in situ, with an average phosphorus concentration of 4 × 10 19 atoms/cm 3 . After high-temperature oxidation, secondary ion mass spectrometry measurements revealed that the bulk of the phosphorus diffuses out of only the SiGe layer and segregates at the oxidizing SiGe–SiO 2 interface. Hall effect measurements corroborate the observed phosphorus loss and show that the phosphorus diffusing to the oxidizing interface is electrically inactive. Through density functional theory (DFT) calculations, it is shown that phosphorus interstitials prefer sites near the SiGe–SiO 2 interface. Finally, based on a combination of experimental data and DFT calculations, we propose that the phosphorus atoms are displaced from their lattice sites by Ge interstitials that are generated during SiGe oxidation. The phosphorus atoms then migrate toward the SiGe–SiO 2 interface through a novel mechanism of hopping between Ge sites as P–Ge split interstitials. Once they reach the interface, they are electrically inactive, potentially in the form of interstitial clusters or as part of the reconstructed interface or oxide.

Thornton, Chappel S.↗

THE CHEMICAL SIGNATURE OF A RELIC STAR CLUSTER IN THE SEXTANS DWARF SPHEROIDAL GALAXY-IMPLICATIONS FOR NEAR-FIELD COSMOLOGY

We present tentative evidence for the existence of a dissolved star cluster at [Fe/H] = -2.7 in the Sextans dwarf spheroidal galaxy. We use the technique of chemical tagging to identify stars that are highly clustered in a multi-dimensional chemical abundance space (C-space). In a sample of six stars, three, possibly four, stars are identified as potential cluster stars. The initial stellar mass of the parent cluster is estimated from two independent observations to be M{sub *,init}=1.9{sup +1.5}{sub -0.9}(1.6{sup +1.2}{sub -0.8}) Multiplication-Sign 10{sup 5} M{sub sun}, assuming a Salpeter (Kroupa) initial mass function. If corroborated by follow-up spectroscopy, this star cluster is the most metal-poor system identified to date. Chemical signatures of remnant clusters in dwarf galaxies like Sextans provide us with a very powerful probe to the high-redshift universe. From available observational data, we argue that the average star cluster mass in the majority of the newly discovered ultra-faint dwarf galaxies was notably lower than it is in the Galaxy today and possibly lower than in the more luminous, classical dwarf spheroidal galaxies. Furthermore, the mean cumulative metallicity function of the dwarf spheroidals falls below that of the ultra-faints, which increases with increasing metallicity as predicted from our stochastic chemical evolution model. These two findings, together with a possible difference in the ([Mg/Fe]) ratio suggest that the ultra-faint dwarf galaxy population, or a significant fraction thereof, and the dwarf spheroidal population were formed in different environments and would thus be distinct in origin.

79 ASTRONOMY AND ASTROPHYSICS↗

Electromagnetic production of kaons near threshold

Kaon photo- and electroproduction off a proton near the production threshold are investigated by utilizing an isobar model. The background amplitude of the model is constructed from Feynman diagrams, whereas the resonance term is calculated by using the multipole formalism. It is found that both pseudoscalar and pseudovector models can nicely describe the available photoproduction data up to W=50 MeV above the threshold. The {Lambda} resonance S{sub 01}(1800) is found to play an important role in improving the model. In the case of double polarization observables O{sub x}{sup '} and O{sub z}{sup '} our result corroborates the finding of Sandorfi et al. (arXiv:0912.3505 [nucl-th]). Due to the large contributions of the K{sup *} and K{sub 1} vector mesons, extending the model to the case of electroproduction is almost impossible unless either special form factors that strongly suppress their contributions are introduced or all hadronic coupling constants are refitted to both photo- and electroproduction databases, simultaneously. It is also concluded that investigation of the kaon electromagnetic form factor is not recommended near the threshold region.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Osmotic stress, endogenous abscisic acid and the control of leaf morphology in Hippuris vulgaris L

Previous reports indicate that heterophyllous aquatic plants can be induced to form aerial-type leaves on submerged shoots when they are grown in exogenous abscisic acid (ABA). This study reports on the relationship between osmotic stress (e.g. the situation encountered by a shoot tip when it grows above the water surface), endogenous ABA (as measured by gas chromatography-electron capture detector) and leaf morphology in the heterophyllous aquatic plant, Hippuris vulgaris. Free ABA could not be detected in submerged shoots of H. vulgaris but in aerial shoots ABA occurred at ca. 40 ng (g fr wt)-1. When submerged shoots were osmotically stressed ABA appeared at levels of 26 to 40 ng (g fr wt)-1. These and other data support two main conclusions: (1) Osmotically stressing a submerged shoot causes the appearance of detectable levels of ABA. (2) The rise of ABA in osmotically stressed submerged shoots in turn induces a change in leaf morphology from the submerged to the aerial form. This corroborates the hypothesis that, in the natural environment, ABA levels rise in response to the osmotic stress encountered when a submerged shoot grows up through the water/air interface and that the increased ABA leads to the production of aerial-type leaves.

NASA Program Space Biology↗

Comparison of Surface Fluxes Derived from CYGNSS and Simulated by WRF Model: An MJO Case Study

This study focuses on ocean surface fluxes, mainly the latent heat flux, and their impact on MJO propagation and associated precipitation structures over the Indian Ocean and Maritime Continent. The Coupled-Ocean-Atmosphere-Wave-Sediment Transport (COAWST) model is used to simulate two MJO events during the 2017-2018 season: the December 10 - January 20, 2017 case, which maintained its strong precipitation signal over the Maritime Continent, and the March 1 - 20, 2018 case, which was weaker and did not propagate through the Maritime Continent. Both simulated MJO events show positive biases in surface rainfall compared with GPM IMERG data. During the MJO suppressed phase, the simulations rain more often than the observations. During the active phase, the westward propagating precipitation structures are more organized and much stronger compared with the observations, sometimes forming westward propagating cyclones that weakened the eastward precipitation signals. Two aspects of the surface flux interactions are investigated: the impact of the domain mean surface fluxes, and the impact of storm scale circulations and their interactions with local surface fluxes. Both aspects affect water vapor budget, atmosphere instability and mean flow, through which convection initiation, organization, and propagation are influenced. Model sensitivity tests with different radiation, microphysics, PBL schemes and nudging schemes indicate that in the control simulations, higher SST and surface fluxes, especially during the suppressed period, are the main reason of rainfall overestimation compared with IMERG data. The strong westward propagating signals are caused by both increased atmosphere instability and reduced mean wind shear. Unfortunately, the small differences in mean SST and surface fluxes between different model sensitivity tests are all within the satellite observation error margin, and cannot be directly corroborated by observations. One of the advantages of CYGNSS satellites is that they observe ocean surface wind and heat fluxes underneath strong rainfall events such as the convective systems associated with MJO active phases. Currently we are comparing CYGNSS level 2 surface fluxes retrievals and the model simulations in order to better understand the second aspect of the MJO and surface fluxes interactions, and how this affects MJO strengths and propagations. The interactive atmosphere-ocean-wave model also provides cases that directly comparing satellite observables (the bistatic radar cross section) and the model simulations (through CYGNSS satellite simulator). These discrepancies are more prominent in coupled ocean simulations, mainly due to higher SST and enhanced surface fluxes.

Li, Xiaowen↗

In Situ Insights into Cathode Calcination for Predictive Synthesis: Kinetic Crystallization of LiNiO 2 from Hydroxides

Abstract Calcination is a solid‐state synthesis process widely deployed in battery cathode manufacturing. However, its inherent complexity associated with elusive intermediates hinders the predictive synthesis of high‐performance cathode materials. Here, correlative in situ X‐ray absorption/scattering spectroscopy is used to investigate the calcination of nickel‐based cathodes, focusing specifically on the archetypal LiNiO 2 from Ni(OH) 2 . Combining in situ observation with data‐driven analysis reveals concurrent lithiation and dehydration of Ni(OH) 2 and consequently, the low‐temperature crystallization of layered LiNiO 2 alongside lithiated rocksalts. Following early nucleation, LiNiO 2 undergoes sluggish crystallization and structural ordering while depleting rocksalts; ultimately, it turns into a structurally‐ordered layered phase upon full lithiation but remains small in size. Subsequent high‐temperature sintering induces rapid crystal growth, accompanied by undesired delithiation and structural degradation. These observations are further corroborated by mesoscale modeling, emphasizing that, even though calcination is thermally driven and favors transformation towards thermodynamically equilibrium phases, the actual phase propagation and crystallization can be kinetically tuned via lithiation, providing freedom for structural and morphological control during cathode calcination.

36 MATERIALS SCIENCE↗

Constraints on helium enhancement in the globular cluster M4 (NGC 6121): The horizontal branch test

Recent pieces of evidence have revealed that most, and possibly all, globular star clusters are composed of groups of stars that formed in multiple episodes with different chemical compositions. In this sense, it has also been argued that variations in the initial helium abundance (Y) from one population to the next are also the rule, rather than the exception. In the case of the metal-intermediate globular cluster M4 (NGC 6121), recent high-resolution spectroscopic observations of blue horizontal branch (HB) stars (i.e., HB stars hotter than the RR Lyrae instability strip) suggest that a large fraction of blue HB stars are second-generation stars formed with high helium abundances. In this paper, we test this scenario by using recent photometric and spectroscopic data together with theoretical evolutionary computations for different Y values. Comparing the photometric data with the theoretically derived color-magnitude diagrams, we find that the bulk of the blue HB stars in M4 have ΔY ≲ 0.01 with respect to the cluster's red HB stars (i.e., HB stars cooler than the RR Lyrae strip)—a result which is corroborated by comparison with spectroscopically derived gravities and temperatures, which also favor little He enhancement. However, the possible existence of a minority population on the blue HB of the cluster with a significant He enhancement level is also discussed.

79 ASTRONOMY AND ASTROPHYSICS↗

Macroscopic impacts of cloud and precipitation processes on maritime shallow convection as simulated by a large eddy simulation model with bin microphysics

This paper discusses impacts of cloud and precipitation processes on macrophysical properties of shallow convective clouds as simulated by a large eddy model applying warm-rain bin microphysics. Simulations with and without collision–coalescence are considered with cloud condensation nuclei (CCN) concentrations of 30, 60, 120, and 240 mg -1 . Simulations with collision–coalescence include either the standard gravitational collision kernel or a novel kernel that includes enhancements due to the small-scale cloud turbulence. Simulations with droplet collisions were discussed in Wyszogrodzki et al. (2013) focusing on the impact of the turbulent collision kernel. The current paper expands that analysis and puts model results in the context of previous studies. Despite a significant increase of the drizzle/rain with the decrease of CCN concentration, enhanced by the effects of the small-scale turbulence, impacts on the macroscopic cloud field characteristics are relatively minor. Model results show a systematic shift in the cloud-top height distributions, with an increasing contribution of deeper clouds for stronger precipitating cases. We show that this is consistent with the explanation suggested in Wyszogrodzki et al. (2013); namely, the increase of drizzle/rain leads to a more efficient condensate offloading in the upper parts of the cloud field. A second effect involves suppression of the cloud droplet evaporation near cloud edges in low-CCN simulations, as documented in previous studies (e.g., Xue and Feingold, 2006). We pose the question whether the effects of cloud turbulence on drizzle/rain formation in shallow cumuli can be corroborated by remote sensing observations, for instance, from space. Although a clear signal is extracted from model results, we argue that the answer is negative due to uncertainties caused by the temporal variability of the shallow convective cloud field, sampling and spatial resolution of the satellite data, and overall accuracy of remote sensing retrievals.

54 ENVIRONMENTAL SCIENCES↗