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NASA NTRS2001

Chemical differentiation in regions of massive star formation

We have reexamined the origin of the apparent differentiation between nitrogen-bearing molecules and complex oxygen-bearing molecules that is observed in hot molecular cores associated with massive protostars. Observations show that methanol is an ubiquitous and abundant component of protostellar ices. Recent observations suggest that ammonia may constitute an appreciable fraction of the ices toward some sources. In contrast to previous theories that suggested that N/O differentiation was caused by an anticorrelation between methanol and ammonia in the precursor grain mantles, we show that the presence of ammonia in mantles and the core temperature are key quantities in determining N/O differentiation. Calculations are presented which show that when large amounts of ammonia are evaporated alkyl cation transfer reactions are suppressed and the abundances of complex O-bearing organic molecules greatly reduced. Cooler cores (100 K) eventually evolve to an oxygen-rich chemical state similar to that attained when no ammonia was injected, but on a timescale that is an order of magnitude longer (~10(5) yr). Hotter cores (300 K) never evolve an O-rich chemistry unless ammonia is almost absent from the mantles. In this latter case, a complex O-rich chemistry develops on a timescale of ~10(4) yr, as in previous models, but disappears in about 2 x 10(5) yr, after which time the core is rich in NH3, HCN, and other N-bearing molecules. There are thus two ways in which N-rich cores can occur. We briefly discuss the implications for the determination of hot-core ages and for explaining N/O differentiation in several well-studied sources.

NASA Center ARC↗

NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 17

The following topics were discussed: A Model for the Formation of Paterae on Io; LIBS-based Detection of As, Br, C, Cl, P, and S in the VUV Spectral Region in a Mars Atmosphere; Mass Independent Sulfur in Achondrites: Possible Evidence of Photochemistry in the Solar Nebula; Grain Size-dependent Viscosity and Oceans in Icy Satellites; Claritas Paleolake Studied from the MEX HRSC Data; Mars Express HRSC Colors of White Rock, Arabia, Mars; Lava and Flows of the Arcadia Region of Mars; Isotopic Composition of Lunar Soils and the Early Differentiation of the Moon; Trace Element Analysis of Lunar Soils by ICP-MS; Highly Siderophile Elements and Osmium Isotope Systematics in Ureilites: Are the Carbonaceous Veins Primary Components?; Evaporative Evolution of Martian Brines Based on Halogens in Nakhlites and MER Samples; Io from High-Resolution Galileo PPR Data Taken Simultaneously with SSI or NIMS Observations; Loki, Io: Groundbased Observations and a Model for Periodic Overturn; Deconstructing a Few Myths in the Interpretation of Satellite-Altitude Crustal Magnetic Field: Examples from Mars Global Surveyor; Semi-Autonomous Rover Operations: A Mars Technology Program Demonstration; Rotational Studies of Asteroids with Small Telescopes; Mineralogy and Temperature-induced Spectral Investigations of A-type Asteroids 246 Asporina and 446 Aeternitas; and Thermal History Calculations Versus Full Convection Models: Application to the Thermal Evolution of Mercury. Recent Solar-Proton Fluxes

Source record↗

NASA NTRS2009

Impact Histories of Vesta and Vestoids inferred from Howardites, Eucrites, and Diogenites

The parent body of the howardites, eucrites and diogenites (HEDs) is thought to be asteroid (4) Vesta [1]. However, several eucrites have now been recognized, like NWA 011 and Ibitira, with major element compositions and mineralogy like normal eucrites but with different oxygen isotope compositions and minor element concentrations suggesting they are not from the same body [2, 3]. The discoveries of abnormal eucrites and V-type asteroids that are probably not from Vesta [see 4] raise the question whether the HEDs with normal oxygen isotopes are coming from Vesta [3]. To address this issue and understand more about the evolution of Vesta in preparation for the arrival of the Dawn spacecraft, we integrate fresh insights from Ar-Ar dating and oxygen isotope analyses of HEDs, radiometric dating of differentiated meteorites, as well as dynamical and astronomical studies of Vesta, the Vesta asteroid family (i.e., the Vestoids), and other V-type asteroids.

Scott, E. R. D.↗

NASA NTRS2020

Ancient Martian aeolian sand dune deposits recorded in the stratigraphy of Valles Marineris and implications for past climates

Aeolian sediment transport, deposition, and erosion have been ongoing throughout Mars’ history. This record of widespread aeolian processes is preserved in landforms and geologic units that retain important clues about past environmental conditions including wind patterns. In this study we describe landforms within Melas Chasma, Valles Marineris, that occur in distinct groups with linear to crescentic shapes, arranged with a characteristic wavelength; some possess slope profiles analogous to modern sand dunes, yet show evidence for lithification. Based on the features’ dimensions, asymmetry, and spatial patterns relative to modern equivalents, we interpret these landforms to be two classes of aeolian bedforms: decameter-scale mega-ripples and sand dunes. The presence of superposed erosional features and depositional units indicates these landforms were cemented and likely ancient. Melas paleo-dunes are found atop Hesperian-aged layered deposits, but we estimate them to be younger, likely lithified in the Amazonian period. Although a range of degradation was observed, some paleo-dunes are >10 m tall and maintain steep lee sides (>25°), an uncommon scenario for terrestrial examples as other geologic processes lead to dune obliteration. The preserved paleo-bedform geometries are largely consistent with those of modern aeolian indicators, suggesting no major shifts in wind regime or contributing boundary conditions. Finally, we propose their appearance and context require sequential periods of dune migration, stabilization following catastrophic burial, cementation, differential erosion, exposure, and burial. The presence of wholly preserved duneforms appears to be more common on Mars compared to the Earth and may signal something important about Martian landscape evolution. Plain Language Summary Wind-driven sand dunes are common on modern Mars and the presence of certain sedimentary rock layers indicates these landforms occurred there in the past. Here, we explore features in the canyons of Valles Marineris which show characteristics frequently attributed to dunes, yet evidence for their lithification and burial is clear. Their horizontal extent, height, shape, slopes, and collective spatial patterns led to our interpretation of them as lithified dune fields. The heavily eroded appearance along with superposed elements such as craters and boulders led to the conclusion that these are relatively ancient landforms. Despite this erosion This level of preservation is rare for terrestrial sand dunes due to erosion and tectonics, thus providing an opportunity to reconstruct the various factors contributing to their history. Understanding the circumstances that led to the preservation of these ancient duneforms will yield crucial information regarding planetary sedimentary processes and the geologic history of the region.

Matthew Chojnacki↗

NASA NTRS1993

Primary differentiation in the early Earth: Nd and Sr isotopic evidence from diamondiferous eclogites for both old depleted and old enriched mantle, Yakutia, Siberia

Ancient, stable, continental cratons possess thick, subcontinental-lithospheric mantle 'keels' which favor particularly the emplacement of diamondiferous kimberlites and included peridotites and eclogites. These refractory mantle samples of the roots provide hard constraints on the theories of formation, growth, and evolution of these cratons. Xenoliths containing only primary garnet and clinopyroxene (eclogites), although rare in most kimberlites, can retain the geochemical signatures of their parent protoliths (e.g., subducted oceanic crust, ancient mantle) thus offering the opportunity to address mantle processes which may have taken place at earlier times in the Earth's history. In fact, it has been postulated that some eclogites are residues from the accretion of the early Earth. Nd and Sr isotopic data are presented which may be interpreted as evidence of an early (greater than 4 Ga) mantle differentiation event. The kimberlites of Yakutia are located both marginal and central to the Siberian craton, and a wide variety of xenoliths are present within them. The Siberian mantle samples have received little attention in the western world, largely because suitable suites of Yakutian samples have not been readily available. Importantly, there is evidence that metasomatism of the Siberian lithosphere has been considerably less intense or extensive than for the Kaapvaal craton. Therefore, it should be considerably easier to elicit the igneous/metamorphic histories of Siberian kimberlitic xenoliths. One of the notable features of the Siberian eclogites is the common appearance of diamonds, especially in the Mir and Udachnaya pipes. In all, eight eclogite samples (eight garnet separates and eight clinopyroxene separates) have been analyzed to date on the Udachnaya pipe, seven from our group.

Snyder, Gregory A.↗

DOE OSTI2025

Virulence and Genetic Diversity of Puccinia spp., Causal Agents of Rust on Switchgrass (Panicum virgatum L.) in the USA

Switchgrass (Panicum virgatum L.) is an important cellulosic biofuel grass native to North America. Rust, caused by Puccinia spp. is the most predominant disease of switchgrass and has the potential to impact biomass conversion. In this study, virulence patterns were determined on a set of 38 switchgrass genotypes for 14 single-spore rust isolates from 14 field samples collected in seven states. Single nucleotide polymorphism (SNP) variation was also assessed in 720 sequenced cloned amplicons representing 654 base pairs of the elongation factor 1-α gene from the field samples. Five major haplotypes were identified differing by 11 out of the 39 SNP positions identified. STRUCTURE, Principal Coordinate Analysis, and phylogenetic analyses divided the rust population into two genetic clusters. Virginia and Georgia had the highest and lowest rust genetic diversity, respectively. Only nine accessions showed a differential disease response between the 14 isolates, allowing the identification of eight races, differing by 1–3 virulence factors. Overall, the results suggested clonal reproduction of the pathogen and a North–South differentiation via local adaptation. However, similar haplotypes and races were also recovered from several states, suggesting migration events, and highlighting the need to further investigate the switchgrass rust population structure and evolution in the USA.

Bahri, Bochra A. (ORCID:0000000159055880)↗

NASA NTRS1978

Comparative planetology: Significance for terrestrial geology

The crustal evolution of the terrestrial planets increase in complexity and duration with increasing size and mass of the planet. The lunar and mercurian surfaces are largely the result of intense, post-differentiation impact bombardment and subsequent volcanic filling of major impact basins. Mars, being larger, has evolved further: crustal uplifts, rifting, and shield volcanoes have begun to modify its largely Moon-like surface. The Earth is the large end-number of this sequence, where modern plate tectonic processes have erased the earlier lunar and martian type of surfaces. Fundamental problems of the origin of terrestrial continents, ocean basins, and plate tectonics are now addressed within the context of the evolutionary pattern of the terrestrial planets.

Frey, H. V.↗

NASA NTRS1988

Apennine Front revisited - Diversity of Apollo 15 highland rock types

The Apollo 15 landing site is geologically the most complex of the Apollo sites, situated at a mare-highland interface within the rings of two of the last major basin-forming impacts. Few of the Apollo 15 samples are ancient highland rocks derived from the early differentiation of the moon, or impact melts from major basin impacts. Most of the samples are regolith breccias containing abundant clasts of younger volcanic mare and KREEP basalts. The early geologic evolution of the region can be understood only by examining the small fragments of highland rocks found in regolith breccias and soils. Geochemical and petrologic studies of clasts and matrices of three impact melt breccias and four regolith breccias are presented. Twelve igneous and metamorphic rocks show extreme diversity and include a new type of ferroan norite. Twenty-five samples of highland impact melt are divided into groups based on composition. These impact melts form nearly a continuum over more than an order of magnitude in REE concentrations. This continuum may result from both major basin impacts and younger local events. Highland rocks from the Apennine Front include most of the highland rock types found at all of the other sites. An extreme diversity of highland rocks is a fundamental characteristic of the Apennine Front and is a natural result of its complex geologic evolution.

Lindstrom, Marilyn M.↗

NASA NTRS2010

Thermal Properties of Lunar Regolith Simulants

Various high temperature chemical processes have been developed to extract oxygen and metals from lunar regolith. These processes are tested using terrestrial analogues of the regolith. But all practical terrestrial analogs contain H2O and/or OH-, the presence of which has substantial impact on important system behaviors. We have undertaken studies of lunar regolith simulants to determine the limits of the simulants to validate key components for human survivability during sustained presence on the Moon. Differential Thermal Analysis (DTA) yields information on phase transitions and melting temperatures. Thermo-Gravimetric Analysis (TGA) with Fourier Transform Infrared (FTIR) analysis provides information on evolved gas species and their evolution temperature profiles. The DTA and TGA studies included JSC-1A fine (Johnson Space Center Mare Type 1A simulant), NU-LHT-2M (National Aeronautics and Space Administration (NASA)-- United States Geological Survey (USGS)--Lunar Highlands Type 2M simulant) and its proposed feedstocks: anorthosite; dunite; high quality (HQ) glass and the norite from which HQ glass is produced. As an example, the DTA and TGA profiles for anorthosite follow. The DTA indicates exothermic transitions at 355 and 490 C and endothermic transitions at 970 and 1235 C. Below the 355 C transition, water is lost accounting for approximately 0.1 percent mass loss. Just above 490 C a second type of water is lost, presumably bound in lattices of secondary minerals along with other volatile oxides. Limited TGA-FTIR data is available at the time of this writing. For JSC-1A fine, the TGA-FTIR indicates at least two kinds of water are evolved in the 100 to 500 and the 700 to 900 C ranges. Evolution of carbon dioxide types occurs in the 250 to 545, 545 to 705, and 705 to 985 C ranges. Geologically, the results are consistent with the evolution of "water" in its several forms, CO2 from break down of secondary carbonates and magmatic, dissolved gas and glass recrystallization

Street, Kenneth W., Jr.↗

NASA NTRS2012

Predicting the Sources and Formation Mechanisms of Evolved Lunar Crust by Linking K/Ca Ratios of Lunar Granites to Analogous Terrestrial Igneous Rocks

Although silicic rocks (i.e. granites and rhyolites) comprise a minor component of the sampled portion of the lunar crust, recent remote sensing studies [e.g., 1-4] indicate that several un-sampled regions of the Moon have significantly higher concentrations of silicic material (also high in [K], [U], and [Th]) than sampled regions. Within these areas are morphological features that are best explained by the existence of chemically evolved volcanic rocks. Observations of silicic domes [e.g., 1-5] suggest that sizable networks of silicic melt were present during crust formation. Isotopic data indicate that silicic melts were generated over a prolonged timespan from 4.3 to 3.9 Ga [e.g., 6-8]. The protracted age range and broad distribution of silicic rocks on the Moon indicate that their petrogenesis was an important mechanism for secondary crust formation. Understanding the origin and evolution of such silicic magmas is critical to determining the composition of the lunar crustal highlands and will help to distinguish between opposing ideas for the Moon's bulk composition and differentiation. The two main hypotheses for generating silicic melts on Earth are fractional crystallization or partial melting. On the Moon silicic melts are thought to have been generated during extreme fractional crystallization involving end-stage silicate liquid immiscibility (SLI) [e.g. 9, 10]. However, SLI cannot account for the production of significant volumes of silicic melt and its wide distribution, as reported by the remote global surveys [1, 2, 3]. In addition, experimental and natural products of SLI show that U and Th, which are abundant in the lunar granites and seen in the remote sensing data of the domes, are preferentially partitioned into the depolymerized ferrobasaltic magma and not the silicic portion [11, 12]. If SLI is not the mechanism that generated silicic magmas on the Moon then alternative processes such as fractional crystallization (only crystal-liquid separation) or partial melting should be considered as viable possibilities to be tested.

Mills, R. D.↗

NASA NTRS1988

Mobile lidar system for measurement of water vapor mixing ratio and ozone number density

The Water Vapor Lidar was modified and extended to make differential absorption measurements of ozone. Water vapor measurements make use of a weak molecular scattering process known as Raman scattering. It is characterized by a shift in wavelength of the scattered beam of light relative to the incident one. Some of the energy of the incident photon is converted to vibrational or rotational energy within the molecule leaving the scattered photon shifted to a slightly longer wavelength. When performing water vapor measurements, profiles are acquired of water vapor mixing ratio from near the ground to beyond 7 km every 2 minutes. By forming a color composite image of the individual profiles, the spatial and temporal evolution of water vapor is visible with vertical resolution of 75 to 150m and temporal resolution of 2 minutes. The ozone lidar is intended for use as a cross calibration facility for other stationary ozone lidar systems. The ozone measurement employs the technique known as differential absorption. The backscattered laser radiation from two different wavelengths is measured. Successful measurements of 308 nm returns were made from 80 km with an averaging period of 6 hours. Using these data and a standard atmosphere density curve, an ozone number density profile was made which agrees very well with the standard ozone curve between 20 and 40 km.

Whiteman, D.↗

NASA NTRS1992

A differential CDM model for fatigue of unidirectional metal matrix composites

A multiaxial, isothermal, continuum damage mechanics (CDM) model for fatigue of a unidirectional metal matrix composite volume element is presented. The model is phenomenological, stress based, and assumes a single scalar internal damage variable, the evolution of which is anisotropic. The development of the fatigue damage model, (i.e., evolutionary law) is based on the definition of an initially transversely isotropic fatigue limit surface, a static fracture surface, and a normalized stress amplitude function. The anisotropy of these surfaces and function, and therefore the model, is defined through physically meaningful invariants reflecting the local stress and material orientation. This transversely isotropic model is shown, when taken to it's isotropic limit, to directly simplify to a previously developed and validated isotropic fatigue continuum damage model. Results of a nondimensional parametric study illustrate (1) the flexibility of the present formulation in attempting to characterize a class of composite materials, and (2) the capability of the formulation in predicting anticipated qualitative trends in the fatigue behavior of unidirectional metal matrix composites. Also, specific material parameters representing an initial characterization of the composite system SiC/Ti 15-3 and the matrix material (Ti 15-3) are reported.

Arnold, S. M.↗

NASA NTRSDate not supplied

Life Finds A Way, the Dynamics of E. Coli Evolution in Microgravity

Investigating the evolutionary dynamics of Escherichia coli in microgravity offers a unique opportunity to understand microbial adaptation to extreme environments. Here, we explored the effects of simulated microgravity (SµG) on gene expression and genome evolution of Escherichia coli REL606, a strain continuously evolved and documented terrestrially for 35 years. We used transcriptomic profiling over a 24-hour growth cycle to examine how short-term exposure to SµG under glucose-limiting and glucose-replete conditions may influence the genetic adaptations in microbial populations. Pathway analyses of differentially expressed genes suggest that SµG may alter cell membrane structure and function across all conditions, while changes to protein synthesis machinery were uniquely observed in glucose-replete samples. Furthermore, altered expression of several prophage genes across conditions in SµG samples and upregulation of general stress response factors hints at the potential for stress-induced mutagenesis in response to microgravity. We further investigated the impact of long-term exposure to SµG on genome evolution and observed a more rapid accumulation of base substitutions and deletions in SµG sample genomes across time. Specifically, mutations in the mraZ and elyC genes suggest a mechanism for increased production of peptidoglycan in the cell membrane. These findings offer insights into bacterial adaptations in long-term microgravity environments and pave the way for further detailed investigations.

Brittney Lozzi↗

NASA NTRS2000

A Composite View of Ozone Evolution in the 1995-1996 Northern Winter Polar Vortex Developed from Airborne Lidar and Satellite Observations

The processes which contribute to the ozone evolution in the high latitude northern lower stratosphere are evaluated using a three dimensional model simulation and ozone observations. The model uses winds and temperatures from the Goddard Earth Observing System Data Assimilation System. The simulation results are compared with ozone observations from three platforms: the differential absorption lidar (DIAL) which was flown on the NASA DC-8 as part of the Vortex Ozone Transport Experiment; the Microwave Limb Sounder (MLS); the Polar Ozone and Aerosol Measurement (POAM II) solar occultation instrument. Time series for the different data sets are consistent with each other, and diverge from model time series during December and January. The model ozone in December and January is shown to be much less sensitive to the model photochemistry than to the model vertical transport, which depends on the model vertical motion as well as the model vertical gradient. We evaluate the dependence of model ozone evolution on the model ozone gradient by comparing simulations with different initial conditions for ozone. The modeled ozone throughout December and January most closely resembles observed ozone when the vertical profiles between 12 and 20 km within the polar vortex closely match December DIAL observations. We make a quantitative estimate of the uncertainty in the vertical advection using diabatic trajectory calculations. The net transport uncertainty is significant, and should be accounted for when comparing observations with model ozone. The observed and modeled ozone time series during December and January are consistent when these transport uncertainties are taken into account.

Douglass, A. R.↗

DOE OSTI2024

Cosmic neutrino decoupling and its observable imprints: insights from entropic-dual transport

Abstract Very different processes characterize the decoupling of neutrinos to form the cosmic neutrino background (CνB) and the much later decoupling of photons from thermal equilibrium to form the cosmic microwave background (CMB). The CνB emerges from the fuzzy, energy-dependent neutrinosphere and encodes the physics operating in the early universe in the temperature rangeT∼ 10 MeV toT∼ 10 keV. This is the epoch where beyond Standard Model (BSM) physics, especially in the neutrino sector, may be influential in setting the light element abundances, the necessarily distorted fossil neutrino energy spectra, and other light particle energy density contributions. Here we use techniques honed in extensive CMB studies to analyze the CνB as calculated in detailed neutrino energy transport and nuclear reaction simulations of the protracted weak decoupling and primordial nucleosynthesis epochs. Our moment method, relative entropy, and differential visibility approach can leverage future high precision CMB and light element primordial abundance measurements to provide new insights into the CνB and any BSM physics it encodes. We demonstrate that the evolution of the energy spectrum of the CνB throughout the weak decoupling epoch is accurately captured in the Standard Model by only three parameters per species, a non-trivial conclusion given the deviation from thermal equilibrium and the impact of the decrease of electron-positron pairs. Furthermore, we can interpret each of the three parameters as physical characteristics of a non-equilibrium system. Though the treatment presented here makes some simplifying assumptions including ignoring neutrino flavor oscillations, the success of our compact description within the Standard Model motivates its use also in BSM scenarios. We further demonstrate how observations of primordial light element abundances can be used to place constraints on the CνB energy spectrum, deriving response functions that can be applied for general deviations from a thermal spectrum. Combined with the description of those deviations that we develop here, our methods provide a convenient and powerful framework to constrain the impact of BSM physics on the CνB.

Astronomy & Astrophysics↗

NASA NTRS1981

A turbulent origin for the rotation of molecular clouds

The observed rotational properties of dark clouds are shown to be consistent with the turbulent character of the interstellar medium. The turbulent flow is easily maintained by the shearing action of differential galactic rotation. The size distribution of molecular clouds inferred from observations is found to closely resemble a Kolmogorov turbulent spectrum. These findings suggest that the processes leading to the formation and evolution of such clouds may depend strongly on the properties and characteristics of interstellar turbulence.

Fleck, R. C., Jr.↗

NASA NTRS1995

Shear-induced opening of the coronal magnetic field

This work describes the evolution of a model solar corona in response to motions of the footpoints of its magnetic field. The mathematics involved is semianalytic, with the only numerical solution being that of an ordinary differential equation. This approach, while lacking the flexibility and physical details of full MHD simulations, allows for very rapid computation along with complete and rigorous exploration of the model's implications. We find that the model coronal field bulges upward, at first slowly and then more dramatically, in response to footpoint displacements. The energy in the field rises monotonically from that of the initial potential state, and the field configuration and energy appraoch asymptotically that of a fully open field. Concurrently, electric currents develop and concentrate into a current sheet as the limiting case of the open field is approached. Examination of the equations shows rigorously that in the asymptotic limit of the fully open field, the current layer becomes a true ideal MHD singularity.

Wolfson, Richard↗

NASA NTRS2012

Experimental Fractional Crystallization of the Lunar Magma Ocean

The current paradigm for lunar evolution is of crystallization of a global scale magma ocean, giving rise to the anorthositic crust and mafic cumulate interior. It is thought that all other lunar rocks have arisen from this differentiated interior. However, until recently this paradigm has remained untested experimentally. Presented here are the first experimental results of fractional crystallization of a Lunar Magma Ocean (LMO) using the Taylor Whole Moon (TWM) bulk lunar composition [1].

Rapp, J. F.↗