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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Similarity solutions for phase-change problems

A modification of Ivantsov's (1947) similarity solutions is proposed which can describe phase-change processes which are limited by diffusion. The method has application to systems that have n-components and possess cross-diffusion and Soret and Dufour effects, along with convection driven by density discontinuities at the two-phase interface. Local thermal equilibrium is assumed at the interface. It is shown that analytic solutions are possible when the material properties are constant.

Canright, D.↗
NASA NTRS1990

Satellite sweeping of electrons at Neptune and Uranus

Knowledge of satellite sweeping parameters at Neptune and Uranus, and of their functional dependences on particle energy and pitch angle, can be critical in the proper identification of parent absorbers for observed absorption signatures in regions where OTD (offset, tilted dipole) models are valid representations of the measured magnetic fields. In this paper, critical electron energies are calculated for longitudinal drift resonance, snowplow (i.e., strong) absorption, leapfrog, and corkscrew effects, using a reduced version of OTD that neglects nonaxial dipole offsets. Earlier analytic work on sweeping rates is extended to give the radial dependence of these rates within the minimum-L region and to set limits on diffusion of electrons with the simplifying approximation that leapfrog effects are ignored.

Cooper, John F.↗
NASA NTRS1992

The interaction of atomic oxygen with thin copper films

A source of thermal, ground-state atomic oxygen has been used to expose thin copper films at a flux of 1.4 x 10 exp 17 atoms/sq cm s for times up to 50 min for each of five temperatures between 140 and 200 C. Rutherford backscattering spectroscopy was used to characterize the oxide formed during exposure. The observations are consistent with the oxide phase Cu2O. The time dependence and the temperature dependence of the oxide layer thickness can be described using oxide film growth theory based on rate limitation by diffusion. Within the time and temperature ranges of this study, the growth of the oxide layers is well described by the equation L(T,t) = 3.6 x 10 to 8th exp(- 1.1/2k sub B T)t exp 1/2, where L,T, and t are measured in angstroms, degrees Kelvin, and minutes, respectively. The deduced activation energy is 1.10 +/- 0.15 eV, with the attendant oxidation rate being greater than that for the corresponding reaction in molecular oxygen.

Gibson, B. C.↗
NASA NTRS1992

Experimental investigation of carbonate formation on Mars

If Mars had an early dense CO2 atmosphere (greater than 1 bar), then the transition to the present low pressure (7 mbar) may require carbonate formation without liquid water (e.g., although the early greenhouse has been questioned on the basis that modeled CO2 condensation prevents buildup of such a pressure). Our experiments have focused on the kinetics of such 'dry' reactions. Booth and Kieffer suggested rates consistent with removal of greater than 1 bar of CO2 over geologic time, but their results were questionable since their reactions did not proceed beyond one monolayer of carbonate formed on powdered silicate under martian conditions. Theoretical considerations implied that if nonporous rinds formed, then the rate of carbonate formation would be limited by diffusion, not reaction. Therefore, our experiments optimize reaction conditions to test for continued carbonate production, as well as to verify previous conclusions for initial growth of carbonate.

Stephens, Stuart K.↗
NASA NTRS1994

Modeling of pickup ion distributions in the Halley cometosheath: Empirical limits on rates of ionization, diffusion, loss and creation of fast neutral atoms

The shape of the velocity distribution of water group ions observed by the Giotto ion mass spectrometer on its approach to comet Halley is modeled to derive empirical values for the rates of ionization, energy diffusion, and loss in the midcometosheath. The model includes the effect of rapid pitch angle scattering into a bispherical shell distribution as well as the effect of the magnetization of the plasma on the charge exchange loss rate. It is found that the average rate of ionization of cometary neutrals in this region of the cometosheath appears to be of the order of a factor 3 faster than the `standard' rates approx. 1 x 10(exp -6)/s that are generally assumed to model the observations in most regions of the comet environment. For the region of the coma studied in the present work (approx. 1 - 2 x 10(exp 5) km from the nucleus), the inferred energy diffusion coefficient is D(sub 0) approx. equals 0.0002 to 0.0005 sq km/cu s, which is generally lower than values used in other models. The empirically obtained loss rate appears to be about an order of magnitude greater than can be explained by charge exchange with the `standard' cross section of approx. 2 x 10(exp -15)sq cm. However such cross sections are not well known and for water group ion/water group neutral interactions, rates as high as 8 x 10(exp -15) sq cm have previously been suggested in the literature. Assuming the entire loss rate is due to charge exchange yields a rate of creation of fast neutral atoms of the order of approx. 10(exp -4)/s or higher, depending on the level of velocity diffusion. The fast neutrals may, in turn, be partly responsible for the higher-than-expected ionization rate.

Huddleston, D. E.↗
NASA NTRS2003

A Role of the Reaction Kernel in Propagation and Stabilization of Edge Diffusion Flames of C1-C3 Hydrocarbons

Diffusion flame stabilization is of essential importance in both Earth-bound combustion systems and spacecraft fire safety. Local extinction, re-ignition, and propagation processes may occur as a result of interactions between the flame zone and vortices or fire-extinguishing agents. By using a computational fluid dynamics code with a detailed chemistry model for methane combustion, the authors have revealed the chemical kinetic structure of the stabilizing region of both jet and flat-plate diffusion flames, predicted the flame stability limit, and proposed diffusion flame attachment and detachment mechanisms in normal and microgravity. Because of the unique geometry of the edge of diffusion flames, radical back-diffusion against the oxygen-rich entrainment dramatically enhanced chain reactions, thus forming a peak reactivity spot, i.e., reaction kernel, responsible for flame holding. The new results have been obtained for the edge diffusion flame propagation and attached flame structure using various C1-C3 hydrocarbons.

Takahashi, Fumiaki↗
NASA NTRS1996

Dissolution kinetics of a lunar glass simulant at 25 degrees C: the effect of pH and organic acids

The dissolution kinetics of a simulated lunar glass were examined at pH 3, 5, and 7. Additionally, the pH 7 experiments were conducted in the presence of citric and oxalic acid at concentrations of 2 and 20 mM. The organic acids were buffered at pH 7 to examine the effect of each molecule in their dissociated form. At pH 3, 5, and 7, the dissolution of the synthetic lunar glass was observed to proceed via a two-stage process. The first stage involved the parabolic release of Ca, Mg, Al, and Fe, and the linear release of Si. Dissolution was incongruent, creating a leached layer rich in Si and Ti which was verified by transmission electron microscopy (TEM). During the second stage the release of Ca, Mg, Al, and Fe was linear. A coupled diffusion/surface dissolution model was proposed for dissolution of the simulated lunar glass at pH 3, 5, and 7. During the first stage the initial release of mobile cations (i.e., Ca, Mg, Al, Fe) was limited by diffusion through the surface leached layer of the glass (parabolic release), while Si release was controlled by the hydrolysis of the Si-O-Al bonds at the glass surface (linear release). As dissolution continued, the mobile cations diffused from greater depths within the glass surface. A steady-state was then reached where the diffusion rate across the increased path lengths equalled the Si release rate from the surface. In the presence of the organic acids, the dissolution of the synthetic lunar glass proceeded by a one stage process. The release of Ca, Mg, Al, and Fe followed a parabolic relationship, while the release of Si was linear. The relative reactivity of the organic acids used in the experiments was citrate > oxalate. A thinner leached layer rich in Si/Ti, as compared to the pH experiments, was observed using TEM. Rate data suggest that the chemisorption of the organic anion to the surface silanol groups was responsible for enhanced dissolution in the presence of the organic acids. It is proposed that the increased rate of Si release is responsible for the one stage parabolic release of mobile cations and the relatively thin leached layer compared to experiments at pH 3 and 5.

NASA Discipline Life Support Systems↗
NASA NTRS2007

An Intriguing Convex Break in the EGRET SED of Mrk 421

Based upon analysis of the entire EGRET data from Mrk 421, it is found that the time-averaged spectra are inconsistent with the predictions of current theoretical models that have had success in describing simultaneous X-ray/TeV observations, and suggest additional components in the GeV band, as well as complex time variability. Current theoretical pictures explain the GeV emission as comptonization of the synchrotron photons in the jet, and predict hard spectra that should join smoothly with the TeV emission. Our analysis shows that the situation is more complex. The spectrum ranges from hard to soft during individual epochs, and shows a convext break in the aggregated data. We also present the mission-averaged EGRET spectrum for PKS 2155-304, which shows a similar (but not as pronounced) convex curvature. We discuss a series of possible explanations for the 10(exp 22) - 10(exp 23) HZ declining part of the EGRET nu F(sub nu), spectrum for Mrk 421, and suggest that it is synchrotron emission from the high energy tail of the electron population that produces the X-rays during the highest X-ray states. Such multi-MeV photons are produced by electrons accelerated close to the limit of diffusive shock acceleration. Simultaneous GLAST and X-ray observations of high X-ray states will address the issue of the convex curvature in the future.

Nandikotkur, Giridhar↗
DOE OSTI2023

Compressible foam electrode

A foam electrode comprising surface treatment by the steps of: 1) impregnating soft compressible polymeric foams with a conductive coating via sequential infiltration synthesis and 2) functionalizing the chemically altered voids with an ultrathin redox coating to enhance capacitive deionization (CDI). The redox coating will allow treated foam to absorb ions under the application of a bias, and mechanical compression/decompression. The CDI apparatus uses the void volume of the foam in the uncompressed state to flow liquids through it while the compressed state is used to enhance desalination by limiting the diffusion pathways for the ions to find an adsorption surface.

Young, Matthias John↗
NASA NTRS1975

Kinetics of boron deposition by the hydrogen reduction of boron trichloride

The chemical vapor deposition of boron filament is generally considered to be limited by the diffusion of the reactive species to the hot substrate. From concentration gradient considerations and from experimental measurements it is concluded that the product species (HCl) is more likely to be involved in limiting the deposition rate. Comparison of theoretically calculated and experimentally measured deposition rates show that the rate is generally partially limited by diffusion and partially by the surface reaction rate (desorption) of HCl. The relative amounts of surface reaction or diffusion rate impedance were determined as a function of temperature and gas velocity. The temperature coefficient for the desorption of HCl was found to be 52 Kcal/mole.

Mehalso, R. M.↗
DOE OSTI2025

The dark matter diffused supernova neutrino background

We consider neutrinos scattering off Milky Way dark matter and the impact of this scattering on supernovae neutrinos. This can take the form of attenuation on the initial flux of neutrinos and a time-delayed flux of scattered neutrinos. Considering dark matter masses above 100 MeV and past Milky Way supernovae, we find this time-delayed flux is nearly constant in time. We call this flux the Dark Matter Diffused Supernova Neutrino Background (DMDSNB), and use Super-K limits on the Diffuse Supernova Neutrino Background (DSNB) flux to set limits on the dark matter-neutrino scattering cross section. We find σ DM-ν /m DM ≲ 2.4 × 10 -24 cm 2 /GeV for m DM ≳ 1 GeV, which is the strongest bound to date on dark matter-neutrino scatterings at MeV energies, and stronger than bounds set from SN1987A neutrino attenuation by an order of magnitude. We end by discussing how the DMDSNB could be distinguished from the DSNB.

dark matter theory↗
NASA NTRS1986

Fluctuation and rotation in diffusion-influenced monomolecular reactions

Models of partially absorbing boundaries for calculating diffusion-influenced chemical reactions are examined analytically. The limitations of diffusion-equation and random-walk models are indicated; the presence of an ambiguous length parameter in a standard radiation-boundary-condition (RBC) model is demonstrated; the RBC model for a boundary with oscillation (at a rate much faster than the rate of thermal collisions) between absorbing and nonabsorbing states is considered; an alternative stochastically switching absorber (SSA) model is introduced and shown to be physically consistent; the equivalence of one-dimensional RBC and SSA models under some conditions is shown; one time passage is calculated for an axially symmetric three-dimensional SSA model with anisotropic absorption; and the analogy between rotation and stochastic switching is explored.

Bashford, Donald↗
NASA NTRS1989

A search for X-ray emission associated with the great attractor

A search is reported for X-ray emission associated with the object, dubbed the 'great attractor', which has been postulated as the cause of the coherent deviations from the Hubble flow which are observed in nearby parts of the universe. The hypothesis that a substantial fraction of the dynamical mass of the great attractor exists in the form of rich clusters of galaxies is ruled out. The possibility is considered that a substantial fraction of the mass of the great attractor could exist in a form which would increase the apparently diffuse X-ray surface brightness. The observational upper limit to the diffuse X-ray sky surface brightness enhancement in the general direction of the great attractor allows interesting limits to be set on the fraction of the dynamical mass of the great attractor which can exist in the form of X-ray-luminous material.

Jahoda, Keith↗
DOE OSTI2021

Does inhomogeneous big bang nucleosynthesis produce an inhomogeneous element distribution today?

Inhomogeneous big bang nucleosynthesis (BBN) produces a spatially inhomogeneous distribution of element abundances at $T \sim 10^9$ K , but subsequent element diffusion will tend to erase these inhomogeneities. In this work, we calculate the cosmological comoving diffusion length for the BBN elements. This diffusion length is limited by atomic scattering and is therefore dominated by diffusion when the atoms are neutral, between the redshifts of recombination and reionization. We find that the comoving diffusion length today is $d_{\text{com}} ≈ 70$ pc for all of the elements of interest except 7 Li , for which $d_{\text{com}}$ is an order of magnitude smaller because 7 Li remains ionized throughout the relevant epoch. This comoving diffusion length corresponds to a substellar baryonic mass scale and is roughly equal to the horizon scale at BBN. These results lend support to the possibility that inhomogeneities on scales larger than the horizon at BBN could lead to a spatially inhomogeneous distribution of elements today, while purely subhorizon fluctuations at BBN can result only in a homogeneous element distribution at present.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1985

Middle atmosphere modeling

Breaking gravity waves generate and maintain a background level of turbulence which is capable of producing substantial cooling and/or heating in the upper mesosphere and lower thermosphere. The net thermodynamic effect of breaking gravity waves is critically dependent on the eddy Prandt number (P sub t) applicable to mesospheric turbulence. When P sub t is approximately 1, the calculations of the heat budget for the mesopause region imply that the globally averaged eddy or turbulent diffusion coefficient cannot exceed .000001 sq cm/s. This upper limit on turbulant diffusion applies to both potential temperature transport and chemically inert tracer transport when radiative damping is neglible. For chemically active species larger diffusion coefficients are permitted, because the effective eddy diffusion coefficient is increased by an additive term L/2 gamma (sup 2), where L is the chemical loss rate and gamma is the vertical wavenumber. For P sub t is approximately 4 to 6, the turbulent diffusion of momentum (D sub M) is sufficiently greater than the turbulent diffusion of heat (D sub H) that the conversion of gravity wave energy to heat with high efficiency nearly balances the divergence of the downward eddy heat flux in the wave breaking zone. Therefore the heat budget of the mesopause region would no longer provide a powerful and useful constraint on D sub H. If P sub t exceeds 6 with high efficiency for energy conversion to heat, gravity waves would heat the mesosphere throughout the wave breaking region.

Strobel, D. F.↗
NASA NTRS1997

Strain-Rate-Free Diffusion Flames: Initiation, Properties, and Quenching

For about a half century, the stabilization of a steady planar deflagration on a heat-sink-type flat-flame burner has been of extraordinary service for the theoretical modeling and diagnostic probing of combusting gaseous mixtures. However, most engineering devices and most unwanted fire involve the burning of initially unmixed reactants. The most vigorous burning of initially separated gaseous fuel and oxidizer is the diffusion flame. In this useful idealization (limiting case), the reactants are converted to product at a mathematically thin interface, so no interpenetration of fuel and oxidizer occurs. This limit is of practical importance because it often characterizes the condition of optimal performance (and sometimes environmentally objectionable operation) of a combustor. A steady planar diffusion flame is most closely approached in the laboratory in the counterflow apparatus. The utility of this simple-strain-rate flow for the modeling and probing of diffusion flames was noted by Pandya and Weinberg 35 years ago, though only in the last decade or so has its use become internationally common place. However, typically, as the strain rate a is reduced below about 20 cm(exp -1), and the diffusion-flame limit (reaction rate much faster than the flow rate) is approached, the burning is observed to become unstable in earth gravity. The advantageous steady planar flow is not available in the diffusion-flame limit in earth gravity. This is unfortunate because the typical spatial scale in a counterflow is (k/a)(sup 1/2), where k denotes a characteristic diffusion coefficient; thus, the length scale becomes large, and the reacting flow is particularly amenable to diagnostic probing, as the diffusion-flame limit is approached. The disruption of planar symmetry is owing the fact that, as the strain rate a decreases, the residence time (l/a) of the throughput in the counterflow burner increases. Observationally, when the residence time exceeds about 50 msec, the inevitably present convective (Rayleigh-Benard) instabilities, associated with hot-under-cold (flame-under-fresh-reactant) stratification of fluid in a gravitational field, have time to grow to finite amplitude during transit of the burner.

Fendell, Francis↗
NASA NTRS1986

Far-ultraviolet background observations at high galactic latitude. II - Diffuse emission

A single spectrum, of extremely long integration time, is used to place stringent new limits on the diffuse far-UV background in the 500-1200 A region. This spectrum, obtained in the vicinity of the North Galactic Pole with the Voyager 2 UV spectrometer, can be explained solely on the basis of resonant scattering from interplanetary H I and He I. Limits on any additional sources of sky background radiation corresponding to 100-200 photons/sq cm per sec/sr per A for continuum emission and 6000 photons/sq cm per sec/sr for line emission are demonstrated. Comparisons of these upper limits with existing measurements and various potential source mechanisms are discussed. The first detection of resonantly scattered interplanetary H I Ly-gamma (973 A) emission is reported.

Holberg, J. B.↗