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At least 451 records · Page 25

Final Technical Report for DE-SC0008149

The major goal of this project is to study spin waves in magnetic thin films, especially how spin waves respond to external stimuli. This is expected to lead to new insight into dynamic processes and new ideas for methods to control spin waves. Experimental studies are being done primarily using time- and spatially-resolved Brillouin light scattering (BLS) measurements on extended and patterned magnetic thin films. BLS is a versatile tool that provides a non-invasive probe of spin dynamics with frequencies of ~1 GHz to well over 100 GHz, diffraction-limited spatial resolution, 250-ps temporal resolution, and it is sensitive enough to detect thermal magnons.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Magnetism dynamics driven by phase separation in Pr-doped manganite thin films: A ferromagnetic resonance study

In this work, we performed ferromagnetic resonance measurements of a (La 1–x Pr x ) 1–y Ca y MnO 3–δ with x = 0.52 ± 0.05, y = 0.23 ± 0.04, and δ = 0.14 ± 0.10 thin single crystalline film which, in combination with micromagnetic simulations, reveal three temperature regions consistent with (i) a ferromagnetic-paramagnetic transition in which ferromagnetic domains nucleate and grow, (ii) followed by a filamentary fluidlike percolation of magnetic domains exhibiting dynamic processes and finally, iii) the existence of a blocking temperature below which the magnetism is a metastable glassy-like state with strong decoherence of the uniform resonance mode. Our results suggest a strain-liquid to strain-glass spin order transition in which the magnetism and fluidlike dynamics of the separated phases freeze at low temperatures. We show the magnetism dynamics depend strongly on the phase-separated state and morphology of the magnetic domains suggesting a route to control of phase separation and realization of spintronic and magnonic devices.

36 MATERIALS SCIENCE↗

Long-term variations in abundance and distribution of sulfuric acid vapor in the Venus atmosphere inferred from Pioneer Venus and Magellan radio occultation studies

Radio occultation experiments have been used to study various properties of planetary atmospheres, including pressure and temperature profiles, and the abundance profiles of absorbing constituents in those planetary atmospheres. However, the reduction of amplitude data from such experiments to determine abundance profiles requires the application of the inverse Abel transform (IAT) and numerical differentiation of experimental data. These two operations preferentially amplify measurement errors above the true signal underlying the data. A new technique for processing radio occultation data has been developed that greatly reduces the errors in the derived absorptivity and abundance profiles. This technique has been applied to datasets acquired from Pioneer Venus Orbiter radio occultation studies and more recently to experiments conducted with the Magellan spacecraft. While primarily designed for radar studies of the Venus surface, the high radiated power (EIRP) from the Magellan spacecraft makes it an ideal transmitter for measuring the refractivity and absorptivity of the Venus atmosphere by such experiments. The longevity of the Pioneer Venus Orbiter has made it possible to study long-term changes in the abundance and distribution of sulfuric acid vapor, H2SO4(g), in the Venus atmosphere between 1979 and 1992. The abundance of H2SO4(g) can be inferred from vertical profiles of 13-cm absorptivity profiles retrieved from radio occultation experiments. Data from 1979 and 1986-87 suggest that the abundance of H2SO4(g) at latitudes northward of 70 deg decreased over this time period. This change may be due to a period of active volcanism in the late 1970s followed by a relative quiescent period, or some other dynamic process in the Venus atmosphere. While the cause is not certain, such changes must be incorporated into dynamic models of the Venus atmosphere. Potentially, the Magellan spacecraft will extend the results of Pioneer Venus Orbiter and allow the continued monitoring of the abundance of distribution of H2SO4(g) in the Venus atmosphere, as well as other interesting atmospheric properties. Without such measurements it will be difficult to address other issues such as the short-term spatial variability of the abundance of H2SO4(g) at similar latitudes in Venus atmosphere, and the identities of particles responsible for large-scale variations observed in NIR images.

Jenkins, J. M.↗

Polar ozone

The observation and interpretation of a large, unexpected ozone depletion over Antarctica has changed the international scientific view of stratospheric chemistry. The observations which show the veracity, seasonal nature, and vertical structure of the Antarctic ozone hole are presented. Evidence for Arctic and midlatitude ozone loss is also discussed. The chemical theory for Antarctic ozone depletion centers around the occurrence of polar stratospheric clouds (PSCs) in Antarctic winter and spring; the climatology and radiative properties of these clouds are presented. Lab studies of the physical properties of PSCs and the chemical processes that subsequently influence ozone depletion are discussed. Observations and interpretation of the chemical composition of the Antarctic stratosphere are described. It is shown that the observed, greatly enhanced abundances of chlorine monoxide in the lower stratosphere are sufficient to explain much if not all of the ozone decrease. The dynamic meteorology of both polar regions is given, interannual and interhemispheric variations in dynamical processes are outlined, and their likely roles in ozone loss are discussed.

Solomon, S.↗

Evidence for Interhemispheric Coupling during the Unusual Northern Polar Summer Mesosphere of 2002

Data from the MaCWAVE MIDAS Rocket Program launched during July, 2002, from Andoya Rocket Range (ARR) in Norway have demonstrated that the temperature structure of the summer polar mesosphere during this period was atypical, at least above ARR. The summer polar mesopause region was warmer than normal and of shorter duration than for other years analyzed. Theoretical studies have since been published that imply that the abnormal characteristics of this polar summer were generated by unusual dynamical processes occurring in the southern polar winter hemisphere. We have used data from the SABER instrument aboard the NASA TIMED Satellite to study these characteristics on a global scale and compare them with the features observed in the ensuing seven years. For background, The TIMED Satellite was launched on December 7, 2001 to study the dynamics and energy of the mesosphere and lower thermosphere (MLT). The SABER instrument on TIMED is a limb scanning infrared radiometer designed to measure a large number of minor constituents as well as temperature of the MLT. In this study, we have investigated the temperature characteristics of the polar mesosphere as a function of spatial and temporal considerations. We have used the most recent SABER dataset (1.07) that includes the improved temperature retrievals in Earth polar regions, Weekly averages were used 10 make the comparisons between the winter and summer hemispheres. The unusually short polar summer in the northern hemisphere during 2002 is clearly defined by this analysis and is shown to be unique for the 7 years analyzed. Furthermore, the data analysis agrees with recent theoretical studies showing that this behavior is a result of anomalous heating events in the southern polar stratosphere. The time sequence of the coupling process, as predicted by recent theoretical models, is well defined in a sequence of weekly temperature contour maps measured by SABER.

Goldberg, Richard A.↗

Review: mechanical behavior of metal/ceramic interfaces in nanolayered composites—experiments and modeling

In this study, recent experimental and modeling studies in nanolayered metal/ceramic composites are reviewed, with focus on the mechanical behaviors of metal/nitrides interfaces. The experimental and modeling studies of the slip systems in bulk TiN are reviewed first. Then, the experimental studies of interfaces, including co-deformation mechanism by micropillar compression tests, in situ TEM straining tests for the dynamic process of the co-deformation, thickness-dependent fracture behavior, and interrelationship among the interfacial bonding, microstructure, and mechanical response, are reviewed for the specific material systems of Al/TiN and Cu/TiN multilayers at nanoscale. The modeling studies reviewed cover first-principles density functional theory-based modeling, atomistic molecular dynamics simulations, and mesoscale modeling of nanolayered composites using discrete dislocation dynamics. The phase transformation between zinc-blende and wurtzite AlN phases in Al/AlN multilayers at nanoscale is also reviewed. Finally, a summary and perspective of possible research directions and challenges are given.

36 MATERIALS SCIENCE↗

On the seat of the solar cycle

A discussion of some of the issues raised in connection with the seat of the solar cycle are presented. Is the cycle controlled by a strictly periodic oscillator that operates in the core, or is it a turbulent dynamo confined to the convection zone and possibly a thin boundary layer beneath it? Sunspot statistics are discussed, with a view to ascertaining the length of the memory of the cycle, without drawing a definitive conclusion. Also discussed are some of the processes that might bring about variations delta L and delta R in the luminosity and the radius of the photosphere. It appears that the ratio W = delta lnR/delta lnL increases with the depth of the disturbance that produces the variations, so that imminent observations might determine whether or not the principal dynamical processes are confined to only the outer layers of the Sun.

Gough, D.↗

Pinatubo eruption winter climate effects: Model versus observations

Large volcanic eruptions, in addition to the well-known effect of producing global cooling for a year or two, have been observed to produce shorter-term responses in the climate system involving non-linear dynamical processes. In this paper, we use the ECHAM2 general circulation model forced with stratospheric aerosols to test some of these ideas. Run in a perpetual-January mode, with tropical stratospheric heating from the volcanic aerosols typical of the 1982 El Chichon eruption or the 1991 Pinatubo eruption, we find a dynamical response with an increased polar night jet in the Northern Hemisphere (NH) and stronger zonal winds which extended down into the troposphere. The Azores High shifts northward with increased tropospheric westerlies at 60N and increased easterlies at 30N. Surface temperatures are higher both in northern Eurasia and North America, in agreement with observations for the NH winters or 1982-83 and 1991-92 as well as the winters following the other 10 largest volcanic eruptions since 1883.

Graf, HANS-F.↗

History of Thermally Processed Solids in the Protoplanetary Disk: Reconciling Theoretical Models and Meteoritical Evidence

In this talk we assess theoretical models of the radial, temporal, and thermal evolution of nebula solids, and their ultimate accretion into planetesimals such as we see today, using meteorite evidence as a guide. Each class of chondrites contains a characteristic suite of chondrules and CAIs that may have formed over a period of several Myr during which planetesimals were accreting in the disk. Details of the various models for transient melting of chondrules and igneous CAIs will be left to others. However, high-temperature processes of different kinds evaporation, alteration, etc did affect these constituents and their environment over this time span. Here we describe evolutionary scenarios consistent with a large time gap between CAI and chondrule formation and the presence of distinctive suites of chondrules and CAIs in each chondrite class. Particle-gas dynamical processes transport particles of all relevant sizes (microns to many meters) within the nebula and affect their evolution in a variety of important ways. Turbulent radial diffusion spreads particles radially down their concentration gradients - as one example, it can prevent CAIs from being lost into the sun on several Myr timescales [1]. Vertical diffusion spreads the dense midplane particle layer, determining its volume density, which in turn affects the particle growth rate and even the dominant growth process [2-4]. Turbulent concentration selects aerodynamically sorted particles for orders-of-magnitude density enhancement, and is applicable to porous, fluffy particles of appropriate size as well as to solid chondrules [5]. Inward radial drift under gas drag brings a surprisingly large amount of material to regions where it evaporates; these evaporation fronts cause significant chemical modification of the nebula gas over a wide range of radii [6]. Radial transport by stellar winds can be important for small particles [7].

Cuzzi, J. N.↗

Inter-Hemispheric Coupling During Recent North Polar Summer Periods as Predicted by MaCWAVE/MIDAS Rocket Data and Traced by TIMED/SABER Measurements

In July, 2002, the MaCWAVE-MIDAS Rocket Program was launched from And0ya Rocket Range (ARR) in Norway. Data from these flights demonstrated that the polar summer mesosphere during this period was unusual, at least above ARR. Theoretical studies have since been published that imply that the abnormal characteristics of this polar summer were generated by dynamical processes occurring in the southern polar winter hemisphere. We have used data from the SABER instrument aboard the NASA TIMED Satellite to study these characteristics and compare them with the features observed in the ensuing eight years. For background, the TIMED Satellite was launched on December 7, 2001 to study the dynamics and energy of the mesosphere and lower thermosphere. The SABER instrument is a limb scanning infrared radiometer designed to measure temperature of the region as well as a large number of minor constituents. In this study, we review the MaCWAVE rocket results. Next, we investigate the temperature characteristics of the polar mesosphere as a function of spatial and temporal considerations. We have used the most recent SABER dataset (1.07). Weekly averages are used to make comparisons between the winter and summer hemispheres. Furthermore, the data analysis agrees with recent theoretical studies showing that this behavior is a result of anomalous dynamical events in the southern hemisphere. The findings discussed here clearly show the value of scientific rocket flights used in a discovery mode.

Goldberg, Richard A.↗

A sub-sampled approach to extremely low-dose STEM

The inpainting of deliberately and randomly sub-sampled images offers a potential means to image specimens at a high resolution and under extremely low-dose conditions (≤1 e - /Å 2 ) using a scanning transmission electron microscope. We show that deliberate sub-sampling acquires images at least an order of magnitude faster than conventional low-dose methods for an equivalent electron dose. More importantly, when adaptive sub-sampling is implemented to acquire the images, there is a significant increase in the resolution and sensitivity which accompanies the increase in imaging speed. Lastly, we demonstrate the potential of this method for beam sensitive materials and in-situ observations by experimentally imaging the node distribution in a metal-organic framework.

47 OTHER INSTRUMENTATION↗

Removing the Effects of Tropical Dynamics from North Pacific Climate Variability

Teleconnections from the Tropics energize variations of the North Pacific climate, but detailed diagnosis of this relationship has proven difficult. Simple univariate methods, such as regression on El Niño-Southern Oscillation (ENSO) indices, may be inadequate since the key dynamical processes involved -- including ENSO diversity in the Tropics, re-emergence of mixed layer thermal anomalies, and oceanic Rossby wave propagation in the North Pacific -- have a variety of overlapping spatial and temporal scales. Here we use a multivariate Linear Inverse Model to quantify tropical and extra-tropical multi-scale dynamical contributions to North Pacific variability, in both observations and CMIP6 models. In observations, we find that the Tropics are responsible for almost half of the seasonal variance, and almost three quarters of the decadal variance, along the North American coast and within the subtropical front region northwest of Hawaii. SST anomalies that are generated by local dynamics within the Northeast Pacific have much shorter time scales, consistent with transient weather forcing by Aleutian low anomalies. Variability within the Kuroshio-Oyashio Extension (KOE) region is considerably less impacted by the Tropics, on all time scales. Consequently, without tropical forcing the dominant pattern of North Pacific variability would be a KOE pattern, rather than the Pacific Decadal Oscillation (PDO). In contrast to observations, most CMIP6 historical simulations produce North Pacific variability that maximizes in the KOE region, with amplitude significantly higher than observed. Correspondingly, the simulated North Pacific in all CMIP6 models is shown to be relatively insensitive to the Tropics, with a dominant spatial pattern generally resembling the KOE pattern, not the PDO.

54 ENVIRONMENTAL SCIENCES↗

Magnetohydrodynamic Convection in the Outer Core and its Geodynamic Consequences

The Earth's fluid outer core is in vigorous convection through much of the Earth's history. In addition to generating and maintaining Earth s time-varying magnetic field (geodynamo), the core convection also generates mass redistribution in the core and a dynamical pressure field on the core-mantle boundary (CMB). All these shall result in various core-mantle interactions, and contribute to surface geodynamic observables. For example, electromagnetic core-mantle coupling arises from finite electrically conducting lower mantle; gravitational interaction occurs between the cores and the heterogeneous mantle; mechanical coupling may also occur when the CMB topography is aspherical. Besides changing the mantle rotation via the coupling torques, the mass-redistribution in the core shall produce a spatial-temporal gravity anomaly. Numerical modeling of the core dynamical processes contributes in several geophysical disciplines. It helps explain the physical causes of surface geodynamic observables via space geodetic techniques and other means, e.g. Earth's rotation variation on decadal time scales, and secular time-variable gravity. Conversely, identification of the sources of the observables can provide additional insights on the dynamics of the fluid core, leading to better constraints on the physics in the numerical modeling. In the past few years, our core dynamics modeling efforts, with respect to our MoSST model, have made significant progress in understanding individual geophysical consequences. However, integrated studies are desirable, not only because of more mature numerical core dynamics models, but also because of inter-correlation among the geophysical phenomena, e.g. mass redistribution in the outer core produces not only time-variable gravity, but also gravitational core-mantle coupling and thus the Earth's rotation variation. They are expected to further facilitate multidisciplinary studies of core dynamics and interactions of the core with other components of the Earth.

Kuang, Weijia↗

An Ab Initio Multiple Cloning Method for Non-Adiabatic Excited-State Molecular Dynamics in NWChem

The recently developed ab-initio multiple cloning (AIMC) approach based on the multicongurational Ehrenfest (MCE) method provides a powerful and accurate way of describing the excited-state dynamics of molecular systems. The AIMC method is a controlled approximation to non-adiabatic dynamics with a particular strength in the proper description of decoherence effects due to branching of vibrational wavepackets at a level crossing. In this work, we report a new implementation of the AIMC algorithm in the open source NWChem computational chemistry program. The framework combines linear-response time-dependent density functional theory with Ehrenfest mean-eld theory to determine the equations of motion for classical trajectories. The multi-dimensional wave function is decomposed into a superposition of Gaussian coherent states guided by Ehrenfest trajectories (i.e., MCE approach), which can clone with fully quantum mechanical amplitudes and phases. By using an efficient time-derivative based non-adiabatic coupling approach within the AIMC method, all observable are calculated on-the-y in the non-adiabatic molecular dynamics process. As a representative example, we apply our implementation to study the ultrafast photoinduced electronic and vibrational energy transfer in a pyridine molecule. The effects of the cloning procedure on electronic and vibrational coherence, relaxation and unidirectional energy transfer are discussed. This new AIMC implementation provides a high-level non-adiabatic molecular dynamics framework for simulating photoexcited dynamics in complex molecular systems and experimentally relevant ultrafast spectroscopic probes, such as nonlinear coherent optical and X-ray signals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Thermospheric composition

The global view of the atmosphere provided by satellite observations and radar backscatter measurements has shown a pattern of composition variability resulting largely from dynamic processes. Important progress has been made in defining composition variability at 120 km, which has greatly improved models which previously had fixed boundary conditions at that altitude. The discovery of the early morning maximum in helium abundance and the better definition of diurnal variation in relative composition have provided a basis for more sophisticated dynamical models. Similarly, models of meridional wind systems have been developed which can account for the better-defined winter enhancements in helium and atomic oxygen. Finally, composition variability has indicated the presence of a high-latitude heat source which during periods of magnetic activity profoundly modifies the state of the atmosphere.

Carignan, G. R.↗

The multiple nesting of mesoscale, submesoscale, and nonhydrostatic microscale numerical models for a case of mesocyclogenesis and severe storm development

A fundamental approach involving the integration of two different numerical models over several different spatial mesh lengths is considered. Model I is a hydrostatic, incompressible, and adiabatic primitive (Newtonian) equation set with no boundary layer forcing, i.e., surface heat or moisture flux or external frictional stresses. Typically this model is initialized from conventional radiosonde data and run for a 12-15 hour forecast period over a 40 km horizontal mesh. If phase I of the tornado developmental processes develops, the data is 'frozen' in space and time, interpolated to a 20 km mesh, and integrated for a shorter time period (3 hours) with a shorter time step. Model II is a nonhydrostatic compressible 18-level complement of model I. If model II indicates the development of the intensification of phase V dynamical processes, the data is frozen and interpolated to finer mesh lengths until the tornadic circulation system is approximated

Kaplan, M. L.↗

Neural processing of gravity information

The goal of this project was to use the linear acceleration capabilities of the NASA Vestibular Research Facility (VRF) at Ames Research Center to directly examine encoding of linear accelerations in the vestibular system of the cat. Most previous studies, including my own, have utilized tilt stimuli, which at very low frequencies (e.g., 'static tilt') can be considered a reasonably pure linear acceleration (e.g., 'down'); however, higher frequencies of tilt, necessary for understanding the dynamic processing of linear acceleration information, necessarily involves rotations which can stimulate the semicircular canals. The VRF, particularly the Long Linear Sled, has promise to provide controlled pure linear accelerations at a variety of stimulus frequencies, with no confounding angular motion.

Schor, Robert H.↗

Improving Global Mass Flux Solutions from Gravity Recovery and Climate Experiment (GRACE) Through Forward Modeling and Continuous Time Correlation

We describe Earth's mass flux from April 2003 through November 2008 by deriving a time series of mas cons on a global 2deg x 2deg equal-area grid at 10 day intervals. We estimate the mass flux directly from K band range rate (KBRR) data provided by the Gravity Recovery and Climate Experiment (GRACE) mission. Using regularized least squares, we take into account the underlying process dynamics through continuous space and time-correlated constraints. In addition, we place the mascon approach in the context of other filtering techniques, showing its equivalence to anisotropic, nonsymmetric filtering, least squares collocation, and Kalman smoothing. We produce mascon time series from KBRR data that have and have not been corrected (forward modeled) for hydrological processes and fmd that the former produce superior results in oceanic areas by minimizing signal leakage from strong sources on land. By exploiting the structure of the spatiotemporal constraints, we are able to use a much more efficient (in storage and computation) inversion algorithm based upon the conjugate gradient method. This allows us to apply continuous rather than piecewise continuous time-correlated constraints, which we show via global maps and comparisons with ocean-bottom pressure gauges, to produce time series with reduced random variance and full systematic signal. Finally, we present a preferred global model, a hybrid whose oceanic portions are derived using forward modeling of hydrology but whose land portions are not, and thus represent a pure GRACE-derived signal.

Sabaka, T. J.↗