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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

In situ recombination junction between p-Si and TiO 2 enables high-efficiency monolithic perovskite/Si tandem cells

Increasing the power conversion efficiency of silicon (Si) photovoltaics is a key enabler for continued reductions in the cost of solar electricity. Here, we describe a two-terminal perovskite/Si tandem design that increases the Si cell’s output in the simplest possible manner: by placing a perovskite cell directly on top of the Si bottom cell. The advantageous omission of a conventional interlayer eliminates both optical losses and processing steps and is enabled by the low contact resistivity attainable between n-type TiO 2 and Si, established here using atomic layer deposition. We fabricated proof-of-concept perovskite/Si tandems on both homojunction and passivating contact heterojunction Si cells to demonstrate the broad applicability of the interlayer-free concept. Stabilized efficiencies of 22.9 and 24.1% were obtained for the homojunction and passivating contact heterojunction tandems, respectively, which could be readily improved by reducing optical losses elsewhere in the device. This work highlights the potential of emerging perovskite photovoltaics to enable low-cost, high-efficiency tandem devices through straightforward integration with commercially relevant Si solar cells.

59 BASIC BIOLOGICAL SCIENCES↗

Potentialities of TEC topping: A simplified view of parametric effects

An examination of the benefits of thermionic-energy-conversion (TEC)-topped power plants and methods of increasing conversion efficiency are discussed. Reductions in the cost of TEC modules yield direct decreases in the cost of electricity (COE) from TEC-topped central station power plants. Simplified COE, overall-efficiency charts presented illustrate this trend. Additional capital-cost diminution results from designing more compact furnaces with considerably increased heat transfer rates allowable and desirable for high temperature TEC and heat pipes. Such improvements can evolve of the protection from hot corrosion and slag as well as the thermal expansion compatibilities offered by silicon-carbide clads on TEC-heating surfaces. Greater efficiencies and far fewer modules are possible with high-temperature, high-power-density TEC: This decreases capital and fuel costs much more and substantially increases electric power outputs for fixed fuel inputs. In addition to more electricity, less pollution, and lower costs, TEC topping used directly in coal-combustion products contributes balance-of-payment gains.

Morris, J. F.↗

Refractive Secondary Concentrators for Solar Thermal Applications

The NASA Glenn Research Center is developing technologies that utilize solar energy for various space applications including electrical power conversion, thermal propulsion, and furnaces. Common to all of these applications is the need for highly efficient, solar concentration systems. An effort is underway to develop the innovative single crystal refractive secondary concentrator, which uses refraction and total internal reflection to efficiently concentrate and direct solar energy. The refractive secondary offers very high throughput efficiencies (greater than 90%), and when used in combination with advanced primary concentrators, enables very high concentration ratios (10,0(X) to 1) and very high temperatures (greater than 2000 K). Presented is an overview of the refractive secondary concentrator development effort at the NASA Glenn Research Center, including optical design and analysis techniques, thermal modeling capabilities, crystal materials characterization testing, optical coatings evaluation, and component testing. Also presented is a discussion of potential future activity and technical issues yet to be resolved. Much of the work performed to date has been in support of the NASA Marshall Space Flight Center's Solar Thermal Propulsion Program. The many benefits of a refractive secondary concentrator that enable efficient, high temperature thermal propulsion system designs, apply equally well to other solar applications including furnaces and power generation systems such as solar dynamics, concentrated thermal photovoltaics, and thermionics.

Wong, Wayne A.↗

Test Results from a High Power Linear Alternator Test Rig

Stirling cycle power conversion is an enabling technology that provides high thermodynamic efficiency but also presents unique challenges with regard to electrical power generation, management, and distribution. The High Power Linear Alternator Test Rig (HPLATR) located at the NASA Glenn Research Center (GRC) in Cleveland, OH is a demonstration test bed that simulates electrical power generation from a Stirling engine driven alternator. It implements the high power electronics necessary to provide a well regulated DC user load bus. These power electronics use a novel design solution that includes active rectification and power factor control, active ripple suppression, along with a unique building block approach that permits the use of high voltage or high current alternator designs. This presentation describes the HPLATR, the test program, and the operational results.

Birchenough, Arthur G.↗

Test Results From a High Power Linear Alternator Test Rig

Stirling cycle power conversion is an enabling technology that provides high thermodynamic efficiency but also presents unique challenges with regard to electrical power generation, management, and distribution. The High Power Linear Alternator Test Rig (HPLATR) located at the NASA Glenn Research Center (GRC) in Cleveland, Ohio is a demonstration test bed that simulates electrical power generation from a Stirling engine driven alternator. It implements the high power electronics necessary to provide a well regulated DC user load bus. These power electronics use a novel design solution that includes active rectification and power factor control, active ripple suppression, along with a unique building block approach that permits the use of high voltage or high current alternator designs. This report describes the HPLATR, the test program, and the operational results.

Birchenough, Arthur G.↗

Development and evaluation of a collection apparatus for recoil products for study of the deexcitation process of {sup 235m}U

The nucleus {sup 235m}U is an isomer with extremely low excitation energy (76.8 eV) and decays dominantly through the internal conversion (IC) process. Because outer-shell electrons are involved in the IC process, the decay constant of {sup 235m}U depends on its chemical environment. We plan to study the deexcitation process of {sup 235m}U by measuring the energy spectra of IC electrons in addition to the decay constants for various chemical forms. In this paper, the preparation method of {sup 235m}U samples from {sup 239}Pu by using alpha-recoil energy is reported. A Collection Apparatus for Recoil Products was fabricated, and then collection efficiencies under various conditions were determined by collecting {sup 224}Ra recoiling out of {sup 228}Th electrodeposited and precipitated sources. The pressure in the apparatus (vacuum or 1 atm of N{sub 2} gas) affected the variations of the collection efficiencies depending on the negative voltage applied to the collector. The maximum values of the collection efficiencies were mainly affected by the thickness of the {sup 228}Th sources. From these results, the suitable conditions of the {sup 239}Pu sources for preparation of {sup 235m}U were determined. In addition, dissolution efficiencies were determined by washing collected {sup 224}Ra with solutions. When {sup 224}Ra was collected in 1 atm of N{sub 2} gas and dissolved with polar solutions such as water, the dissolution efficiencies were nearly 100%. The method of rapid dissolution of recoil products would be applicable to rapid preparation of short-lived {sup 235m}U samples for various chemical forms.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Levelized-Cost-of-Electricity-Driven Design Optimization for Medium-Voltage Transformerless Photovoltaic Converters

Design approaches for power electronics are typically focused on efficiency and power density; however, these strategies do not guarantee cost optimality in any well-defined sense. To overcome this shortcoming, we propose a design framework that yields circuit parameters that minimize the levelized cost of electricity (LCOE) of a generation system. LCOE serves as a meaningful metric since it captures total lifetime costs - including hardware, balance of system, and maintenance costs - and includes the impacts of power conversion efficiency and revenue from harvested energy. To obtain a tractable design problem, we formulate an approximate LCOE improvement model that quantifies the changes in LCOE resulting from a candidate converter design. We apply this framework to a multilevel cascaded topology for low-voltage dc to medium-voltage ac conversion without line-frequency transformers. An example 200 kW commercial-scale system is studied and the solution yields a design with 15 cascaded stages, 98.01% efficiency, and an LCOE reduction of 2.0%.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Enabling Ultra-Compact, Lightweight, Efficient, and Reliable 6.6 kW On-Board Bi-Directional Electric Vehicle Charger with Advanced Topology and Control

The research explored new topologies, control methods, mechanical integration, and thermal management methods for electric vehicle (EV) on-board chargers. The team investigated capacitor-based power conversion, leveraging the high energy densities inherent to capacitive energy storage compared to inductive methods. The proposed topologies simultaneously enabled high power density and high efficiency of the design. The proposed architecture was demonstrated in a 6.6 kW bi-directional charger prototype. The research pursued several directions to improve system performance. Innovative topologies were studied for both the main power conversion stage as well as the single-phase twice-line-frequency energy buffer. To ensure robust and efficient operation, new control methods were developed to integrate these two subsystems. To achieve high power density in the full system solution, the mechanical structure of the charger is highly optimized to maximally fill the converter box volume. In parallel with the mechanical design effort, the converter was packaged with high-performance cooling methods which removed heat from key areas of power dissipation in the converter. The thermal management system was optimized to minimize its weight and volume, ultimately motivating the design of a custom additively manufactured cold-plate. The full system achieves a peak power of 7 kW with less than 0.3% total harmonic distortion (THD) and greater than 0.994 power factor in power factor correction (PFC) operation, corresponding to a total box-volume power density of 47.9 kW/L and gravimetric power density of 24.6 W/g. The system achieves a peak efficiency of 98.9%, with 97.9% efficiency at maximum power.

33 ADVANCED PROPULSION SYSTEMS↗

The dish-Rankine SCSTPE program (Engineering Experiment no. 1)

Activities planned for phase 2 Of the Small Community Solar Thermal Power Experiment (PFDR) program are summarized with emphasis on a dish-Rankine point focusing distributed receiver solar thermal electric system. Major design efforts include: (1) development of an advanced concept indirect-heated receiver;(2) development of hardware and software for a totally unmanned power plant control system; (3) implementation of a hybrid digital simulator which will validate plant operation prior to field testing; and (4) the acquisition of an efficient organic Rankine cycle power conversion unit. Preliminary performance analyses indicate that a mass-produced dish-Rankine PFDR system is potentially capable of producing electricity at a levelized busbar energy cost of 60 to 70 mills per KWh and with a capital cost of about $1300 per KW.

Pons, R. L.↗

Improving reliability and reducing cost in CdTe photovoltaics via grain boundary engineering

A key pathway toward achieving the SunShot 2030 goals for thin films devices is to increase the overall module efficiency and reliability. Photovoltaic devices based on polycrystalline CdTe thin films are the leading candidate, followed closely by Si, that have achieved the 2020 SunShot target of $\$0.05$/kWh. However, to reach the goal for the levelized cost of electricity (LCOE) of less than $\$0.03$/kWh by 2030, several fundamental problems of CdTebased devices will need to be addressed: i) low Voc and conversion efficiencies of even the best research cell, ii) large variability of individual cell performances manufactured under identical conditions, and iii) degradation of cell performance within the first few years of operation in the field.

14 SOLAR ENERGY↗

VASIMR{sup R} Interfaced High Temperature Gas-Cooled Fast Reactor for Space Applications

This project was undertaken to assess the feasibility and advantages of utilizing a gas-cooled fast reactor to supply power to an electric propulsion system for deep space exploration to Europa, one of Jupiter's moons. Specifically, the primary objective of this project was to design a 9 MWe gas cooled fast reactor with an accompanying power conversion system to supply electricity to multiple electrically-powered thrusters for a four year mission duration. The thruster design chosen for this analysis is the Variable Specific Impulse Magnetoplasma Rocket (VASIMR). The VASIMR propulsion system, currently being developed by Ad Astra Rocket Company (AARC), is an electric propulsion rocket that uses electric power to accelerate neutral plasma propellant. Advanced electric space propulsion systems such as the VASIMR offer unique capabilities that allow for higher exhaust velocities that are up to ten times that of traditional chemical rockets. Furthermore, the thrust and specific impulse of the VASIMR system can be varied in order to achieve optimal travel times to given destinations for a desired payload. As a result, electric propulsion systems characteristically have lower ratios of system mass to power output than chemical rockets. This ratio is commonly known as the alpha parameter. Alpha parameters of approximately 10 kg/kWe or less make electric propulsion more attractive for deep space exploration missions in terms of resource efficiency and cost. However, the primary challenge with electric propulsion is to develop a high power density source of electricity in order to minimize the total system mass. The alpha parameter is the main benchmark used in this project to test whether or not the proposed coupled gas cooled reactor and power conversion system design is more competitive than other proposed systems. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Advanced photovoltaic power systems using tandem GaAs/GaSb concentrator modules

In 1989, Boeing announced the fabrication of a tandem gallium concentrator solar cell with an energy conversion efficiency of 30 percent. This research breakthrough has now led to panels which are significantly smaller, lighter, more radiation resistant, and potentially less expensive than the traditional silicon flat plate electric power supply. The new Boeing tandem concentrator (BTC) module uses an array of lightweight silicone Fresnel lenses mounted on the front side of a light weight aluminum honeycomb structure to focus sunlight onto small area solar cells mounted on a thin back plane. This module design is shown schematically. The tandem solar cell in this new module consists of a gallium arsenide light sensitive cell with a 24 percent energy conversion efficiency stacked on top of a gallium antimonide infrared sensitive cell with a conversion efficiency of 6 percent. This gives a total efficiency 30 percent for the cell-stack. The lens optical efficiency is typically 85 percent. Discounting for efficiency losses associated with lens packing, cell wiring, and cell operating temperature still allows for a module efficiency of 22 percent which leads to a module power density of 300 Watts/sq. m. This performance provides more than twice the power density available from a single crystal silicon flat plate module and at least four times the power density available from amorphous silicon modules. The fact that the lenses are only 0.010 ft. thick and the aluminum foil back plane is only 0.003 ft. thick leads to a very lightweight module. Although the cells are an easy to handle thickness of 0.020 ft., the fact that they are small, occupying one-twenty-fifth of the module area, means that they add little to the module weight. After summing all the module weights and given the high module power, we find that we are able to fabricate BTC modules with specific power of 100 watts/kg.

Fraas, L. M.↗

Energy Conversion Alternatives Study (ECAS), General Electric Phase 1. Volume 2: Advanced energy conversion systems. Part 1: Open-cycle gas turbines

Ten energy conversion systems are defined and analyzed in terms of efficiency. These include: open-cycle gas turbine recuperative; open-cycle gas turbine; closed-cycle gas turbine; supercritical CO2 cycle; advanced steam cycle; liquid metal topping cycle; open-cycle MHD; closed-cycle inert gas MHD; closed-cycle liquid metal MHD; and fuel cells. Results are presented.

Brown, D. H.↗

Electric Aircraft Cooling with Bio-Inspired Exergy Management

Future air vehicles will increasingly incorporate electrical powertrains that require very tight system-level integration of power, propulsion, thermal, fault protection, and airframe technologies. This chapter provides an overview of a new category of thermal energy conversion technology and describes the development of the resulting Thermal Recovery Exergy Efficient System, TREES. TREES can be used to enable a fully solid-state integrated thermal and fault management electric aircraft protection system, while synergistically managing and recycling both the low-grade waste heat from electrical components and the high-grade waste heat from engine components. This is achieved with exergy amplification of the powertrain waste heat, a new class of fast flight-weight breakers, a new class of long variable-conductance heat pipes with multiple switchable condensers, a new class of turbofan-integrated heat exchangers, and a gradient-based powertrain system optimizer. This approach is like the human body’s thermal management system in which the heart, arteries, and veins are analogous to the turbofan, acoustic tubes, and heat pipes proposed herein.

Rodger W Dyson↗

A transmissive concentrator photovoltaic module with cells directly cooled by silicone oil for solar cogeneration systems

Hybrid concentrator photovoltaic-thermal systems can cogenerate electricity and heat by beam-splitting incoming concentrated light onto photovoltaic cells and a thermal receiver to increase total conversion efficiency and potentially reduce system cost. To demonstrate this, we have designed and prototyped a transmissive spectrum-splitting concentrator photovoltaic module that maximizes solar energy conversion by utilizing the entire solar spectrum. Visible light is collected using infrared-transmissive triple-junction photovoltaic cells to achieve an in-band module efficiency of 43.3% for light of wavelength λ < 873 nm, while 44.2% of out-of-band light with λ > 873 nm is transmitted through for collection by a thermal receiver. During testing on a dual-axis tracked parabolic concentrator dish at up to 166 suns, cell temperatures were maintained at 119 °C or below via a novel active cooling method. This cooling system strictly flows silicone oil directly across both sides of the cells, without inhibiting optical transmission, as verified through experimentation and simulation. The module was validated outdoors for 572 sun·hrs, and achieved a maximum thermal receiver temperature of 180 °C. 86.1% of incident solar power is collected at 166 suns average concentration collectively among the electrical, cooling, and thermal receiver subsystems. The remaining 13.9% is lost to mirror reflectivity, dish shadowing, receiver reflection, and thermal losses. The ability to directly cool the cells with an inert silicone oil offers the potential for reduced system cost relative to previous transmissive hybrid concentrator photovoltaic-thermal systems, including microfluidic-cooled designs. This solar cogeneration capability is valuable in a wide range of commercial and industrial applications.

14 SOLAR ENERGY↗

Levelized-Cost-of-Electricity-Driven Design Optimization for Medium-Voltage Transformerless Photovoltaic Converters: Preprint

Design approaches for power electronics are typically focused on efficiency and power density; however, these strategies do not guarantee cost optimality in any well-defined sense. To overcome this shortcoming, we propose a design framework that yields circuit parameters that minimize the levelized cost of electricity (LCOE) of a generation system. LCOE serves as a meaningful metric since it captures total lifetime costs -- including hardware, balance of system, and maintenance costs\textemdash and includes the impacts of power conversion efficiency and revenue from harvested energy. To obtain a tractable design problem, we formulate an approximate LCOE improvement model that quantifies the changes in LCOE resulting from a candidate converter design. We apply this framework to a multilevel cascaded topology for low-voltage dc to medium-voltage ac conversion without line-frequency transformers. An example 200-kW commercial-scale system is studied and the solution yields a design with 15 cascaded stages, 98.89% efficiency, and an LCOE reduction of 3.6%.

14 SOLAR ENERGY↗

Thermal Modeling of a Dual-Stage Sodium Thermal-Electrochemical Converter (Na-TEC)

The sodium thermal electrochemical converter (Na-TEC) is a heat engine that generates electricity through the isothermal expansion of sodium ions through a beta”-alumina solid-electrolyte. The Na-TEC is a closed system that can theoretically achieve conversion efficiencies above 45% when operating between thermal reservoirs at 1150 K and 550 K. However, thermal designs have confined previous single-stage devices to thermal efficiencies below 20%. To mitigate some of these limitations, we consider dividing the isothermal expansion into two stages; one at the evaporator temperature (1150 K) and another at an intermediate temperature (550 K – 950 K). This dual-stage Na-TEC takes advantage of regeneration and reheating, and could be amenable to better thermal management through a reduction of parasitic losses. These losses are comprised of (i) the heat input that does not participate in power production but simply bypasses the thermo-electrochemical process and is transferred to the condenser, and (ii) heat that is lost from the device directly to the surroundings due to poor insulation. Heat loss to the surroundings occurs from a lower average hot-side temperature given that a fraction of the power conversion occurs at an intermediate stage. Also, the condenser now directly interacts with the lower temperature of the intermediate stage, thereby reducing radiation loss. A simplified geometry is developed for this device to help guide its design from a heat transfer perspective. All thermal contact and boundary conditions are discussed, including the evaporation and condensation of sodium vapor, thermal leakage through the housing, and the thermal contact between the beta”-alumina and the housing. A ray tracing method assuming gray, diffuse surfaces is used to account for the internal radiation heat transfer within the device. Liquid sodium flows in a capillary wick between the condenser and the evaporator with Pe << 1, so only conduction heat transfer is considered within this liquid return path. For simplicity, natural convection between the sodium vapor and the device housing is neglected. A numerical linear resistance model (<5% error when compared to a finite element model) is used to determine the expected conversion temperatures of each stage for a range of candidate materials. Furthermore, a numerical model (<2% error) is developed to find the factor of increase in the thermal resistance for several designs of corrugated features for the device housing. By using an iterative scheme, efficiency vs. power curves are created for a number of material and size combinations. Finally, the fundamental tradeoff between the power and efficiency is explored in conjunction with the total system size.

14 SOLAR ENERGY↗

Self-Aligned Selective Area Front Contacts on Poly -Si/SiO x Passivating Contact c -Si Solar Cells

We report both polarity poly-Si/SiO x passivating contacts in a front/back device configuration may represent the next solar cell architecture after tunnel oxide passivating contacts (TOPCon) cells, but high parasitic absorption in the front poly -Si layer often limits its performance. This work explores a wet etching technique to remove the front poly -Si in the nonmetallized regions using self-aligned metal grids as an etch mask. We systematically examine various dielectric layers (SiN x ,Al 2 O 3 , and stacks thereof) to study the repassivation of the etched n + surface, and find that an SiN x /Al 2 O 3 passivation stack can effectively repassivate the etched surface, which we attribute to field-effect passivation from the positive fixed charge from the SiN x layer, and excellent chemical passivation property from Al 2 O 3 in the form of atomic H. We demonstrate a front/back poly-Si/SiO x passivating contact device, with an open-circuit voltage (V oc ) of 690 mV, short-circuit current density (J sc ) of 39.8 mA/cm 2 , fill factor of 78%, and power conversion efficiency of 21.4%. Furthermore, simulations using SunSolve and Quokka 3 show good agreement with both the optical and electrical properties of the experimental device. The power loss analysis reveals improvements in the optical loss from the back Ti adhesion and front SiN x layers would lead to a 23.5% device. Lastly, a techno-economic model compares the production cost of this improved cell with the current TOPCon cells. Our results highlight that further cost reductions in single-sided doped poly -Si layers are needed to compete with mainstream passivated emitter and rear cell, and TOPCon technologies.

14 SOLAR ENERGY↗