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At least 451 records · Page 25

Isothermal Equation Of State For Compressed Solids

Same equation with three adjustable parameters applies to different materials. Improved equation of state describes pressure on solid as function of relative volume at constant temperature. Even though types of interatomic interactions differ from one substance to another, form of equation determined primarily by overlap of electron wave functions during compression. Consequently, equation universal in sense it applies to variety of substances, including ionic, metallic, covalent, and rare-gas solids. Only three parameters needed to describe equation for given material.

Vinet, Pascal↗

Hydrogen detection study

The effectiveness was assessed of a hydrogen (H2) detection concept for regenerative environmental control life support systems (EC/LSS). The concept evaluated was that utilized for the electrochemical depolarized concentrator (EDC) design, constructed, and tested for the EC/LSS space station prototype program. The EDC contains combustible gas detectors (CGDs) which were evaluated with H2. The CGDs were evaluated for linearity, position sensitivity, reproducibility, ambient effects, repeatability, speed of response, recovery time, and interchangeability. The effectiveness of CGDs located within the EDC for sensing H2 leaks at various line replaceable units in the subsystem was determined. The effects of H2 leak rate, H2 concentration of leaking gas and air currents in the vicinity of the EDC were determined. Proposed improvements for the H2 detection concept were documented and alternative H2 detection approaches were identified and analyzed.

Shumar, J. W.↗

Building-Integrated Microscale Sensors for CO 2 -Level Monitoring

This research effort enabled the development of new classes of small-scale sensing systems that use mass and/or electrochemical sensors to detect the presence of carbon dioxide (CO 2 ). The concentration of this gas within the indoor environment is an important metric, as it can help enable the use of variable speed ventilation fans in commercial and governmental buildings, thus saving a significant amount of energy. Furthermore, there is a pressing need for enhanced CO 2 sensing to improve the comfort and productivity of people in commercial and government buildings, including academic spaces.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Trace Gas Measurements on Mars and Earth Using Optical Parametric Generation

Trace gases and their isotopic ratios in planetary atmospheres offer important but subtle clues as to the origins of a planet's atmosphere, hydrology, geology, and potential for biology. An orbiting laser remote sensing instrument is capable of measuring trace gases on a global scale with unprecedented accuracy, and higher spatial resolution that can be obtained by passive instruments. We have developed an active sensing instrument for the remote measurement of trace gases in planetary atmospheres (including Earth). The technique uses widely tunable, seeded optical parametric generation (OPG) to measure methane, CO2, water vapor, and other trace gases in the near and mid-infrared spectral regions. Methane is a strong greenhouse gas on Earth and it is also a potential biogenic marker on Mars and other planets. Methane in the Earth's atmosphere survives for a shorter time than CO2 but its impact on climate change can be larger than CO2. Methane levels have remained relatively constant over the last decade around 1.78 parts per million (ppm) but recent observations indicate that methane levels may be on the rise. Increasing methane concentrations may trigger a positive feedback loop and a subsequent runaway greenhouse effect, where increasing temperatures result in increasing methane levels. The NRC Decadal Survey recognized the importance of global observations of greenhouse gases and called for simultaneous CH4, CO, and CO2 measurements but also underlined the technological limitations for these observations. For Mars, methane measurements are of great interest because of its potential as a strong biogenic marker. A remote sensing instrument that can measure day and night over all seasons and latitudes can identify and localize sources of biogenic gas plumes produced by subsurface chemistry or biology, and aid in the search for extra-terrestrial life. It can identify the dynamics of methane generation over time and latitude and identify future lander mission sites for more detailed in-situ analysis. In this paper we report on remote sensing measurements of methane using a high peak power, widely tunable optical parametric generator (OPG) operating at 3.3 micron and 1.65 micron. The OPG is pumped by a passively q-switched single frequency laser (3ns, 5KHz, 50uJ) and seeded by a diode laser. The spectral width of both signal and idler of seeded OPG is nearly Fourier transform limited. The output of seeded OPG is single frequency with high spectral purity and is widely tunable. Both 1650 nm and 3300 nm can be generated with a conversion efficiency of more than 30%. We have demonstrated detection of methane at 3274 nm and 1650 nm in a cell and also performed open path atmospheric measurements of methane at the same wavelengths. Finally, we were able to demonstrate simultaneous detection of methane at 3270.4 nm and CO2 at 1578.2 nm. In this paper we will discuss the OPG performance and atmospheric open path measurement results.

Numata, Kenji↗

Remote Sensing for Climate and Environmental Change

Remote sensing is being used more and more for decision-making and policy development. Specific examples are: (1) Providing constraints on climate models used in IPCC assessments (2) Framing discussions about greenhouse gas monitoring (3) Providing support for hazard assessment and recovery.

Environmental Change↗

Remote Raman measurement techniques

The use of laser Raman measurement techniques in remote sensing applications is surveyed. A feasibility index is defined as a means to characterize the practicality of a given remote Raman measurement application. Specific applications of Raman scattering to the measurement of atmospheric water vapor profiles, methane plumes from liquid natural gas spills, and subsurface ocean temperature profiles are described. This paper will survey the use of laser Raman measurement techniques in remote sensing applications using as examples specific systems that the Computer Genetics Corporation (CGC) group has developed and engineered.

Leonard, D. A.↗

On the origin of the absorption spectra of quasistellar and BL Lacertae objects

Following the earlier work of Wagoner (1967) we have reexamined the possibility that the absorption spectra of QSOs are due to gas in the disks, coronae, or halos of intervening galaxies. Comparison of the expected number of absorption systems with the number observed in all of the QSOs and BL Lacertae objects so far cataloged shows that there is a gross discrepancy in the sense that the multiplicity of absorption systems already found is far higher than the numbers expected if the absorption is due to gas in known disks or hypothetical small coronae. A discussion of the selection effects suggests that the number of absorption systems so far reported is an underestimate, so that an even greater discrepancy is likely to be present. High multiplicities can be explained only if very large halos or clouds containing heavy elements are commonly present, and there is no independent evidence for this. We conclude that the bulk of the absorption is likely to be intrinsic to the QSOs.

Burbidge, G.↗

Periodically Discharging, Gas-Coalescing Filter

A proposed device would remove bubbles of gas from a stream of liquid (typically water), accumulate the gas, and periodically release the gas, in bulk, back into the stream. The device is intended for use in a flow system (1) in which there is a requirement to supply bubble-free water to a downstream subsystem and (2) that includes a sensor and valves, just upstream of the subsystem, for sensing bubbles and diverting the flow from the subsystem until the water stream is again free of bubbles. By coalescing the gas bubbles and then periodically releasing the accumulated gas, the proposed device would not contribute to net removal of gas from the liquid stream; nevertheless, it would afford an advantage by reducing the frequency with which the diverter valves would have to be activated. The device (see figure) would include an upper and a lower porous membrane made of a hydrophilic material. Both membranes would cover openings in a tube leading to an outlet. These membranes would allow water, but not gas bubbles, to pass through to the interior of the tube. Inside the tube, between the two membranes, there would be a flow restrictor that would play a role described below. Below both membranes there would be a relief valve. Water, possibly containing bubbles, would enter from the top and would pass through either the lower membrane or both membranes, depending how much gas had been accumulated thus far. When the volume of accumulated gas was sufficient to push the top surface of the liquid below the lower porous membrane, water could no longer flow through either membrane toward the outlet. This blockage would cause an increase in back pressure that would cause the relief valve to open. The opening of the relief valve would allow both the water and the bulk-accumulated gas to pass through to the outlet. Once the gas had been pushed out, water would once again flow through both membranes at a much lower pressure drop. The flow restrictor would maintain enough pressure drop to keep the relief valve open until gas had been cleared from both hydrophilic membranes.

Carter, Donald Layne↗

Multi-Scale Integrated Monitoring System for Enhancing Methane Emission Detection, Quantification & Prediction

This report details the progress and findings of a comprehensive study on reviewing existing solutions, identifying technology gaps, and formulating an “all-in-one” integrated strategy for developing the next-generation multiscale methane monitoring and modeling platform, conducted under grant number DE-FE0032292. Co-led by Dr. David Ebert, Dr. Binbin Weng, and Dr. Chenghao Wang at the University of Oklahoma, the project’s goal was to develop an integrated approach for building this engineering platform to detect, quantify, and mitigate methane emissions across various temporal scale, spatial scales, and sectors. The planning grant study began with an extensive review of various methane sensing and monitoring technologies and systems, surveying over 100 technology providers globally. This review revealed the prevalence of optical methods over chemical methods in commercially available sensors, with Non-Dispersive Infrared (NDIR), Tunable Diode Laser Absorption Spectroscopy (TDLAS), and Optical Gas Imaging (OGI) cameras being the most prevalent options. A trend towards more advanced optical techniques was observed, driven by increased regulatory focus and technological advancements. The technical evaluation of these sensing technologies provided crucial insights into their capabilities and limitations. The study examined emerging technologies such as Differential Absorption LiDAR (DIAL), which show promise for high-precision and long-range detection. The team then investigated the features and application bandwidth of various sensing platforms, including handheld, fixed/stationary, mobile, aerials, and spaceborne monitors. Pilot field studies were conducted to assess the capabilities of solutions for different emission scenarios. Field work with sensor deployments was conducted at three distinct site types: an oil & gas industry site, a cattle ranching operation, and a waste processing facility. The team also conducted a thorough review of methane flux inverse modeling approaches, focused on physically based methods. These approaches were categorized into simple, intermediate, and advanced methods. A realtime WRF-GHG (Weather Research and Forecasting-Greenhouse Gas) modeling system was developed and applied, incorporating multiple data sources to guide field experiments and inform methane plume detection. The project identified and analyzed numerous categories of methane data sources, including satellite measurements, ground-based sensors, and inventory databases. Key platforms examined include EDGAR, EPA GHGI, NASA TROPOMI, Carbon Mapper, and Climate TRACE, among others. The team proposed an architecture for a comprehensive methane monitoring platform. This system incorporates multi-source data acquisition, advanced data processing and assimilation, interactive visualization tools, and analytical capabilities for emissions forecasting and scenario analysis. The proposed platform aims to provide a user-friendly interface catering to various stakeholders, from researchers to policymakers. The architecture includes sophisticated data ingestion methods, a centralized data warehouse, and advanced analytical tools for data fusion and interpretation. To ensure the relevance and effectiveness of the proposed system, a comprehensive survey was conducted to gather stakeholder input on system requirements. Key findings include a strong need for integrating various data types and formats, a preference for real-time data updates and advanced visualization tools, and a demand for user-friendly interfaces catering to different expertise levels.

03 NATURAL GAS↗

Observed Relationships Between Cloud Droplet Effective Radius and Biogenic Gas Concentrations in Summertime Marine Stratocumulus Over the Eastern North Atlantic

Abstract Biogenic gases are a prominent component of the summertime marine boundary layer (MBL) over the Eastern North Atlantic. One of these gases, dimethyl sulfide (DMS), can produce sulfate cloud condensation nuclei (CCN) that, in theory, can brighten clouds through photolysis, and produces a reaction product, methane sulfonic acid (MSA). It is also possible that DMS can interact with sea‐salt or other marine aerosols changing their CCN activation spectrum, which could also modify cloud microphysical structure. Data collected aboard the G1 aircraft during the Aerosol Cloud Experiment Eastern North Atlantic (ACE‐ENA) in well‐mixed and decoupled marine boundary layers (MBLs) were used to examine relationships between the cloud droplet effective radii, , and the concentrations of DMS and MSA in constant cloud liquid water content (LWC) bins. A weak but statistically significant negative correlation was observed between CCN concentration and in most LWC bins, regardless of the source of the CCN, while a weak but statistically significant positive correlation between and DMS was observed. No correlation between the cloud droplet number concentration and DMS was found. The presence of MSA indicated that DMS‐to‐sulfate photolysis was likely occurring, but data sparsity prevented a statistically significant conclusion regarding the relationship between MSA and . Data sparsity in decoupled conditions also prevented statistically significant conclusions. To properly address biogenic gas impacts on cloud microphysics, it is recommended that aircraft data be supplemented by long‐term biogenic gas measurements at the surface in marine locations with appropriate remote and in‐situ cloud sensing capabilities, and the analysis limited to well‐mixed MBL's.

54 ENVIRONMENTAL SCIENCES↗

Investigation of forestry resources and other remote sensing data. 1: LANDSAT. 2: Remote sensing of volcanic emissions

Computer classification of LANDSAT data was used for forest type mapping in New England. The ability to classify areas of hardwood, softwood, and mixed tree types was assessed along with determining clearcut regions and gypsy moth defoliation. Applications of the information to forest management and locating potential deer yards were investigated. The principal activities concerned with remote sensing of volcanic emissions centered around the development of remote sensors for SO2 and HCl gas, and their use at appropriate volcanic sites. Two major areas were investigated (Masaya, Nicaragua, and St. Helens, Washington) along with several minor ones.

Birnie, R. W.↗

Optical remote sensing for measurement of toxic gases

There is renewed interest in using optical remote sensing techniques for measuring and monitoring airborne toxins. Many instruments have been used to measure traces of atmospheric molecular species. Some optical remote sensing technology is in use for measuring or monitoring toxic or pollutant gases. The examples in this article provide a number of lessons that may be of use in the new field of optical remote sensing of toxic gases. Topics covered include the following: atmospheric properties, Fourier transform spectrometry, gas-filter correlation, differential absorption laser systems, aircraft missions, laser long-path instruments, differential optical absorption spectrometry, and ozone measurement.

Grant, William B.↗

Science Capabilities of the Common Habitat

The Common Habitat is the primary habitable element in a conceptual architecture feasibility study for long-duration space exploration with an eight-person crew size. On lunar or planetary surfaces, the Common Habitat forms the core of a Surface Base Camp. In microgravity, the Common Habitat is the core of the Deep Space Exploration Vehicle (DSEV), an in-space transportation spacecraft. The Common Habitat employs a horizontal orientation that is divided internally into a lower deck, mid deck, and upper deck, roughly separating outfitting into individual, work, and group functions. On a planetary surface, the habitat is incorporated into a base camp, located near the south pole in the case of the Moon. The Mars base camp is currently location agnostic. Each base camp is divided into habitation, landing, resource production, and power zones. In microgravity, the habitat is incorporated into the Deep Space Exploration Vehicle, a vessel capable of transporting the crew within the inner solar system. In addition to crew and teleoperated control of external science assets, the Common Habitat employs a suite of life and physical science laboratory systems to enable it to support science investigations across a variety of destination environments, primarily featuring the Moon and Mars, along with the intervening interplanetary space. Other potential destinations include Near Earth Asteroids and Venus and Earth orbits. Located in the aft starboard section of the Common Habitat mid deck, the life science laboratory supports primarily biology and human research. In its baseline configuration, the laboratory includes horizontal work surfaces, freezers, multiple gloveboxes, sample transfer/exposure capability, large instruments, and reconfigurable ISPR-compatible payload bays. The Medical Care Facility and exercise facility can also support life science research. In the aft port section of the mid deck, the physical science laboratory supports physics, chemistry, materials science, geology, and remote sensing (including astrophysics, heliophysics, Earth science, planetary science, and meteorology). It provides a baseline of similar ISPR-compatible payload bays and adds additional freezers, including those for cryogenic sample storage, a remote sensing workstation, more gloveboxes, also with sample transfer/exposure, combustion chambers, fluid mechanics chambers, and a gas chromatograph. It leverages the Command & Control Center for teleoperations of mobile science assets. Both laboratories are highly modular, with the ability to swap out both payloads and instruments on an as-needed basis. The integrated science outfitting of the Common Habitat positions its crew to contribute to all of NASA’s Moon to Mars science objectives and extend human understanding into the inner solar system.

Lunar Suface↗

Laser-Assisted Synthesis of Monolayer 2D MoSe 2 Crystals with Tunable Vacancy Concentrations: Implications for Gas and Biosensing

We report tuning the structural and electronic properties of atomically thin two-dimensional (2D) materials via defect and vacancy engineering is the key to enabling their potential use in various applications, including electronics, energy, and sensing devices. Vacancies are, for instance, becoming highly promising for the enhanced interaction of gases and biomolecules with 2D materials in energy and sensing applications. However, the deterministic generation of desirable vacancies with tunable concentrations remains a challenge in 2D materials due to the limitations in the current growth methods, such as the complex reaction chemistries and gas flow dynamics. Therefore, engineering defects and vacancies in 2D materials have been mainly limited to destructive top-down processes such as heating, ion bombardments, and laser postprocessing. Here, we introduce a single-step bottom-up synthesis approach for the growth of monolayer MoSe 2 crystals with tunable vacancy concentrations. This method utilizes the spatiotemporal properties and adjustable power densities of the lasers to control the vaporization dynamics of the stoichiometric MoSe 2 powders. Such a mechanism in the vaporization allows us to grow tunable stoichiometry monolayer MoSe 2–x crystals on the substrates. The localized and time-controlled (250 ms to 2 s) vaporization of the MoSe 2 powder by a CO 2 laser enables the formation of monolayer crystals with controlled vacancy concentrations ranging from ~1 to 20%. The effects of laser power, laser irradiation time, and background pressure on the tuning range and subsequent properties of the crystals are investigated and quantified using Raman and photoluminescence spectroscopy, scanning transmission electron microscopy (STEM), and time-correlated single-photon counting (TCSPC). This bottom-up synthesis is a promising approach that allows the deterministic vacancy tuning for future electronics and, in particular, gas and biosensing applications without the need for further postprocessing and potential structural disruption of the crystals.

2D materials↗

Zero-Gravity Vortex Vent and PVT Gaging System

Space Station and satellite reservicing will require the ability to vent gas on orbit from liquid supply or storage tanks and to gage liquid quantity under microgravity conditions. In zero gravity, (zero-g) the vortex vent is capable of venting gas from a tank of liquid containing gas randomly distributed as bubbles. The concept uses a spinning impeller to create centrifugal force inside a vortex tube within a tank. This creates a gas pocket and forces the liquid through a venturi and back into the tank. Gas is then vented from the gas pocket through a liquid detector and then out through an exhaust port. If the liquid detector senses liquid in the vent line, the fluid is directed to the low-pressure port on the venturi and is returned to the tank. The advantages of this system is that it has no rotating seals and is compatible with most corrosive and cryogenic fluids. A prototype was designed and built at the NASA Johnson Space Center and flown on the KC-135 zero-g aircraft. During these test flights, where microgravity conditions are obtained for up to 30 sec, the prototype demonstrated that less than 0.10 percent of the volume of fluid vented was liquid when the tank was half full of liquid. The pressure volume temperature (PVT) gaging system is used in conjunction with the vortex vent to calculate the amount of liquid remaining in a tank under microgravity conditions. The PVT gaging system is used in conjunction with the vortex vent to gage liquid quantity in zero or low gravity. The system consists of a gas compressor, accumulator, and temperature and pressure instrumentation. To measure the liquid in a tank a small amount of gas is vented from the tank to the compressor and compressed into the accumulator. Pressure and temperature in the tank and accumulator are measured before and after the gas transfer occurs. Knowing the total volume of the tank, the volume of the accumulator, the volume of the intermediate lines, and initial and final pressures and temperatures, the mass of the gas leaving the tank is equated to the mass of the gas entering the accumulator. The volume of liquid remaining in the tank is calculated using the ideal gas law.

Downey, M. G.↗

Combining Multi-Faceted Laboratory Studies of 74001-2 and Regional Remote Sensing to Address How Pyroclastic Eruptions Record and Affect the Lunar Volatile Budget

Basaltic magmatism is an efficient process for bringing volatiles from a planetary interior to its surface, with the possibility of generation of a transient lunar atmosphere as abundant volcanic materials de-gassed. However, pyroclastic deposits are locations where trapped gases may be studied [e.g., 2,3]. Volatile-rich pyroclastic deposits occur over a wide surface area of the Moon, indicating that the transport of volatiles and associated pyroclastic materials from the Moon’s mantle to the surface was a wide-spread phenomenon. Numerous studies analyzing remotely sensed data and using empirical modeling have demonstrated that various stages of pyroclastic eruptions significantly influence gas release patterns, morphology, and mineralogy of the deposit. Many observations based on mare basalts and pyroclastic deposits have identified potential histories of gas release [e.g., 2-10] and their influence on volatiles and their stable isotopes [e.g., 11-13]. The best representation of these pyroclastic deposits in the sample collection is core sample 74001-74002 that was collected during the Apollo 17 mission to the Taurus-Littrow Valley (TLV). The double drive tube penetrated a part of a regional-scale pyroclastic deposit and sampled approximately 68.1 cm of that deposit in the TLV. Remnants of this and other pyroclastic depos-its are represented throughout and beyond the TLV [e.g., 14-16]. The stratigraphy of this core has been investigated and defined by numerous studies. The CASA Moon SSERVI research team is conducting a multi-faceted analytical study of this deposit. Data generated from revisiting the stratigraphy of 74001-74002 will be used to place stable isotopes (H, B, Cl, S, Zn, Cu, Rb, Ga, Pb), Ar-Ar and U-Pb chronology, geochemistry, nanometer-scale observations of mineral surfaces, orbital observations, and experiments and modeling within a stratigraphic, eruptive, and geologic context. It is important to place these data into such a context. For example, recent S isotope measurements reported by Dottin et al. show differences within this core that may be related to either changes in source or eruptive process over the course of the eruption (vs. multiple eruptions). A fuller understanding of the stratigraphy is fundamental to resolving this interpretation. This comprehensive approach can only be achieved within the context of a program such as SSERVI. In addition, imaging produced in this project will be incorporated into a citizen scientist program to further identify many of the textural features of this double drive tube.

SSERVI↗

SEASAT demonstration experiments with the offshore oil, gas and mining industries

Despite its failure, SEASAT-1 acquired a reasonable volume of data that can be used by industrial participants on a non-real-time basis to prove the concept of microwave sensing of the world's oceans from a satellite platform. The amended version of 8 experimental plans are presented, along with a description of the satellite, its instruments, and the data available. Case studies are summarized for the following experiments: (1) Beaufort Sea oil, gas, and Arctic operations; (2) Labrador Sea oil, gas, and sea ice; (3) Gulf of Mexico pipelines; (4) U.S. East Coast offshore oil and gas; (5) worldwide offshore drilling and production operations; (6) Equatorial East Pacific Ocean mining; (7) Bering Sea ice project; and (8) North Sea oil and gas.

Mourad, A. G.↗