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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

The Infrared Spectrum of H2S From 1 to 5 Microns

The absorption spectra of H2S from 2000 to 11,147 cm(exp -1) have been obtained with spectral resolutions of 0.006, 0.012, and 0.021 cm(exp -1) using the Fourier transform spectrometer at Kitt Peak National Observatory. The transitions of 21 bands have been assigned for the first time and 9 others reanalyzed so that accurate energy levels, band origins, and rotational parameters could be determined. The analysis of these data revealed some remarkable features in the energy spectrum, e.g., fourfold clustering of rotational levels belonging to the symmetric and asymmetric components of local mode manifolds at a high degree of stretching excitation. This paper reports fitted vibrational parameters and predicted band origins of H2S-32 up to 12,735 cm(exp -1). It also presents the degenerate rotational constants and upper state energies of (301)-(202) and (311)-(212) at 1 micron as illustrations of clustering in the local mode limit.

Alexander D. Bykov↗
NASA NTRS2000

Retrieving the Balanced Winds on the Globe as a Generalized Inverse Problem

A generalized inverse technique is applied to retrieve two types of balanced winds that characterize the large-scale dynamics of the atmosphere: rotational winds based upon the linear balance equation, and divergent winds based upon the vorticity budget equation. Both balance equations are singular at or near the equator. The balance equations are transformed in spherical harmonic function space to an under-determined system, for which the scale-weighed least-squares solution consists of a sum of principal and singular components. The principal components represent the response to the source function for the regular eigenmodes, while the singular components are determined by the projection of an independent measurement on the singular eigenmodes. The method was tested with the NCEP/NCAR reanalysis data in which a quasi-balance condition exists. A realistic balanced wind field is retrievable when the singular components are computed based upon the reanalyzed wind data.

Lu, Huei-Iin↗
NASA NTRS1992

Registering and resampling images in STSDAS

Registering different images can be difficult, especially if the images to be registered are images at different wavelengths, where features in one image may look entirely different or be absent from the second image. Using two new packages soon to be added to the STSDAS package, REGISTER and RESAMPLE, this job is done automatically. The REGISTER package allows the user to determine the amount of translation, rotation, and/or magnification needed to make two images, spectra, or time series congruent. The methods implemented to compute the registration parameters use: a set of the pixel coordinates of the same features identified in two files, or the FITS coordinate transformation parameters in the headers of two data files, or a single feature identified as the peak of a cross-correlation between two vectors. The coefficients describing the registration are defined by the equations (for a two-dimensional image): x = a + bx + cy, y = d + ex + fy, where (X,Y) are the pixel coordinates of a feature in the reference image, (x,y) are the pixel coordinates of a feature in the secondary image, and the computed coefficients are a, b, c, d, e, and f. Results may be produced by linking the output of REGISTER to RESAMPLE in a command language procedure. The output from REGISTER and the input to RESAMPLE consists of a matrix of coefficients (a through f above) fully specifying the registration. The RESAMPLE package resamples simple vector or image data for a given amount of translation, rotation (images only), and magnification, or reflection of the science data. Specific options included are: image rotation about the FITS reference pixel; scale changes, i.e. magnification or demagnification (for images, independently on both axes); simple translation; reflection (for images, about one or both axes); and resampling and registration to a reference data set. Output from the RESAMPLE task is the resampled image which may then be displayed and compared with the reference image.

Williamson, R. L., II↗
DOE OSTI2021

Predicting orientation-dependent plastic susceptibility from static structure in amorphous solids via deep learning

It has been a long-standing materials science challenge to establish structure-property relations in amorphous solids. Here we introduce a rotationally non-invariant local structure representation that enables different predictions for different loading orientations, which is found essential for high-fidelity prediction of the propensity for stress-driven shear transformations. This novel structure representation, when combined with convolutional neural network (CNN), a powerful deep learning algorithm, leads to unprecedented accuracy for identifying atoms with high propensity for shear transformations (i.e., plastic susceptibility), solely from the static structure in both two- and three-dimensional model glasses. The data-driven models trained on samples at one composition and a given processing history are found transferrable to glass samples with different processing histories or at different compositions in the same alloy system. Our analysis of the new structure representation also provides valuable insight into key atomic packing features that influence the local mechanical response and its anisotropy in glasses.

36 MATERIALS SCIENCE↗
DOE OSTI2026

AmeriFlux FLUXNET-1F US-NC2 NC_Loblolly Plantation

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-NC2 NC_Loblolly Plantation. This is the FLUXNET version of the carbon flux data for the site US-NC2 NC_Loblolly Plantation produced by applying the standard ONEFlux (1F) software. Site Description - The North Carolina Loblolly Pine site is located in a pine plantation amongst the mixed forests of the North Carolina lower coastal plain. During the late 19th and early 20th centuries the region was logged extensively. After a series of clearcuts, the land was transformed for agricultural practices. In 1967 and 1969, 4000 ha was sold to the Weyerhauser company for agriculture, preservation, and commercial logging of loblolly pines in a series of plantations. The fifth rotation stand surrounding the tower was established in 1992. The only significant natural disturbances during the measurement period was a severe drought that spanned the entire duration of the 2007 growing season. Consequently, the 2007 total amount of precipitation was 486 mm below the 30-year norm. In the same year, the plantation was thinned and fertilized. The stand was thinned in Oct 2009. The eastern half of the site was fertilized in January 2011, and the entire site was fertilized in October 2012.

Noormets, Asko [Texas A&M University]↗
NASA NTRS2001

High Resolution Infrared Spectroscopy of Molecules of Terrestrial and Planetary Interest

In collaboration with the laboratory spectroscopy group of the Ames Atmospheric Physics Research Branch (SGP), high resolution infrared spectra of molecules that are of importance for the dynamics of the earth's and other planets' atmospheres were acquired using the SGP high resolution Fourier transform spectrometer and gas handling apparatus. That data, along with data acquired using similar instrumentation at the Kitt Peak National Observatory was analyzed to determine the spectral parameters for each of the rotationally resolved transitions for each molecule. Those parameters were incorporated into existing international databases (e.g. HITRANS and GEISA) so that field measurements could be converted into quantitative information regarding the physical and chemical structures of earth and planetary atmospheres.

Freedman, Richard S.↗
DOE OSTI2022

Deformation Mechanism Transition in Additively Manufactured Compositionally Graded Fe-Base Alloys

Microstructure-dependent deformation and fracture behavior was investigated for an additively manufactured compositionally graded alloy (CGA) printed using the laser-directed energy deposition (L-DED) method to explore an alternative approach for dissimilar metal joints in nuclear energy systems. The electron backscatter diffraction (EBSD) maps from scanning electron microscopy (SEM) display a clear microstructural transition with decreasing austenite-forming elements (Ni and Mn), from an austenite (γ) dominant structure, to a complex composite structure containing ferrite (α), martensite (α') and retained austenite, and then to a fully ferritic structure. EBSD data were recorded in situ during tensile testing in SEM, and the evolution of the deformation mechanism and microstructure was characterized using Kikuchi diffraction pattern analysis. Complementary analysis for high-resolution features was also performed using scanning transmission electron microscopy (STEM). The Ni/Mn-rich austenite-dominant microstructures showed a complex deformation mechanism of two-step martensitic transformation (γ→ε→α'), whereas the minor austenite phase retained in the ferrite and/or martensite matrix showed a single transformation route (γ→α'). Ordinary dislocation glide and twinning via partial dislocation glide were observed in the austenite deformation. Meanwhile, the ferrite and martensite grains deformed mainly by ordinary dislocation slips and grain rotation. Furthermore, static tensile fracture was also highly dependent on local composition and phase constituents.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Crystallographic ordering of Al and Sn in α-Ti

Increasing attention is being paid to α (2) Ti 3 (Al,Sn) precipitation from the α phase of titanium alloys owing to its effect on slip band formation, localisation and the implications for fatigue performance in jet engine titanium. However, the early stages of α 2 precipitation have historically been difficult to observe by electron microscopy, neutron diffraction or atom probe analysis. Here, small angle X-ray scattering is used to reexamine the phase boundary in binary Ti-Al and Ti-Sn alloys with around 500 ppmw O. It is found that the phase boundaries in the literature are approximately correct, at 6.2 wt.% Al and 16.9 wt.% Sn, and that this favours the use of Al as a solid solution strengthener over Sn for ambient temperature applications. However, once O content and phase partitioning in α + β alloys are taken into account, this implies that Al eq limits for future alloy design of critical rotating parts should be lowered substantially.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Optical pulse-induced ultrafast antiferrodistortive transition in SrTiO 3

The ultrafast dynamics of the antiferrodistortive phase transition in perovskite SrTiO 3 is monitored via time-domain Brillouin scattering. Using femtosecond optical pulses, we initiate a thermally driven tetragonal-to-cubic structural transformation and detect the crystal phase through changes in the frequency of Brillouin oscillations (BO) induced by propagating acoustic phonons. Coupling the measured BO frequency with a spatiotemporal heat diffusion model, we demonstrate that, for a sample kept in the tetragonal phase, deposition of sufficient thermal energy induces a rapid transformation of the heat-affected region to the cubic phase. The initial phase change is followed by a slower reverse cubic-to-tetragonal phase transformation occurring on a timescale of hundreds of picoseconds. Here, we attribute this ultrafast phase transformation in the perovskite to a structural resemblance between atomic displacements of the R-point soft optic mode of the cubic phase and the tetragonal phase, both characterized by anti-phase rotation of oxygen octahedra. The structural relaxation time exhibits a strong temperature dependence consistent with the prediction of the equation of motion describing collective oxygen octahedra rotation based on the energy landscape of the phenomenological Landau theory of phase transitions. Evidence of such a fast structural transition in perovskites can open up new avenues in information processing and energy storage sectors.

36 MATERIALS SCIENCE↗
NASA NTRS1984

An analytic solution for the orbital perturbations of the Venus Radar Mapper due to gravitational harmonics

Hill's variational equations are solved analytically for the orbital perturbations of a spacecraft nominally in an elliptic orbit around a non-spherical body. The rotation of the central planet about its spin-axis is not considered in the analysis. The perturbations are restricted to the planetary gravitational harmonics only. An extremely simple algorithm is derived to transform the spherical harmonic potentials to the orbital coordinate system, and the resulting accelerations are shown to be simply trigonometric functions of the true anomaly. With the principal matrix solution for the differential equations of the adjoint system given in closed form, the orthogonality of the trigonometric functions makes it possible to obtain an analytic solution for the non-homogeneous problem, at intervals of 2 pi in true anomaly. The solution for orbital perturbations can be extended over several revolutions by applying well-known results from Floquet's theory. The technique is demonstrated with results presented on the spacecraft periapsis altitude for the forthcoming Venus Radar Mapper Mission.

Vijayaraghavan, A.↗
NASA NTRS1995

Precise laboratory measurements of methanol rotational transition frequencies in the 5 to 13 GHz region

Rotational transitions for CH3OH were measured in the 5-13 GHz range with a precision and accuracy of a few kilohertz or less using a Flygare-Balle type pulsed-beam Fourier transform microwave spectrometer. The accurate center frequencies measured should be useful in determining accurate Doppler shifts and making positive molecule identification in radio astronomy.

Breckenridge, S. M.↗
NASA NTRS1988

A feedback linearization approach to spacecraft control using momentum exchange devices

Recent developments in the area of nonlinear control theory have shown how coordiante changes in the state and input spaces can be used with nonlinear feedback to transform certain nonlinear ordinary differential equations into equivalent linear equations. These feedback linearization techniques are applied to resolve two problems arising in the control of spacecraft equipped with control moment gyroscopes (CMGs). The first application involves the computation of rate commands for the gimbals that rotate the individual gyroscopes to produce commanded torques on the spacecraft. The second application is to the long-term management of stored momentum in the system of control moment gyroscopes using environmental torques acting on the vehicle. An approach to distributing control effort among a group of redundant actuators is described that uses feedback linearization techniques to parameterize sets of controls which influence a specified subsystem in a desired way. The approach is adapted for use in spacecraft control with double-gimballed gyroscopes to produce an algorithm that avoids problematic gimbal configurations by approximating sets of gimbal rates that drive CMG rotors into desirable configurations. The momentum management problem is stated as a trajectory optimization problem with a nonlinear dynamical constraint. Feedback linearization and collocation are used to transform this problem into an unconstrainted nonlinear program. The approach to trajectory optimization is fast and robust. A number of examples are presented showing applications to the proposed NASA space station.

Dzielski, John Edward↗
NASA NTRS1999

Reactions and Surface Transformations of a Bone-Bioactive Material in a Simulated Microgravity Environment

A comprehensive program to investigate the expeditious in vitro formation of three-dimensional bone-like tissue is currently underway at the University of Pennsylvania. The study reported here forms a part of that program. Three-dimensional bone-like tissue structures may be grown under the simulated microgravity conditions of NASA designed Rotating Wall Bioreactor Vessels (RWV's). Such tissue growth will have wide clinical applications. In addition, an understanding of the fundamental changes that occur to bone cells under simulated microgravity would yield important information that will help in preventing or minimizing astronaut bone loss, a major health issue with travel or stay in space over long periods of time. The growth of three-dimensional bone-like tissue structures in RWV's is facilitated by the use of microcarriers which provide structural support. If the microcarrier material additionally promotes bone cell growth, then it is particularly advantageous to employ such microcarriers. We have found that reactive, bone-bioactive glass (BBG) is an attractive candidate for use as microcarrier material. Specifically, it has been found that BBG containing Ca- and P- oxides upregulates osteoprogenitor cells to osteoblasts. This effect on cells is preceded by BBG reactions in solution which result in the formation of a Ca-P surface layer. This surface further transforms to a bone-like mineral (i.e., carbonated crystalline hydroxyapatite (c-HA)). At normal gravity, time-dependent, immersion-induced BBG reactions and transformations are greatly affected both by variations in the composition of the milieu in which the glass is immersed and on the immersion conditions. However, the nature of BBG reactions and phase transformations under the simulated microgravity conditions of RWV's are unknown, and must be understood in order to successfully use BBG as microcarrier material in RWV'S. In this paper, we report some of our recent findings in this regard using experimental and numerical methods. BBG composition 45S5, the most reactive among known bone-bioactive glasses, was chosen for the study. BBG 45S5 behavior in physiological solutions was tested in simulated microgravity and compared with that at normal gravity. On the basis of our numerical study, we have chosen the BBG granule size to be in the range 40-70 microns, and a RWV rotational speed of 10 rpm. Our numerical study has shown that these parameters enable the microcarrier to remain suspended in the medium without experiencing collisions with the wall of the vessel. Immersion-induced changes in the solution composition and the material surface were analyzed after immersion.

Radin, S.↗
NASA NTRS1972

Complex eigenvalue analysis of rotating structures

A FORTRAN subroutine to NASTRAN which constructs coriolis and centripetal acceleration matrices, and a centrifugal load vector due to spin about a selected point or about the mass center of the structure is discussed. The rigid translational degrees of freedom can be removed by using a transformation matrix T and its explicitly given inverse. These matrices are generated in the subroutine and their explicit expressions are given.

Patel, J. S.↗
DOE OSTI2023

Evolution of microstructure and strength of a high entropy alloy undergoing the strain-induced martensitic transformation

In a recent work, we have reported outstanding strength and work hardening exhibited by a metastable high entropy alloy (HEA), Fe 42 Mn 28 Co 10 Cr 15 Si 5 (in at. %), undergoing the strain-induced martensitic transformation from metastable gamma austenite (γ) to stable epsilon martensite (ε). However, the alloy exhibited poor ductility, which was attributed to the presence of the brittle sigma (σ) phase in its microstructure. The present work reports the evolution of microstructure, strength, and ductility of a similar HEA, Fe 38.5 Mn 20 Co 20 Cr 15 Si 5 Cu 1.5 (in at. %), designed to suppress the formation of σ phase. A cast and then rolled plate of the alloy was processed into four conditions by annealing for 10 and 30 min at 1100 °C and by friction stir processing (FSP) at tool rotation rates of 150 and 400 revolutions per minute (RPM) to facilitate detailed examinations of variable initial grain structures. Neutron diffraction and electron microscopy were employed to characterize the microstructure and texture evolution. The initial materials had variable grain size but nearly 100% γ structure. Diffusionless strain induced γ→ε phase transformation took place under compression with higher rate initially and slower rate at the later stages of deformation, independent on the initial grain size. The transformation facilitated part of plastic strain accommodation and rapid strain hardening owing to a transformation-induced dynamic Hall-Petch-type barrier effect, increase in dislocation density, and texture. Here, the peak strength of nearly 2 GPa was achieved under compression using the structure created by double pass FSP (150 RPM followed by 150 RPM). Remarkably, the tensile elongation exhibited by the alloy was nearly 20% with fracture surfaces featuring a combination of ductile dimples and cleavage.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Effect of rotation on negative triangularity plasmas in DIII-D

At the DIII-D tokamak, plasmas with negative triangularity (NT) have been found to have similar energy confinement times as H-mode plasmas with positive triangularity. These NT plasmas also have a stable edge that inhibits H-mode, lacks dangerous edge transients, and has naturally low impurity confinement. For these reasons, NT plasmas have the potential to be a transformative reactor scenario. To determine the importance of strong co-current neutral beam torque for NT performance at DIII-D, scans of neutral beam torque at constant neutral beam power have been performed. These scans have shown that the energy confinement time for a basic, inductive NT scenario (q 95 ≈ 2.8) decreases by 16% when torque is reduced to reactor levels. This reduction in confinement can be replicated with gyrofluid modeling that isolates the role of E x B shear in the change in transport. In a separate set of discharges with lower plasma current (q 95 ≈ 2.5), no significant correlation between confinement time and rotation was found. Throughout this investigation, excellent MHD stability was observed, even with very low toroidal rotation. Further, low impurity confinement was found at multiple rotation levels. Throughout the campaign, rotation near the edge was counter-current, consistent with the measurement of counter-current intrinsic edge rotation, and these observations agree with NT results from the TCV tokamak.

confinement↗
NASA NTRS1983

Design of shock-free compressor cascades including viscous boundary layer effects

A computer code that generates shock-free transonic compressor cascade shapes while taking into account viscosity effects is developed. The mathematical model for the inviscid flow field is the full potential equation. The Kutta-Joukowski condition is satisfied by varying the free stream angle at downstream infinity. A boundary fitted computational grid of C-type is generated using a sequence of conformal mapping and nonorthogonal coordinate stretching and shearing transformations. The inviscid calculation is performed sequentially on up to four consecutively refined grids thereby accelerating the convergence of the solution process. The full potential equation is solved using a finite area technique and rotated, type-dependent finite differencing. Artificial viscosity of the first order is added in a fully conservative form. Shock-free cascade airfoil shapes are obtained using the fictitious gas concept of Sobieczky and the method of characteristics in the rheograph plane. Viscosity effects are incorporated via a boundary layer displacement thickness. The integral boundary layer code is based on Rotta's turbulence model and assumes transition region of zero length.

Dulikravich, G. S.↗
NASA NTRS1986

Advanced Rotordynamic Nonlinear Transient Simulation

Advanced rotordynamic nonlinear transient-simulation program, TRANSIM, developed to predict response of high-performance rotating machinery to variety of forcing functions. Works by modal superposition of rotor and casing subsystems. Transient response of system calculated by numerical integration of equations of motion, performed in modal coordinates. Resulting data transformed back into physical coordinates as required to determine user-requested loads and accelerations as function of time. Used to analyze Space Shuttle main engine high-pressure fuel turbopump. TRANSIM written in FORTRAN 77.

Becht, D. G.↗