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At least 451 records · Page 25

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DOE OSTI2023

Discovering polyelemental nanostructures with redistributed plasmonic modes through combinatorial synthesis

Coupling plasmonic and functional materials provides a promising way to generate multifunctional structures. However, finding plasmonic nanomaterials and elucidating the roles of various geometric and dielectric configurations are tedious. This work describes a combinatorial approach to rapidly exploring and identifying plasmonic heteronanomaterials. Symmetry-broken noble/non-noble metal particle heterojunctions (~100 nanometers) were synthesized on multiwindow silicon chips with silicon nitride membranes. The metal types and the interface locations were controlled to establish a nanoparticle library, where the particle morphology and scattering color can be rapidly screened. By correlating structural data with near- and far-field single-particle spectroscopy data, we found that certain low-energy plasmonic modes could be supported across the heterointerface, while others are localized. Furthermore, we found a series of triangular heteronanoplates stabilized by epitaxial Moiré superlattices, which show strong plasmonic responses despite largely comprising a lossy metal (~70 atomic %). These architectures can become the basis for multifunctional and cost-effective plasmonic devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2020

3D diffractive imaging of nanoparticle ensembles using an x-ray laser

Single particle imaging at x-ray free electron lasers (XFELs) has the potential to determine the structure and dynamics of single biomolecules at room temperature. Two major hurdles have prevented this potential from being reached, namely, the collection of sufficient high-quality diffraction patterns and robust computational purification to overcome structural heterogeneity. We report the breaking of both of these barriers using gold nanoparticle test samples, recording around 10 million diffraction patterns at the European XFEL and structurally and orientationally sorting the patterns to obtain better than 3-nm-resolution 3D reconstructions for each of four samples. With these new developments, integrating advancements in x-ray sources, fast-framing detectors, efficient sample delivery, and data analysis algorithms, we illuminate the path towards sub-nanometer biomolecular imaging. The methods developed here can also be extended to characterize ensembles that are inherently diverse to obtain their full structural landscape.

47 OTHER INSTRUMENTATION↗

DOE OSTI2023

Particle Flux Measurements during TRACER (TRACER PFM) (Field Campaign Report)

The purpose of this campaign was to deploy an instrument payload collocated with a suite of in situ and remote-sensing aerosol instruments at the urban site at the La Porte, Texas Municipal Airport during the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Tracking Aerosol Convection Interactions Experiment (TRACER) in Houston, Texas. The payload was designed to characterize the physicochemical properties, mixing state, and size-resolved vertical fluxes of aerosols. Deployed aerosol instruments associated with the flux measurements included three condensation particle counters (CPCs) with different lower cutoff diameters ( D > 2.5 nm, D > 10 nm, and D > 40 nm), a single-particle soot photometer (SP2) measuring refractory black carbon, and a portable optical particle spectrometer (POPS) measuring the optical size distribution (~180 nm < D < ~5000 nm). A 10-m flux tower hosted a sonic anemometer (SONIC) for vertical velocity measurements. In addition, a humidified tandem differential mobility analyzer (HTDMA) was deployed to measure the growth factors and hygroscopicity parameter of 15-50 nm-sized particles in order to constrain the composition of compounds responsible for modal aerosol growth during new particle formation/growth events. Finally, a radial differential mobility analyzer (RDMA) was deployed to extend the size distribution measurement to 5 nm.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Arctic Black Carbon Aerosol Deposition Study North Slope of Alaska 2020- SP2 Measurements

Particles are removed from the atmosphere through both wet and dry deposition. These processes are poorly understood, though they constitute important uncertainties in climate and air quality models. This project aims to use observational constraints on particle fluxes to improve model representations of dry deposition. Within this data set, we measured refractory black carbon with a single particle soot photometer (SP2) at the ARM facility’s North Slope of Alaska site. Measurements were made at the meteorological tower between 9 Sept and 27 Oct 2021. This site is a coastal tundra location, and received snow during the project.

Black carbon mass concentration↗

NASA NTRS2018

"Independent" and "Dependent" Scattering by Particles in a Multi-Particle Group

The terms "independent" and "dependent" scattering are ubiquitous in the phenomenological discipline of light scattering by particulate media. Yet there is a wide range of ad hoc definitions of these terms, many of which are vague and conceptually inconsequential. In this paper we perform a first-principles analysis of these terms based on the rigorous volume-integral-equation formulation of electromagnetic scattering. We argue that scattering by a multi-particle group can be called independent if certain optical observables for the entire group can be expressed in appropriate single-particle observables. Otherwise one deals with the dependent scattering regime. The prime (and perhaps the only) examples of independent scattering are scattering scenarios described by the first-order scattering approximation and the first-principles radiative transfer theory.

Particle scattering↗

NASA NTRSDate not supplied

Eruption Characterisitics of Lunar Localized Pyroclastic Deposits Based on Water Content, Mineralogy, Regolith Properties

Lunar pyroclastic deposits are low albedo deposits present throughout the lunar surface including both maria and highlands, nearside and farside, and high latitudes and equatorial regions [e.g., 1]. There are two main types of pyroclastic deposits based upon size: localized (<2500 km2) and regional pyroclastic deposits (>2500 km2) [1]. In this study, we focus on the smaller localized pyroclastic deposits. The first and most detailed study of localized pyroclastic deposits are the deposits in Alphonsus crater [2]. This study included examining the radar and volumetric properties of these deposits. They found that vulcanian-like eruptions are most consistent with their observations. They imagined that a dike intrudes into the crust and creates a cooled basaltic cap. With increasing pressure under the basaltic cap, the pressure eventually overwhelms the surrounding rocks and results in explosive decompression. Later studies examined several pyroclastic deposits across the lunar surface using radar [2–4], digital terrain models (DTMs) [2,4], visible and near-infrared spectrometers [1,4–7], and a radiometer [4] to determine the mineralogy (e.g., olivine, glass, clinopyroxene, orthopyroxene, and plagioclase), deposit thickness and volume, proportion of juvenile material, radar backscatter, surface rock abundance, and regolith density. These various properties were examined against one another to better group localized pyroclastic deposits and understand how they relate to one another [4]. One of the studies divided pyroclastic deposits into three groups based upon the shape of the 1-μm absorption feature. The three Groups could be interpretated as having highlands and pyroclastic material (Group I), mare and pyroclastic material (Group II), and glass and orthopyroxene material (Group III) [5]. Building on that foundation, another study divided the pyroclastic deposits into four groups based upon their surface rock abundance and glass abundance [4], where deposits are classified based upon low surface rock abundance and high glass abundance (Glassy deposits); high rock abundance, high glass abundance (Blocky deposits); moderate rock abundance and low glass abundance (Crystalline deposits); and high rock abundance and low glass abundance (Indistinct Group). In addition to these studies, we can now look at their water contents using the new Effective Single Particle Absorption Thickness (ESPAT) parameter map [8]. The ESPAT map measures the strength of the 3-μm absorption feature in single scattering albedo space. The strength of this feature and its relationship to water content has been calibrated to returned samples, which allows for water content to be derived from remote spectral data (i.e., Moon Mineralogy Mapper). The goal of this study is to examine how water content in the pyroclastic deposits varies with respect to the geometric, mineralogic, and physical properties of the localized pyroclastic deposits as measured by a previous study [i.e., 4]. A more complete version of this work is found in [9].

D Trang↗

NASA NTRS1981

An optical model for composite nuclear scattering

The optical model of composite particle scattering is considered and compared to the accuracies of other models. A nonrelativistic Schroedinger equation with two-body potentials is used for the scattering of a single particle by an energy-dependent local potential. The potential for the elastic channel is composed of matrix elements of a single scattering operator taken between the ground states of the projectile and the target; the coherent amplitude is considered as dominating the scattering in the forward direction. A multiple scattering series is analytically explored and formally summed by the solution of an equivalent Schroedinger equation. Cross sections of nuclear scattering are then determined for He-4 and C-12 nuclei at 3.6 GeV/nucleus and O-16 projectiles at 2.1 GeV/nucleus, and the optical model approximations are found to be consistently lower and more accurate than approximations made by use of Glauber's theory.

Wilson, J. W.↗

NASA NTRS1988

Confined turbulent fluid-particle flow modeling using multiple-realization particle trajectory schemes

A multiple-realization particle trajectory scheme has been developed and applied to the numerical prediction of confined turbulent fluid-particle flows. The example flows investigated include the vertical pipe upflow experimental data of Tsuji et al. and the experimental data of Leavitt for a coaxial jet flow, comprising a particle-laden central jet and a clean annular jet, into a large recirculation chamber. The results obtained from the numerical scheme agree well with the experimental data, lending confidence to the modeling approach. The multiple-realization particle trajectory turbulent flow modeling scheme is believed to be a more elegant and accurate approach to the extension of single-particle hydrodynamics to dilute multi-particle systems than the more commonly employed two-fluid modeling approach. It is also better able to incorporate additional force items such as lift, virtual mass and Bassett history terms directly into the particle equation of motion as appropriate. This makes it a suitable candidate for particle migration studies and an extension to situations involving liquid particulate phases with possible propulsion applications, such as in spray combustion, follows naturally.

Adeniji-Fashola, A. A.↗

DOE OSTI2025

Engineering spin coherence in core-shell diamond nanocrystals

Fluorescent diamond nanocrystals can host spin qubit sensors capable of probing the physical properties of biological systems with nanoscale spatial resolution. Sub-100 nm diamond nanosensors can readily be delivered into intact cells and even living organisms. However, applications beyond current proof-of-principle experiments require a substantial increase in sensitivity, which is limited by surface induced charge instability and electron-spin dephasing. In this work, we utilize engineered core-shell structures to achieve a drastic increase in qubit coherence times (T 2 ) from 1.1 to 35 μs in bare nanodiamonds to upward of 52 to 87 μs. We use electron-paramagnetic-resonance results to present a band bending model and connect silica encapsulation to the removal of deleterious mid-gap surface states that are negatively affecting the qubit’s spin properties. Combined with a 1.9-fold increase in particle luminescence these advances correspond to up to two-order-of-magnitude reduction in integration time. Probing qubit dynamics at a single particle level further reveals that the noise characteristics fundamentally change from a bath with spins that rearrange their spatial configuration during the course of an experiment to a more dilute static bath. The observed results shed light on the underlying mechanisms governing fluorescence and spin properties in diamond nanocrystals and offer an effective noise mitigation strategy based on engineered core-shell structures.

core-shell↗

NASA NTRS1974

Lunar particle shadows and boundary layer experiment: Plasma and energetic particles on the Apollo 15 and 16 subsatellites

The lunar particle shadows and boundary layer experiments aboard the Apollo 15 and 16 subsatellites and scientific reduction and analysis of the data to date are discussed with emphasis on four major topics: solar particles; interplanetry particle phenomena; lunar interactions; and topology and dynamics of the magnetosphere at lunar orbit. The studies of solar and interplanetary particles concentrated on the low energy region which was essentially unexplored, and the studies of lunar interaction pointed up the transition from single particle to plasma characteristics. The analysis concentrated on the electron angular distributions as highly sensitive indicators of localized magnetization of the lunar surface. Magnetosphere experiments provided the first electric field measurements in the distant magnetotail, as well as comprehensive low energy particle measurements at lunar distance.

Anderson, K. A.↗

NASA NTRS1989

Application of a vectorized particle simulation in high-speed near-continuum flow

An efficient particle simulation technique, developed for use on vector architecture based supercomputers for studying hypersonic rarefied gas flows is employed to simulate the complex wake generated by Mach six flow over a 10 deg half-angle wedge for freestream Reynolds numbers of 1780 and 3560. Data obtained are compared against higher Reynolds number experimental results. Simulations utilized as many as 10 to the 5th computational cells and 10 to the 7th simulated particles having power-law interaction potentials. A code performance of 1.8-2.4 microsec of Cray-2 CPU time to process a single particle per timestep is achieved. Diffuse adiabatic and isothermal wedge surface models are used in this investigation. Although the wedge geometry is two-dimensional, the simulation incorporates a width-wise direction, resulting in a three-dimensional computation.

Woronowicz, Michael S.↗

DOE OSTI2020

Nucleon localization function in rotating nuclei

An electron localization function was originally introduced to visualize in positional space bond structures in molecules. It became a useful tool to describe electron configurations in atoms, molecules, and solids. In nuclear physics, a nucleon localization function (NLF) has been used to characterize cluster structures in light nuclei, formation of fragments in fission, and pasta phases appearing in the inner crust of neutron stars. In the case of a deformed rotating nucleus, several NLFs can be introduced, depending on the definition of the spin-quantization axis, direction of the total angular momentum, and self-consistent symmetries of the system. Contributions to the NLF from the current density, spin-current tensor density, and density gradient terms are negligible in the nuclear interior. The oscillating pattern of the simplified NLF can be explained in terms of a constructive interference between kinetic-energy and particle densities. The characteristic nodal pattern seen in the NLF in the direction of major axis of a rotating nucleus comes from single-particle orbits carrying large aligned angular momentum. The variation of the NLF along the minor axis of the nucleus can be traced back to deformation-aligned orbits.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2020

Radiative heating rate profiles over the southeast Atlantic Ocean during the 2016 and 2017 biomass burning seasons

Marine boundary layer clouds, including the transition from stratocumulus to cumulus, are poorly represented in numerical weather prediction and general circulation models. Further uncertainties in the cloud structure arise in the presence of biomass burning carbonaceous aerosol, as is the case over the southeast Atlantic Ocean, where biomass burning aerosol is transported from the African continent. As the aerosol plume progresses across the southeast Atlantic Ocean, radiative heating within the aerosol layer has the potential to alter the thermodynamic environment and therefore the cloud structure; however, limited work has been done to quantify this along the trajectory of the aerosol plume in the region. The deployment of the first Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF1) in support of the Layered Atlantic Smoke Interactions with Clouds field campaign provided a unique opportunity to collect observations of cloud and aerosol properties during two consecutive biomass burning seasons during July through October of 2016 and 2017 over Ascension Island (7.96° S, 14.35° W). Using observed profiles of temperature, humidity, and clouds from the field campaign alongside aerosol optical properties from Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), as input for the Rapid Radiation Transfer Model (RRTM), profiles of the radiative heating rate due to aerosols and clouds were computed. Radiative heating is also assessed across the southeast Atlantic Ocean using an ensemble of back trajectories from the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model. Idealized experiments using the RRTM with and without aerosols and a range of values for the single-scattering albedo (SSA) demonstrate that shortwave (SW) heating within the aerosol layer above Ascension Island can locally range between 2 and 8 K d -1 depending on the aerosol optical properties, though impacts of the aerosol can be felt elsewhere in the atmospheric column. When considered under clear conditions, the aerosol has a cooling effect at the TOA, and based on the observed cloud properties at Ascension Island, the cloud albedo is not large enough to overcome this. Shortwave radiative heating due to biomass burning aerosol is not balanced by additional longwave (LW) cooling, and the net radiative impact results in a stabilization of the lower troposphere. However, these results are extremely sensitive to the single-scattering albedo assumptions in models.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1993

Diffusion coefficients of energetic water group ions near Comet Giacobini-Zinner

Data from the ultralow-energy charge analyzer and energetic particle anisotropy spectrometer sensors, acquired when the ICE spacecraft flew past Comet Giacobini-Zinner on September 11, 1985, are combined, and a single, self-consistent analysis technique is applied to derive a single-particle spectrum from about 200 to 1600 km/s. This information, together with the deduced bulk flow speed of the ions, is used to calculate a parallel diffusion coefficient in the transition region downstream of the bow wave (2.3 +/- 0.5) x 10 exp 17 sq cm/s; the corresponding scattering mean free path is (6 +/- 1) x 10 exp 4 km. The parallel diffusion coefficient is found to depend on the collision frequency of water group ions with Alfven waves, which are assumed to be propagating parallel (antiparallel) to the magnetic field.

Tan, L. C.↗

DOE OSTI2022

Design and construction of a quantum matter synthesizer

The quantum matter synthesizer (QMS) is a new quantum simulation platform in which individual particles in a lattice can be resolved and re-arranged into arbitrary patterns. The ability to spatially manipulate ultracold atoms and control their tunneling and interactions at the single-particle level allows full control of a many-body quantum system. We present the design and characterization of the QMS, which integrates into a single ultra-stable apparatus a two-dimensional optical lattice, a moving optical tweezer array formed by a digital micromirror device, and site-resolved atomic imaging. We demonstrate excellent mechanical stability between the lattice and tweezer array with relative fluctuations below 10 nm, diffraction-limited imaging at a resolution of 655 nm, and high-speed real-time control of the tweezer array at a 2.52 kHz refresh rate, which will be adopted to realize fast rearrangement of atoms. The QMS also features new technologies and schemes, such as nanotextured anti-reflective windows and all-optical long-distance transport of atoms.

47 OTHER INSTRUMENTATION↗

DOE OSTI2025

Velocity-space signatures of shock-drift acceleration at quasi-perpendicular collisionless shocks

The shock-drift acceleration of ions at quasi-perpendicular shocks is a well-known kinetic mechanism for the acceleration of a small fraction of incoming ions to high energy. Here, we use a suite of sixteen hybrid simulations of quasi-perpendicular collisionless shocks over the range of Alfvén Mach number 4.3 ≤ M A ≤ 15.8 (corresponding to a range of fast magnetosonic Mach numbers 2.6 ≤ M f ≤ 9.4) and shock-normal angle 45°≤ θ Bn ≤ 90° to identify the velocity-space signature of shock-drift acceleration using the field-particle correlation technique. We show that the features of the ion velocity distribution in the shock foot and ramp regions can be clearly interpreted by analysis of the single-particle trajectory of a reflected ion through the full 3D-3V phase space. The characteristic features of the velocity-space signature of shock-drift acceleration remain qualitatively robust over the full parameter range of our simulations, providing a potential means for its identification using single-point spacecraft measurements. At higher Alfvén Mach numbers M A ≳8 (M f ≳5), kinetic instabilities generate fluctuations of the electromagnetic fields within the shock transition region, leading to fluctuations in and smearing out of the resulting velocity-space signatures, but the signature remains generally robust and identifiable. The results on the shock-drift acceleration of ions presented here represent a novel means to determine more completely the partitioning of upstream bulk flow kinetic energy into plasma heating, particle acceleration, and electromagnetic fields in collisionless shocks.

Howes, Gregory G. [Univ. of Iowa, Iowa City, IA (U↗

DOE OSTI2026

Characterizing microscale signatures in uranium ore concentrates using electron probe microanalyzer

Impurities in uranium ore concentrates (UOCs) serve as forensic signatures of processing history and origin. Here, this study utilizes Electron Probe Microanalyzer (EPMA) to characterize microscale compositional and textural features in individual UOC particles from both commercial and bench-scale production. At the particle scale, multiple internal phases with distinct morphologies, chemical signatures, and stoichiometries are documented. Our data shows that chemical impurities are heterogeneously distributed within single particles and among particles within a sample. These microscale heterogeneities correlate with known processing histories, indicating that microscale signatures of early fuel cycle materials can provide valuable information for nuclear forensic material analysis.

organic↗

DOE OSTI2022

Enhanced Transport of TiO 2 in Unsaturated Sand and Soil after Release from Biodegradable Plastic during Composting

Biodegradable plastics can reach full degradation when disposed of appropriately and thus alleviate plastic pollution caused by conventional plastics. But additives can be released into the environment during degradation, and the fate of these additives can be affected by the degradation process. In this study, we characterized TiO 2 particles released from a biodegradable plastic mulch during composting and studied the transport of the released TiO 2 particles in inert sand and agricultural soil columns under unsaturated flow conditions. TiO 2 microparticles were released from the biodegradable plastic mulch in both single particle and cluster forms. The released TiO 2 microparticles were fully retained in unsaturated soil columns due to its ne texture, slow flow rate, and favorable attachment conditions. But in unsaturated sand columns, the released TiO 2 microparticles were highly mobile. Additionally, comparison with the pristine TiO 2 microparticles revealed that the enhanced mobility of the released TiO 2 microparticles was caused by the presence of compost residues which blocked attachment sites on the sand surface. This study demonstrates that TiO 2 microparticles can be released during composting of biodegradable plastics, and the transport potential of the released TiO 2 microparticles in the terrestrial environment can be enhanced by the presence of compost material.

54 ENVIRONMENTAL SCIENCES↗