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Cryogenic Moisture Uptake in Foam Insulation for Space Launch Vehicles

Rigid polyurethane foams and rigid polyisocyanurate foams (spray-on foam insulation), like those flown on Shuttle, Delta IV, and will be flown on Ares-I and Ares-V, can gain an extraordinary amount of water when under cryogenic conditions for several hours. These foams, when exposed for eight hours to launch pad environments on one side and cryogenic temperature on the other, increase their weight from 35 to 80 percent depending on the duration of weathering or aging. This effect translates into several thousand pounds of additional weight for space vehicles at lift-off. A new cryogenic moisture uptake apparatus was designed to determine the amount of water/ice taken into the specimen under actual-use propellant loading conditions. This experimental study included the measurement of the amount of moisture uptake within different foam materials. Results of testing using both aged specimens and weathered specimens are presented. To better understand cryogenic foam insulation performance, cryogenic moisture testing is shown to be essential. The implications for future launch vehicle thermal protection system design and flight performance are discussed.

Fesmire, James E.↗

Analyzing the Ages of South Polar Craters on the Moon: Implications for the Sources and Evolution of Surface Water Ice

Surface water ice in the permanently shadowed polar regions of the Moon has a patchy surficial distribution and is not found within all available cold-trapping areas. To date it is not well understood when the ice was delivered, which has important implications for the surficial characteristics of the ice as well as for possible delivery mechanisms. Here we present absolute model ages for 20 south polar craters that host surface water ice, providing maximum estimates of the ages of surface ice contained within these craters. We quantify the amount of available cold-trapping surface area that is occupied by water ice in order to examine the relationship between the patchiness of ice within each crater and the age of each host crater. The majority of surface ice is contained in old craters ≥∼3.1 Gyr, where the majority of cold-trapping area on the pole exists. The ice is these ancient craters is very patchy in surficial distribution, occupying <11.5% of cold-trapping surface area available in individual craters. This patchy distribution of ice in old craters is likely to be due to impact bombardment and regolith overturn within the polar regions. Interestingly, surface ice is also located within smaller craters (<15 km in diameter), whose sharp crater rim crest morphologies suggest that they may be relatively young. Ice in fresh-looking craters suggests that ice has been delivered to the lunar surface more recently, perhaps from micrometeorites or through solar wind interactions with the lunar regolith. Finally, we also analyze a group of ancient craters that does not host surface water ice, even though these craters are present-day cold traps. These specific ancient craters would not have been thermally stable for the cold-trapping of water ice before the onset of true polar wander suggested by Siegler et al. (2016). If true polar wander did occur on the Moon, then the ages of ice-bearing craters presented here set an upper limit for the age of post-true polar wander hydrogen emplacement of 4.1 ± 0.1 Gyr.

Deutsch, Ariel N.↗

Evolution of Martian Volcanism and Lithosphere: Geochemical Insights from Noachian to Amazonian Volcanic Terrains

The lithosphere of Mars has played a crucial role in shaping its geological features, influencing volcanic activity, climate shifts, and the planet's early habitability. Understanding the evolution of Mars' litho-sphere through different geological eons has been challenging due to weathering and resurfacing affecting the study of early Noachian volcanic chemistry. Therefore, in our study we have focused on recently discovered Noachian volcanic terranes [1-2], along with Hesperian and Amazonian volcanic terranes [3], to trace the evolution of the Martian lithosphere and thermal flux. The composition of igneous rock formed from the eruption of magma tends to preserve the record of thermal properties viz. pressure, temperature, or degree of partial melting at which it forms. Therefore, Martian volcanic provinces are of great geologic interest; they have been active throughout its history, from Noachian (>3.7 Ga) to the Late Amazonian (<500 Ma) [4]. Earlier studies focused on the evolved magmatism from Hesperian to Amazonian [4], but the type and style of Noachian-aged volcanism remain to be understood. We have investigated the geochemical compositions of Noachian volcanic provinces and compared them with relatively younger volcanic provinces on Mars using remote sensing (Mars Odyssey Gamma Ray and Neutron Spectrometer suite-GRS) and in-situ observations. Furthermore, petrologic modeling is performed to understand magmatic processes and thermal evolution. Our findings reveal distinct Pressure-Temperature (P-T) conditions across different Martian geological eras. In the Noachian terranes, we model P-T conditions ranging from 1.3-1.6 GPa and temperatures between 1350-1390°C. Conversely, the Hesperian volcanic terrane exhibits variations between 1.6-1.7 GPa and temperatures spanning 1370-1395°C. For the Amazonian volcanic terrane, P-T conditions ranged notably higher, from 1.9-2.8 GPa with temperatures between 1380-1415°C. Based on our modeling, we estimated the corresponding litho-spheric thicknesses and depths of melting for each eon. In the Noachian, the lithospheric thickness ranged from 110-135 km. Meanwhile, for the Hesperian terranes, it varied between 120-235 km, and for the Amazonian, it extended from 160-235 km. We also calculated partial melting percentages (F), observing a range of 8-12% for the Noachian, 10-11% for the Hesperian, and 10-12% for the Amazonian. Mantle potential temperatures (Tp) were calculated to illustrate variations across these geological eons. Our estimates of heat flux depicted temporal changes, showing ranges from 51-65 mW/m 2 for the Noachian, 38-45 mW/m 2 for the Hesperian, and 27-39 mW/m 2 for the Amazonian. Our study implies that the lithosphere remained consistently uniform until the Hesperian eon, indicating sustained weaker volcanic systems from mid-Noachian to Hesperian. This contrasts with fewer deep-seated plumes observed in the Amazonian era. These variations suggest potential implications for Martian climatic conditions which show a milder climate prevailed until the Hesperian, differing from Mars' current cold, arid conditions.

Mars↗

Applications of activation analysis to geochemical, meteoritic and lunar studies.

The application of activation analysis techniques to the analysis of cosmological materials, i.e., terrestrial, tektitic, meteoritic, and lunar matter, is reviewed. Elemental determinations can be made by instrumental fast-neutron and thermal-neutron activation analysis, photonuclear and charged-particle activation analysis, and by radiochemical neutron activation analysis. Partition-coefficient methods, autoradiography studies, gamma-gamma coincidence counting, and age determination by neutron activation are discussed. Attention is given to K-Ar and I-Xe dating of meteorites.

Showalter, D. L.↗

Oceanic lithosphere and asthenosphere: The thermal and mechanical structure

A coupled thermal and mechanical solid state model of the oceanic lithosphere and asthenosphere is presented. The model includes vertical conduction of heat with a temperature dependent thermal conductivity, horizontal and vertical advection of heat, viscous dissipation or shear heating, and linear or nonlinear deformation mechanisms with temperature and pressure dependent constitutive relations between shear stress and strain rate. A constant horizontal velocity u sub 0 and temperature t sub 0 at the surface and zero horizontal velocity and constant temperature t sub infinity at great depth are required. In addition to numerical values of the thermal and mechanical properties of the medium, only the values of u sub 0, t sub 0 and t sub infinity are specified. The model determines the depth and age dependent temperature horizontal and vertical velocity, and viscosity structures of the lithosphere and asthenosphere. In particular, ocean floor topography, oceanic heat flow, and lithosphere thickness are deduced as functions of the age of the ocean floor.

Schubert, G.↗

Cosmology of a charged universe

The Proca generalization of electrodynamics admits the possibility that the universe could possess a net electric charge uniformly distributed throughout space, while possessing no electric field. A general-relativistic model of cosmological expansion dominated by such a charged background has been calculated, and is consistent with present observational limits on the Hubble constant, the deceleration parameter, and the age of the universe. However, if this cosmology applied at the present epoch, the very early expansion of the universe would have been too rapid for cosmological nucleosynthesis or thermalization of the background radiation to have occurred. Hence, domination of the present expansion by background charge appears to be incompatible with the 3-K background and big-bang production of light elements. If the present background charge density were sufficiently small (but not strictly zero), expansion from the epoch of nucleosynthesis would proceed according to the conventional scenario, but the energy due to the background charge would have dominated at some earlier epoch. This last possibility leads to equality of pressure and energy density in the primordial universe.

Barnes, A.↗

Oxygen atom reaction with Shuttle materials at orbital altitudes - Data and experiment status

Significant surface characteristics changes have been noticed on materials that were exposed in the payload bay of the Space Shuttle Orbiter on the first four flights. The most notable change was mass loss of Kapton film used as a component of thermal blankets. This film exhibited as much as 35 percent mass loss on STS-3 and loss of material was noticed on all flights. Other changes consist of rapid aging of paints and oxidation of Torlon surfaces. A mechanism has been proposed for the effects described, which involves the interaction of these organic materials with atomic oxygen available at low earth orbital altitudes. Evidence derived from measurements made on Shuttle materials that supports this mechanism will be presented. Experiments planned for near-term Shuttle flights are being developed to obtain quantitative data on reaction rates.

Leger, L.↗

A Suzaku Study of Ejecta Structure and Origin of Hard X-ray Emission in the Supernova Remnant G156.2+5.7

We report an X-ray study of the evolved Galactic supernova remnant (SNR) G1S6.2+S.7 based on six pointing observations with Suzaku. The remnant's large extent (100' in diameter) allows us to investigate its radial structure in the northwestern and eastern directions from the apparent center. The X-ray spectra. were well fit with a two-component non-equilibrium ionization model representing the swept-up interstellar medium (ISM) and the metal-rich ejecta. We found prominent central concentrations of Si, S and Fe from the ejecta component; the lighter elements of O, Ne and Mg were distributed more uniformly. The temperature of the ISM component suggests a slow shock (610-960 km/s), hence the remnant's age is estimated to be 7,000-15,000 yr, assuming its distance to be approx. 1.1 kpc. G1S6.2+5.7 has also been thought to emit hard, non-thermal X-rays, despite being considerably older than any other such remnant. In response to a recent discovery of a background cluster of galaxies (2XMM J045637.2+522411), we carefully excluded its contribution, and reexamined the origin of the hard X-ray emission. We found that the residual hard X-ray emission is consistent with the expected level of the cosmic X-ray background. Thus, no robust evidence for the non-thermal emission was obtained from G156.2+5.7. These results are consistent with the picture of an evolved SNR.

Uchida, Hiroyuki↗

Thermal Cycling Fatigue in DIPs Mounted with Eutectic Tin-Lead Solder Joints in Stub and Gullwing Geometries

It has long been known that solder joints under mechanical stress are subject to failure. In early electronic systems, such failures were avoided primarily by avoiding the use of solder as a mechanical structural component. The rule was first to make sound wire connections that did not depend mechanically on solder, and only then to solder them. Careful design and miniaturization in modern electronic systems limits the mechanical stresses exerted on solder joints to values less than their yield points, and these joints have become integral parts of the mechanical structures. Unfortunately, while these joints are strong enough when new, they have proven vulnerable to fatigue failures as they age. Details of the fatigue process are poorly understood, making predictions of expected lifetimes difficult.

fatigue failure solder joints failure mechanisms s↗

Thermomechanical deformation testing and modeling in the presence of metallurgical instabilities

A number of viscoplastic constitutive models were developed to describe deformation behavior under complex combinations of thermal and mechanical loading. Questions remain, however, regarding the validity of procedures used to characterize these models for specific structural alloys. One area of concern is that the majority of experimental data available for this purpose are determined under isothermal conditions. This experimental study is aimed at determining whether viscoplastic constitutive theories characterized using an isothermal data base can adequately model material response under the complex thermomechanical loading conditions typical of power generation service. The approach adopted was to conduct a series of carefully controlled thermomechanical experiments on a nickel-based superalloy, Hastelloy Alloy X. Previous investigations had shown that this material experiences metallurgical instabilities leading to complex hardening behavior, termed dynamic strain aging. Investigating this phenomenon under full thermomechanical conditions leads to a number of challenging experimental difficulties which up to the present work were unresolved. To correct this situation, a number of advances were made in thermomechanical testing techniques. Advanced methods for dynamic temperature gradient control, phasing control and thermal strain compensation were developed and incorporated into real time test control software. These advances allowed the thermomechanical data to be analyzed with minimal experimental uncertainty. The thermomechanical results were evaluated on both a phenomenological and microstructural basis. Phenomenological results revealed that the thermomechanical hardening trends were not bounded by those displayed under isothermal conditions. For the case of Hastelloy Alloy X (and similar dynamic strain aging materials), this strongly suggests that some form of thermomechanical testing is necessary when characterizing a thermoviscoplastic deformation model. Transmission electron microscopy was used to study the microstructural physics, and analyze the unique phenomenological behavior.

Castelli, Michael G.↗

Thermal treatment and mechanical properties of aluminum-2021

Mechanical properties, after thermal treatments, are summarized for sheet and plate of copper-rich, high-strength, heat-treatable aluminum-2021. The alloy is quench sensitive, quench rate and variations in aging affect corrosion behavior. Aging effects on yield strength, tensile strength, and elongation of sheet and plate are compared.

Brennecke, M. W.↗

Transient liquid phase diffusion bonding of Udimet 720 for Stirling power converter applications

Udimet 720 has been selected for use on Stirling power converters for space applications. Because Udimet 720 is generally considered susceptible to strain age cracking if traditional fusion welding is used, other joining methods are being considered. A process for transient liquid phase diffusion bonding of Udimet 720 has been theoretically developed in an effort to eliminate the strain age crack concern. This development has taken into account such variables as final grain size, joint homogenization, joint efficiency related to bonding aid material, bonding aid material application method, and thermal cycle.

Mittendorf, Donald L.↗

Proposed Mars Surveyor Landing Sites in Northern Meridiani Sinus, Southern Elysium Planitia, and Argyre Planitia

Our objective is to propose two landing sites that the Mars Surveyor 2001 Lander and Athena Rover could go to on Mars that should meet the safety requirements of the spacecraft landing system and optimize surface operations (chiefly driven by power and communications requirements). An additional site within Argyre Planitia, initially proposed by Parker to the Mars Surveyor Landing Site program, is also proposed for potential consideration for post-2001 missions to Mars, as it is well outside the current latitude limits for the Athena Rover. All three sites are designed to be situated as close to a diversity of geologic units within a few kilometers of the landing site so that diversity can be placed in a geologic context. This objective is very different from the Mars Pathfinder requirement to land at a site with a maximum chance for containing a diversity of rocks within a few tens of meters of the lander. That requirement was driven by the Sojourner mobility limit of a few tens of meters. It can be argued that the Athena project, with its much larger mobility capability, might actually want to avoid such a site, because placing collected samples in geologic context would be difficult. While it has been argued, both before and after the Mars Pathfinder landing, that the provenance for local blocks may be determined by orbiter spectra, primarily from the MGS TES instrument, our ability to do so has yet to be demonstrated. Indeed, several months after conclusion of the Pathfinder mission, we have yet to reach a consensus on the composition of local materials. Our primary data set for selecting a landing site within the latitude and elevation constraints of the 2001 mission is the Viking Orbiter image archive. The site must be selected to place the landing ellipse so as to avoid obvious hazards, such as steep slopes, large or numerous craters, or abundant large knobs. For this purpose, we chose a resolution limit of better than 50 m/pixel. This necessarily excludes from the present study images from current and future orbiter spacecraft, until such data does become readily available. Within each proposed region, it may be possible to identify additional sites once these data become available. Second, the fine-component thermal inertia data, should be greater than about 5 or 6 cgs Units (10(exp -3) cal/sq cm s(exp -0.5)/K). Low thermal inertias imply dusty environments, which could pose a mobility hazard. Similarly, the albedo of the site should not be particularly high, which would also suggest dusty surfaces. Low albedos are preferred, as they often coincide with low Viking red:violet ratios and indicate less dusty surfaces. Next, the Modeled Block Abundance should also not be too high or too low. Based on the Viking Lander and Mars Pathfinder experiences, percentages of blocks should be on the order of 5-25%. Too many blocks could pose a hazard to the landing and mobility. Too few blocks could also indicate a dusty surface. Primary Landing Site: Northern Meridiani Sinus (Proposed by T. J. Parker and K., S. Edgett) Vital Statistics: (1) Latitude, Longitude: 0-3 N, 350-2 W. *Elevation (Viking): about0.5-1.5 Ian. (2) Viking Orbiter Image coverage: Excellent coverage by 15 - 25 m/pixel images (orbits 709A and 410B). Possible stereo coverage in region where two orbits overlap (probably small parallax angle, as these orbits are not listed in NASA Contractor Report 3501) (3) Albedo: about .18 -.26 (4) Block Abundance: 5-26% (5)Fine-Component Thermal Inertia: 5-9 cgs units This region consists of bright deposits similar to those described by Edgett et al, that also lie within a prominent dark albedo region. These deposits are flat-lying, to such a degree that they ramp against topography rather than draping over it. This led Edgett and Parker to suggest that they may be subaqueous sediments, possibly lacustrine or marine evaporites, laid down sometime from the late Noachian to middle Hesperian (age determination pending crater counts). A contact between this material and elevated, dissected highlands to the south was identified , and is described by Edgett et al. Our desire in proposing this landing site is to sample the edge of this deposit where it has been exposed through etching, presumably eolian deflation (the deposit, though in the highlands, is itself only lightly to moderately cratered). This should enable access to in situ stratigraphy. The actual landing site will be selected where slopes are not expected to be steep, such that the rover itself should be able to traverse them and sample layered materials on the way, either up or down the slope. Perhaps due to uncertainties at this time as to the friability or meter-scale roughness of the deposit, it might make sense to place the landing ellipse on the exhumed highland surface adjacent to the deflated margin of the deposit and plan on driving to the deposit rather than landing on it and driving downslope. This should also enable imaging the margin for evidence of layering should it prove too difficult to climb. A target ellipse on the highland surface should also allow Athena access to ancient Noachian highland materials, particularly if placed near crater ejecta or an inlier of knobby material. Secondary Landing Site: Southern Elysium Planitia (Proposed by T. J. Parker) Vital Statistics: (1) Latitude, Longitude: 1.5-3.5 S, 195-198 W. (2) Elevation (Viking): -1.0 km. (3) Viking Orbiter Image coverage: Excellent coverage by 15 - 25 m/pixel images (orbit 725). Possible stereo coverage between images from beginning and end of orbit that overlap (probably small parallax angle) (4) Albedo: about .27-.28 (5) Block Abundance: 4-7% (6) Fine-Component Thermal Inertia: about 3 cgs units This region consists of eroded knobby material, probably of Noachian age, though much of the crater population has been destroyed, that is onlapped at a sharp contact by an extensive plains unit in southern Elysium Planitia that is Amazonian in age. The plains materials have been attributed to unusually low-viscosity flood lavas from fissures south of the Elysium volcanic rise, or to lacustrine materials associated with a large, Amazonian lake at the source of Marte Vallis. Parker and Schenk presented evidence in support of the latter interpretation, though they attributed the putative shore morphology to an embayment of a northern plains ocean into the southern Elysium region. Detailed examination of the margin of the deposit, showing erosion, not simply burial, of small crater rims and fluidized ejecta blankets, also points to lacustrine or marine sedimentation rather than volcanic plains burial. The plains surface exhibits a "crusty" appearance that many researchers have attributed to pressure ridges in lava flows. In a lacustrine context, they also resemble pressure ridges in desiccated evaporite deposits and salt-rimmed pools (now dry) similar in scale and morphology to spectacular, hundred meter-scale pool rims in alkaline Lake Natron, East African Rift. The eroded highland margin surface adjacent to these plains appears to be fairly smooth, even at 15 m/pixel. Isolated knob inliers are scattered from a few kilometers to several tens of "kilometers apart. Heights of the knobs have not been measured yet but, based on experience with similar features in the Pathfinder landing ellipse, are probably typically on the order of several tens of meters high and smaller, though some of the largest knobs in the region are probably up to a few hundred meters high. Two craters larger than a kilometer in diameter, with fluidized deposits, lie nearby the proposed landing site. Very high-resolution images from MOC should help to determine whether a landing site navigable by the Athena rover could be placed in this region. The space between knobs and craters is large enough to enable placement of a target landing ellipse between them but still provide access to one or more of them and to the margin of the Elysium plains material. Post-2001 Mars Surveyor Landing Site: Argyre Planitia (Proposed by T. J. Parker) Vital Statistics: (1) Latitude, Longitude: 55-56 S, 41-43 W. (2) Elevation (Viking): 1.0 km. (3) Viking Orbiter Image coverage: Excellent coverage by 40 m/pixel images (orbits 567B, 568B, and 569B). Excellent stereo coverage with large parallax angles over the entire landing site region, and much of central and southern Argyre. (4) Albedo: about .23-.24 (5) Block Abundance: No data (6) Fine-Component Thermal Inertia: No data The floors of both the Argyre and Hellas basins contain etched layered materials that are probably thick accumulations of channel or lacustrine sediments. The deposits in Hellas are much more eroded than those in Argyre, and Hellas lacks a channel outlet. Argyre is unique in that Uzboi Vallis flowed out of the basin, requiring overflow of a standing body of water within Argyre. This makes it the largest impact basin on Mars with channels both draining into it and flowing out from it. Hellas' channels may be catastrophic flood channels, whereas Argyre was fed by modest-scale valley networks, though the outlet at Uzboi Vallis was a catastrophic flood Highland craters and basins of this kind should be high-priority landing targets for missions intended to focus on the search for either prebiotic organic materials or even simple fossil microorganisms. Basins with internally-draining valley networks should be preferred over flood channels, as they could have provided the long-term influx of water favorable to the origin of life. (Catastrophic floods are not conducive to fossil preservation, due to their very short durations and high transportation energies). They also afford an opportunity to study the evolution of the planet's climate and volatiles during the period of time between the late Noachian and early Hesperian, when a drastic change from a proposed early warm, wet climate to one more closely resembling the modern environment is thought to have occurred. Large basin

Parker, T. J.↗

Long-Term Durability of a Matrix for High-Temperature Composites Predicted

Polymer matrix composites (PMC's) are being increasingly used in applications where they are exposed for long durations to harsh environments such as elevated temperatures, moisture, oils and solvents, and thermal cycling. The exposure to these environments leads to the degradation of structures made from these materials. This also affects the useful lifetimes of these structures. Some of the more prominent aerospace applications of polymer matrix composites include engine supports and cowlings, reusable launch vehicle parts, radomes, thrust-vectoring flaps, and the thermal insulation of rocket motors. This demand has led to efforts to develop lightweight, high-strength, high-modulus materials that have upper-use temperatures over 316 C. A cooperative program involving two grants to the Massachusetts Institute of Technology and in-house work at the NASA Glenn Research Center was conducted to identify the mechanisms and the measurement of mechanical and physical properties that are necessary to formulate a mechanism-based model for predicting the lifetime of high-temperature polymer matrix composites. The polymer that was studied was PMR-15 polyimide, a leading matrix resin for use in high-temperature-resistant aerospace composite structures such as propulsion systems. The temperature range that was studied was from 125 to 316 C. The diffusion behavior of PMR-15 neat resin was characterized and modeled. Thermogravimetric analysis (TGA) was also conducted in nitrogen, oxygen, and air to provide quantitative information on thermal and oxidative degradation reactions. A new low-cost technique was developed to collect chemical degradation data for isothermal tests lasting up to 4000 hr in duration. In the temperature range studied, results indicate complex behavior that was not observed by previous TGA tests, including the presence of weight-gain reactions. These were found to be significant in the initial periods of aging from 125 to 225 C. Two types of weight loss reactions dominated at aging temperatures above 225 C. One was concentrated at the surface of the polymer and was very active at temperatures above 225 C. The second was observed to dominate in the latter stages of aging at temperatures below 260 C. This three-reaction model satisfactorily explains past findings that the degradation mechanism of PMR-15 appears to change around 316 C. It also indicates that the second weight gain mechanism is a significant factor at temperatures below 204 C. On the basis of these results, a predictive model was developed for the thermal degradation of PMR-15 at 316 C. A comparison of data generated by this model with actual experimental data is shown in the following figure.

Bowles, Kenneth J.↗

Ganymede - A relationship between thermal history and crater statistics

An approach for factoring the effects of a planetary thermal history into a predicted set of crater statistics for an icy satellite is developed and forms the basis for subsequent data inversion studies. The key parameter is a thermal evolution-dependent critical time for which craters of a particular size forming earlier do not contribute to present-day statistics. An example is given for the satellite Ganymede and the effect of the thermal history is easily seen in the resulting predicted crater statistics. A preliminary comparison with the data, subject to the uncertainties in ice rheology and impact flux history, suggests a surface age of 3.8 x 10 to the 9th years and a radionuclide abundance of 0.3 times the chondritic value.

Phillips, R. J.↗

Contact integrity testing of stress-tested silicon terrestrial solar cells

A test procedure was developed and applied to terrestrial silicon solar cells in order to determine the effect of accelerated environmental and time-temperature aging on metal contact integrity. Quantities of cells of four different manufacturers were given the contact integrity test after being subjected to accelerated stress tests that included forward bias-temperature, thermal cycle and thermal shock, power cycle, and bias-temperature humidity tests at two temperature-humidity levels. Significant effects due to certain stress tests were found for some cell types. It is concluded that cells fabricated using plated nickel/solder metallization showed significantly more serious contact integrity degradation than silver-metallized cells.

Prince, J. L.↗

The hemispherical asymmetry of the residual polar caps on Mars

A model of the polar caps of Mars was created which allows: (1) for light penetration into the cap; (2) ice albedo to vary with age, latitude, hemisphere, dust content, and solar zenith angle; and (3) for diurnal variability. The model includes the radiative effects of clouds and dust, and heat transport as represented by a thermal wind. The model reproduces polar cap regression data very well, including the survival of CO2 frost at the south pole and reproduces the general trend in the Viking Lander pressure data.

Lindner, Bernhard Lee↗

Asteroids and Archaean crustal evolution: Tests of possible genetic links between major mantle/crust melting events and clustered extraterrestrial bombardments

Since the oldest intact terrestrial rocks of ca. 4.0 Ga and oldest zircon xenocrysts of ca. 4.3 Ga measured to date overlap with the lunar late heavy bombardment, the early Precambrian record requires close reexamination vis a vis the effects of megaimpacts. The identification of microtektite-bearing horizons containing spinals of chondritic chemistry and Ir anomalies in 3.5-3.4-Ga greenstone belts provides the first direct evidence for large-scale Archaean impacts. The Archaean crustal record contains evidence for several major greenstone-granite-forming episodes where deep upwelling and adiabatic fusion of the mantle was accompanied by contemporaneous crustal anatexis. Isotopic age studies suggest evidence for principal age clusters about 3.5, 3.0, and 2.7 (+/- 0.8) Ga, relics of a ca. 3.8-Ga event, and several less well defined episodes. These peak events were accompanied and followed by protracted thermal fluctuations in intracrustal high-grade metamorphic zones. Interpretations of these events in terms of internal dynamics of the Earth are difficult to reconcile with the thermal behavior of silicate rheologies in a continuously convecting mantle regime. A triggering of these episodes by mantle rebound response to intermittent extraterrestrial asteroid impacts is supported by (1) identification of major Archaean impacts from microtektite and distal ejecta horizons marked by Ir anomalies; (2) geochemical and experimental evidence for mantle upwelling, possibly from levels as deep as the transition zone; and (3) catastrophic adiabatic melting required to generate peridotitic komatites. Episodic differentiation/accretion growth of sial consequent on these events is capable of resolving the volume problem that arises from comparisons between modern continental crust and the estimated sial produced by continuous two-stage mantle melting processes. The volume problem is exacerbated by projected high accretion rates under Archaean geotherms. It is suggested that impact shock effects have been largely obscured by (1) outpouring of voluminous basic/ultrabasic lavas, inundating shock-deformed crust and extending beyond the perimeters of impact excavated basins; (2) gravity subsidence and downfaulting of terrestrial maria, accounting for the burial and anatexis of subgreenstone basement; and (3) extensive shearing and recrystallization at elevated temperatures of impact structure, breccias, and mineral deformation features beneath impact-excavated basins, relics of which may be retained in structural windows in high-grade metamorphic terranes.

Glikson, A. Y.↗